JP5480147B2 - 担持非メタロセン触媒およびその製造方法 - Google Patents
担持非メタロセン触媒およびその製造方法 Download PDFInfo
- Publication number
- JP5480147B2 JP5480147B2 JP2010529214A JP2010529214A JP5480147B2 JP 5480147 B2 JP5480147 B2 JP 5480147B2 JP 2010529214 A JP2010529214 A JP 2010529214A JP 2010529214 A JP2010529214 A JP 2010529214A JP 5480147 B2 JP5480147 B2 JP 5480147B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- nonmetallocene
- magnesium compound
- magnesium
- porous support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 0 CC(C)(C)c(cc1C(C)(C)C)cc(C=C[C@@]2C=CC=CC2*=I=C)c1O Chemical compound CC(C)(C)c(cc1C(C)(C)C)cc(C=C[C@@]2C=CC=CC2*=I=C)c1O 0.000 description 11
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710162672.2 | 2007-10-16 | ||
| CN200710162675.6 | 2007-10-16 | ||
| CN2007101626756A CN101412767B (zh) | 2007-10-16 | 2007-10-16 | 一种负载型非茂金属催化剂及其制备方法 |
| CN 200710162672 CN101412764A (zh) | 2007-10-16 | 2007-10-16 | 一种负载型非茂金属催化剂及其制备方法 |
| CN200710162677.5A CN101412769B (zh) | 2007-10-16 | 2007-10-16 | 一种负载型非茂金属催化剂及其制备方法 |
| CN200710162677.5 | 2007-10-16 | ||
| PCT/CN2008/001738 WO2009052700A1 (en) | 2007-10-16 | 2008-10-15 | Supported non-metallocene catalyst and its preparation method |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011500900A JP2011500900A (ja) | 2011-01-06 |
| JP2011500900A5 JP2011500900A5 (https=) | 2011-03-10 |
| JP5480147B2 true JP5480147B2 (ja) | 2014-04-23 |
Family
ID=40579059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010529214A Active JP5480147B2 (ja) | 2007-10-16 | 2008-10-15 | 担持非メタロセン触媒およびその製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8193288B2 (https=) |
| EP (1) | EP2202247B1 (https=) |
| JP (1) | JP5480147B2 (https=) |
| KR (1) | KR101207294B1 (https=) |
| WO (1) | WO2009052700A1 (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2202247B1 (en) | 2007-10-16 | 2012-12-12 | Sinopec Yangzi Petrochemical Company Ltd. | Supported non-metallocene catalyst and its preparation method |
| JP5480148B2 (ja) * | 2007-10-16 | 2014-04-23 | 中国石化揚子石油化工有限公司 | マグネシウム化合物担持非メタロセン触媒およびその製造 |
| WO2011050566A1 (zh) * | 2009-10-26 | 2011-05-05 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| JP5670460B2 (ja) * | 2009-10-26 | 2015-02-18 | 中国石油化工股▲ふん▼有限公司 | 担持型非メタロセン触媒、その製造方法およびその使用 |
| EP2500365B1 (en) * | 2009-11-13 | 2020-05-06 | China Petroleum & Chemical Corporation | Supported non-metallocene catalyst and preparation method and uses thereof |
| WO2011057468A1 (zh) * | 2009-11-13 | 2011-05-19 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| EP2610271B1 (en) * | 2011-12-30 | 2019-03-20 | Borealis AG | Preparation of phthalate free ZN PP catalysts |
| CN103304694B (zh) * | 2012-03-06 | 2016-02-24 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| US10221264B2 (en) * | 2012-04-27 | 2019-03-05 | W. R. Grace & Co.-Conn. | Activator compositions, their preparation, and their use in catalysts |
| EP2900702B1 (en) * | 2012-09-30 | 2018-05-02 | Bridgestone Corporation | Polymerization method employing an organometallic catalyst complex |
| SG2014001325A (en) * | 2013-05-21 | 2014-12-30 | China Petroleum & Chemical | A supported nonmetallocene catalyst, preparation and use thereof |
| SG11201608923UA (en) * | 2014-04-24 | 2016-11-29 | China Petroleum & Chem Corp | Catalyst component for propylene polymerization, preparation method therefor and catalyst having same |
| JP6898107B2 (ja) * | 2017-02-15 | 2021-07-07 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造方法 |
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| US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| CA1268754A (en) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| CN1053673A (zh) | 1989-07-12 | 1991-08-07 | 雷晓磊 | 改传统击发为电击发的枪枝及其子弹 |
| IT1237812B (it) * | 1989-12-22 | 1993-06-17 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| CA2032543A1 (en) | 1989-12-26 | 1991-06-27 | Robert Olds Hagerty | Dimethylaluminum chloride-activated olefin polymerisation catalyst composition |
| IT1245249B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| BE1007148A3 (fr) | 1993-05-17 | 1995-04-11 | Solvay | Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur. |
| IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| DE59503827D1 (de) | 1994-06-03 | 1998-11-12 | Pcd Polymere Ag | Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen |
| FR2725993B1 (fr) | 1994-10-21 | 1996-11-29 | Atochem Elf Sa | Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence |
| CN1049439C (zh) | 1996-08-26 | 2000-02-16 | 中国石油化工总公司 | 负载型金属茂催化剂、其制备及应用 |
| CN1060179C (zh) | 1998-05-08 | 2001-01-03 | 中国石油化工集团公司 | 一种负载型茂金属催化剂的制备方法 |
| FI981148A7 (fi) | 1998-05-25 | 1999-11-26 | Borealis As | Uusia aktivaattorijärjestelmä metalloseeniyhdisteitä varten |
| CN1363537A (zh) | 2001-01-08 | 2002-08-14 | 柳忠奇 | 复合硼镁肥及其制备工艺 |
| CN1136239C (zh) | 2001-01-18 | 2004-01-28 | 中国石油化工股份有限公司 | 卤化镁/二氧化硅负载的半茂金属催化剂及其制备与应用 |
| EP1229055A1 (en) | 2001-02-06 | 2002-08-07 | BP Chemicals S.N.C. | Process for the gas-phase (co)-polymerisation of olefins in a fluidised bed reactor |
| EP1426385B1 (en) | 2001-07-23 | 2012-08-22 | Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences | Catalyst for polymerization or copolymerization of olefins, preparation and use of the same |
| CN1137909C (zh) | 2001-10-26 | 2004-02-11 | 中国科学院长春应用化学研究所 | 插层型负载茂金属催化剂及其催化烯烃聚合 |
| AU2002365867A1 (en) | 2001-11-30 | 2003-06-17 | Exxonmobil Chemical Patents Inc. | Method of making mixed ziegler-natta/metallocene catalysts |
| CN1691979A (zh) | 2001-11-30 | 2005-11-02 | 埃克森美孚化学专利公司 | 具有高活性的双金属催化剂 |
| KR100491627B1 (ko) | 2002-12-31 | 2005-05-27 | 삼성토탈 주식회사 | 카르보디이미드계열 리간드에 의해 킬레이트 결합된촉매를 이용한 에틸렌 중합 및 공중합방법 |
| US20080116179A1 (en) * | 2003-04-11 | 2008-05-22 | Hypertherm, Inc. | Method and apparatus for alignment of components of a plasma arc torch |
| CN1281634C (zh) | 2003-10-29 | 2006-10-25 | 扬子石油化工股份有限公司 | 复合载体负载的非茂金属催化剂的负载化方法和聚合应用 |
| CN1269852C (zh) | 2003-10-29 | 2006-08-16 | 扬子石油化工股份有限公司 | 负载型非茂金属催化剂的负载化方法和聚合应用 |
| US7348383B2 (en) | 2003-11-20 | 2008-03-25 | Union Carbide Chemicals And Plastics Technology Corporation | Spray-dried, mixed metal ziegler catalyst compositions |
| CN1789291A (zh) | 2004-12-17 | 2006-06-21 | 扬子石油化工股份有限公司 | 负载型非茂金属催化剂的烯烃聚合和共聚合方法 |
| KR101075404B1 (ko) * | 2004-12-17 | 2011-10-24 | 양지 페트로케미컬 컴퍼니 코., 리미티드. | 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도 |
| CN100362024C (zh) | 2004-12-17 | 2008-01-16 | 扬子石油化工股份有限公司 | 非茂金属催化剂的高活性负载化方法 |
| CN1789292A (zh) | 2004-12-17 | 2006-06-21 | 扬子石油化工股份有限公司 | 负载型非茂金属催化剂在淤浆法乙烯聚合工艺中的应用方法 |
| CN100569808C (zh) | 2005-03-31 | 2009-12-16 | 中国石油化工股份有限公司 | 一种负载型非茂金属催化剂及其制备方法 |
| CN100460423C (zh) | 2005-06-30 | 2009-02-11 | 中国石油化工股份有限公司 | 原位合成的负载型钒系非茂聚烯烃催化剂及制备与应用 |
| CN1962702B (zh) | 2005-11-10 | 2010-10-27 | 中国石化扬子石油化工有限公司 | 一种负载型非茂金属烯烃聚合催化剂、其制备方法及其应用 |
| JP4996779B2 (ja) * | 2006-02-22 | 2012-08-08 | 日本ポリプロ株式会社 | オレフィン重合用触媒成分、及び当触媒成分の製造法、並びに当触媒成分を用いた重合触媒によるオレフィン重合体の製造方法 |
| CN100569734C (zh) | 2006-05-22 | 2009-12-16 | 中国科学院上海有机化学研究所 | 一类含杂原子的有机化合物及其在齐格勒-纳塔催化剂中的应用 |
| CN100482697C (zh) | 2006-05-22 | 2009-04-29 | 中国科学院上海有机化学研究所 | 一类单活性中心齐格勒-纳塔烯烃聚合催化剂 |
| JP5201907B2 (ja) * | 2007-08-07 | 2013-06-05 | 日本ポリエチレン株式会社 | オレフィン重合用触媒の製造方法、およびその方法により得られるオレフィン重合用触媒、並びにその触媒を用いたオレフィン重合体の製造方法 |
| EP2202247B1 (en) | 2007-10-16 | 2012-12-12 | Sinopec Yangzi Petrochemical Company Ltd. | Supported non-metallocene catalyst and its preparation method |
| JP5480148B2 (ja) * | 2007-10-16 | 2014-04-23 | 中国石化揚子石油化工有限公司 | マグネシウム化合物担持非メタロセン触媒およびその製造 |
-
2008
- 2008-10-15 EP EP08842385A patent/EP2202247B1/en active Active
- 2008-10-15 JP JP2010529214A patent/JP5480147B2/ja active Active
- 2008-10-15 WO PCT/CN2008/001738 patent/WO2009052700A1/zh not_active Ceased
- 2008-10-15 US US12/669,394 patent/US8193288B2/en active Active
- 2008-10-15 KR KR1020097023956A patent/KR101207294B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2202247B1 (en) | 2012-12-12 |
| JP2011500900A (ja) | 2011-01-06 |
| EP2202247A4 (en) | 2011-11-30 |
| EP2202247A1 (en) | 2010-06-30 |
| WO2009052700A1 (en) | 2009-04-30 |
| US8193288B2 (en) | 2012-06-05 |
| KR20100101049A (ko) | 2010-09-16 |
| KR101207294B1 (ko) | 2012-12-03 |
| US20110152486A1 (en) | 2011-06-23 |
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