JP5405488B2 - 酵素及び布地色調剤を含む組成物 - Google Patents
酵素及び布地色調剤を含む組成物 Download PDFInfo
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- JP5405488B2 JP5405488B2 JP2010541121A JP2010541121A JP5405488B2 JP 5405488 B2 JP5405488 B2 JP 5405488B2 JP 2010541121 A JP2010541121 A JP 2010541121A JP 2010541121 A JP2010541121 A JP 2010541121A JP 5405488 B2 JP5405488 B2 JP 5405488B2
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- POELEEGOWIJNBI-UHFFFAOYSA-N 3-[2-[[4-(diethylamino)phenyl]diazenyl]-6-ethoxy-1,3-benzothiazol-3-ium-3-yl]propanamide;chloride Chemical compound [Cl-].S1C2=CC(OCC)=CC=C2[N+](CCC(N)=O)=C1N=NC1=CC=C(N(CC)CC)C=C1 POELEEGOWIJNBI-UHFFFAOYSA-N 0.000 claims description 3
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- YDGHROMBRLEXLZ-UHFFFAOYSA-L disodium 3-hydroxy-4-[(4-phenyldiazenylphenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].Oc1c(cc2cc(ccc2c1N=Nc1ccc(cc1)N=Nc1ccccc1)S([O-])(=O)=O)S([O-])(=O)=O YDGHROMBRLEXLZ-UHFFFAOYSA-L 0.000 claims description 3
- QCWPZYSLMIXIHM-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(3-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].Nc1c(N=Nc2cccc(c2)[N+]([O-])=O)c(cc2cc(c(N=Nc3ccccc3)c(O)c12)S([O-])(=O)=O)S([O-])(=O)=O QCWPZYSLMIXIHM-UHFFFAOYSA-L 0.000 claims description 3
- LARMRMCFZNGNNX-UHFFFAOYSA-L disodium 7-anilino-3-[[4-[(2,4-dimethyl-6-sulfonatophenyl)diazenyl]-2-methoxy-5-methylphenyl]diazenyl]-4-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].COc1cc(N=Nc2c(C)cc(C)cc2S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O LARMRMCFZNGNNX-UHFFFAOYSA-L 0.000 claims description 3
- WSALIDVQXCHFEG-UHFFFAOYSA-L disodium;4,8-diamino-1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulfonate Chemical compound [Na+].[Na+].O=C1C2=C(N)C=C(S([O-])(=O)=O)C(O)=C2C(=O)C2=C1C(O)=C(S([O-])(=O)=O)C=C2N WSALIDVQXCHFEG-UHFFFAOYSA-L 0.000 claims description 3
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- SYGRIMFNUFCHJC-UHFFFAOYSA-N hydron;4-methyl-6-phenyldiazenylbenzene-1,3-diamine;chloride Chemical compound Cl.C1=C(N)C(C)=CC(N=NC=2C=CC=CC=2)=C1N SYGRIMFNUFCHJC-UHFFFAOYSA-N 0.000 claims description 3
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 claims description 3
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 3
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 claims description 3
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 claims description 3
- FJBHGWADYLMEJG-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 FJBHGWADYLMEJG-UHFFFAOYSA-M 0.000 claims description 3
- QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 claims description 3
- JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 claims description 3
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 3
- PEAGNRWWSMMRPZ-UHFFFAOYSA-L woodstain scarlet Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 PEAGNRWWSMMRPZ-UHFFFAOYSA-L 0.000 claims description 3
- IVFRHOQHKQWEHJ-UHFFFAOYSA-N 1-amino-4-[4-[(dimethylamino)methyl]anilino]anthracene-9,10-dione Chemical compound C1=CC(CN(C)C)=CC=C1NC1=CC=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O IVFRHOQHKQWEHJ-UHFFFAOYSA-N 0.000 claims description 2
- UWOFGIXNNCPENM-UHFFFAOYSA-N 3,3-difluoropentan-2-one Chemical compound CCC(F)(F)C(C)=O UWOFGIXNNCPENM-UHFFFAOYSA-N 0.000 claims description 2
- BDFZFGDTHFGWRQ-UHFFFAOYSA-N basic brown 1 Chemical compound NC1=CC(N)=CC=C1N=NC1=CC=CC(N=NC=2C(=CC(N)=CC=2)N)=C1 BDFZFGDTHFGWRQ-UHFFFAOYSA-N 0.000 claims description 2
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- FTGXCLZZPPMCHU-UHFFFAOYSA-F dicopper;tetrasodium;3-oxido-4-[[2-oxido-4-[3-oxido-4-[(2-oxido-3,6-disulfonatonaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].[Cu+2].[O-]S(=O)(=O)C1=CC=C2C(N=NC3=CC=C(C=C3[O-])C=3C=C(C(=CC=3)N=NC=3C4=CC=C(C=C4C=C(C=3[O-])S([O-])(=O)=O)S([O-])(=O)=O)[O-])=C([O-])C(S([O-])(=O)=O)=CC2=C1 FTGXCLZZPPMCHU-UHFFFAOYSA-F 0.000 claims description 2
- LHRXTFDXJQAGAV-UHFFFAOYSA-L disodium 3-hydroxy-4-(naphthalen-1-yldiazenyl)naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].Oc1c(cc2cc(ccc2c1N=Nc1cccc2ccccc12)S([O-])(=O)=O)S([O-])(=O)=O LHRXTFDXJQAGAV-UHFFFAOYSA-L 0.000 claims description 2
- UHXQPQCJDDSMCB-UHFFFAOYSA-L disodium;3-[[9,10-dioxo-4-(2,4,6-trimethyl-3-sulfonatoanilino)anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=C(C)C=C(C)C(S([O-])(=O)=O)=C1C UHXQPQCJDDSMCB-UHFFFAOYSA-L 0.000 claims description 2
- XPRMZBUQQMPKCR-UHFFFAOYSA-L disodium;8-anilino-5-[[4-[(3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C3=CC=CC=C3C(N=NC=3C4=CC=CC(=C4C(NC=4C=CC=CC=4)=CC=3)S([O-])(=O)=O)=CC=2)=C1 XPRMZBUQQMPKCR-UHFFFAOYSA-L 0.000 claims description 2
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- AXMCIYLNKNGNOT-UHFFFAOYSA-M sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfonatophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-M 0.000 claims description 2
- IXNUVCLIRYUKFB-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)-2-methylphenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].CC1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 IXNUVCLIRYUKFB-UHFFFAOYSA-M 0.000 claims description 2
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- CXOMTHVASMLVLX-UHFFFAOYSA-N naphtho[2,3-f]quinazoline-1-carboxamide Chemical compound C1=CC=CC2=CC3=C4C(C(=O)N)=NC=NC4=CC=C3C=C21 CXOMTHVASMLVLX-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- KUIXZSYWBHSYCN-UHFFFAOYSA-L remazol brilliant blue r Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=C2C(=O)C3=CC=CC=C3C(=O)C2=C1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 KUIXZSYWBHSYCN-UHFFFAOYSA-L 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 150000003573 thiols Chemical group 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- YKSGNOMLAIJTLT-UHFFFAOYSA-N violanthrone Chemical compound C12=C3C4=CC=C2C2=CC=CC=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC=CC=C3C3=CC=C4C1=C32 YKSGNOMLAIJTLT-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
この洗濯洗剤組成物は典型的に、約0.00003重量%〜約0.1重量%、約0.00008重量%〜約0.05重量%、又は更には約0.0001重量%〜約0.04重量%の布地色調剤と、約0.0005重量%〜約0.1重量%、約0.001重量%〜約0.05重量%、又は更には約0.002重量%〜約0.03重量%のグリコシル加水分解酵素を含む。前述の組成物のいずれかの態様の残部は、1つ以上の補助剤で構成されている。布地色調剤及びグリコシル加水分解酵素は、下記に詳しく記述される。
本発明の一実施形態では、この組成物は固体洗濯洗剤組成物であり、好ましくは固体洗濯粉末洗剤組成物である。
グリコシル加水分解酵素は、キシログルカンと非晶質セルロース基質の両方に対して酵素活性を有し、このグリコシル加水分解酵素は、GHファミリー5、12、44又は74の中から選択される。
pH7.5において下記のアッセイに従い、純粋な酵素が50000XyloU/gを超える特異的活性を有している場合、その酵素はキシログルカンに対して活性を有していると見なされる。
pH7.5において下記のアッセイに従い、純粋な酵素が20000EBG/gを超える特異的活性を有している場合、その酵素は非晶質セルロースに対して活性を有していると見なされる。緩衝剤として用いる化学物質及び基質は、少なくとも試薬等級の市販製品であった。
0.1Mリン酸塩緩衝液、pH7.5
Cellazyme C錠剤(アイルランドのMegazyme Internationalより入手)。
試験管中で、1mLのpH7.5緩衝液と5mLの脱イオン水を混合する。
蛍光増白剤は、少なくとも何らかの可視光線を放出する。対照的に布地色調剤は、可視光線スペクトルの少なくとも一部を吸収するため、表面の色合いを変えることができる。適切な布地色調剤としては、本明細書の試験方法の項に記載の試験方法1の要件を満たす染料、染料−粘土共役体、及び顔料が挙げられる。適切な染料としては、小分子染料及びポリマー染料が挙げられる。適切な小分子染料としては、ダイレクトブルー、ダイレクトレッド、ダイレクトバイオレット、アシッドブルー、アシッドレッド、アシッドバイオレット、ベーシックブルー、ベーシックバイオレット、及びベーシックレッドのカラーインデックス(C.I.)分類に該当する染料、又はこれらの混合物からなる群から選択される小分子染料が挙げられ、例えば、次のものが挙げられる。
本発明の目的には必須ではないが、以下に例示されている添加剤の非限定的なリストは、当該組成物中で使用するのに適しており、例えば、洗浄性能を補助若しくは向上させるために、洗浄すべき基材の処理のために、又は香料、着色剤、染料などを用いる場合のように洗浄組成物の審美性を変化させるために、本発明の特定の実施形態に組み込むのが望ましい場合がある。このような追加成分の明確な性質及びそれらを組み込む濃度は、組成物の物理的形態及びそれが使用される洗浄作業の性質に依存する。適切な添加剤物質としては、界面活性剤、ビルダー、キレート剤、移染防止剤、分散剤、追加の酵素及び酵素安定剤、触媒材料、漂白活性化剤、過酸化水素、過酸化水素源、予備形成過酸、ポリマー分散剤、粘土汚れ除去/再付着防止剤、増白剤、泡抑制剤、染料、香料、構造伸縮性付与剤、柔軟仕上げ剤、キャリア、向水性物質、加工助剤、溶媒、及び/又は顔料が挙げられるが、これらに限定されない。下記の開示に加え、このような他の補助剤の好適な例及び使用濃度は、米国特許第5,576,282号、同第6,306,812B1号、及び同第6,326,348B1号に記載されており、これらは参照により組み込まれる。
(3)アルカリ金属塩、例えば、過ホウ酸塩(通常は、一又は四水和物)、過炭酸塩、過硫酸塩、過リン酸塩、過ケイ酸塩、及びこれらの混合物のナトリウム塩を含む、過酸化水素供給源(例えば、無機過水和物塩)。発明の1つの態様では、無機過水和物塩は、過ホウ酸塩、過炭酸塩、及びこれらの混合物のナトリウム塩からなる群から選択される。無機過水和物塩(用いた場合)は、典型的には、全組成物の0.05〜40重量%、又は1〜30重量%の量で存在し、典型的には、当該組成物中へ結晶固形物(コーティングされていてもよい)として組み込まれる。好適なコーティングとしては、無機塩(アルカリ金属ケイ酸塩、炭酸塩若しくはホウ酸塩、又はこれらの混合物など)、又は有機物質(水溶性若しくは分散性ポリマー、ワックス、油又は脂肪石鹸など)が挙げられる、及び、
(4)R−(C=O)−Lを有する漂白活性化剤(式中、Rはアルキル基であり、所望により分枝状であり、漂白活性化剤が疎水性の場合には、6〜14個の炭素原子、又は8〜12個の炭素原子を有し、漂白活性化剤が親水性の場合、6個未満の炭素原子、又は更に4個未満の炭素原子を有し、Lは脱離基である)。適切な脱離基の例は、安息香酸及びその誘導体(特に、ベンゼンスルホネート)である。好適な漂白活性化剤としては、ドデカノイルオキシベンゼンスルホネート、デカノイルオキシベンゼンスルホネート、デカノイルオキシ安息香酸又はその塩、3,5,5−トリメチルヘキサノイルオキシベンゼンスルホネート、テトラアセチルエチレンジアミン(TAED)及びノナノイルオキシベンゼンスルホネート(NOBS)が挙げられる。適切な漂白活性剤は、国際特許第WO98/17767号にも開示されている。いかなる好適な漂白活性化剤も使用してもよいが、本発明の1つの態様では、標記洗浄組成物は、NOBS、TAED又はこれらの混合物を含んでもよい。
本発明の組成物は、いずれかの適切な形状で配合可能であり、配合者に選択されるいずれかのプロセスによって調製可能であり、それらの非限定的な実施例は、本出願人の実施例、及び米国特許第4,990,280号、同第20030087791A1号、同第20030087790A1号、同第20050003983A1号、同第20040048764A1号、同第4,762,636号、同第6,291,412号、同第20050227891A1号、欧州特許出願第1070115A2号、米国特許第5,879,584号、同第5,691,297号、同第5,574,005号、同第5,569,645号、同第5,565,422号、同第5,516,448号、同第5,489,392号、同第5,486,303号に記載されており、これらはすべて参照として本明細書に組み込まれる。
本発明は、ある場所、とりわけ布地表面を洗浄及び/又は処理する方法を含む。これらの方法は、本出願人の洗浄組成物の実施形態を、希釈していない形状で、又は洗浄溶液中で希釈して、布地表面の少なくとも一部に接触させてから、所望により布地表面をすすぐ工程を含む。布地表面は前述のすすぎ工程の前に洗浄工程にさらされてもよい。本発明の目的上、洗浄には、擦ること及び機械的攪拌が挙げられるが、これらに限定されない。それ故に、本発明は布地を洗濯するための方法を含む。この方法は、洗濯されるべき布地を、本出願の組成物の少なくとも1つの実施形態を含む清浄洗濯溶液と接触させる工程を含む。布地は、標準的な消費者の使用条件で洗濯され得る大抵の任意の布地を含んでもよい。溶液は、好ましくは、pH約7〜約11を有する。組成物は、溶液中で約500ppm〜約15,000ppmの濃度で用いてもよい。水温は、典型的には約5℃〜約90℃の範囲である。水対布地の比率は典型的には、約1:1〜約30:1である。
染料又は顔料物質が本発明の意図する布地色調剤であるかどうかを定義するための手順プロトコルを以下に記載する。
2)ポットをターゴトメーターに挿入する。試験中は水温を30℃に制御し、攪拌を40rpmに設定する。
3)各ポットにwfk(ドイツ・Bruggen−Bracht)から供給されているIEC−B洗剤(IEC 60456洗濯機用基準塩基洗剤タイプB)を4.8g加える。
4)2分後、第1のポットに活性着色剤を2.0mg加える。
5)1分後、5cm×5cmの材料見本に切断した平坦な綿肌着(Warwick Equest(英国ダラム州コンセット)から供給)50gを各ポットに加える。
6)10分後、ポットを排水し、硬度14.4(イギリスクラーク硬度)を有しカルシウム対マグネシウムのモル比が3:1の冷水(16℃)を最充填する。
7)2分間すすいだ後、布地を取り出す。
8)同じ処理を用いて更に3回のサイクルで工程3〜7を繰り返す。
9)布地を収集し、屋内で12時間自然乾燥させる。
10)D65光源及びUVA遮断フィルタを取り付けたハンターミニスキャン(Hunter Miniscan)スペクトロメーターを使用して材料見本を分析し、ハンターa(赤−緑軸)及びハンターb(黄−青軸)値を得る。
11)各組の布地についてハンターa及びハンターb値の平均値を計算する。着色剤で処理した評価対象布地がa軸又はb軸のいずれかにおいて平均で0.2単位より大きい色相の差を示した場合、本発明の意図する布地色調剤であると判断される。
下記は、布地洗濯に適した、本発明に従って製造された顆粒状洗剤組成物である。
2−NHにつき20個のエトキシル基を有するポリエチレンイミン(MW=600)。
3両親媒性グリース洗浄ポリマーは、−NHにつき24個のエトキシル基、及び−NHにつき16個のプロポキシル基を有するポリエチレンイミン(MW=600)である。
4次の構造を有する可逆性プロテアーゼ抑制剤。
*注:酵素濃度はすべて、酵素原材料の%として表わされているが、ただしキシログルカナーゼは、洗剤100g当たりの活性酵素タンパク質mg単位で示されている。XYG1006酵素は配列:1による。
Claims (9)
- (a)キシログルカンと非晶質セルロース基質の両方に対して酵素活性を有するグリコシル加水分解酵素であって、GHファミリー5、12、44又は74の中から選択され、かつ0.0005重量%〜0.1重量%の濃度で存在するグリコシル加水分解酵素と、
(b)布地色調剤であって、染料、染料−粘土共役体、及びこれらの混合物からなる群から選択され、0.00003重量%〜0.1重量%の濃度で存在する布地色調剤と、
(c)非イオン性洗浄性界面活性剤と、
を含む、洗濯洗剤組成物。 - 前記グリコシル加水分解酵素が、グリコシル加水分解酵素ファミリー44である、請求項1に記載の組成物。
- 前記グリコシル加水分解酵素が、配列番号1と少なくとも80%相同の配列を有する、請求項1または2に記載の組成物。
- 前記組成物が液体の形態である、請求項1〜3のいずれか一項に記載の組成物。
- 前記染料が、小分子染料、ポリマー染料、及びこれらの混合物からなる群から選択され、前記染料−粘土共役体が、少なくとも一つのカチオン性/塩基性染料及びスメクタイト粘土を含む染料粘土共役体、及びこれらの混合物からなる群から選択される、請求項1〜4のいずれか一項に記載の組成物。
- 前記小分子染料が、ダイレクトバイオレット9、ダイレクトバイオレット35、ダイレクトバイオレット48、ダイレクトバイオレット51、ダイレクトバイオレット66、ダイレクトブルー1、ダイレクトブルー71、ダイレクトブルー80、ダイレクトブルー279、アシッドレッド17、アシッドレッド73、アシッドレッド88、アシッドレッド150、アシッドバイオレット15、アシッドバイオレット17、アシッドバイオレット24、アシッドバイオレット43、アシッドレッド52、アシッドバイオレット49、アシッドブルー15、アシッドブルー17、アシッドブルー25、アシッドブルー29、アシッドブルー40、アシッドブルー45、アシッドブルー75、アシッドブルー80、アシッドブルー83、アシッドブルー90、アシッドブルー113、アシッドブラック1、ベーシックバイオレット1、ベーシックバイオレット3、ベーシックバイオレット4、ベーシックバイオレット10、ベーシックバイオレット35、ベーシックブルー3、ベーシックブルー16、ベーシックブルー22、ベーシックブルー47、ベーシックブルー66、ベーシックブルー75、ベーシックブルー159、及びこれらの混合物からなる群から選択され、前記ポリマー染料が、共役色原体を含有するポリマー、ポリマーの骨格に共重合した色原体を有するポリマー及びこれらの混合物からなる群から選択され、前記染料−粘土共役体が、C.I.ベーシックイエロー1〜108、C.I.ベーシックオレンジ1〜69、C.I.ベーシックレッド1〜118、C.I.ベーシックバイオレット1〜51、C.I.ベーシックブルー1〜164、C.I.ベーシックグリーン1〜14、C.I.ベーシックブラウン1〜23、CIベーシックブラック1〜11からなる群から選択される染料と、モンモリロナイト粘土、ヘクトライト粘土、サポナイト粘土及びこれらの混合物からなる群から選択される粘土とを含む染料粘土共役体から選択される、請求項5に記載の組成物。
- 前記小分子染料が、アシッドバイオレット17、アシッドバイオレット43、アシッドレッド52、アシッドレッド73、アシッドレッド88、アシッドレッド150、アシッドブルー25、アシッドブルー29、アシッドブルー45、アシッドブルー113、アシッドブラック1、ダイレクトブルー1、ダイレクトブルー71、ダイレクトバイオレット51、及びこれらの混合物からなる群から選択される、請求項6に記載の組成物。
- 前記小分子染料が、べーシックバイオレット1、べーシックバイオレット3、べーシックバイオレット4、べーシックバイオレット10、べーシックバイオレット35、べーシックブルー3、べーシックブルー16、べーシックブルー22、べーシックブルー47、べーシックブルー66、べーシックブルー75、べーシックブルー159、及びこれらの混合物からなる群から選択される、請求項6に記載の組成物。
- 前記色調剤が、アルコキシル化トリフェニルメタン及び/又はアルコキシル化チオフェンポリマー着色料を含む、請求項1〜8のいずれか一項に記載の組成物。
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- 2008-12-19 CA CA2709609A patent/CA2709609C/en active Active
- 2008-12-19 WO PCT/IB2008/055469 patent/WO2009087524A1/en active Application Filing
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- 2008-12-19 BR BRPI0822220-7A patent/BRPI0822220A2/pt not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
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PL2242830T3 (pl) | 2013-08-30 |
PL2242830T5 (pl) | 2021-08-16 |
EP2242830B2 (en) | 2020-03-11 |
ES2412683T5 (es) | 2020-11-13 |
EP2242830A1 (en) | 2010-10-27 |
RU2470070C2 (ru) | 2012-12-20 |
ES2412683T3 (es) | 2013-07-12 |
CA2709609A1 (en) | 2009-07-16 |
RU2010125315A (ru) | 2012-02-10 |
US8512418B2 (en) | 2013-08-20 |
CA2709609C (en) | 2013-05-28 |
US20090172895A1 (en) | 2009-07-09 |
ZA201004547B (en) | 2011-12-28 |
EG25965A (en) | 2012-11-13 |
BRPI0822220A2 (pt) | 2015-06-23 |
AR070102A1 (es) | 2010-03-17 |
CN101910392B (zh) | 2012-09-05 |
CN101910392A (zh) | 2010-12-08 |
EP2242830B1 (en) | 2013-03-13 |
JP2011511099A (ja) | 2011-04-07 |
WO2009087524A1 (en) | 2009-07-16 |
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