CN113825829A - 洗衣组合物 - Google Patents
洗衣组合物 Download PDFInfo
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- CN113825829A CN113825829A CN202080036119.8A CN202080036119A CN113825829A CN 113825829 A CN113825829 A CN 113825829A CN 202080036119 A CN202080036119 A CN 202080036119A CN 113825829 A CN113825829 A CN 113825829A
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- laundry
- composition
- perfume
- rinse
- composition according
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/38—Products with no well-defined composition, e.g. natural products
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- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
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Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
本发明涉及一种漂洗添加的辅助洗衣组合物，其用于改善织物调理剂的软化效果，所述辅助洗衣组合物包含：a.纤维素酶；b.0.5‑12重量％的非离子表面活性剂；c.0.5至20重量％的游离香料；和d.水。
Description
技术领域
本发明涉及一种包含酶的辅助洗衣组合物。
背景技术
消费者越来越注重环保。人们对快时尚等问题的认识不断提高，防止浪费织物和避免过早扔掉衣服的愿望也在增加。
消费者正在寻求洗衣产品来帮助延长衣服的使用寿命。织物调理剂提供了一些益处，例如软化，但是仍然需要提供有助于延长衣服寿命的制剂。
本发明的发明人已经发现本发明所述的组合物和方法改善了织物调理剂的软化效果，提供了新衣服的感觉。
发明内容
在本发明的第一方面，提供了一种漂洗添加的辅助洗衣组合物，其用于改善织物调理剂的软化效果，所述辅助洗衣组合物包含：
a.纤维素酶；
b.0.5-12重量％的非离子表面活性剂；
c.0.5至20重量％的游离香料；和
d.水。
在本发明的第二方面，提供了一种在洗衣周期的漂洗阶段将酶递送至织物的方法，其中除了织物调理剂制剂之外，将本文所述的辅助洗衣组合物添加至漂洗中。
在本发明的第三方面，提供了一种改善织物调理剂的软化益处的方法，其中除了织物调理剂制剂之外，将本文所述的辅助洗衣组合物添加至漂洗中。
在本发明的第四方面，提供了根据本文所述的辅助洗衣组合物在洗衣周期的漂洗阶段将酶递送至织物的用途。
在本发明的第五方面，提供了根据本文所述的辅助洗衣组合物改善织物调理剂的软化益处的用途。
具体实施方式
通过阅读以下详细描述和所附权利要求，这些和其他方面、特征和优点对于本领域普通技术人员将变得显而易见。为避免疑义，本发明的一个方面的任何特征可用于本发明的任何其他方面。“包含(comprising)”一词旨在表示“包括(including)”，但不一定表示“由……组成”或“由……构成”。换言之，列出的步骤或选项不必是详尽无遗的。需要注意的是，以下描述中给出的例旨在阐明本发明，并不旨在将本发明限制于这些实施例本身。类似地，除非另有说明，所有百分比均为重量/重量百分比。除了在操作和比较实施例中，或者在另外明确指出的情况下，本说明书中指示材料的量或反应条件、材料的物理性质和/或用途的所有数字应理解为由词“约”修饰。以“从x到y”格式表示的数字范围被理解为包括x和y。当针对特定特征以“x至y”的形式描述多个优选范围时，应当理解，还考虑了组合不同端点的所有范围。
发明形式
术语“辅助洗衣组合物”用于指代特定形式的洗衣产品。这是一种液体产品，旨在除了洗衣洗涤剂和/或织物调理剂以外使用，以在洗涤或漂洗循环中为材料提供额外或改善的益处。然而，可以使用所述制剂代替织物调理剂制剂。辅助洗衣组合物也可称为精华素(serum)。
这种特殊形式提供了改善的益处递送。其还为消费者提供了一种简单的添加剂产品，可以将其添加到他们常用的织物调理剂中。
酶
本发明所述的辅助洗衣组合物至少包含纤维素酶。可以存在其他酶，这些酶可以选自：蛋白酶、α-淀粉酶、脂肪酶、过氧化物酶/氧化酶、果胶酸裂解酶和甘露聚糖酶，或其混合物。优选地，其他酶选自蛋白酶、脂肪酶、淀粉酶及其混合物。
本发明所述的辅助洗衣组合物中存在的每一类酶以所述组合物的0.0001重量％至0.1重量％的水平存在。例如，如果所述组合物包含纤维素酶和淀粉酶，则所述组合物将包含0.0001重量％至0.1重量％的纤维素酶和0.0001重量％至0.1重量％的淀粉酶。
存在于所述辅助洗衣组合物中的每种酶的量特别重要，因为这是漂洗添加制剂。需要足够的酶在短的漂洗周期中提供益处。然而，一些酶会沉积在洗涤过的织物上并在使用过程中留在织物上，因此重要的是酶不要过多。
所述组合物中存在的酶水平优选地与作为纯蛋白的酶水平相关。
合适的纤维素酶包括细菌或真菌来源的那些。包括化学修饰或蛋白工程突变体。合适的纤维素酶包括来自芽孢杆菌属(Bacillus)、假单胞菌属(Pseudomonas)、腐质霉属(Humicola)、镰刀菌属(Fusarium)、硫霉属(Thielavia)、枝顶孢属(Acremonium)的纤维素酶，例如US4,435,307、US5,648,263、US5,691,178、US5,776,757、WO25907、WO8907、WO8907、WO8907、WO8907、WO8907、WO8907/4,435,307中公开的特异腐质霉(Humicola insolens)、土生梭孢霉(Thielavia terrestris)、嗜热毁丝霉(Myceliophthora thermophila)和尖孢镰刀菌(Fusarium oxysporum)产生的真菌纤维素酶。市售纤维素酶包括CelluzymeTM、CarezymeTM、CellucleanTM、EndolaseTM、RenozymeTM(NovozymesA/S)、ClazinaseTM和PuradaxHATM(GenencorInternationalInc.)和KAC-500(B)TM(KaoCorporation)。优选CellucleanTM。
合适的脂肪酶包括细菌或真菌来源的脂肪酶。包括化学修饰或蛋白工程突变体。有用的脂肪酶的实例包括来自腐质霉(同义词嗜热真菌属(Thermomyces))的脂肪酶，例如来自EP258068和EP305216中所述的柔毛腐质霉(H.lanuginosa)(柔毛嗜热真菌(T.lanuginosus))或来自WO96/13580中所述的特异腐质霉；假单胞菌(Pseudomonas)脂肪酶，例如来自产碱假单胞菌(P.alcaligenes)或类产碱假单胞菌(P.pseudoalcaligenes)(EP218272)，洋葱假单胞菌(P.cepacia)(EP331376)，施氏假单胞菌(P.stutzeri)(GB1,372,034)，荧光假单胞菌(P.fluorescens)，假单胞属物种菌株SD705(WO95/06720和WO96/27002)，威斯康星假单胞菌(P.wisconsinensis)(WO96/12012)，芽孢杆菌(Bacillus)脂肪酶，例如来自枯草杆菌(B.subtilis)(Dartois等(1993)，Biochemica et BiophysicaActa,1131,253-360)，嗜热脂肪芽孢杆菌(B.stearothemophilus)(JP64/744992)或短小芽孢杆菌(B.pumilus)(WO91/16422)。其他实例是脂肪酶变体，例如在WO92/05249、WO94/01541、EP407225、EP260105、WO95/35381、WO96/00292、WO95/30744、WO94/25578、WO95/14783、WO95/22615、WO97/04079和WO97/07202、WO00/60063中描述的那些。
优选的市售脂肪酶包括LipolaseTM和LipolaseUltraTM、LipexTM和LipocleanTM(NovozymesA/S)。
本发明可以在分类为EC3.1.1.4和/或EC3.1.1.32的磷脂酶的存在下进行。如本文所用，术语磷脂酶是对磷脂具有活性的酶。
磷脂，例如卵磷脂或磷脂酰胆碱，由在外侧(sn-1)和中间(sn-2)位置被两个脂肪酸酯化并在第三位被磷酸酯化的甘油组成；磷酸又可以酯化成氨基醇。磷脂酶是参与磷脂水解的酶。可以区分几种类型的磷脂酶活性，包括水解一个脂肪酰基(分别在sn-1和sn-2位置)以形成溶血磷脂的磷脂酶A1和A2；溶血磷脂酶(或磷脂酶B)可水解溶血磷脂中的剩余脂肪酰基。磷脂酶C和磷脂酶D(磷酸二酯酶)分别释放二酰基甘油或磷脂酸。
蛋白酶水解肽和蛋白内的键，在洗衣环境中这导致增强去除含蛋白或肽的污渍。合适的蛋白酶家族的实例包括天冬氨酸蛋白酶；半胱氨酸蛋白酶；谷氨酸蛋白酶；天冬酰胺肽裂解酶；丝氨酸蛋白酶和苏氨酸蛋白酶。此类蛋白酶家族在MEROPS肽酶数据库(http://merops.sanger.ac.uk/)中有描述。优选丝氨酸蛋白酶。更优选枯草杆菌酶型丝氨酸蛋白酶。术语“枯草蛋白酶”是指根据Siezen等，Protein Engng.4(1991)719-737和Siezen等，Protein Science 6(1997)501-523的丝氨酸蛋白酶的亚组。丝氨酸蛋白酶是蛋白酶的一个亚组，其特征在于在活性位点具有丝氨酸，其与底物形成共价加合物。枯草杆菌酶可分为6个亚类，即枯草杆菌蛋白酶家族、Thermitase家族、蛋白酶K家族、羊毛硫抗生素肽酶家族、Kexin家族和Pyrolysin家族。
枯草杆菌酶的实例是源自芽孢杆菌属，例如迟缓芽孢杆菌(Bacillus lentus)、嗜碱芽孢杆菌(B.alkalophilus)、枯草芽孢杆菌(B.subtilis)、解淀粉芽孢杆菌(B.amyloliquefaciens)、短小芽孢杆菌(Bacillus pumilus)和吉布森芽孢杆菌(Bacillusgibsonii)的那些；US7262042和WO09/021867，以及迟缓枯草杆菌蛋白酶、枯草杆菌蛋白酶Novo、嘉士伯枯草杆菌、地衣芽孢杆菌(Bacillus licheniformis)、枯草杆菌蛋白酶BPN'、枯草杆菌蛋白酶309、枯草杆菌蛋白酶147和枯草杆菌蛋白酶168(描述于WO89/06279中)和蛋白酶PD138(描述于WO 93/18140中)。其他有用的蛋白酶可以是WO92/175177、WO01/016285、WO02/026024和WO02/016547中描述的那些。胰蛋白酶样蛋白酶的实例是胰蛋白酶(例如猪或牛来源的)和WO89/06270、WO94/25583和WO05/040372中描述的镰刀菌(Fusarium)蛋白酶，以及WO 05/052161和WO 05/052146中描述的源自纤维单胞菌属(Cellumonas)的胰凝乳蛋白酶。
最优选的蛋白酶是枯草杆菌蛋白酶(EC3.4.21.62)。
枯草杆菌酶的实例是源自芽孢杆菌，例如迟缓芽孢杆菌、嗜碱芽孢杆菌、枯草芽孢杆菌、解淀粉芽孢杆菌、短小芽孢杆菌和吉布森芽孢杆菌的那些；US7262042和WO09/021867，以及迟缓枯草杆菌蛋白酶、枯草杆菌蛋白酶Novo、嘉士伯枯草杆菌蛋白酶、地衣芽孢杆菌、枯草杆菌蛋白酶BPN'、枯草杆菌蛋白酶309、枯草杆菌蛋白酶147和枯草杆菌蛋白酶168(描述于WO89/06279中)和蛋白酶PD138(描述于WO93/18140中)。优选地，枯草杆菌蛋白酶源自芽孢杆菌，优选迟缓芽孢杆菌、嗜碱芽孢杆菌、枯草芽孢杆菌、解淀粉芽孢杆菌、短小芽孢杆菌和吉布森芽孢杆菌(描述于US 6,312,936 Bl、US 5,679,630、US 4,760,025、US7,262,042和WO 09/021867中)。最优选地，枯草杆菌蛋白酶源自吉布森芽孢杆菌或迟缓芽孢杆菌。
合适的市售蛋白酶包括以商品名
DuralaseTm,DurazymTm,
Ultra,
Ultra,
Ultra,
Ultra,
和
售卖的那些，其均可以
或
(Novozymes A/S)售卖。
本发明可以使用分类在EC3.1.1.74中的角质酶。根据本发明使用的角质酶可以是任何来源的。优选角质酶是微生物来源的，特别是细菌来源的、真菌来源的或酵母来源的。
合适的淀粉酶(α和/或β)包括细菌或真菌来源的淀粉酶。包括化学修饰或蛋白工程突变体。淀粉酶包括，例如，从芽孢杆菌，例如，地衣芽孢杆菌的一种特殊菌株(在GB1,296,839中有更详细的描述)，或芽孢杆属物种菌株(公开于WO95/026397或WO00/060060中)获得的α-淀粉酶。市售淀粉酶是DuramylTM、TermamylTM、TermamylUltraTM、NatalaseTM、StainzymeTM、FungamylTM和BANTM(NovozymesA/S)、RapidaseTM和PurastarTM(来自GenencorInternational Inc.)。
合适的过氧化物酶/氧化酶包括植物、细菌或真菌来源的那些。包括化学修饰或蛋白工程突变体。有用的过氧化物酶的实例包括来自鬼伞属(Coprinus)，例如，来自灰盖鬼伞(C.cinereus)的过氧化物酶及其变体，如WO93/24618、WO95/10602和WO98/15257中所述。可商购的过氧化物酶包括GuardzymeTM和NovozymTM51004(NovozymesA/S)。
适合使用的其他酶在WO 2009/087524、WO 2009/090576、WO 2009/107091、WO2009/111258和WO 2009/148983中讨论。
酶稳定剂
组合物中存在的任何酶可以使用常规稳定剂进行稳定，所述常规稳定剂例如多元醇如丙二醇或甘油、糖或糖醇、乳酸、硼酸或硼酸衍生物，例如芳族硼酸酯，或苯基硼酸衍生物例如4-甲酰基苯基硼酸，并且所述组合物可以如在例如WO92/19709和WO92/19708中描述的那样制备。
游离香料
本发明所述的组合物包含游离香料。
游离香料可以以选自以下的含量存在：按所述组合物的重量计，小于20％、小于15％和小于10％。游离香料可以以选自以下的含量存在：按所述组合物的重量计，大于0.5％、大于1％和大于2％水平存在。合适的游离香料以选自以选自以下范围的量存在于所述组合物中：按所述辅助洗衣组合物的重量计的约0.5％至约20％、优选地约1％至约15％、更优选地约2％至约10％。
有用的香料成分可包括天然和合成来源的材料。其包括单一化合物和混合物。此类组分的具体实例可以在当前文献中找到，例如Fenaroli's Handbook of FlavorIngredients,1975,CRC Press；Synthetic Food Adjuncts,1947by M.B.Jacobs,VanNostrand编辑；或Perfume and Flavor Chemicals by S.Arctander 1969,Montclair,N.J.(USA)中。这些物质是给加香、调味和/或芳香化消费品领域的技术人员所熟知的。
已知多种化学品(包括诸如醛、酮、酯等的材料)用于香料用途。更常见的是，已知天然存在的植物油和动物油以及包含各种化学组分的复杂混合物的渗出物可用作香料，并且此类材料可在本文中使用。典型的香料可以包括例如木质/泥土基调，包含檀香油、果子狸和广藿香油等奇异材料。香料也可以是淡淡的花香，例如玫瑰或紫罗兰提取物。此外，可以配制香料以提供所需的水果气味，例如，酸橙、柠檬或橙子。
有用的香料组分和组合物的具体实例是茴香脑、苯甲醛、乙酸苄酯、苄醇、甲酸苄基酯、乙酸异冰片酯、莰烯、顺式柠檬醛(橙花醛)、香茅醛、香茅醇、乙酸香茅酯、对伞花烃、癸醛、二氢芳樟醇、二氢月桂烯醇、二甲基苯基甲醇、桉油脑、香叶醛、香叶醇、乙酸香叶酯、香叶腈、顺-3-己烯乙酸酯、羟基香茅醛、d-柠檬烯、芳樟醇、氧化芳樟醇、乙酸芳樟酯、丙酸芳樟酯、邻氨基苯甲酸甲酯、α-甲基紫罗酮、甲酯壬基乙醛、甲基苯基乙酸原(carbinyl)酯、左旋-乙酸薄荷酯、薄荷酮、异薄荷酮、月桂烯、月桂烯乙酸酯、月桂烯醇、橙花醇、乙酸橙花酯、乙酸壬基酯、苯乙醇、α-蒎烯、β-蒎烯、γ-萜品烯，α-萜品醇、β-萜品醇、乙酸萜品酯、vertenex(乙酸对叔丁基环己酯)、戊基肉桂醛、水杨酸异戊酯、β-石竹烯、雪松烯、肉桂醇、香豆素、乙酸二甲基苄基原(carbinyl)酯)、乙基香兰素、丁香酚、异丁香酚、醋酸氟(floracetate)、天芥菜碱、3-顺式-己烯基水杨酸酯、己基水杨酸酯、铃兰醛(lilial)(对叔丁基-α-甲基氢化肉桂醛)、γ-甲基紫罗酮、橙花叔醇、广藿香醇、苯基己醇、β-蛇床烯、三氯甲基苯基甲醇酯、柠檬酸三乙酯、香兰醛、藜芦醛、α-雪松烯、β-雪松烯、C15H24倍半萜烯、二苯甲酮、水杨酸苄酯、巴西酸乙二醇酯、佳乐麝香(1,3,4,6,7,8-六氢-4,6,6,7,8,8,-六甲基-环-戊-γ-2-苯并吡喃)、己基肉桂醛、新铃兰醛(4-(4-羟基-4-甲基戊基)-3-环己烯-10-甲醛)、甲基柏木酮、二氢茉莉酸甲酯、甲基-β-萘基酮、葵子麝香、茚酮麝香(musk idanone)、麝香酮、西藏麝香、二甲苯麝香、橙花醇和苯乙基乙酸酯。
本组合物的游离香料组合物包含浓烈(blooming)香料成分。浓烈香料成分定义为沸点低于250℃且LogP或大于2.5。优选地，本发明所述的游离香料组合物包含至少10重量％的浓烈香料成分、更优选地至少20重量％的浓烈香料成分、最优选地至少25重量％的浓烈香料成分。优选地，本发明所述的游离香料组合物包含小于58重量％的浓烈成分、更优选地小于50重量％的浓烈成分、最优选地小于45重量％的浓烈成分。合适地，本发明组合物的游离香料组合物包含10至58重量％的浓烈成分、优选地20至50重量％的浓烈成分、更优选地25至45重量％的浓烈成分。
合适的浓烈香料成分的实例包括：异罗勒烯、庚酸烯丙酯、反式茴香脑、丁酸苄基酯、莰烯、香芹酚、顺式-3-己烯基惕各酸酯、香茅醇、乙酸香茅酯、香茅基腈、乙酸环己基乙酯、癸基醛(癸醛)、二氢月桂烯醇、乙酸二氢月桂烯酯、3,7-二甲基-1-辛醇、乙酸葑酯、乙酸香叶酯、甲酸香叶酯、香叶基腈、异丁酸顺式-3-己烯酯、新戊酸己酯、惕各酸己酯、α-紫罗酮、乙酸异冰片酯、苯甲酸异丁酯、乙酸异壬酯、异壬醇、乙酸异胡薄荷酯(isopulegylacetate))、月桂醛、乙酸芳樟酯、Lorysia、D-柠檬烯、Lymolene、(-)-L-乙酸薄荷酯、甲基胡椒酚(草蒿脑)、甲基正正乙醛、甲基辛基乙醛、β-月桂烯、醋酸橙花酯、醋酸壬酯、壬醛、对伞花烃、α-蒎烯,β-蒎烯、α-萜品烯、γ-萜品烯、萜品油烯、α-醋酸萜品酯、四氢芳樟醇、四氢月桂烯醇、2-十一烯醛、Verdox(乙酸邻叔丁基环己酯)和vertenex(4-叔丁基环己基醋酸酯)。
其他有用的香料成分包括耐久(substantive)香料成分。耐久香料成分定义为沸点高于250℃且LogP高于2.5。优选地，游离香料组合物还包含耐久香料成分。
沸点是在标准压力(760mmHg)下测量的。优选地，香料组合物将包含浓烈和耐久香料组分的混合物。香料组合物可包含其他香料组分。
已经报道了许多香料成分的logP；例如，可从Daylight Chemical InformationSystems,Inc.(Daylight CIS),Irvine,Calif.获得的Pomona92数据库包含许多以及对原始文献的引用。然而，logP值最方便地通过同样可从Daylight CIS获得的“CLOGP”程序计算。该程序还列出了Pomona 92数据库中可用的实验logP值。“计算的logp”(ClogP)由Hansch和Leo的片段方法确定(参见A Leo,in Comprehensive Medicinal Chemistry,第4卷,C.Hansch,P.G.Sammens,J.B.Taylor and C.A.Ramsden,Eds.,第295页,PergamonPress,1990，在此引入作为参考)。片段方法基于每种香料成分的化学结构，并考虑原子的数量和类型、原子连接性和化学键。本文在选择本发明的香料成分时，使用最可靠和广泛用于估计该物理化学性质的ClogP来代替实验logP值。
在游离油香料组合物中存在多种香料组分是司空见惯的。在用于本发明所述的组合物中，设想将存在三种或更多种、优选四种或更多种、更优选五种或更多种、最优选六种或更多种不同的香料组分。可以应用300种香料成分的上限。
本发明所述的游离香料为乳剂形式。乳剂的粒度可在约1纳米至30微米，优选地约100纳米至约20微米的范围内。将粒度测量为体积平均直径D[4,3]，这可以使用来自Malvern instruments的Malvern Mastersizer 2000进行测量。
游离油香料在本组合物中形成乳剂。乳剂可以在组合物之外或原位形成。当原位形成时，优选将至少一种乳化剂与游离油香料一起加入以稳定乳剂。优选地，乳化剂是阴离子的或非离子的。用于游离油香料的合适阴离子乳化剂的实例是烷基芳基磺酸盐(例如十二烷基苯磺酸钠)、烷基硫酸盐(例如月桂基硫酸钠)、烷基醚硫酸盐(例如月桂基醚硫酸钠nEO，其中n是1至20)、烷基苯酚醚硫酸盐(例如辛基苯酚醚硫酸盐nEO，其中n为1至20)以及磺基琥珀酸盐(例如二辛基磺基琥珀酸钠)。用作用于游离油香料的乳化剂的合适非离子表面活性剂的实例是烷基酚乙氧基化物(例如壬基酚乙氧基化物nEO，其中n为1至50)、醇乙氧基化物(例如月桂醇nEO，其中n为1至50)、酯乙氧基化物(例如聚氧乙烯单硬脂酸酯，其中氧乙烯单元的数目为1至30)和PEG-40氢化蓖麻油。游离香料中包含的任何非离子表面活性剂都计入非离子表面活性剂的总量。
包封香料
本发明所述的辅助洗衣组合物优选包含包封的香料。这些也可称为香料微囊。辅助洗衣组合物优选包含按所述组合物重量计0.1至20重量％的香料微囊、更优选地0.5至12重量％的香料微囊、最优选1至8重量％的香料微囊。微囊的重量是所提供的材料重量。
当香料组分被包封时，合适的包封材料可包括但不限于；氨基塑料类、蛋白类、聚氨酯类、聚丙烯酸酯类、聚甲基丙烯酸酯类、多糖类、聚酰胺类、聚烯烃类、树胶类、硅酮类、脂质类、改性纤维素、聚磷酸盐、聚苯乙烯、聚酯类或其的组合。特别优选的材料是氨基塑料微囊，例如三聚氰胺甲醛或脲甲醛微囊。
本发明的香料微囊可以是易碎的微囊和/或水分活化的微囊。易碎是指在施加力时香料微囊会破裂。水分活化是指香料在水的存在下释放。本发明所述的辅助洗衣组合物优选包含易碎的微囊。可以另外存在水分活化的微囊。易碎的微囊的实例包括氨基塑料微囊。
包含在微囊中的香料组分可包括散发气味的(odiferous)材料和/或香料前体材料。
包含在微囊中的特别优选的香料组分是浓烈香料组分和耐久香料组分。浓烈香料组分定义为沸点低于250℃且LogP高于2.5。耐久香料成分定义为沸点高于250℃且且LogP高于2.5。沸点是在标准压力(760mm Hg)下测量的。优选地，香料组合物将包含浓烈和耐久香料组分的混合物。香料组合物可包含其他香料组分。
多种香料组分存在于微囊中是司空见惯的。在用于本发明所述的组合物中，设想在微囊中有三种或更多种、优选四种或更多种、更优选五种或更多种、最优选六种或更多种不同的香料组分。可以应用300种香料成分的上限。
微囊可包含香料组分和用于香料成分的载体，例如沸石或环糊精。
非离子表面活性剂
本发明所述的辅助洗衣组合物优选包含小于辅助洗衣组合物重量的12重量％、更优选地小于8重量％和最优选地小于5重量％的非离子表面活性剂。本发明所述的辅助洗衣组合物优选包含大于0.5重量％的非离子表面活性剂。合适地，本发明所述的辅助洗衣组合物优选包含0.5至12重量％、更优选地0.5至8重量％和最优选地0.5至5重量％的非离子表面活性剂。正确量的非离子表面活性剂对于实现有益剂的期望递送是重要的。辅助洗衣组合物需要足够的表面活性剂来携带有益剂，但是过多的表面活性剂会干扰与其一起使用的洗衣液或洗衣粉的作用，并且会由于稀释不足而阻止有益剂的释放。
非离子表面活性剂优选具有12至20、更优选地14至18的HLB值。
非离子表面活性剂材料的实例包括：乙氧基化的材料、多元醇如多元醇和多元醇酯、烷基多糖苷、EO-PO嵌段共聚物(泊洛沙姆)。优选地，非离子表面活性剂选自乙氧基化的材料。
优选的乙氧基化的材料包括：脂肪酸乙氧基化物、脂肪胺乙氧基化物、脂肪醇乙氧基化物、壬基酚乙氧基化物、烷基酚乙氧基化物、酰胺乙氧基化物、脱水山梨醇酯乙氧基化物、甘油酯乙氧基化物(蓖麻油或其氢化蓖麻油乙氧基化物的混合物)。
更优选地，非离子表面活性剂选自具有通式的乙氧基化的表面活性剂：
R1O(R2O)xH
R1＝疏水部分。
R2＝C2H4或C2H4和C3H6单元的混合物
x＝4至120
R1优选包含8至25个碳原子及其混合物、更优选地10至20个碳原子及其混合物、最优选地12至18个碳原子及其混合物。优选地，R选自包含醇、羧基或酚基团的伯、仲和支链饱和的和/或不饱和的烃基。优选地，R是天然或合成的醇。
R2优选包含至少50％C2H4，更优选75％C2H4，最优选R2是C2H4。
x优选为8至90，最优选为10至60。
可商购的、合适的非离子表面活性剂的实例包括Genapol C200，来自Clariant；和Eumulgin CO40，来自BASF。
其他表面活性剂
本发明所述的辅助洗衣组合物不是传统的洗衣洗涤剂或织物调理组合物。本发明优选包含低含量或不包含阴离子或阳离子表面活性剂。
本发明的液体辅助组合物优选包含按所述组合物的重量计小于2重量％的阴离子和阳离子表面活性剂、更优选地小于1重量％的表面活性剂、甚至更优选地小于0.85重量％的阴离子和阳离子表面活性剂和最优选地小于0.5重量％的阴离子和阳离子表面活性剂。
所述组合物可以完全不含阴离子和阳离子表面活性剂。
换言之，组合物优选包含按所述组合物的重量计0至2重量％的阴离子和阳离子表面活性剂、更优选地0至1重量％的阴离子和阳离子表面活性剂、甚至更优选地0至0.85重量％和最优选地0至0.5重量％的阴离子和阳离子表面活性剂。所述组合物可以完全不含阴离子和阳离子表面活性剂。
结构化剂
如果辅助洗衣组合物包含微囊，则可能需要结构化剂，合适结构化剂的非限制性实例包括：果胶、藻酸盐、阿拉伯半乳聚糖、角叉菜胶、结冷胶、多糖如黄原胶、瓜尔胶、丙烯酸酯/丙烯酸聚合物、水可溶胀粘土、气相二氧化硅、丙烯酸酯/氨基丙烯酸酯共聚物及其混合物。
此处优选的分散剂包括选自丙烯酸酯/丙烯酸聚合物、结冷胶、气相二氧化硅、丙烯酸酯/氨基丙烯酸酯共聚物、水可溶胀粘土、多糖如黄原胶及其混合物的那些。最优选地，结构化剂选自多糖，例如黄原胶、丙烯酸酯/丙烯酸聚合物、丙烯酸酯/氨基丙烯酸酯共聚物和水可溶胀粘土。最优选的结构化剂是多糖，例如黄原胶。
当存在结构化剂时，结构化剂优选以所述组合物的0.001-10重量％、优选地0.005-5重量％、更优选0.01-3重量％的量存在。
流变改性剂
在本发明的一些实施例中，本发明所述的辅助洗衣组合物可包含流变改性剂。这些可以是无机的或有机的、聚合的或非聚合的。优选类型的流变改性剂是盐。
防腐剂
本发明所述的辅助洗衣组合物优选包含防腐剂。防腐剂优选以所述组合物的0.001至1重量％的量存在，更优选地为所述组合物的0.005至0.5重量％，最优选地为所述组合物的0.01至0.1重量％。
防腐剂可以包括抗微生物剂，例如基于异噻唑啉酮的化学品(特别是异噻唑-3-酮杀菌剂)或基于戊二醛的产品。合适的防腐剂的实例包括苯并异噻唑啉、氯-甲基-异噻唑-3-酮、甲基-异噻唑-3-酮及其混合物。合适的防腐剂作为来自Dow的Kathon CG和来自Lonza的Proxel市售可得。
其他成分
本发明所述的辅助洗衣组合物可包含其他有益剂。合适的其他有益剂的实例包括：
·硅油、树脂、乳剂及其改性物，例如直链和环状聚二甲基硅氧烷、氨基改性的、烷基、芳基和烷芳基硅油
·异味剂(malodour agents)，例如：未复合的环糊精；气味阻滞剂；活性醛类；黄酮类；沸石；活性炭；及其混合物
·染料转移抑制剂
·调色染料
·荧光剂/光学明亮剂
·驱虫剂
·有机防晒活性物质，例如甲氧基肉桂酸辛酯；
·抗微生物剂，例如2-羟基-4,2,4-三氯二苯醚；
·酯溶剂；例如，肉豆蔻酸异丙酯；
·抗再沉积剂
·脂质和脂质类物质，例如胆固醇；
·碳氢化合物，如石蜡、凡士林和矿物油
·鱼油和植物油；
·疏水性植物提取物；
·蜡；
·色素，包括具有疏水改性表面和/或分散在油或疏水液体中的无机化合物；
·糖酯，如蔗糖聚酯(SPE)；
及其组合。
优选的其他有益剂可以选自：硅氧烷、异味剂、染料转移抑制剂、荧光剂/光学明亮剂、调色染料、抗微生物剂。
适用于本发明的硅氧烷的实例是织物柔软硅氧烷。此类有机硅的非限制性实例包括：
·非官能化有机硅，例如聚二甲基硅氧烷(PDMS)，
·官能化有机硅，例如烷基(或烷氧基)官能化、环氧烷官能化、氨基官能化、苯基官能化、羟基官能化、聚醚官能化、丙烯酸酯官能化、氢化硅官能化、羧基官能化、磷酸盐官能化、硫酸盐官能化、膦酸酯官能化、磺酸官能化、甜菜碱官能化、季铵化氮官能化及其混合物。
·具有一种或多种不同类型官能团(例如烷基、环氧烷、氨基、苯基、羟基、聚醚、丙烯酸酯、氢化硅、羧基、磷酸盐、磺酸盐、膦酸盐、甜菜碱、季铵化氮及其混合物)的共聚物、接枝共聚物和嵌段共聚物。
本发明的产品还可包含本领域技术人员已知的其他任选的洗衣成分，例如消泡剂、驱虫剂、pH缓冲剂、香料载体、水溶助剂、聚电解质、抗氧化剂、染料、着色剂、防晒剂、抗腐蚀剂和螯合剂。本发明的产品可包含珠光剂和/或遮光剂。
本发明所述的组合物是水性组合物并且包含水。
粘度
辅助洗衣组合物的粘度优选为20-15000mPa.s，更优选50-15000mPa.s，最优选100-10000mPa.s。该粘度提供了洗衣液将辅助洗衣组合物带入洗衣过程的益处。
在整个说明书中，粘度测量是在DHR-2流变仪(来自TA仪器)上使用4cm直径2°锥板几何形状于25℃进行的。
具体而言，所有测量均使用带有4cm直径2度角锥板测量系统的TA-InstrumentsDHR-2流变仪进行。下部Peltier板用于将测量温度控制在25℃。测量方案是一个“流动曲线”，其中施加的剪切应力从0.01Pa到400Pa以对数方式变化，每十倍应力有10个测量点。在每个应力下，在施加应力的10秒期间的最后5秒内测量剪切应变速率，在该应力下的粘度计算为剪切应力和剪切速率的商。
对于那些在大剪切应力范围至少到1Pa表现出低剪切粘度平台的体系，特征粘度被认为是在0.3Pa的剪切应力下的粘度。对于那些粘度响应是由低剪切应力引起的剪切稀化的系统，特征粘度被视为剪切速率为21s-1时的粘度。
优选地，辅助洗衣组合物漂浮在与其一起使用的洗衣液上。漂浮是指辅助洗衣组合物将在洗衣液表面保留至少5分钟、优选10分钟和最优选至少15分钟的时间。漂浮提供了洗衣液将辅助洗衣组合物带入洗衣过程的益处。
为了使辅助洗衣组合物能够漂浮，其密度不必低于与其一起使用的洗衣液的密度，但是优选的是辅助洗衣组合物的密度小于与其一起使用的洗衣液.该密度提供了洗衣液将辅助洗衣组合物带入洗衣过程的益处。
辅助洗衣组合物优选不与与其一起使用的洗衣液混溶。不可容性防止辅助洗衣组合物和洗衣液混合并确保最大性能。
多洗
本发明所述的辅助洗衣组合物设计用于多次连续洗涤。使用本发明所述的辅助洗衣组合物的益处可以在多次洗涤中累积。特别地，5次或更多次洗涤，优选10次或更多次洗涤，更优选15次或更多次洗涤并且最优选20次或更多次洗涤。
方法
除了织物调理剂制剂之外，还打算使用辅助洗衣组合物。织物调理剂是指设计用于在洗衣过程的漂洗阶段软化织物的制剂。织物调理剂组合物通常包含2-25重量％的织物柔软活性剂。优选的织物柔软活性剂是季铵表面活性剂。
在本发明的一个方面，提供了一种在洗衣周期的漂洗阶段将酶递送至织物的方法，其中除了织物调理剂制剂之外，还将本文所述的辅助洗衣组合物添加到漂洗中。
添加至所述漂洗中是指在洗衣过程的漂洗阶段将制剂添加至漂洗液中。
在本发明的另一方面，提供了一种改善织物调理剂的软化益处的方法，其中除了织物调理剂制剂之外，还将本文所述的辅助洗衣组合物添加至漂洗中。
上述任一方法的优选方法包括：
a.将织物调理剂制剂倒入洗涤容器、洗衣机抽屉或加料梭中
b.将本文所述的辅助洗衣组合物倒在洗衣产品的顶部上。
洗涤容器是指在其中进行洗涤的任何容器。这可以是例如前装式或顶装式洗衣机的滚筒或在其中执行手洗的碗/水槽。抽屉是指洗衣机抽屉中的任何一个隔室。加料球是指任何形式的容器，其通常容纳衣物洗涤剂组合物并直接放置在洗衣机中。
优选地，将织物调理剂倒入洗衣机抽屉或加料球中，然后将辅助洗衣组合物倒入抽屉或加料球中的洗衣产品顶部。将辅助洗衣组合物倒在洗衣产品顶部上提供的益处是织物调理剂将辅助洗衣组合物带入洗涤或漂洗中而不与两种组合物混合。
尽管本文所述的辅助漂洗组合物的主要目的是用于洗涤的漂洗阶段，但除了织物调理制剂之外，其还可以用于洗衣过程的主洗涤阶段。辅助洗衣组合物可用于将酶递送至织物的方法中，其中将辅助洗衣组合物添加至主洗涤中，然后在漂洗中添加至织物调理剂制剂中。这将提供一种改善织物调理剂的软化益处的方法，其中将辅助洗衣组合物添加至主洗涤中，然后在漂洗中添加织物调理剂制剂。
优选地，将辅助洗衣组合物以2-50ml、优选2-30ml、最优选2-20ml的体积添加至洗衣过程中。该剂量通常用于4-8kg装载量的织物，优选5-6kg装载量的织物负载。
用途
在本发明的一个实施方式中，提供了本文所述的辅助洗衣组合物在洗衣周期的漂洗阶段将酶递送至织物的用途。
在本发明的另一个实施方式中，提供了本文所述的辅助洗衣组合物改善织物调理剂的软化益处的用途。改善的软化可以通过小组测试或通过合适的设备来测量。
示例组合物
表1：本发明的示例组合物
| 成分 | 1(重量％) | 2(重量％) |
| 非离子表面活性剂<sup>1</sup> | 3 | 5 |
| 纤维素酶 | 0.0001 | 0.1 |
| 游离香料 | 10 | 8 |
| 包封香料 | - | 4 |
| 水 | 至100 | 至100 |
非离子表面活性剂1-Eumulgin CO40，来自BASF。
这些组合物提供了改善的软化。
Claims (11)
1.一种漂洗添加的辅助洗衣组合物，其用于改善织物调理剂的软化效果，所述辅助洗衣组合物包含：
a.纤维素酶；
b.0.5-12重量％的非离子表面活性剂；
c.0.5至20重量％的游离香料；和
d.水；
其中所述组合物包含小于2重量％的阴离子和/或阳离子表面活性剂。
2.根据权利要求1所述的辅助洗衣组合物，其中所述组合物进一步包含0.1至20重量％的包封香料。
3.根据前述权利要求中任一项所述的辅助洗衣组合物，其中所述非离子表面活性剂包含乙氧基化的非离子表面活性剂。
4.根据前述权利要求中任一项所述的辅助洗衣组合物，其中所述组合物进一步包含结构化剂。
5.根据前述权利要求中任一项所述的辅助洗衣组合物，其中所述辅助洗衣组合物的粘度是20-15000mPa.s。
6.一种在洗衣周期的漂洗阶段将酶递送至织物的方法，其中除了织物调理剂制剂之外，将根据权利要求1至6所述的辅助洗衣组合物添加至漂洗中。
7.一种改善织物调理剂的软化益处的方法，其中除了织物调理剂制剂之外，将根据权利要求1至6所述的辅助洗衣组合物添加至漂洗中。
8.一种在洗衣周期的洗涤阶段将酶递送至织物的方法，其中将根据权利要求1至6所述的辅助洗衣组合物添加至洗衣过程的洗涤阶段，然后在漂洗中添加织物调理剂制剂。
9.一种改善织物调理剂的软化益处的方法，其中将根据权利要求1至6所述的辅助洗衣组合物添加至洗衣过程的洗涤阶段，然后在漂洗中添加织物调理剂制剂。
10.根据权利要求1至6所述的辅助洗衣组合物在洗衣周期的漂洗阶段将酶递送至织物的用途。
11.根据权利要求1至6所述的辅助洗衣组合物改善织物调理剂的软化益处的用途。
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| WO2024028160A1 (en) * | 2022-08-04 | 2024-02-08 | Unilever Ip Holdings B.V. | Packaged homecare product |
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| US20220195337A1 (en) | 2022-06-23 |
| WO2020229535A1 (en) | 2020-11-19 |
| EP3969556A1 (en) | 2022-03-23 |
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