JP5268087B2 - 超臨界条件におけるポリマー製造 - Google Patents
超臨界条件におけるポリマー製造 Download PDFInfo
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- JP5268087B2 JP5268087B2 JP2007520528A JP2007520528A JP5268087B2 JP 5268087 B2 JP5268087 B2 JP 5268087B2 JP 2007520528 A JP2007520528 A JP 2007520528A JP 2007520528 A JP2007520528 A JP 2007520528A JP 5268087 B2 JP5268087 B2 JP 5268087B2
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- methyl
- hydrogen
- polymer
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- 229920000642 polymer Polymers 0.000 title claims description 217
- 238000004519 manufacturing process Methods 0.000 title claims description 38
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 158
- 239000000178 monomer Substances 0.000 claims description 156
- 238000000034 method Methods 0.000 claims description 152
- 239000003054 catalyst Substances 0.000 claims description 149
- 229910052739 hydrogen Inorganic materials 0.000 claims description 140
- 239000001257 hydrogen Substances 0.000 claims description 138
- 238000006116 polymerization reaction Methods 0.000 claims description 132
- 239000000203 mixture Substances 0.000 claims description 117
- 230000008569 process Effects 0.000 claims description 116
- 150000001875 compounds Chemical class 0.000 claims description 104
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 99
- 150000001336 alkenes Chemical class 0.000 claims description 98
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- 125000000524 functional group Chemical group 0.000 claims description 79
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 54
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- 230000000379 polymerizing effect Effects 0.000 claims description 8
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 8
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- 125000002091 cationic group Chemical group 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 4
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- UTLQFNPZWCRAIP-UHFFFAOYSA-N 3-(diethylamino)propyl 2-phenylheptanoate;hydrochloride Chemical compound [Cl-].CC[NH+](CC)CCCOC(=O)C(CCCCC)C1=CC=CC=C1 UTLQFNPZWCRAIP-UHFFFAOYSA-N 0.000 claims description 3
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| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
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| US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| US20090203041A1 (en) * | 2006-04-21 | 2009-08-13 | Wei Shi | Bmp4 inhibitors |
| EP1921200A3 (en) * | 2006-11-08 | 2010-07-21 | LG Electronics Inc. | Exhaust structure for clothes dryer in apartment building |
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| CN101679556B (zh) * | 2007-06-04 | 2012-06-06 | 埃克森美孚化学专利公司 | 超溶液均相丙烯聚合 |
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| US6444833B1 (en) | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| US6562920B2 (en) | 1999-12-20 | 2003-05-13 | Exxonmobil Chemical Patents Inc. | Processes for the preparation polyolefin resins using supported ionic catalysts |
| KR100374154B1 (ko) | 2000-06-24 | 2003-02-26 | 장학선 | 전원신호 및 데이터신호를 송수신하기 위한 시스템 |
| EP1195391A1 (en) | 2000-10-05 | 2002-04-10 | ATOFINA Research | Production of polypropylene |
| ATE337341T1 (de) * | 2000-10-25 | 2006-09-15 | Exxonmobil Chem Patents Inc | Verfahren und vorrichtung zur kontinuierlichen lösungspolymerisation |
| JP2004514775A (ja) * | 2000-11-30 | 2004-05-20 | エクソンモービル・ケミカル・パテンツ・インク | 精密射出成形用ポリプロピレンポリマー |
| JP3678726B2 (ja) * | 2000-12-04 | 2005-08-03 | ユニベーション・テクノロジーズ・エルエルシー | 重合方法 |
| WO2002050145A1 (en) | 2000-12-20 | 2002-06-27 | Exxonmobil Chemical Patents Inc. | Olefin polymerization process to produce branched polymer compositions |
| WO2002083753A1 (en) | 2001-04-12 | 2002-10-24 | Exxonmobil Chemical Patents Inc. | Propylene ethylene copolymers |
| GB0111020D0 (en) | 2001-05-04 | 2001-06-27 | Borealis Tech Oy | Process |
| EP1546223A2 (en) * | 2002-09-20 | 2005-06-29 | ExxonMobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| ES2394304T3 (es) * | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| AU2003284027A1 (en) * | 2002-10-24 | 2004-05-13 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| JP4758650B2 (ja) * | 2002-12-04 | 2011-08-31 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンポリマーの製造方法 |
| EP1774485B1 (en) * | 2004-07-08 | 2016-05-04 | ExxonMobil Chemical Patents Inc. | Polymer production at supercritical conditions |
-
2005
- 2005-07-08 EP EP05769521.5A patent/EP1774485B1/en not_active Expired - Lifetime
- 2005-07-08 US US11/178,147 patent/US7601666B2/en active Active
- 2005-07-08 CA CA002576840A patent/CA2576840A1/en not_active Abandoned
- 2005-07-08 WO PCT/US2005/024240 patent/WO2006025949A2/en not_active Ceased
- 2005-07-08 WO PCT/US2005/024708 patent/WO2006010139A2/en not_active Ceased
- 2005-07-08 DE DE602005010255T patent/DE602005010255D1/de not_active Expired - Lifetime
- 2005-07-08 BR BRPI0513057-3A patent/BRPI0513057A/pt not_active IP Right Cessation
- 2005-07-08 JP JP2007520528A patent/JP5268087B2/ja not_active Expired - Fee Related
- 2005-07-08 JP JP2007520591A patent/JP4988568B2/ja not_active Expired - Fee Related
- 2005-07-08 CN CN2005800297572A patent/CN101010705B/zh not_active Expired - Fee Related
- 2005-07-08 CN CN2005800250909A patent/CN101124235B/zh not_active Expired - Fee Related
- 2005-07-08 KR KR1020077002106A patent/KR20070039930A/ko not_active Ceased
- 2005-07-08 EP EP05771412A patent/EP1765841B1/en not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20070039930A (ko) | 2007-04-13 |
| DE602005010255D1 (de) | 2008-11-20 |
| JP2008505932A (ja) | 2008-02-28 |
| CN101010705B (zh) | 2011-03-23 |
| BRPI0513057A (pt) | 2008-04-22 |
| EP1774485B1 (en) | 2016-05-04 |
| JP2008506018A (ja) | 2008-02-28 |
| WO2006025949A2 (en) | 2006-03-09 |
| WO2006010139A3 (en) | 2006-03-16 |
| EP1765841B1 (en) | 2008-10-08 |
| CN101124235A (zh) | 2008-02-13 |
| EP1765841A2 (en) | 2007-03-28 |
| US7279536B2 (en) | 2007-10-09 |
| US7601666B2 (en) | 2009-10-13 |
| US20060293474A1 (en) | 2006-12-28 |
| CN101010705A (zh) | 2007-08-01 |
| WO2006010139A2 (en) | 2006-01-26 |
| CA2576840A1 (en) | 2006-03-09 |
| CN101124235B (zh) | 2010-12-15 |
| JP4988568B2 (ja) | 2012-08-01 |
| WO2006025949A3 (en) | 2006-08-31 |
| EP1774485A2 (en) | 2007-04-18 |
| US20060009595A1 (en) | 2006-01-12 |
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