CN101010705B - 在超临界条件下生产聚合物 - Google Patents

在超临界条件下生产聚合物 Download PDF

Info

Publication number
CN101010705B
CN101010705B CN2005800297572A CN200580029757A CN101010705B CN 101010705 B CN101010705 B CN 101010705B CN 2005800297572 A CN2005800297572 A CN 2005800297572A CN 200580029757 A CN200580029757 A CN 200580029757A CN 101010705 B CN101010705 B CN 101010705B
Authority
CN
China
Prior art keywords
preferred
methyl
boric acid
hydrogen
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2005800297572A
Other languages
English (en)
Chinese (zh)
Other versions
CN101010705A (zh
Inventor
P·布兰特
F·C·里克斯
G·奇斯
R·P·雷诺兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN101010705A publication Critical patent/CN101010705A/zh
Application granted granted Critical
Publication of CN101010705B publication Critical patent/CN101010705B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2005800297572A 2004-07-08 2005-07-08 在超临界条件下生产聚合物 Expired - Fee Related CN101010705B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US58646504P 2004-07-08 2004-07-08
US60/586,465 2004-07-08
PCT/US2005/024240 WO2006025949A2 (en) 2004-07-08 2005-07-08 Polymer production at supercritical conditions

Publications (2)

Publication Number Publication Date
CN101010705A CN101010705A (zh) 2007-08-01
CN101010705B true CN101010705B (zh) 2011-03-23

Family

ID=34956137

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2005800297572A Expired - Fee Related CN101010705B (zh) 2004-07-08 2005-07-08 在超临界条件下生产聚合物
CN2005800250909A Expired - Fee Related CN101124235B (zh) 2004-07-08 2005-07-08 烯烃聚合催化剂体系及其使用方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2005800250909A Expired - Fee Related CN101124235B (zh) 2004-07-08 2005-07-08 烯烃聚合催化剂体系及其使用方法

Country Status (9)

Country Link
US (2) US7601666B2 (enExample)
EP (2) EP1774485B1 (enExample)
JP (2) JP5268087B2 (enExample)
KR (1) KR20070039930A (enExample)
CN (2) CN101010705B (enExample)
BR (1) BRPI0513057A (enExample)
CA (1) CA2576840A1 (enExample)
DE (1) DE602005010255D1 (enExample)
WO (2) WO2006025949A2 (enExample)

Families Citing this family (116)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0205455D0 (en) 2002-03-07 2002-04-24 Molecular Sensing Plc Nucleic acid probes, their synthesis and use
EP1546223A2 (en) * 2002-09-20 2005-06-29 ExxonMobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
US7807769B2 (en) * 2002-09-20 2010-10-05 Exxonmobil Chemical Patents Inc. Isotactic polypropylene produced from supercritical polymerization process
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US6877246B1 (en) * 2003-12-30 2005-04-12 Kimberly-Clark Worldwide, Inc. Through-air dryer assembly
EP1774485B1 (en) * 2004-07-08 2016-05-04 ExxonMobil Chemical Patents Inc. Polymer production at supercritical conditions
US8022142B2 (en) * 2008-12-15 2011-09-20 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
US20090203041A1 (en) * 2006-04-21 2009-08-13 Wei Shi Bmp4 inhibitors
EP1921200A3 (en) * 2006-11-08 2010-07-21 LG Electronics Inc. Exhaust structure for clothes dryer in apartment building
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) * 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
CN101595137B (zh) * 2006-12-20 2012-03-28 埃克森美孚化学专利公司 在超临界条件下的聚合物制备
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
US8080610B2 (en) * 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
CN101679556B (zh) * 2007-06-04 2012-06-06 埃克森美孚化学专利公司 超溶液均相丙烯聚合
EP2195349B1 (en) * 2007-09-13 2012-07-11 ExxonMobil Research and Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
WO2009035579A1 (en) * 2007-09-13 2009-03-19 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
US7868104B2 (en) 2007-10-26 2011-01-11 Exxonmobil Chemical Patents Inc. Crystallizable propylene copolymers
EP2070953A1 (en) 2007-12-11 2009-06-17 Total Petrochemicals Research Feluy Activating supports based on phosphonium complexes
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
CN101945942B (zh) * 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
CN101945940B (zh) * 2007-12-20 2014-04-09 埃克森美孚研究工程公司 聚丙烯乙烯-丙烯共聚物共混物和生产它的在线方法
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US8067512B2 (en) 2008-04-10 2011-11-29 Exxonmobil Research And Engineering Company Monomer/solvent separation and recycle process for propylene containing polymers
US7939610B2 (en) 2008-05-22 2011-05-10 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US8580902B2 (en) * 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US8399586B2 (en) 2008-09-05 2013-03-19 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
US8710148B2 (en) 2011-12-02 2014-04-29 Exxonmobil Chemical Patents Inc. Polymer compositions and nonwoven compositions prepared therefrom
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
US8664129B2 (en) 2008-11-14 2014-03-04 Exxonmobil Chemical Patents Inc. Extensible nonwoven facing layer for elastic multilayer fabrics
US9168718B2 (en) * 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
CN101721277A (zh) * 2008-10-22 2010-06-09 3M创新有限公司 医用胶带及由其制成的医用制品
JP5650138B2 (ja) 2009-02-27 2015-01-07 エクソンモービル・ケミカル・パテンツ・インク 多層不織ｉｎ ｓｉｔｕラミネートおよびその製造方法
EP2738182A1 (en) 2009-07-16 2014-06-04 Dow Global Technologies LLC Polymerization process for olefin-based polymers
US8602103B2 (en) * 2009-11-24 2013-12-10 Conocophillips Company Generation of fluid for hydrocarbon recovery
US8668975B2 (en) 2009-11-24 2014-03-11 Exxonmobil Chemical Patents Inc. Fabric with discrete elastic and plastic regions and method for making same
CA2789948C (en) 2010-02-19 2014-10-14 Exxonmobil Chemical Patents Inc. Elastomeric polymer blends and processes for their production
WO2011157278A1 (en) * 2010-06-18 2011-12-22 Coloplast A/S A permeable pressure sensitive adhesive
US8383848B2 (en) 2010-06-29 2013-02-26 Sumitomo Chemical Company, Limited Transition metal compound and catalyst for olefin polymerization
WO2012096698A2 (en) * 2010-10-21 2012-07-19 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
WO2012064468A2 (en) 2010-11-09 2012-05-18 Exxonmobil Chemical Patents Inc. Meltblown nonwoven compositions and methods for making them
CN103201416B (zh) 2010-11-09 2016-07-06 埃克森美孚化学专利公司 双组分纤维及其制造方法
EP2495264B1 (en) * 2011-03-04 2013-05-08 Borealis AG Exterior automotive article with reduced paintability failure
US20140323665A1 (en) 2011-03-30 2014-10-30 Exxonmobil Chemical Patents Inc. Polyalphaolefins by Oligomerization and Isomerization
CN103596686B (zh) * 2011-06-08 2015-08-12 埃克森美孚化学专利公司 包含多种非配位阴离子化活化剂的催化剂体系以及使用其的聚合方法
US8658556B2 (en) 2011-06-08 2014-02-25 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
US9260635B2 (en) 2011-06-17 2016-02-16 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and methods for preparing the same
KR101564159B1 (ko) 2011-06-17 2015-10-28 엑손모빌 케미칼 패턴츠 인코포레이티드 반결정성 중합체의 냉각 및 펠렛화 방법
CN103635619B (zh) 2011-06-21 2017-02-22 埃克森美孚化学专利公司 包含基于丙烯和基于乙烯的聚合物的弹性非织造材料
US10059081B2 (en) 2011-12-22 2018-08-28 Exxonmobil Chemical Patents Inc. Fibers and nonwoven materials prepared therefrom
ES2681494T3 (es) 2012-03-09 2018-09-13 Exxonmobil Chemical Patents Inc. Composiciones adhesivas poliolefínicas y métodos de preparación de las mismas
US9238763B2 (en) 2013-10-18 2016-01-19 Exxonmobil Chemical Patents Inc. Tackified polyolefin adhesive compositions
CN103665217B (zh) * 2012-09-21 2016-02-24 中国石油化工股份有限公司 一种连续聚合方法
US9434795B2 (en) 2012-09-24 2016-09-06 Exxonmobil Chemical Patents Inc. Production of vinyl terminated polyethylene using supported catalyst system
WO2014047538A1 (en) * 2012-09-24 2014-03-27 Exxonmobil Chemical Patents Inc. Production of vinyl terminated polyethylene using supported catalyst system
US9376512B2 (en) * 2012-09-24 2016-06-28 Exxonmobil Chemical Patents Inc. Production of vinyl terminated polyethylene
WO2014070655A1 (en) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems and methods of preparation thereof
US11549201B2 (en) 2013-06-18 2023-01-10 Exxonmobil Chemicals Patents Inc. Fibers and nonwoven materials prepared therefrom
US11214036B2 (en) 2013-06-18 2022-01-04 Exxonmobil Chemical Patents Inc. Fibers and nonwoven materials prepared therefrom
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US9553867B2 (en) * 2013-08-01 2017-01-24 Bitglass, Inc. Secure application access system
US9376518B2 (en) 2013-08-28 2016-06-28 Exxonmobil Chemical Patents Inc. Racemo selective metallation process
US10442962B2 (en) 2013-10-18 2019-10-15 Exxonmobil Chemical Patents Inc. High polymer load polyolefin adhesive compositions
CA3206038A1 (en) 2014-02-11 2015-08-20 Univation Technologies, Llc Producing polyolefin products
EP3124505B1 (en) * 2014-03-28 2025-03-19 Mitsui Chemicals, Inc. Ethylene/alpha-olefin copolymer and lubricating oil
US20170073556A1 (en) 2014-04-22 2017-03-16 Exxonmobil Chemical Patents Inc. Hydrocarbon Tackifiers for Adhesive Compositions
WO2015164016A1 (en) 2014-04-22 2015-10-29 Exxonmobil Chemical Patents Inc. Adhesive compositions for nonwoven applications
US10106676B2 (en) 2014-06-10 2018-10-23 Exxonmobil Chemical Patents Inc. Propylene-based polymers having improved stability and methods for producing the same
WO2016036466A2 (en) 2014-09-05 2016-03-10 Exxomobil Chemical Patents Inc. Polymer compositions and nonwoven materials prepared therefrom
WO2016069089A1 (en) 2014-10-29 2016-05-06 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions for elastic applications
EP3029101B1 (en) 2014-12-04 2017-02-15 ExxonMobil Chemical Patents Inc. Multi-modal polymer blend, hot melt adhesive comprising same and use thereof
WO2016099666A1 (en) 2014-12-19 2016-06-23 Exxonmobil Chemical Patents Inc. Adhesive compositions made from propylene-based polymers for elastic attachments
CN107109000B (zh) 2014-12-19 2021-04-27 埃克森美孚化学专利公司 由含有基于丙烯的聚合物的共混物制造的热活化的织物
WO2016114855A1 (en) 2015-01-14 2016-07-21 Exxonmobil Chemical Patents Inc. Adhesive compositions made from propylene-based polymers and crystalline c2/c3 homopolymer
CN105047295A (zh) * 2015-07-02 2015-11-11 傅宇晓 耐酸碱工业用电缆
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
CN106845796B (zh) * 2016-12-28 2018-04-13 中南大学 一种加氢裂化流程产品质量在线预测方法
JP6921563B2 (ja) * 2017-03-07 2021-08-18 出光興産株式会社 遷移金属化合物及びオレフィン系重合体の製造方法
CN111225927A (zh) * 2017-10-25 2020-06-02 埃克森美孚化学专利公司 非桥连的引达省基茂金属
US11001657B2 (en) 2017-10-25 2021-05-11 Exxonmobil Chemical Patents Inc. Unbridged indacenyl metallocenes
US11525041B2 (en) 2018-06-15 2022-12-13 Exxonmobil Chemicals Patents Inc. Process for producing polymers
EP3844329B1 (en) 2018-08-30 2025-01-01 ExxonMobil Chemical Patents Inc. Bicomponent polymeric fibers
SG11202105884XA (en) * 2018-12-14 2021-07-29 Dow Global Technologies Llc Solution polymerization process
WO2020131311A1 (en) 2018-12-18 2020-06-25 Exxonmobil Research And Engineering Company Modified asphalts and methods for producing the same
US12031091B2 (en) 2019-05-24 2024-07-09 Eastman Chemical Company Recycle content cracked effluent
CN113993977B (zh) 2019-05-24 2024-09-13 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
US12338211B2 (en) 2019-07-29 2025-06-24 Eastman Chemical Company Recycle content (C4)alkanal
WO2021025903A1 (en) * 2019-08-02 2021-02-11 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators for use with polyolefin polymerization catalysts
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
CN114641555A (zh) 2019-10-31 2022-06-17 伊士曼化工公司 用于回收废物的热解方法和系统
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
CN114641465B (zh) 2019-11-07 2024-12-31 伊士曼化工公司 回收成分混合酯和溶剂
CN114650981A (zh) 2019-11-07 2022-06-21 伊士曼化工公司 回收成分α烯烃和脂肪醇
CN115315452A (zh) * 2020-02-11 2022-11-08 埃克森美孚化学专利公司 使用过渡金属双(酚盐)催化剂络合物获得的丙烯聚合物及生产该丙烯聚合物的均相方法
US20230192958A1 (en) * 2020-05-22 2023-06-22 Kureha Corporation Polyarylene sulfide production method
CN113337311A (zh) * 2021-04-16 2021-09-03 华东理工大学 一种超高粘度指数聚α-烯烃基础油及其制备方法和应用
CN113046130B (zh) * 2021-04-16 2023-04-04 华东理工大学 一种窄分布、低粘度和高粘度指数的pao基础油及其制备方法
CN115232236B (zh) * 2021-04-25 2024-05-07 中国石油化工股份有限公司 一种丙烯基共聚物及其制备方法和应用和聚丙烯组合物
TW202309112A (zh) * 2021-04-25 2023-03-01 大陸商中國石油化工科技開發有限公司 丙烯基共聚物、其製備方法和用途和包含其的聚丙烯組合物
US12398338B2 (en) * 2021-07-20 2025-08-26 Mitsui Chemicals, Inc. Viscosity modifier for lubricating oil and lubricating oil composition for hydraulic fluid
US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic
KR20230069618A (ko) * 2021-11-12 2023-05-19 주식회사 에스피씨아이 초고분자량 폴리올레핀 중합용 메탈로센 화합물 및 이를 이용한 초고분자량 폴리올레핀 중합체의 제조방법
CN116284530B (zh) * 2023-03-17 2024-06-07 山东京博中聚新材料有限公司 一种丁基橡胶的制备方法和应用
WO2024242949A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Polyethylenes having improved processability and films thereof
WO2024242936A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
WO2024242933A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
WO2024242931A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts, polyethylenes, polymerizations thereof, and films thereof
WO2024242929A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Low density polethylenes, films thereof, and methods and catalysts for production thereof
WO2024242932A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Polethylenes, catalysts for their polymerization, and films thereof
CN119467169A (zh) * 2024-11-22 2025-02-18 中国船舶集团有限公司第七一一研究所 一种船用甲醇燃料调控系统和方法
CN119795714B (zh) * 2024-12-18 2025-10-17 黄山永新股份有限公司 一种具有稳定摩擦系数的聚乙烯薄膜及其制备方法和应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1231678A (zh) * 1996-09-24 1999-10-13 埃克森化学专利公司 制备载体上的金属茂催化剂体系的改进方法

Family Cites Families (129)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE420895A (enExample) * 1936-02-04 1900-01-01
US2852501A (en) * 1954-10-05 1958-09-16 Monsanto Chemicals Polymerization of ethylene
US3725378A (en) * 1958-12-17 1973-04-03 Monsanto Co Polymerization of ethylene
US3294772A (en) * 1963-06-17 1966-12-27 Phillips Petroleum Co Supercritical polymerization
US4153774A (en) * 1976-02-17 1979-05-08 Basf Aktiengesellschaft Manufacture of high pressure polyethylene
US4135044A (en) * 1977-08-08 1979-01-16 Exxon Research & Engineering Co. Process for achieving high conversions in the production of polyethylene
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
IN172494B (enExample) 1986-12-19 1993-09-04 Exxon Chemical Patents Inc
ES2018182B3 (enExample) * 1986-03-24 1991-04-01
DE3615563A1 (de) * 1986-05-09 1987-11-12 Basf Ag Verfahren zur herstellung von copolymerisaten des ethylens mit vinylestern in einem roehrenreaktor bei druecken oberhalb 500 bar
US4740550A (en) * 1986-06-18 1988-04-26 Shell Oil Company Multistage copolymerization process
US5543394A (en) * 1986-07-01 1996-08-06 Genetics Institute, Inc. Bone morphogenetic protein 5(BMP-5) compositions
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
CA1284549C (en) 1986-09-26 1991-05-28 Fathi David Hussein Process for the polymerization of propylene
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
JPH0216916A (ja) 1988-07-01 1990-01-19 Iseki & Co Ltd 普通型コンバイン
US5382630A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution
US5382631A (en) * 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
DE3904468A1 (de) * 1989-02-15 1990-08-16 Hoechst Ag Polypropylenwachs und verfahren zu seiner herstellung
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5504169A (en) * 1989-09-13 1996-04-02 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5036034A (en) * 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
US5324799A (en) 1990-03-06 1994-06-28 Akihiro Yano Polyethylene and process of production thereof
AU7875791A (en) * 1990-05-07 1991-11-27 Exxon Chemical Patents Inc. Unsaturated alpha-olefin copolymers and method for preparation thereof
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
DE4030379A1 (de) 1990-09-26 1992-04-02 Basf Ag Polymerwachse des propylens mit hoher haerte und kristallinitaet
FI89929C (fi) * 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
FI86867C (fi) * 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
DE4130299A1 (de) * 1991-09-12 1993-03-18 Basf Ag Verfahren zur herstellung von polypropylen unter hochdruck
JPH0625357A (ja) 1991-10-23 1994-02-01 Mitsui Toatsu Chem Inc 新規なプロピレン系共重合体およびその製造方法
TW309523B (enExample) 1991-11-30 1997-07-01 Hoechst Ag
GB9125934D0 (en) * 1991-12-05 1992-02-05 Exxon Chemical Patents Inc Process for polymerising olefinic feeds under pressure
EP0552945B1 (en) * 1992-01-23 1997-05-07 Mitsui Petrochemical Industries, Ltd. Process for the preparation of polyolefin
TW285680B (enExample) * 1992-03-31 1996-09-11 Hoechst Ag
EP0571882B1 (de) * 1992-05-26 1997-03-12 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinwachsen
TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag
ATE165832T1 (de) * 1992-08-03 1998-05-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
TW303368B (enExample) 1992-08-08 1997-04-21 Hoechst Ag
US5608009A (en) 1992-10-28 1997-03-04 Idemitsu Kosan Co., Ltd. Olefin copolymer and process for preparing same
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
JPH0790035A (ja) 1993-07-27 1995-04-04 Ube Ind Ltd プロピレンブロック共重合体の製造方法
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
ES2154664T3 (es) * 1993-11-24 2001-04-16 Targor Gmbh Metalocenos, procedimientos para su obtencion, y su empleo como catalizadores.
NO178790C (no) * 1993-12-13 1996-06-05 Borealis Holding As Fremgangsmåte ved fremstilling av olefinpolymerer i en autoklavrektor
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
EP0766704B1 (en) 1994-06-24 1998-12-23 Exxon Chemical Patents Inc. Polymerization process and catalyst systems useful therein
US5552489A (en) * 1994-07-22 1996-09-03 Exxon Chemical Patents Inc. Tackifiers and a process to obtain tackifiers
US6143686A (en) 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
US6300451B1 (en) 1994-10-24 2001-10-09 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
CA2162946C (en) 1994-11-21 2004-01-06 Kazuyuki Watanabe Propylene block copolymer and process for producing the same
FI96216C (fi) 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
TW383314B (en) 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
JPH08208535A (ja) 1995-02-03 1996-08-13 Mitsui Toatsu Chem Inc アルキルベンゼンの製造方法
FI951970A7 (fi) 1995-04-25 1996-10-26 Borealis As Olefiinipolymeerit, jotka sisältävät polaarisia ryhmiä, ja menetelmä niiden valmistamiseksi
US6143682A (en) * 1995-06-07 2000-11-07 Exxon Chemical Patents Inc. Bimetallocyclic transition metal catalyst systems
US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
SE504455C2 (sv) 1995-07-10 1997-02-17 Borealis Polymers Oy Kabelmantlingskomposition, dess användning samt sätt för dess framställning
FI954475A7 (fi) 1995-09-21 1997-03-22 Neste Oy Olefiinipolymeerit, jotka sisältävät polaarisia ryhmiä, ja menetelmä niiden valmistamiseksi
DE69606188T2 (de) 1995-10-10 2000-06-08 Borealis A/S, Lyngby Verfahren zur herstellung von propylen homo- oder copolymeren
FI105820B (fi) * 1995-10-10 2000-10-13 Borealis Tech Oy Prosessi propeenin homo- tai kopolymeerien valmistamiseksi
EP0868440B1 (de) * 1995-10-14 2001-12-12 Basell Polyolefine GmbH Verfahren zur herstellung von ethylen-copolymerisaten unter hochdruck
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
IT1283630B1 (it) 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
FI102476B (fi) 1996-05-31 1998-12-15 Borealis As Uudet siirtymämetallikompleksit ja menetelmä niiden valmistamiseksi
HU223533B1 (hu) * 1996-06-17 2004-08-30 Exxonmobil Chemical Patents Inc. Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására
EP0906344B2 (en) 1996-06-17 2009-02-18 ExxonMobil Chemical Patents Inc. Elevated pressure polymerization processes with late transition metal catalyst systems
ATE276263T1 (de) 1996-08-08 2004-10-15 Dow Global Technologies Inc Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren
US6583227B2 (en) * 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
US6576306B2 (en) 1996-09-04 2003-06-10 Exxonmobil Chemical Patents Inc. Propylene polymers for films
JP3421202B2 (ja) 1996-10-09 2003-06-30 三菱化学株式会社 プロピレンの重合方法及びそれを用いて得られるプロピレン系重合体
ATE199025T1 (de) 1996-11-07 2001-02-15 Oklahoma Med Res Found Test zur diagnose eines erhöhten brustkrebs- risikos
DE19648895A1 (de) * 1996-11-26 1998-05-28 Clariant Gmbh Polar modifizierte Polypropylen-Wachse
EP1312619B1 (en) 1996-12-09 2007-11-14 Mitsubishi Chemical Corporation Catalyst for the polymerisation of alpha olefins
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
WO1998033823A1 (en) 1997-02-05 1998-08-06 The Penn State Research Foundation METAL CATALYZED SYNTHESIS OF HYPERBRANCHED ETHYLENE AND/OR α-OLEFIN POLYMERS
EP0977808B1 (en) 1997-04-29 2002-10-16 The Dow Chemical Company Amorphous propylene-polyene copolymers and compositions thereof
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
TW513442B (en) 1997-06-06 2002-12-11 Idemitsu Petrochemical Co Olefinic polymer
FI111847B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin kopolymeerien valmistamiseksi
FI972946L (fi) 1997-07-11 1999-01-12 Borealis As Uudet metalloseeniyhdisteet etyleenisesti tyydyttämätt"mien monomeerien polymeroimiseksi
US6525157B2 (en) 1997-08-12 2003-02-25 Exxonmobile Chemical Patents Inc. Propylene ethylene polymers
JP3846193B2 (ja) 1997-09-04 2006-11-15 チッソ株式会社 プロピレン系共重合体およびその製造方法
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
CA2311624A1 (en) 1997-12-19 1999-07-01 Phillips Petroleum Company Nickel diimine catalysts with methylalumoxane as cocatalyst, method of polymerization of olefins therewith and polymers produced
DE19804970A1 (de) 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
DE19808253A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
CN1133660C (zh) * 1998-03-04 2004-01-07 埃克森美孚化学专利公司 烯烃的高温聚合方法
ATE222913T1 (de) * 1998-03-11 2002-09-15 Dow Chemical Co Integriertes verfahren zur herstellung von dien- komplexen
US6225285B1 (en) * 1998-03-11 2001-05-01 Exelixis Pharmaceuticals, Inc. Semaphorin K1
DE19823168A1 (de) * 1998-05-23 1999-11-25 Aventis Res & Tech Gmbh & Co Katalysatorsystem
WO2000006621A1 (en) 1998-07-25 2000-02-10 Bp Chemicals Limited Alpha olefin-diene copolymers
CN1167718C (zh) * 1998-08-26 2004-09-22 埃克森美孚化学专利公司 支化聚丙烯组合物
KR100592621B1 (ko) * 1998-08-26 2006-06-23 엑손모빌 케미칼 패턴츠 인코포레이티드 고활성의 지지된 촉매 조성물
US6002648A (en) 1998-10-16 1999-12-14 Western Atlas International, Inc. Slotted cylinder marine siesmic method and source
US6158771A (en) 1998-10-23 2000-12-12 Hexcel Corporation Honeycomb crash pad
US6479424B1 (en) 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
CA2356667A1 (en) 1998-12-21 2000-06-29 Exxonmobil Chemical Patents Inc. Branched semi-crystalline ethylene-propylene compositions
JP2002534538A (ja) 1999-01-08 2002-10-15 ザ ボード オブ トラスティーズ オブ ザ リーランド スタンフォード ジュニア ユニバーシティ 狭い組成分布と高融点を有するエチレンコポリマーおよびその製法
US6469188B1 (en) 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
US6620896B1 (en) 1999-02-23 2003-09-16 Eastman Chemical Company Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom
FI990948A0 (fi) 1999-04-27 1999-04-27 Borealis As Ei-ristisilloitettu polyeteeni
EP1083183A1 (en) * 1999-09-10 2001-03-14 Fina Research S.A. Process for producing polyolefins
KR100746676B1 (ko) 1999-10-08 2007-08-06 미쓰이 가가쿠 가부시키가이샤 메탈로센 화합물, 메탈로센 화합물의 제조 방법, 올레핀 중합 촉매, 및 폴리올레핀의 제조 방법
US20020013440A1 (en) * 1999-12-10 2002-01-31 Agarwal Pawan Kumar Propylene diene copolymers
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
US6562920B2 (en) 1999-12-20 2003-05-13 Exxonmobil Chemical Patents Inc. Processes for the preparation polyolefin resins using supported ionic catalysts
KR100374154B1 (ko) 2000-06-24 2003-02-26 장학선 전원신호 및 데이터신호를 송수신하기 위한 시스템
EP1195391A1 (en) 2000-10-05 2002-04-10 ATOFINA Research Production of polypropylene
ATE337341T1 (de) * 2000-10-25 2006-09-15 Exxonmobil Chem Patents Inc Verfahren und vorrichtung zur kontinuierlichen lösungspolymerisation
JP2004514775A (ja) * 2000-11-30 2004-05-20 エクソンモービル・ケミカル・パテンツ・インク 精密射出成形用ポリプロピレンポリマー
JP3678726B2 (ja) * 2000-12-04 2005-08-03 ユニベーション・テクノロジーズ・エルエルシー 重合方法
WO2002050145A1 (en) 2000-12-20 2002-06-27 Exxonmobil Chemical Patents Inc. Olefin polymerization process to produce branched polymer compositions
WO2002083753A1 (en) 2001-04-12 2002-10-24 Exxonmobil Chemical Patents Inc. Propylene ethylene copolymers
GB0111020D0 (en) 2001-05-04 2001-06-27 Borealis Tech Oy Process
EP1546223A2 (en) * 2002-09-20 2005-06-29 ExxonMobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
ES2394304T3 (es) * 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
AU2003284027A1 (en) * 2002-10-24 2004-05-13 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
JP4758650B2 (ja) * 2002-12-04 2011-08-31 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテンポリマーの製造方法
EP1774485B1 (en) * 2004-07-08 2016-05-04 ExxonMobil Chemical Patents Inc. Polymer production at supercritical conditions

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1231678A (zh) * 1996-09-24 1999-10-13 埃克森化学专利公司 制备载体上的金属茂催化剂体系的改进方法

Also Published As

Publication number Publication date
KR20070039930A (ko) 2007-04-13
DE602005010255D1 (de) 2008-11-20
JP2008505932A (ja) 2008-02-28
BRPI0513057A (pt) 2008-04-22
EP1774485B1 (en) 2016-05-04
JP2008506018A (ja) 2008-02-28
WO2006025949A2 (en) 2006-03-09
JP5268087B2 (ja) 2013-08-21
WO2006010139A3 (en) 2006-03-16
EP1765841B1 (en) 2008-10-08
CN101124235A (zh) 2008-02-13
EP1765841A2 (en) 2007-03-28
US7279536B2 (en) 2007-10-09
US7601666B2 (en) 2009-10-13
US20060293474A1 (en) 2006-12-28
CN101010705A (zh) 2007-08-01
WO2006010139A2 (en) 2006-01-26
CA2576840A1 (en) 2006-03-09
CN101124235B (zh) 2010-12-15
JP4988568B2 (ja) 2012-08-01
WO2006025949A3 (en) 2006-08-31
EP1774485A2 (en) 2007-04-18
US20060009595A1 (en) 2006-01-12

Similar Documents

Publication Publication Date Title
CN101010705B (zh) 在超临界条件下生产聚合物
CN1326888C (zh) 在超临界条件生产聚合物的方法
US20060025545A1 (en) Polymer production at supercritical conditions
US5468440A (en) Process of making oriented film or structure
CN101855249B (zh) 在线生产增塑聚合物和增塑聚合物共混物的方法
JP5186362B2 (ja) ポリプロピレンによる繊維および不織布
CN101595137A (zh) 在超临界条件下的聚合物制备
US20080153997A1 (en) Polymer production at supercritical conditions
US6809168B2 (en) Articles formed from propylene diene copolymers
US7339018B2 (en) Diene-modified propylene copolymers
CN104755511A (zh) 丙烯共聚物组合物及其制备方法
JP2017101229A (ja) 二軸延伸ポリプロピレンシート
JP5577105B2 (ja) フラットヤーンクロス積層シート
Kulshreshtha et al. I. HISTORY OF POLYOLEFIN POLYMERIZATION
MXPA96005445A (es) Aplicaciones de polipropileno isotactico, procesos y productos del mismo

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110323

Termination date: 20170708