JP5209468B2 - 再充電リチウムイオン単電池用のｎ−オキシドレドックスシャトル - Google Patents

再充電リチウムイオン単電池用のｎ−オキシドレドックスシャトル Download PDF

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JP5209468B2
JP5209468B2 JP2008512347A JP2008512347A JP5209468B2 JP 5209468 B2 JP5209468 B2 JP 5209468B2 JP 2008512347 A JP2008512347 A JP 2008512347A JP 2008512347 A JP2008512347 A JP 2008512347A JP 5209468 B2 JP5209468 B2 JP 5209468B2
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cell
charge
potential
positive electrode
lithium
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Japanese (ja)
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JP2008541401A (ja
JP2008541401A5 (OSRAM
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アール． ダーン，ジェフリー
ブールメスター，クラウディア
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y10T29/4911—Electric battery cell making including sealing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
JP2008512347A 2005-05-17 2006-05-09 再充電リチウムイオン単電池用のｎ−オキシドレドックスシャトル Expired - Fee Related JP5209468B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/130,849 US7615317B2 (en) 2005-05-17 2005-05-17 N-oxide redox shuttles for rechargeable lithium-ion cell
US11/130,849 2005-05-17
PCT/US2006/017835 WO2006124389A2 (en) 2005-05-17 2006-05-09 N-oxide redox shuttles for rechargeable lithium-ion cell

Publications (3)

Publication Number Publication Date
JP2008541401A JP2008541401A (ja) 2008-11-20
JP2008541401A5 JP2008541401A5 (OSRAM) 2009-06-18
JP5209468B2 true JP5209468B2 (ja) 2013-06-12

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JP2008512347A Expired - Fee Related JP5209468B2 (ja) 2005-05-17 2006-05-09 再充電リチウムイオン単電池用のｎ−オキシドレドックスシャトル

Country Status (9)

Country Link
US (1) US7615317B2 (OSRAM)
EP (1) EP1882283B1 (OSRAM)
JP (1) JP5209468B2 (OSRAM)
KR (1) KR101299880B1 (OSRAM)
CN (1) CN101595591B (OSRAM)
AT (1) ATE479211T1 (OSRAM)
DE (1) DE602006016432D1 (OSRAM)
TW (1) TWI389369B (OSRAM)
WO (1) WO2006124389A2 (OSRAM)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7498100B2 (en) * 2003-08-08 2009-03-03 3M Innovative Properties Company Multi-phase, silicon-containing electrode for a lithium-ion battery
CN100517856C (zh) * 2004-04-01 2009-07-22 3M创新有限公司 用于可再充电锂离子电池中过放电保护的氧化还原对
WO2005099024A2 (en) 2004-04-01 2005-10-20 3M Innovative Properties Company Redox shuttle for rechargeable lithium-ion cell
US7851085B2 (en) * 2005-07-25 2010-12-14 3M Innovative Properties Company Alloy compositions for lithium ion batteries
US7767349B2 (en) 2005-07-25 2010-08-03 3M Innovative Properties Company Alloy compositions for lithium ion batteries
US7871727B2 (en) * 2005-07-25 2011-01-18 3M Innovative Properties Company Alloy composition for lithium ion batteries
US7906238B2 (en) * 2005-12-23 2011-03-15 3M Innovative Properties Company Silicon-containing alloys useful as electrodes for lithium-ion batteries
CA2679526A1 (en) * 2007-03-09 2008-09-18 Basf Se Nitroxides for lithium-ion batteries
JP5272398B2 (ja) * 2007-12-14 2013-08-28 株式会社豊田中央研究所 有機ラジカル化合物、蓄電デバイス用電極及び蓄電デバイス
KR20100137447A (ko) 2008-02-12 2010-12-30 쓰리엠 이노베이티브 프로퍼티즈 컴파니 고전압 캐소드용 산화환원 셔틀
US8283074B2 (en) * 2008-08-15 2012-10-09 Uchicago Argonne, Llc Electrolyte salts for nonaqueous electrolytes
JP5350849B2 (ja) * 2009-03-23 2013-11-27 株式会社豊田中央研究所 リチウム二次電池
US8968940B2 (en) 2010-05-25 2015-03-03 Uchicago Argonne, Llc Redox shuttles for high voltage cathodes
US8877390B2 (en) 2010-05-25 2014-11-04 Uchicago Argonne, Llc Redox shuttles for lithium ion batteries
CN103553886B (zh) 2010-05-25 2016-07-06 U芝加哥阿尔贡股份有限公司 用于锂离子电池的聚醚官能化的氧化还原穿梭添加剂
US9431660B2 (en) 2010-09-23 2016-08-30 Robert Bosch Gmbh Lithium battery with charging redox couple
US9761878B2 (en) 2010-09-23 2017-09-12 Robert Bosch Gmbh Metal/oxygen battery with a clean surface for oxidizing redox additives
JP2013546138A (ja) 2010-11-09 2013-12-26 スリーエム イノベイティブ プロパティズ カンパニー 高容量合金アノード及び同アノードを含むリチウムイオン電気化学セル
WO2012076093A1 (en) * 2010-12-08 2012-06-14 Merck Patent Gmbh Additives for dye-sensitized solar cells
CN102694197B (zh) * 2011-03-21 2015-02-11 珠海银隆新能源有限公司 环型锂离子电池
CN102694198B (zh) * 2011-03-21 2014-08-13 珠海银隆新能源有限公司 环型锂离子动力电池
FR2975098B1 (fr) * 2011-05-12 2014-02-07 Centre Nat Rech Scient Composes a groupement redox, leur utilisation comme additif d'electrolyte, composition d'electrolyte et systemes electrochimiques les contenant
CN103563155B (zh) 2011-06-07 2017-07-21 3M创新有限公司 包含碳氟化合物电解质添加剂的锂离子电化学电池
US9966625B2 (en) * 2012-02-28 2018-05-08 Uchicago Argonne, Llc Organic non-aqueous cation-based redox flow batteries
US9300000B2 (en) * 2012-02-28 2016-03-29 Uchicago Argonne, Llc Organic non-aqueous cation-based redox flow batteries
US9263736B2 (en) 2012-03-27 2016-02-16 Tdk Corporation Positive electrode material for lithium ion secondary battery, positive electrode for lithium ion secondary battery, and lithium ion secondary battery
JP6244623B2 (ja) * 2012-12-18 2017-12-13 株式会社Ｇｓユアサ 非水電解質二次電池の製造方法及び非水電解質二次電池
US9005822B2 (en) 2013-03-06 2015-04-14 Uchicago Argonne, Llc Functional electrolyte for lithium-ion batteries
DE112015003328T5 (de) 2014-07-18 2017-04-13 Board Of Trustees Of Michigan State University Wiederaufladbare Lithiumionenzelle mit einem Redox-Shuttle-Additiv
US10026984B2 (en) 2015-08-31 2018-07-17 Uchicago Argonne, Llc Multi-electron redox active molecules for energy storage applications
US9991542B2 (en) 2015-08-31 2018-06-05 Uchicago Argonne, Llc Two-electron high potential and high capacity redox active molecules for energy storage applications
US10840531B2 (en) 2015-08-31 2020-11-17 Uchicago Argonne, Llc Two-electron redox active molecules with high capacity and energy density for energy storage applications
KR102069836B1 (ko) * 2016-03-03 2020-01-23 주식회사 엘지화학 리튬-설퍼 전지용 전해액 및 이를 포함하는 리튬-설퍼 전지
CN106410205B (zh) * 2016-06-28 2019-08-02 宁德时代新能源科技股份有限公司 一种锂电池聚合物正极材料，其制备方法及其电池
CN109496375B (zh) * 2016-07-26 2022-12-02 株式会社村田制作所 电解液和电化学设备
AU2017363603B2 (en) 2016-11-22 2023-01-05 Board Of Trustees Of Michigan State University Rechargeable electrochemical cell
US10374239B2 (en) 2016-12-29 2019-08-06 Uchicago Argonne, Llc Aqueous pyridinium cation-based redox flow batteries
US10553890B2 (en) 2017-06-23 2020-02-04 Uchicago Argonne, Llc Aqueous redox flow batteries
US10622676B2 (en) 2017-06-29 2020-04-14 Uchicago Argonne, Llc Functional organic salt for lithium-ion batteries
US11545691B2 (en) 2017-07-20 2023-01-03 Board Of Trustees Of Michigan State University Redox flow battery
US10424805B2 (en) 2017-08-15 2019-09-24 Uchicago Argonne, Llc Benzothiophene-based redox molecules for flow battery
US10727545B1 (en) * 2019-04-12 2020-07-28 Ses Holdings Pte. Ltd. Methods of charging secondary lithium metal batteries to reactive dead lithium with redox shuttling additives and battery control systems incorporating the same
US11437610B2 (en) * 2019-05-03 2022-09-06 Unist(Ulsan National Institute Of Science And Technology) High capacity secondary battery
US11271237B2 (en) 2019-07-29 2022-03-08 Uchicago Argonne, Llc Organic redox molecules for flow batteries

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1066928A (en) 1964-07-13 1967-04-26 American Cyanamid Co Electroluminescence
US4869977A (en) 1988-04-25 1989-09-26 Amoco Corporation Electrolyte additive for lithium-sulfur dioxide electrochemical cell
JPH05295058A (ja) 1992-04-17 1993-11-09 Yuasa Corp イオン伝導性高分子化合物及びその製造方法
JP3809657B2 (ja) 1994-03-07 2006-08-16 ソニー株式会社 非水電解液二次電池
US5976731A (en) 1996-09-03 1999-11-02 Fuji Photo Film Co., Ltd. Non-aqueous lithium ion secondary battery
US6203946B1 (en) * 1998-12-03 2001-03-20 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and uses thereof
US6203944B1 (en) 1998-03-26 2001-03-20 3M Innovative Properties Company Electrode for a lithium battery
US6255017B1 (en) 1998-07-10 2001-07-03 3M Innovative Properties Co. Electrode material and compositions including same
US20010004507A1 (en) * 1998-10-22 2001-06-21 Hong Gan Organic carbonate additives for nonaqueous electrolyte rechargeable electrochemical cells
JP4229510B2 (ja) * 1999-02-15 2009-02-25 株式会社Ａｄｅｋａ 難燃性電解液および非水電解液二次電池
JP4020528B2 (ja) * 1999-03-19 2007-12-12 三洋電機株式会社 非水系電解液二次電池
JP2001015156A (ja) 1999-06-30 2001-01-19 Sony Corp 非水電解質電池
JP2001023687A (ja) 1999-07-09 2001-01-26 Sony Corp 非水電解質電池
WO2001073884A1 (fr) * 2000-03-28 2001-10-04 Ngk Insulators, Ltd. Accumulateur au lithium
JP2001283920A (ja) 2000-03-28 2001-10-12 Ngk Insulators Ltd リチウム二次電池
CN1249840C (zh) * 2001-01-24 2006-04-05 宇部兴产株式会社 非水电解液和锂二次电池
JP4830207B2 (ja) * 2001-03-30 2011-12-07 日本電気株式会社 電池
JP2003022809A (ja) * 2001-07-09 2003-01-24 Nec Corp 電池および電池用電極
JP3714205B2 (ja) * 2001-07-10 2005-11-09 ソニー株式会社 非水電解液二次電池
US6942949B2 (en) * 2002-08-12 2005-09-13 Lg Chem, Ltd. Rechargeable lithium electrochemical cell
EP1528616B1 (en) 2003-10-31 2017-03-08 Samsung SDI Co., Ltd. Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same
US7354680B2 (en) * 2004-01-06 2008-04-08 Sion Power Corporation Electrolytes for lithium sulfur cells
US7358012B2 (en) * 2004-01-06 2008-04-15 Sion Power Corporation Electrolytes for lithium sulfur cells
US7019494B2 (en) * 2004-01-06 2006-03-28 Moltech Corporation Methods of charging lithium sulfur cells
CN100517856C (zh) 2004-04-01 2009-07-22 3M创新有限公司 用于可再充电锂离子电池中过放电保护的氧化还原对
JP5082198B2 (ja) 2005-03-10 2012-11-28 日本電気株式会社 リチウムイオン二次電池

Also Published As

Publication number Publication date
KR20080007468A (ko) 2008-01-21
CN101595591A (zh) 2009-12-02
EP1882283A2 (en) 2008-01-30
JP2008541401A (ja) 2008-11-20
US7615317B2 (en) 2009-11-10
KR101299880B1 (ko) 2013-08-23
TWI389369B (zh) 2013-03-11
TW200703740A (en) 2007-01-16
US20060263695A1 (en) 2006-11-23
WO2006124389A3 (en) 2007-06-07
EP1882283B1 (en) 2010-08-25
WO2006124389A2 (en) 2006-11-23
DE602006016432D1 (de) 2010-10-07
ATE479211T1 (de) 2010-09-15
CN101595591B (zh) 2012-03-21

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