JP5028767B2 - 粘着付与樹脂エマルジョン、その製造方法および水性粘接着剤組成物 - Google Patents
粘着付与樹脂エマルジョン、その製造方法および水性粘接着剤組成物 Download PDFInfo
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- JP5028767B2 JP5028767B2 JP2005242681A JP2005242681A JP5028767B2 JP 5028767 B2 JP5028767 B2 JP 5028767B2 JP 2005242681 A JP2005242681 A JP 2005242681A JP 2005242681 A JP2005242681 A JP 2005242681A JP 5028767 B2 JP5028767 B2 JP 5028767B2
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- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N alpha-mercaptoacetic acid Natural products OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000004148 curcumin Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- OGRPJZFGZFQRHZ-UHFFFAOYSA-M sodium;4-octoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].CCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O OGRPJZFGZFQRHZ-UHFFFAOYSA-M 0.000 description 1
- MWZFQMUXPSUDJQ-KVVVOXFISA-M sodium;[(z)-octadec-9-enyl] sulfate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCOS([O-])(=O)=O MWZFQMUXPSUDJQ-KVVVOXFISA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
(1)水44.46部
(2)アニオン系乳化剤(商品名ハイテノールS、固形分50%。第一工業製薬(株)製) 0.90部
(3)ブチルアクリレート43.90部、およびアクリル酸1.36部
(4)開始剤(過硫酸カリウム)0.23部、pH調整剤(重曹)0.11部、および蒸留水9.04部
攪拌装置、冷却管、滴下ロートおよび窒素導入管を備えた4ツ口フラスコ中、70℃の窒素ガス気流下で、上記(1)、(2)を溶解した後、攪拌下に上記(3)および(4)の合計の1/10量を添加し70℃で窒素気流下にて30分間予備重合反応を行い、その後、(3)および(4)の合計の9/10量を2時間かけて滴下し、滴下重合を行なった。(3)および(4)の全量を滴下終了後、1時間完結反応を70℃で行い、室温に冷却後、100メッシュの金網濾過を行いながら取り出し、固形分45.6%のアクリル重合体のエマルジョンを得た。
(粘着付与樹脂エマルジョンの製造)
重合ロジンエステル(ペンセルD−160、荒川化学工業(株)製、軟化点158℃、酸価16)100部、トリエチルアミン10部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル10部を加えた。この溶液を75℃まで昇温した後にアニオン系乳化剤(ドデシルベンセンスルホン酸ナトリウム)を3部(固形換算)および水を170部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
実施例1のようにして得た粘着付与樹脂のエマルジョンを10部(固形換算)と製造例1で得られたアクリル重合体のエマルジョン90部(固形換算)を混合し、さらに増粘剤としてプライマルASE−60(日本アクリル社製)0.5部(固形換算)を添加し増粘させて水性粘着剤組成物を得た。
得られた水性粘着剤組成物を乾燥後の糊厚が30μmとなるように厚さ40μmのポリエステルフィルムに塗布し、115℃の乾燥機の中で20分間乾燥し、粘着シートを作成して各種試験を行なった。結果を表1に示す。
測定温度20℃と80℃において、引張速度300mm/分で180°剥離試験した時の粘着力(g/cm 2 )を測定した。被着体はポリエチレン板(PE)である。
JIS Z0237に記載されたJ.DOW法により傾斜30°、測定温度20℃で測定した。表1中の数値はボールNoを示す。
JIS C2107により貼付け面積25×25mm 荷重1.0kgで対ステンレス板に対する60℃での1時間のずれmmを測定した。
乾燥後の粘着シートを目視で判定した。×は濁りのあるものを、○は濁りの無いものを示す。
フェノール変性ロジン(タマノル803L、荒川化学工業(株)製、軟化点149℃、酸価47、水酸基価13)100部、トリエチルアミン15部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル12部を加えた。この溶液を75℃まで昇温した後にアニオン系乳化剤(ドデシルベンセンスルホン酸ナトリウム)を3部(固形換算)および水を160部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
不均化ロジンエステル(スーパーエステルA−100、荒川化学工業(株)製、軟化点100℃、酸価6)100部、トリエチルアミン6部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル6部を加えた。この溶液を75℃まで昇温した後にアニオン系乳化剤(ドデシルベンセンスルホン酸ナトリウム)を3部(固形換算)および水を160部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
テルペンフェノール樹脂(YSポリスターS−145、ヤスハラケミカル(株)製、軟化点145℃、水酸基価100)100部、トリエチルアミン20部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル15部を加えた。この溶液を75℃まで昇温した後にアニオン系乳化剤(ドデシルベンセンスルホン酸ナトリウム)を3部(固形換算)および水を160部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
フェノール変性C9石油樹脂(ネオポリマーE−100、新日本石油化学(株)製、軟化点97℃、水酸基価75)100部、トリエチルアミン15部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル15部を加えた。この溶液を75℃まで昇温した後にアニオン系乳化剤(ドデシルベンセンスルホン酸ナトリウム)を3部(固形換算)および水を170部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
酸変性石油樹脂(ハイレジンMN60、東邦化学(株)製、軟化点98℃、酸価60)100部、トリエチルアミン10部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル10部を加えた。この溶液を75℃まで昇温した後にアニオン系乳化剤(ドデシルベンセンスルホン酸ナトリウム)を3部(固形換算)および水を170部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
重合ロジンエステル(ペンセルD−160、荒川化学工業(株)製、軟化点158℃、酸価16)100部、トリエチルアミン10部をトルエン70部に溶解し50℃で8時間攪拌した。次いでトリエチレングリコールジビニルエーテル10部を加えた。この溶液を75℃まで昇温した後にアニオン系高分子乳化剤(スチレン12.5部、メタクリル酸メチル12.5部、メタクリル酸40部、スチレンスルホン酸ソーダ10部を反応性乳化剤アクアロンRN−50(第一工業製薬(株)製)25部(固形換算)を用い、乳化重合して得られたポリマー。GPCによる重量平均分子量(ポリスチレン換算)32000)を5部(固形換算)および水を180部添加して75℃に保ち、1時間30分強攪拌して予備乳化を行なった。得られた予備乳化物を高圧乳化機により30MPaの圧力で高圧乳化し乳化物を得た。次いで、減圧蒸留装置に前記乳化物を仕込み、50℃、13.3kPaの条件下に7時間減圧蒸留を行い、固形分50.0%の粘着付与樹脂のエマルジョンを得た。
実施例1の粘着付与樹脂エマルジョンの製造において、トリエチルアミン及びトリエチレングリコールジビニルエーテルを加えないこと以外は実施例1と同様にして、粘着付与樹脂のエマルジョンを得た。
実施例2〜7それぞれにおいて、トリエチルアミン及びトリエチレングリコールジビニルエーテルを加えないこと以外は実施例2〜7と同様にして、粘着付与樹脂のエマルジョンを得た。
実施例2〜7、比較例1〜7で得た粘着付与樹脂のエマルジョンを10部(固形換算)と製造例1で得られたアクリル重合体のエマルジョン90部(固形換算)を混合し、さらに増粘剤としてプライマルASE−60(日本アクリル社製)0.5部(固形換算)を添加し増粘させて水性粘着剤組成物を得た。
実施例1で示したと同様の方法で性能評価を実施した。結果を表1に示す。
粘着付与樹脂のエマルジョンを添加することなしに、製造例1で得られたアクリル重合体のエマルジョン100部(固形換算)に増粘剤としてプライマルASE−60(日本アクリル社製)0.5部(固形換算)を添加し増粘させて水性粘着剤組成物を得た。実施例1で示したと同様の方法で性能評価を実施した。結果を表1に示す。
Claims (7)
- アニオン性官能基を有し、ビニルエーテル基またはビニルチオエーテル基を有しない粘着付与樹脂(A)の揮発性塩基(B)中和物およびビニルエーテル基またはビニルチオエーテル基を2つ以上有する化合物(C)を含有する組成物を水中に分散させた粘着付与樹脂エマルジョン。
- 前記粘着付与樹脂(A)が、ロジン系樹脂、カルボキシル基またはフェノール性水酸基を有する石油樹脂およびテルペンフェノール樹脂からなる群より選ばれる少なくとも1種である請求項1記載の粘着付与樹脂エマルジョン。
- ロジン系樹脂の酸価が、2〜250mgKOH/gである請求項2記載の粘着付与樹脂エマルジョン。
- 揮発性塩基(B)が、三級アミンである請求項1〜3のいずれかに記載の粘着付与樹脂エマルジョン。
- アニオン性官能基を有し、ビニルエーテル基またはビニルチオエーテル基を有しない粘着付与樹脂(A)を揮発性塩基(B)で中和させた後、ビニルエーテル基またはビニルチオエーテル基を2つ以上有する化合物(C)を加え、乳化させることを特徴とする粘着付与樹脂エマルジョンの製造方法。
- 請求項1〜4のいずれかに記載の粘着付与樹脂エマルジョンを含有する水性粘着剤組成物。
- アクリル樹脂を含有する請求項6に記載の水性粘着剤組成物。
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