JP4878028B2 - オキシムエステル光開始剤 - Google Patents

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Publication number

JP4878028B2

JP4878028B2 JP2007526449A JP2007526449A JP4878028B2 JP 4878028 B2 JP4878028 B2 JP 4878028B2 JP 2007526449 A JP2007526449 A JP 2007526449A JP 2007526449 A JP2007526449 A JP 2007526449A JP 4878028 B2 JP4878028 B2 JP 4878028B2

Authority

JP

Japan

Prior art keywords

meth

acrylate

alkyl

phenyl

acid

Prior art date

2004-08-18

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• -1 Oxime ester Chemical class 0.000 title claims abstract description 164
• 150000001875 compounds Chemical class 0.000 claims abstract description 116
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 30
• 239000001257 hydrogen Substances 0.000 claims abstract description 23
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
• 229910052760 oxygen Inorganic materials 0.000 claims abstract description 16
• 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 9
• 125000001624 naphthyl group Chemical group 0.000 claims abstract description 7
• 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 claims abstract description 6
• 125000005561 phenanthryl group Chemical group 0.000 claims abstract description 6
• 229910052717 sulfur Inorganic materials 0.000 claims abstract description 6
• 239000000203 mixture Substances 0.000 claims description 163
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 129
• 239000000758 substrate Substances 0.000 claims description 71
• 239000000049 pigment Substances 0.000 claims description 69
• 238000000034 method Methods 0.000 claims description 61
• 239000000463 material Substances 0.000 claims description 54
• 238000004519 manufacturing process Methods 0.000 claims description 53
• 238000000576 coating method Methods 0.000 claims description 51
• 125000000217 alkyl group Chemical group 0.000 claims description 45
• 229920000642 polymer Polymers 0.000 claims description 45
• 229920005989 resin Polymers 0.000 claims description 43
• 239000011347 resin Substances 0.000 claims description 43
• 239000000178 monomer Substances 0.000 claims description 40
• 239000011248 coating agent Substances 0.000 claims description 39
• 239000011159 matrix material Substances 0.000 claims description 30
• 125000006850 spacer group Chemical group 0.000 claims description 25
• 230000003287 optical effect Effects 0.000 claims description 22
• 239000011230 binding agent Substances 0.000 claims description 21
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 21
• 229920002120 photoresistant polymer Polymers 0.000 claims description 18
• 239000000843 powder Substances 0.000 claims description 18
• 239000000654 additive Substances 0.000 claims description 13
• 238000007639 printing Methods 0.000 claims description 13
• 230000008569 process Effects 0.000 claims description 12
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
• 238000005530 etching Methods 0.000 claims description 11
• 150000002431 hydrogen Chemical class 0.000 claims description 11
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
• 238000013500 data storage Methods 0.000 claims description 9
• 239000000976 ink Substances 0.000 claims description 9
• 239000007788 liquid Substances 0.000 claims description 8
• 229910000679 solder Inorganic materials 0.000 claims description 8
• 230000015572 biosynthetic process Effects 0.000 claims description 7
• 239000003365 glass fiber Substances 0.000 claims description 6
• 239000002491 polymer binding agent Substances 0.000 claims description 6
• 238000007650 screen-printing Methods 0.000 claims description 6
• 238000010894 electron beam technology Methods 0.000 claims description 5
• 238000003384 imaging method Methods 0.000 claims description 5
• 230000001070 adhesive effect Effects 0.000 claims description 4
• 150000008064 anhydrides Chemical class 0.000 claims description 4
• 238000009713 electroplating Methods 0.000 claims description 4
• 229920000620 organic polymer Polymers 0.000 claims description 4
• 239000003973 paint Substances 0.000 claims description 4
• 239000003504 photosensitizing agent Substances 0.000 claims description 4
• 238000002360 preparation method Methods 0.000 claims description 4
• 150000001266 acyl halides Chemical class 0.000 claims description 3
• 230000000996 additive effect Effects 0.000 claims description 3
• 239000000853 adhesive Substances 0.000 claims description 3
• 125000005037 alkyl phenyl group Chemical group 0.000 claims description 3
• 125000005843 halogen group Chemical group 0.000 claims description 3
• 239000003094 microcapsule Substances 0.000 claims description 3
• 238000007747 plating Methods 0.000 claims description 3
• 238000007789 sealing Methods 0.000 claims description 3
• 230000005670 electromagnetic radiation Effects 0.000 claims description 2
• 238000004377 microelectronic Methods 0.000 claims description 2
• 239000002966 varnish Substances 0.000 claims description 2
• 238000004042 decolorization Methods 0.000 claims 2
• 230000001678 irradiating effect Effects 0.000 claims 1
• 238000006243 chemical reaction Methods 0.000 abstract description 28
• 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
• 239000010410 layer Substances 0.000 description 84
• 229920001577 copolymer Polymers 0.000 description 57
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 56
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 53
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 44
• 239000010408 film Substances 0.000 description 37
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 31
• 239000004973 liquid crystal related substance Substances 0.000 description 30
• 239000002904 solvent Substances 0.000 description 26
• 229920005862 polyol Polymers 0.000 description 25
• 239000002253 acid Substances 0.000 description 21
• 239000011342 resin composition Substances 0.000 description 21
• 239000007787 solid Substances 0.000 description 21
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 20
• TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 19
• 150000003077 polyols Chemical class 0.000 description 19
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 19
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 18
• 230000005855 radiation Effects 0.000 description 18
• 239000000243 solution Substances 0.000 description 18
• 229910052757 nitrogen Inorganic materials 0.000 description 17
• 239000011521 glass Substances 0.000 description 16
• 210000004027 cell Anatomy 0.000 description 15
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 15
• 229910052751 metal Inorganic materials 0.000 description 15
• 239000002184 metal Substances 0.000 description 15
• 229920003145 methacrylic acid copolymer Polymers 0.000 description 15
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 14
• FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 14
• 239000007795 chemical reaction product Substances 0.000 description 14
• 238000010438 heat treatment Methods 0.000 description 14
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 14
• 239000000047 product Substances 0.000 description 14
• 239000000600 sorbitol Substances 0.000 description 14
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 13
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 13
• 239000000975 dye Substances 0.000 description 13
• 239000011241 protective layer Substances 0.000 description 13
• 239000000126 substance Substances 0.000 description 13
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 12
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 12
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
• 230000004888 barrier function Effects 0.000 description 12
• 239000011976 maleic acid Substances 0.000 description 12
• 239000003960 organic solvent Substances 0.000 description 12
• 239000002585 base Substances 0.000 description 11
• 238000011161 development Methods 0.000 description 11
• 125000003700 epoxy group Chemical group 0.000 description 11
• 150000002148 esters Chemical class 0.000 description 11
• 229920006395 saturated elastomer Polymers 0.000 description 11
• 230000035945 sensitivity Effects 0.000 description 11
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 10
• 239000004642 Polyimide Substances 0.000 description 10
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
• 125000004432 carbon atom Chemical group C* 0.000 description 10
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 10
• JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 10
• 239000006185 dispersion Substances 0.000 description 10
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 10
• 239000001301 oxygen Substances 0.000 description 10
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 10
• 229920000647 polyepoxide Polymers 0.000 description 10
• 229920000728 polyester Polymers 0.000 description 10
• 229920001721 polyimide Polymers 0.000 description 10
• 239000002243 precursor Substances 0.000 description 10
• 229920003002 synthetic resin Polymers 0.000 description 10
• 239000000057 synthetic resin Substances 0.000 description 10
• 229920001187 thermosetting polymer Polymers 0.000 description 10
• 229920002554 vinyl polymer Polymers 0.000 description 10
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 9
• 238000000465 moulding Methods 0.000 description 9
• 229920003986 novolac Polymers 0.000 description 9
• 239000004814 polyurethane Substances 0.000 description 9
• 229920002635 polyurethane Polymers 0.000 description 9
• BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 9
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 9
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
• 239000004952 Polyamide Substances 0.000 description 8
• 239000004793 Polystyrene Substances 0.000 description 8
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
• 150000008065 acid anhydrides Chemical class 0.000 description 8
• 239000003513 alkali Substances 0.000 description 8
• 150000001412 amines Chemical class 0.000 description 8
• AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 8
• WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 8
• DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 8
• 150000001735 carboxylic acids Chemical class 0.000 description 8
• BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 8
• LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 8
• CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 8
• 239000003999 initiator Substances 0.000 description 8
• 239000011229 interlayer Substances 0.000 description 8
• 239000000123 paper Substances 0.000 description 8
• XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 8
• 229920002647 polyamide Polymers 0.000 description 8
• 229920001223 polyethylene glycol Polymers 0.000 description 8
• 238000006116 polymerization reaction Methods 0.000 description 8
• 229920002223 polystyrene Polymers 0.000 description 8
• 150000003254 radicals Chemical class 0.000 description 8
• 239000011541 reaction mixture Substances 0.000 description 8
• HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 7
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
• YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 7
• 125000003118 aryl group Chemical group 0.000 description 7
• 239000003086 colorant Substances 0.000 description 7
• ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 7
• 238000001723 curing Methods 0.000 description 7
• 150000002009 diols Chemical class 0.000 description 7
• 238000001035 drying Methods 0.000 description 7
• 235000011187 glycerol Nutrition 0.000 description 7
• 150000007519 polyprotic acids Polymers 0.000 description 7
• LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 7
• 125000001424 substituent group Chemical group 0.000 description 7
• 229940117958 vinyl acetate Drugs 0.000 description 7
• VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 6
• QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
• FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 6
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
• SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
• 239000002202 Polyethylene glycol Substances 0.000 description 6
• ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
• 125000001931 aliphatic group Chemical group 0.000 description 6
• SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 6
• 238000009472 formulation Methods 0.000 description 6
• 125000002768 hydroxyalkyl group Chemical group 0.000 description 6
• LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 6
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
• 150000002923 oximes Chemical class 0.000 description 6
• 229920003023 plastic Polymers 0.000 description 6
• 239000004033 plastic Substances 0.000 description 6
• 229920000768 polyamine Polymers 0.000 description 6
• 229920000570 polyether Polymers 0.000 description 6
• KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 6
• YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 6
• ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 5
• GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 5
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 5
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
• GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
• 239000007864 aqueous solution Substances 0.000 description 5
• 239000012965 benzophenone Substances 0.000 description 5
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
• 125000002843 carboxylic acid group Chemical group 0.000 description 5
• 239000003795 chemical substances by application Substances 0.000 description 5
• LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 5
• 239000000499 gel Substances 0.000 description 5
• 229920001519 homopolymer Polymers 0.000 description 5
• FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
• 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
• 238000012545 processing Methods 0.000 description 5
• YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
• 229920005992 thermoplastic resin Polymers 0.000 description 5
• LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 5
• 239000002023 wood Substances 0.000 description 5
• 239000001052 yellow pigment Substances 0.000 description 5
• JWTGRKUQJXIWCV-UHFFFAOYSA-N 1,2,3-trihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(O)C(O)CO JWTGRKUQJXIWCV-UHFFFAOYSA-N 0.000 description 4
• OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
• JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
• XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 4
• XLLXMBCBJGATSP-UHFFFAOYSA-N 2-phenylethenol Chemical compound OC=CC1=CC=CC=C1 XLLXMBCBJGATSP-UHFFFAOYSA-N 0.000 description 4
• ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 4
• YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
• KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
• SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
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