JP4871871B2 - 高いuv露光最終用途で有用なポリ(トリメチレンテレフタレート)繊維 - Google Patents
高いuv露光最終用途で有用なポリ(トリメチレンテレフタレート)繊維 Download PDFInfo
- Publication number
- JP4871871B2 JP4871871B2 JP2007527758A JP2007527758A JP4871871B2 JP 4871871 B2 JP4871871 B2 JP 4871871B2 JP 2007527758 A JP2007527758 A JP 2007527758A JP 2007527758 A JP2007527758 A JP 2007527758A JP 4871871 B2 JP4871871 B2 JP 4871871B2
- Authority
- JP
- Japan
- Prior art keywords
- poly
- trimethylene terephthalate
- fiber
- fibers
- pat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims description 106
- 229920002215 polytrimethylene terephthalate Polymers 0.000 title claims description 96
- 239000000975 dye Substances 0.000 claims description 46
- 239000006096 absorbing agent Substances 0.000 claims description 18
- 239000000986 disperse dye Substances 0.000 claims description 16
- OWQPOVKKUWUEKE-UHFFFAOYSA-N 1,2,3-benzotriazine Chemical class N1=NN=CC2=CC=CC=C21 OWQPOVKKUWUEKE-UHFFFAOYSA-N 0.000 claims description 12
- 239000003352 sequestering agent Substances 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 description 55
- 238000012360 testing method Methods 0.000 description 24
- 239000004744 fabric Substances 0.000 description 21
- 238000004043 dyeing Methods 0.000 description 20
- 230000005855 radiation Effects 0.000 description 20
- 238000010998 test method Methods 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 8
- 229920013627 Sorona Polymers 0.000 description 8
- 229920001519 homopolymer Polymers 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical group O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- -1 polyethylene terephthalate Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- DYALWCKAJBVSBZ-UHFFFAOYSA-N 1-anilino-4,5-dihydroxy-8-nitroanthracene-9,10-dione Chemical compound C1=2C(=O)C(C(=CC=C3O)[N+]([O-])=O)=C3C(=O)C=2C(O)=CC=C1NC1=CC=CC=C1 DYALWCKAJBVSBZ-UHFFFAOYSA-N 0.000 description 5
- BBFRYSKTTHYWQZ-UHFFFAOYSA-N 4-anilino-3-nitro-n-phenylbenzenesulfonamide Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)NC=2C=CC=CC=2)=CC=C1NC1=CC=CC=C1 BBFRYSKTTHYWQZ-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- XREZMAAQVYVESP-UHFFFAOYSA-N acetyloxymethyl 2-[n-[2-(acetyloxymethoxy)-2-oxoethyl]-2-[2-[2-[bis[2-(acetyloxymethoxy)-2-oxoethyl]amino]-4-fluorophenoxy]ethoxy]-5-fluoroanilino]acetate Chemical compound CC(=O)OCOC(=O)CN(CC(=O)OCOC(C)=O)C1=CC(F)=CC=C1OCCOC1=CC=C(F)C=C1N(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O XREZMAAQVYVESP-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- BXIGAWRFDMDLTL-UHFFFAOYSA-N n-(4-amino-3-methoxy-9,10-dioxoanthracen-1-yl)-4-methylbenzenesulfonamide Chemical compound C=12C(=O)C3=CC=CC=C3C(=O)C2=C(N)C(OC)=CC=1NS(=O)(=O)C1=CC=C(C)C=C1 BXIGAWRFDMDLTL-UHFFFAOYSA-N 0.000 description 5
- 230000002035 prolonged effect Effects 0.000 description 5
- 229920004934 Dacron® Polymers 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- VOCYGZAHYQXJOF-UHFFFAOYSA-N 1,8-dihydroxy-4-[4-(2-hydroxyethyl)anilino]-5-nitroanthracene-9,10-dione Chemical compound C1=CC(CCO)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=C([N+]([O-])=O)C=CC(O)=C1C2=O VOCYGZAHYQXJOF-UHFFFAOYSA-N 0.000 description 3
- RQLMZSLFKGNXTO-UHFFFAOYSA-N 1-amino-4-hydroxy-2-(6-hydroxyhexoxy)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC(OCCCCCCO)=C2N RQLMZSLFKGNXTO-UHFFFAOYSA-N 0.000 description 3
- 229920001634 Copolyester Polymers 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920006309 Invista Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 235000005018 Pinus echinata Nutrition 0.000 description 1
- 241001236219 Pinus echinata Species 0.000 description 1
- 235000017339 Pinus palustris Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229960000250 adipic acid Drugs 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- WQOMVNPUJAWPFR-UHFFFAOYSA-M sodium;2-carboxynaphthalene-1-carboxylate Chemical compound [Na+].C1=CC=CC2=C(C([O-])=O)C(C(=O)O)=CC=C21 WQOMVNPUJAWPFR-UHFFFAOYSA-M 0.000 description 1
- GJTNGKDEAATFNA-UHFFFAOYSA-M sodium;benzene-1,3-dicarboxylate;hydron Chemical compound [Na+].OC(=O)C1=CC=CC(C([O-])=O)=C1 GJTNGKDEAATFNA-UHFFFAOYSA-M 0.000 description 1
- DJYPJBAHKUBLSS-UHFFFAOYSA-M sodium;hydron;terephthalate Chemical compound [Na+].OC(=O)C1=CC=C(C([O-])=O)C=C1 DJYPJBAHKUBLSS-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000007447 staining method Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
- C09B67/0082—Preparations of disperse dyes or solvent dyes in liquid form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Artificial Filaments (AREA)
- Coloring (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本件出願は、参照により本明細書に援用される、2004年6月10日出願の米国特許出願第10/865,112号明細書の優先権を主張するものである。
a.ポリ(トリメチレンテレフタレート)繊維を提供する工程と、
b.好ましくは、すべての重量パーセントが繊維の重量を基準にして、約2:1〜約40:1の水:繊維比を提供して形成するために十分な量の水入りの、ベンゾトリアジン誘導体UV吸収剤を含む水溶液を含有する染浴を提供する工程と
c.染浴のpHを約4〜約6に調整する工程と、
d.染浴を(好ましくは少なくとも約1℃毎分の速度で)約105〜約145℃の温度に加熱する工程と、
e.ポリ(トリメチレンテレフタレート)繊維を染浴に浸漬する工程と、
f.染浴温度を少なくとも約30分間(好ましくは145分間以下)維持して染色されたポリ(トリメチレンテレフタレート)繊維を生成する工程と、
g.染浴を放冷する工程と、
h.染色されたポリ(トリメチレンテレフタレート)繊維をリンスする工程と
を含む、染色されたポリ(トリメチレンテレフタレート)繊維の製造方法である。
a.ポリ(トリメチレンテレフタレート)繊維を提供する工程と、
b.水性媒体中室温で、すべての重量パーセントが繊維の重量を基準にして、約0.5重量パーセントのアルコールエトキシレート界面活性剤、約0.25重量パーセントの金属イオン封鎖剤、3重量パーセントのベンゾトリアジン誘導体UV吸収剤、0.5重量パーセントの分散染料、および約2:1〜約40:1の水:繊維比を提供するために十分な水を組み合わせて染浴を形成する工程と、
c.染浴のpHを約4〜約5に調整する工程と、
d.染浴を少なくとも約1℃毎分の速度で132〜145℃の温度に加熱する工程と、
e.ポリ(トリメチレンテレフタレート)繊維を染浴に浸漬する工程と、
f.染浴温度を少なくとも約30分間維持して染色されたポリ(トリメチレンテレフタレート)繊維を生成する工程と、
g.染浴を放冷する工程と、
h.染色されたポリ(トリメチレンテレフタレート)繊維をリンスする工程と
を含む。
次の実施例で報告されるポリ(トリメチレンテレフタレート)糸のテナシティは、Instron Corp.引張試験機モデルNo.1122を用いて測定した。テナシティはASTM(米国材料試験協会)D−2256に従って測定した。
キセノン耐光堅牢度試験は、AATCC方法16−1998およびブルーウール耐光堅牢度標準L−4(ロット5)の確立された試験手順に従って「Atlas」ウェザロメーター(Atlas Material Testing Technology LLC,4114 N.Ravenswood Ave.,Chicago,IL 60613)を用いて行った。
Sorona(登録商標)PTTの糸の引張特性への紫外光への長時間露光の影響を試験した。ベースライン・テナシティはSorona(登録商標)PTTのテクスチャー加工糸の「模擬染色した」ニットチューブについての測定値から得た。「模擬染色」は、着色染料以外の染浴の全成分が使用され、そして温度、圧力などをはじめとする、染色法の工程のすべてが含まれることを意味する。模擬染色は、ポリマーの強度保持試験のためのベースラインを提供するために用いられる。報告されるデータは、10の個々のInstron測定値の平均である。
本明細書で使用するすべての原料は商業的に入手可能である。Sorona(登録商標)ポリ(トリメチレンテレフタレート)繊維製の延伸テクスチャー加工糸は米国特許第6,333,106号明細書に記載されたものに類似の方法で製造した。Dacron(登録商標)ポリ(エチレンテレフタレート)繊維(PET)はInvista,Inc.(Wilmington,DE.)から入手した。使用した化学試薬は次の通りであった。
試験および対照サンプルのニットチューブを、
・0.50%のSurfactant LF−H(登録商標)界面活性剤
・0.25%のVersene(登録商標)100(金属イオン封鎖剤)
・0.50%のピロリン酸四ナトリウム
を含有する浴中60℃で20分間前洗浄した。
・0.50%の「Surfactant」LF−H
・0.25%の「Versene」100(金属イオン封鎖剤)
・3.00%の「Cibafast」USM(UV吸収剤)
・分散染料(量および染料は表1に示す)
・pHを4.50〜4.75に調整するために必要とされるような酢酸
を含有する染浴を室温で容器中調製した。
2.0g/lのBurco Reduct T(登録商標)ハイドロサルファイトナトリウムおよび2.0g/lのソーダ灰を含有する後洗浄浴を室温で調製した。温度を2℃毎分で60℃(140°F)に上げた。布を後洗浄浴に浸漬し、60℃で20分間保持し、十分にリンスし、酢酸で6〜7に調整したpHの浴中での最終リンスで中和した。
次に、本発明の好ましい態様を示す。
1. ポリ(トリメチレンテレフタレート)、染料、およびベンゾトリアジン誘導体UV吸収剤を含む、試験方法AATCC方法16−1998を用いて488kJ入射UV放射線の露光後に4以上の耐光堅牢度を有する着色繊維。
2. 前記繊維中のポリマーの総量を基準にして、少なくとも80モル%のポリ(トリメチレンテレフタレート)を含む上記1に記載の着色繊維。
3. 少なくとも70モル%のトリメチレンテレフタレート繰り返し単位を含有するポリ(トリメチレンテレフタレート)を含む上記1または2に記載の着色繊維。
4. 少なくとも98モル%のトリメチレンテレフタレート繰り返し単位を含有するポリ(トリメチレンテレフタレート)を含む上記1〜3のいずれか一項に記載の着色繊維。
5. 試験方法AATCC方法16−1998を用いて779kJ入射UV放射線への露光後に4以上の耐光堅牢度を有する上記1〜4のいずれか一項に記載の着色繊維。
6. 前記染料がCIディスパース・レッド(Disperse Red)86、CIディスパース・レッド91、CIディスパース・レッド161、CIディスパース・レッド279、CIディスパース・イエロー(Disperse Yellow)42、CIディスパース・イエロー96、CIディスパース・イエロー160、CIディスパース・ブルー(Disperse Blue)27、CIディスパース・ブルー60、およびCIディスパース・ブルー77から選択される上記1〜5のいずれか一項に記載の着色繊維。
7. 前記繊維の重量を基準にして2〜4重量パーセントのベンゾトリアジン誘導体UV吸収剤を含む上記1〜6のいずれか一項に記載の着色繊維。
8. 前記初期テナシティが試験方法AATCC方法16−1998を用いて試験された時に481kJ入射UV放射線での露光後に約10%以下だけ低下する、初期テナシティを有する上記1〜7のいずれか一項に記載の着色繊維。
9. 試験方法AATCC方法16−1998を用いて488kJ入射UV放射線の露光後に4〜5の耐光堅牢度を有する上記1〜8のいずれか一項に記載の着色繊維。
10. ポリ(トリメチレンテレフタレート)が0.80〜1.5dl/gの固有粘度を有する上記1〜9のいずれか一項に記載の着色繊維。
11. a.ポリ(トリメチレンテレフタレート)繊維を提供する工程と、
b.ベンゾトリアジン誘導体UV吸収剤を含有する水溶液を含有する染浴を提供する工程と、
c.前記染浴のpHを約4〜約6に調整する工程と、
d.前記染浴を105〜145℃の温度に加熱する工程と、
e.前記ポリ(トリメチレンテレフタレート)繊維を前記染浴に浸漬する工程と、
f.染浴温度を少なくとも約30分間維持して染色されたポリ(トリメチレンテレフタレート)繊維を生成する工程と、
g.前記染浴を放冷する工程と、
h.前記染色されたポリ(トリメチレンテレフタレート)繊維をリンスする工程と
を含む、染色されたポリ(トリメチレンテレフタレート)繊維の製造方法。
12. 前記染色された繊維がAATCC方法番号16−1998による448kJ入射UV放射線での露光後に4以上の耐光堅牢度を有する上記11に記載の方法。
13. 前記繊維がAATCC方法番号16−1998を用いて488kJ入射UV放射線での露光後に4〜5の耐光堅牢度を有する上記11〜13のいずれか一項に記載の方法。
14. 前記繊維がある初期テナシティを有し、そして前記初期テナシティがAATCC方法番号16−1998を用いて488kJ入射UV放射線での露光後に約10%以下だけ低下する上記11〜14のいずれか一項に記載の方法。
Claims (1)
- a.ポリ(トリメチレンテレフタレート)繊維を提供する工程と、
b.0.50重量パーセントのアルコールエトキシレート界面活性剤、0.25重量パーセントの金属イオン封鎖剤、3.00重量パーセントのベンゾトリアジン誘導体UV吸収剤、および0.5重量パーセントの分散染料が水性媒体中で室温で組み合わせられて2:1〜40:1の水:繊維比を提供する染浴を提供する工程と、
c.前記染浴のpHを4〜6に調整する工程と、
d.前記繊維と染浴を室温で組み合わせる工程と、
e.前記染浴を少なくとも1℃毎分の加熱速度で132〜145℃の温度に加熱する工程と、
f.染浴温度を少なくとも30分間維持して染色されたポリ(トリメチレンテレフタレート)繊維を生成する工程と、
g.前記染浴を放冷する工程と、
h.前記染色されたポリ(トリメチレンテレフタレート)繊維をリンスする工程と
を含む、染色されたポリ(トリメチレンテレフタレート)繊維の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/865,112 US7196125B2 (en) | 2004-06-10 | 2004-06-10 | Poly(trimethylene terephthalate) fibers useful in high-UV exposure end uses |
US10/865,112 | 2004-06-10 | ||
PCT/US2005/020415 WO2005123823A2 (en) | 2004-06-10 | 2005-06-08 | Poly(trimethylene terephthalate) fibers useful in high-uv exposure end uses |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2008502820A JP2008502820A (ja) | 2008-01-31 |
JP2008502820A5 JP2008502820A5 (ja) | 2008-07-31 |
JP4871871B2 true JP4871871B2 (ja) | 2012-02-08 |
Family
ID=35461348
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007527758A Expired - Fee Related JP4871871B2 (ja) | 2004-06-10 | 2005-06-08 | 高いuv露光最終用途で有用なポリ(トリメチレンテレフタレート)繊維 |
Country Status (7)
Country | Link |
---|---|
US (1) | US7196125B2 (ja) |
EP (1) | EP1753809B1 (ja) |
JP (1) | JP4871871B2 (ja) |
KR (1) | KR101238117B1 (ja) |
CN (1) | CN1965023A (ja) |
TW (1) | TWI381080B (ja) |
WO (1) | WO2005123823A2 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20051202A1 (it) * | 2005-06-24 | 2006-12-25 | Alcantara Spa | Tessuto non tessuto microfibroso scamosciato ad elevata solidita' alla luce e procedimento per la sua preparazione |
JP2009505034A (ja) * | 2005-08-10 | 2009-02-05 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 耐貫通性複合材料およびそれを含んでなる物品 |
US20090152761A1 (en) * | 2007-12-12 | 2009-06-18 | Sam Louis Samuels | Process for preparation of modified poly |
CN101984002B (zh) * | 2010-07-30 | 2014-02-05 | 江苏亚邦染料股份有限公司 | 一种用于聚酯纤维高耐光牢度的蓝色分散染料 |
SG11201808168TA (en) | 2016-03-29 | 2018-10-30 | Covestro Deutschland Ag | Method for the partial coloring of plastic parts |
KR101942305B1 (ko) | 2016-11-25 | 2019-01-25 | 아크로마코리아 주식회사 | 신규의 피리딘 적색 분산 염료 조성물 및 그 제조방법 |
JP7140070B2 (ja) * | 2019-07-24 | 2022-09-21 | 日東紡績株式会社 | 混用染色布帛及びその製造方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000045186A (ja) * | 1998-05-19 | 2000-02-15 | Toray Ind Inc | 人工皮革 |
JP2000144583A (ja) * | 1998-11-12 | 2000-05-26 | Toray Ind Inc | シート状物 |
JP2002180384A (ja) * | 2000-12-11 | 2002-06-26 | Asahi Kasei Corp | 染色物 |
JP2003301387A (ja) * | 2002-02-06 | 2003-10-24 | Asahi Kasei Corp | 染色物とその製造方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6385111A (ja) | 1986-09-25 | 1988-04-15 | Toray Ind Inc | ポリエステル繊維 |
DE59105836D1 (de) * | 1990-07-23 | 1995-08-03 | Ciba Geigy Ag | Wässrige Dispersion schwerlöslicher UV-Absorber. |
ATE162242T1 (de) | 1994-02-21 | 1998-01-15 | Degussa | Verfahren zum anfärben von fasern des polytrimethylenterephthalats sowie verwendung von nach diesem verfahren erhältlichen gefärbten fasern |
JPH11269779A (ja) | 1998-03-16 | 1999-10-05 | Asahi Chem Ind Co Ltd | 混用品の染法 |
US6071835A (en) * | 1998-06-16 | 2000-06-06 | Alliedsignal Inc. | Load limiting webbing |
CA2333324A1 (en) * | 1998-06-22 | 1999-12-29 | Ciba Specialty Chemicals Holding Inc. | Trisaryl-1,3,5-triazine ultraviolet light absorbers containing hindered phenols |
JP3235991B2 (ja) | 1998-12-22 | 2001-12-04 | 旭化成株式会社 | ポリトリメチレンテレフタレート繊維の染色方法 |
US6187900B1 (en) | 1999-06-07 | 2001-02-13 | Industrial Technology Research Institute | Polyester fiber of easy dyeability |
KR100339275B1 (ko) * | 2000-07-21 | 2002-06-03 | 조정래 | 이염성(易染性) 폴리에스테르 섬유 |
JP2002054047A (ja) | 2000-08-08 | 2002-02-19 | Teijin Ltd | ミシン糸 |
DE10129366B4 (de) | 2001-06-20 | 2009-06-10 | Freudenberg, Carl | Mit Pigmenten gefärbter und/oder bedruckter Vliesstoff, Verfahren zu dessen Herstellung und diese umfassende Textilien |
-
2004
- 2004-06-10 US US10/865,112 patent/US7196125B2/en not_active Expired - Lifetime
-
2005
- 2005-06-08 JP JP2007527758A patent/JP4871871B2/ja not_active Expired - Fee Related
- 2005-06-08 CN CNA2005800187591A patent/CN1965023A/zh active Pending
- 2005-06-08 WO PCT/US2005/020415 patent/WO2005123823A2/en not_active Application Discontinuation
- 2005-06-08 KR KR1020067025862A patent/KR101238117B1/ko active IP Right Grant
- 2005-06-08 EP EP05784957A patent/EP1753809B1/en not_active Ceased
- 2005-06-10 TW TW094119341A patent/TWI381080B/zh not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000045186A (ja) * | 1998-05-19 | 2000-02-15 | Toray Ind Inc | 人工皮革 |
JP2000144583A (ja) * | 1998-11-12 | 2000-05-26 | Toray Ind Inc | シート状物 |
JP2002180384A (ja) * | 2000-12-11 | 2002-06-26 | Asahi Kasei Corp | 染色物 |
JP2003301387A (ja) * | 2002-02-06 | 2003-10-24 | Asahi Kasei Corp | 染色物とその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
KR101238117B1 (ko) | 2013-03-04 |
EP1753809A2 (en) | 2007-02-21 |
WO2005123823A2 (en) | 2005-12-29 |
EP1753809B1 (en) | 2012-11-07 |
CN1965023A (zh) | 2007-05-16 |
WO2005123823A3 (en) | 2006-05-26 |
TWI381080B (zh) | 2013-01-01 |
JP2008502820A (ja) | 2008-01-31 |
EP1753809A4 (en) | 2009-12-23 |
US20050277714A1 (en) | 2005-12-15 |
TW200617239A (en) | 2006-06-01 |
US7196125B2 (en) | 2007-03-27 |
KR20070031325A (ko) | 2007-03-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4871871B2 (ja) | 高いuv露光最終用途で有用なポリ(トリメチレンテレフタレート)繊維 | |
ES2328859T3 (es) | Spandex que tiene blancura potenciada, y telas y prendas que lo comprenden. | |
US10174454B2 (en) | Polyester composition with improved dyeing properties | |
JP2007247116A (ja) | 天然系繊維製品及びその染色方法 | |
EP3141636A1 (en) | Polyester composition with improved dyeing properties | |
JP2003278017A (ja) | 保温裏地 | |
JP2004011062A (ja) | 保温靴下 | |
JP2003339503A (ja) | 保温毛布 | |
JPH08311781A (ja) | 染色法 | |
CN106519197B (zh) | 染色性能改善的聚酯组合物 | |
Avinc et al. | Colorfastness Properties of Dyed, Reduction Cleared, and Softened Poly (lactic acid) Fabrics. | |
JP2001200471A (ja) | 耐光堅牢性の改良された全芳香族ポリアミド繊維構造物 | |
JP3862063B2 (ja) | 難燃性及び抗菌性を有するポリエステル布帛の染色加工方法 | |
WO2023032387A1 (ja) | 繊維布帛及び繊維布帛の染色方法 | |
JP2003020564A (ja) | 保温サポーター | |
JP2005344262A (ja) | メタ型芳香族ポリアミド繊維 | |
Udon et al. | Properties of basic dyes on polyacrylonitrile treated m-aramid fabrics | |
JP2007084974A (ja) | ポリエステル繊維構造体およびその製造方法 | |
JPH04185701A (ja) | パンテイストツキング | |
JP2008240200A (ja) | 共重合ポリエステル繊維の製造方法 | |
JP2002249990A (ja) | 着色ポリフェニレンサルファイド部材 | |
JP2002294554A (ja) | 難燃カーテン用基布の処理方法 | |
JP2006009192A (ja) | ポリアミド系繊維を含む布帛およびその製造方法 | |
JP2002356570A (ja) | 耐光性に優れるポリフェニレンサルファイド部材の製造方法 | |
JP2011017092A (ja) | 防汚性繊維構造体および繊維製品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080609 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080609 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20101213 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101227 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110328 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110404 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110627 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110719 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111019 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111114 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111121 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4871871 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141125 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |