JP4532907B2 - ランタニド錯体を含有するインク組成物 - Google Patents
ランタニド錯体を含有するインク組成物 Download PDFInfo
- Publication number
- JP4532907B2 JP4532907B2 JP2003571358A JP2003571358A JP4532907B2 JP 4532907 B2 JP4532907 B2 JP 4532907B2 JP 2003571358 A JP2003571358 A JP 2003571358A JP 2003571358 A JP2003571358 A JP 2003571358A JP 4532907 B2 JP4532907 B2 JP 4532907B2
- Authority
- JP
- Japan
- Prior art keywords
- ink composition
- formula
- ink
- printing
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 *[n]1cncc1 Chemical compound *[n]1cncc1 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/004—Dyeing with phototropic dyes; Obtaining camouflage effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
- D06P1/0012—Effecting dyeing to obtain luminescent or phosphorescent dyeings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Description
(a)式I
Ch-は、少なくとも1個のUV吸収性二重結合を含む、負に帯電した配位子であり、
nは3又は4を表し、mは1〜4の数を表し、
nが3である場合、mは1〜4の数を表し、Lは、2,2′−ビピリジルを除き、中性の単座又は多座の窒素、酸素又は硫黄含有UV吸収性配位子であり、nが4である場合、mは1を表し、Lは、1個の電荷を有するカチオンである)
の化合物、及び
(b)液体インクキャリヤ
を含有するインク組成物に関する。
nは3又は4を表し、mは1〜4の数を表し、
nが3である場合、mは1〜4の数を表し、Lは、2,2′−ビピリジルを除き、中性の単座又は多座の窒素、酸素又は硫黄含有UV吸収性配位子であり、nが4である場合、mは1を表し、Lは、1個の電荷を有するカチオンであり、
R2は、水素又はC1〜C6アルキルであり、
R1及びR3は、互いに独立して、水素、C1〜C6アルキル、CF3、C5〜C24アリール又はC4〜C24ヘテロアリールである。
の化合物である式Iの化合物である。
1,2−プロピレングリコール中の化合物XIIの濃縮物
インク組成物A6重量部を標準のポリウレタン−アクリレート水性インクジェット用インク配合物4重量部で希釈することにより、無色の水性インクジェット用インクを調製した。上記の準無色の配合物は、白い紙、色付きの紙、白又は色付きの織物に印刷されると、UV露光下で強い赤色の発光を生じさせた。
インク組成物A1部を標準の市販ポリウレタン−アクリレート顔料含有黄色水性インクジェット用インク配合物1部で希釈することにより、顔料含有黄色水性インクジェット用インクを調製した。上記の黄色の配合物は、白い紙、色付きの紙、白又は色付きの織物に印刷されると、UV露光下で強い赤色の発光を生じさせた。
インク組成物A3部を標準の市販ポリウレタン−アクリレート顔料含有赤色水性インクジェット用インク配合物1部で希釈することにより、顔料含有赤色水性インクジェット用インクを調製した。上記の赤色の配合物は、白い紙、色付きの紙、白又は色付きの織物に印刷されると、UV露光下で強い赤色の発光を生じさせた。
Claims (7)
- (a)式II、III又はIV
nは3を表し、mは1〜4の数を表し、Lは、式V、VI、VII、VIII又はIX
R 2 は、水素又はC 1 〜C 6 アルキルであり、
R 1 及びR 3 は、互いに独立して、メチル、tert−ブチル、n−ペンチル又はフェニルである)
の化合物、及び
(b)液体インクキャリヤ
を含有するインク組成物。 - (c)バインダー樹脂をさらに含有する、請求項1記載のインク組成物。
- (d)1種以上の着色剤をさらに含有する、請求項1〜3のいずれか1項記載のインク組成物。
- UV露光下でのみ出現することができる隠しマークで物品をマーキングするためのシステムであって、前記マークを前記物品に印刷するための印刷手段を内蔵し、前記印刷手段が、内蔵された請求項1〜4のいずれか1項記載のインク組成物を用いるシステム。
- 物体に隠しマークを付ける方法であって、請求項1〜4のいずれか1項記載のインク組成物を前記物体に塗布することと、前記インクキャリヤのすべて又は実質すべてを蒸発又は前記物体中への吸収によって除去することとを含む方法。
- 前記物体が織物材料である、請求項6記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02405139 | 2002-02-26 | ||
PCT/EP2003/001620 WO2003072664A1 (en) | 2002-02-26 | 2003-02-18 | Ink compositions containing lanthanide complexes |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2005518472A JP2005518472A (ja) | 2005-06-23 |
JP2005518472A5 JP2005518472A5 (ja) | 2006-04-06 |
JP4532907B2 true JP4532907B2 (ja) | 2010-08-25 |
Family
ID=27763474
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003571358A Expired - Fee Related JP4532907B2 (ja) | 2002-02-26 | 2003-02-18 | ランタニド錯体を含有するインク組成物 |
Country Status (16)
Country | Link |
---|---|
US (1) | US7108742B2 (ja) |
EP (1) | EP1478706A1 (ja) |
JP (1) | JP4532907B2 (ja) |
KR (1) | KR101015026B1 (ja) |
CN (1) | CN1308403C (ja) |
AR (1) | AR038597A1 (ja) |
AU (1) | AU2003206918B2 (ja) |
BR (1) | BR0307945A (ja) |
CA (1) | CA2473180A1 (ja) |
MX (1) | MXPA04007383A (ja) |
NZ (1) | NZ534637A (ja) |
PL (1) | PL370078A1 (ja) |
RU (1) | RU2004129273A (ja) |
TW (1) | TW200303336A (ja) |
WO (1) | WO2003072664A1 (ja) |
ZA (1) | ZA200405408B (ja) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
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MXPA05004229A (es) * | 2002-10-30 | 2005-07-05 | Ciba Sc Holding Ag | Proceso para la incorporacion de compuestos luminiscentes de uv en materiales polimericos. |
KR100561466B1 (ko) * | 2003-08-08 | 2006-03-16 | 삼성전자주식회사 | 자가분산가능한 비피리딘계 금속 착화합물 및 이를 포함한잉크조성물 |
EP1531171A1 (en) * | 2003-11-12 | 2005-05-18 | Sicpa Holding S.A. | Inkjet ink composition exhibiting low gloss |
DE102005003596B4 (de) | 2005-01-25 | 2011-12-15 | ITCF Institut für Textilchemie und Chemiefasern | Gemisch und Verfahren zur Bedruckung von Textilien |
US10072168B2 (en) * | 2005-10-13 | 2018-09-11 | Hewlett-Packard Development Company L.P. | Marking fluids for vinyl substrates |
JP5046543B2 (ja) * | 2006-04-06 | 2012-10-10 | オリヱント化学工業株式会社 | 赤色発光材料を含有するインキ組成物 |
CN101573239B (zh) * | 2006-11-07 | 2011-07-06 | 西巴控股有限公司 | 颜料化基材的激光标记 |
BRPI0808446A2 (pt) | 2007-03-15 | 2014-08-05 | Basf Se | Composição de revestimento, processo para a preparação da mesma, substrato, processo para a preparação de um substrato marcado, e, composto. |
US9834660B2 (en) * | 2007-06-28 | 2017-12-05 | Honeywell International Inc. | Rare earth metal complexes that excite in the long UV wavelength range |
ES2377852T3 (es) * | 2007-08-22 | 2012-04-02 | Datalase Ltd | Composición de revestimiento sensible al láser |
EP2207933B1 (en) * | 2007-11-07 | 2014-05-21 | DataLase Ltd | New fiber products |
US9353275B2 (en) * | 2007-11-14 | 2016-05-31 | Hewlett-Packard Development Company, L.P. | Ink visible under narrow band UV radiation |
JP2009292748A (ja) * | 2008-06-03 | 2009-12-17 | National Institute Of Advanced Industrial & Technology | 希土類金属錯体並びにそれを用いたインク組成物及び蛍光標識剤。 |
US8936357B2 (en) * | 2008-06-30 | 2015-01-20 | Eastman Kodak Company | Inkjet printer with inks containing polyoxygenated-polyols |
US7857900B2 (en) | 2008-09-19 | 2010-12-28 | Xerox Corporation | Solid phase change fluorescent ink and ink sets |
JP5645832B2 (ja) | 2008-10-27 | 2014-12-24 | データレース リミテッドDatalase Ltd. | 基材にマーキングするためのレーザー感受性水性組成物 |
KR101658805B1 (ko) * | 2008-11-14 | 2016-09-22 | 삼성전자주식회사 | 란탄계 착물 및 이를 포함하는 비가시 발광 잉크 |
UY32616A (es) * | 2009-05-12 | 2010-12-31 | Sicpa Holding Sa | Documento seguro que comprende quelatos luminiscentes |
ES2531960T3 (es) * | 2011-02-11 | 2015-03-23 | Fábrica Nacional De Moneda Y Timbre - Real Casa De La Moneda | Pigmentos luminiscentes y su uso en aplicaciones de seguridad |
US20120314000A1 (en) * | 2011-06-10 | 2012-12-13 | George Sarkisian | Pre-treatment compositions for inkjet printing |
IN2014DN09258A (ja) | 2012-06-11 | 2015-07-10 | Sicpa Holding Sa | |
JP2015537061A (ja) | 2012-09-28 | 2015-12-24 | シクパ ホルディング ソシエテ アノニムSicpa Holding Sa | 発光性ランタニド錯体並びに該発光性錯体を含有する物品及びインク |
CA2884917A1 (en) | 2012-11-09 | 2014-05-14 | Olivier Lefebvre | Irreversibly magnetically induced images or patterns |
WO2014086531A1 (en) | 2012-12-07 | 2014-06-12 | Sicpa Holding Sa | Non-periodic tiling document security element |
KR102272449B1 (ko) | 2013-05-01 | 2021-07-06 | 시크파 홀딩 에스에이 | 동적 시각 이동을 나타내는 보안 요소 |
FR3008104B1 (fr) * | 2013-07-03 | 2015-07-17 | Commissariat Energie Atomique | Marquage fluorescent d'un substrat polymerique |
TW201601928A (zh) | 2014-03-31 | 2016-01-16 | 西克帕控股有限公司 | 包含對掌性液晶聚合物與發光物質的標記 |
FR3025206A1 (fr) * | 2014-09-01 | 2016-03-04 | Commissariat Energie Atomique | Encre coloree et luminescente, procede d'elaboration d'une telle encre et procede de marquage d'un substrat par une telle encre. |
US20180144664A1 (en) | 2015-07-01 | 2018-05-24 | Sicpa Holding Sa | Postage stamps |
CA3041994A1 (en) | 2016-12-09 | 2018-06-14 | Sicpa Holding Sa | Low energy curing offset and letterpress printing inks and printing process |
AU2017371109B2 (en) | 2016-12-09 | 2022-12-08 | Sicpa Holding Sa | Low energy curing offset and letterpress printing inks and printing process |
EP3638741B1 (en) | 2017-06-26 | 2022-06-15 | Sicpa Holding Sa | Printing of security features |
CN110684369A (zh) * | 2018-07-05 | 2020-01-14 | 中国科学技术大学 | 一种水溶性红色有机荧光染料及其制备方法以及一种水性隐形红色荧光防伪油墨和使用方法 |
CN110680767B (zh) * | 2018-07-05 | 2022-04-19 | 中国科学技术大学 | 一种水性荧光指甲油其制备方法以及使用方法 |
TW202128639A (zh) | 2019-12-18 | 2021-08-01 | 瑞士商西克帕控股有限公司 | Uv-led自由基可固化膠印墨水及印刷製程 |
EP3988320A1 (en) | 2021-12-20 | 2022-04-27 | Sicpa Holding SA | Security marking, corresponding engraved intaglio printing plate, and methods and devices for producing, encoding/decoding and authenticating said security marking |
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JPS53140105A (en) * | 1977-05-12 | 1978-12-06 | Dainippon Toryo Kk | Jet printing aqueous ink visually recognized by ultraviolet ray radiation |
FR2585987B1 (fr) * | 1985-08-08 | 1989-02-03 | Petrel Sarl | Procede de marquage de securite, matieres pourvues de marques de securite |
FR2603043B1 (fr) * | 1986-08-19 | 1988-11-10 | Petrel Sarl | Marquage de securite, matieres pourvus de marques de securite, appareil pour reveler la marque de securite |
JPS63191870A (ja) * | 1987-02-03 | 1988-08-09 | Mitsui Toatsu Chem Inc | 発光性インク組成物 |
JPS646085A (en) * | 1987-06-30 | 1989-01-10 | Mitsui Toatsu Chemicals | Luminescent compound and ink composition and resin composition containing same |
JPS646085U (ja) * | 1987-07-01 | 1989-01-13 | ||
JPH01287043A (ja) * | 1988-05-12 | 1989-11-17 | Mitsui Petrochem Ind Ltd | パラフィン系炭化水素化合物および/または水酸基を有する炭化水素化合物の製造方法 |
JPH0350291A (ja) * | 1989-07-18 | 1991-03-04 | Mitsui Toatsu Chem Inc | 発光性インク組成物 |
US5158703A (en) * | 1991-04-03 | 1992-10-27 | Mitsui Toatsu Chemicals Inc. | Resin composition for ultraviolet luminescent screen |
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JP4530569B2 (ja) * | 2000-04-10 | 2010-08-25 | 日本化薬株式会社 | 赤色蛍光材料およびそれを含有する組成物 |
JP4386565B2 (ja) * | 2000-12-07 | 2009-12-16 | オリヱント化学工業株式会社 | 紫外線励起型インキ組成物 |
JP2002275182A (ja) | 2001-03-22 | 2002-09-25 | Nippon Kayaku Co Ltd | 赤色蛍光材料およびそれを含有する組成物 |
JP4266538B2 (ja) * | 2001-07-16 | 2009-05-20 | オリヱント化学工業株式会社 | 赤色発光性インキ組成物 |
JP4266542B2 (ja) * | 2001-08-31 | 2009-05-20 | オリヱント化学工業株式会社 | 青色発光性インキ組成物 |
-
2003
- 2003-02-18 US US10/503,153 patent/US7108742B2/en not_active Expired - Fee Related
- 2003-02-18 AU AU2003206918A patent/AU2003206918B2/en not_active Ceased
- 2003-02-18 RU RU2004129273/04A patent/RU2004129273A/ru not_active Application Discontinuation
- 2003-02-18 KR KR1020047013260A patent/KR101015026B1/ko not_active IP Right Cessation
- 2003-02-18 PL PL03370078A patent/PL370078A1/xx unknown
- 2003-02-18 CA CA002473180A patent/CA2473180A1/en not_active Abandoned
- 2003-02-18 MX MXPA04007383A patent/MXPA04007383A/es active IP Right Grant
- 2003-02-18 BR BR0307945-7A patent/BR0307945A/pt not_active IP Right Cessation
- 2003-02-18 EP EP03704644A patent/EP1478706A1/en not_active Withdrawn
- 2003-02-18 JP JP2003571358A patent/JP4532907B2/ja not_active Expired - Fee Related
- 2003-02-18 CN CNB038046113A patent/CN1308403C/zh not_active Expired - Fee Related
- 2003-02-18 WO PCT/EP2003/001620 patent/WO2003072664A1/en active Application Filing
- 2003-02-18 NZ NZ534637A patent/NZ534637A/en unknown
- 2003-02-24 AR ARP030100593A patent/AR038597A1/es not_active Application Discontinuation
- 2003-02-24 TW TW092103776A patent/TW200303336A/zh unknown
-
2004
- 2004-07-07 ZA ZA200405408A patent/ZA200405408B/en unknown
Also Published As
Publication number | Publication date |
---|---|
MXPA04007383A (es) | 2004-10-11 |
BR0307945A (pt) | 2004-12-21 |
WO2003072664A1 (en) | 2003-09-04 |
CN1308403C (zh) | 2007-04-04 |
US20050119368A1 (en) | 2005-06-02 |
AU2003206918B2 (en) | 2007-12-06 |
CN1639281A (zh) | 2005-07-13 |
RU2004129273A (ru) | 2005-08-10 |
NZ534637A (en) | 2006-02-24 |
US7108742B2 (en) | 2006-09-19 |
PL370078A1 (en) | 2005-05-16 |
TW200303336A (en) | 2003-09-01 |
KR20040088546A (ko) | 2004-10-16 |
AR038597A1 (es) | 2005-01-19 |
CA2473180A1 (en) | 2003-09-04 |
AU2003206918A1 (en) | 2003-09-09 |
KR101015026B1 (ko) | 2011-02-16 |
JP2005518472A (ja) | 2005-06-23 |
ZA200405408B (en) | 2005-06-17 |
EP1478706A1 (en) | 2004-11-24 |
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