JP4217155B2 - プロピレンランダム共重合体及びその製造方法 - Google Patents
プロピレンランダム共重合体及びその製造方法 Download PDFInfo
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- JP4217155B2 JP4217155B2 JP2003509004A JP2003509004A JP4217155B2 JP 4217155 B2 JP4217155 B2 JP 4217155B2 JP 2003509004 A JP2003509004 A JP 2003509004A JP 2003509004 A JP2003509004 A JP 2003509004A JP 4217155 B2 JP4217155 B2 JP 4217155B2
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- ethylene
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- 238000000034 method Methods 0.000 title claims abstract description 48
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 44
- 229920005604 random copolymer Polymers 0.000 title claims abstract description 33
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000005977 Ethylene Substances 0.000 claims abstract description 54
- 239000004711 α-olefin Substances 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 239000002002 slurry Substances 0.000 claims description 28
- 239000003054 catalyst Substances 0.000 claims description 23
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 abstract description 60
- 229920001577 copolymer Polymers 0.000 abstract description 33
- 238000010828 elution Methods 0.000 abstract description 10
- 238000009826 distribution Methods 0.000 description 32
- 239000007789 gas Substances 0.000 description 19
- -1 polypropylene Polymers 0.000 description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 10
- 229920001155 polypropylene Polymers 0.000 description 10
- 239000008096 xylene Substances 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 8
- 230000002902 bimodal effect Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 230000007547 defect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000000071 blow moulding Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical group C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- 101100399299 Dictyostelium discoideum limG gene Proteins 0.000 description 1
- 101100280118 Homo sapiens ETV7 gene Proteins 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 102100027263 Transcription factor ETV7 Human genes 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- OANIYCQMEVXZCJ-UHFFFAOYSA-N ditert-butyl(dimethoxy)silane Chemical compound CO[Si](OC)(C(C)(C)C)C(C)(C)C OANIYCQMEVXZCJ-UHFFFAOYSA-N 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01115471A EP1270628B1 (en) | 2001-06-27 | 2001-06-27 | Propylene random copolymer and process for the production thereof |
| PCT/EP2002/007081 WO2003002625A1 (en) | 2001-06-27 | 2002-06-26 | Propylene random copolymer and process for the production thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004530778A JP2004530778A (ja) | 2004-10-07 |
| JP2004530778A5 JP2004530778A5 (enExample) | 2006-01-05 |
| JP4217155B2 true JP4217155B2 (ja) | 2009-01-28 |
Family
ID=8177837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003509004A Expired - Fee Related JP4217155B2 (ja) | 2001-06-27 | 2002-06-26 | プロピレンランダム共重合体及びその製造方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (3) | US7470756B2 (enExample) |
| EP (3) | EP1270628B1 (enExample) |
| JP (1) | JP4217155B2 (enExample) |
| KR (1) | KR100869164B1 (enExample) |
| CN (1) | CN100386354C (enExample) |
| AT (3) | ATE278723T1 (enExample) |
| CZ (1) | CZ20033535A3 (enExample) |
| DE (3) | DE60106219T2 (enExample) |
| ES (2) | ES2273300T3 (enExample) |
| PL (1) | PL202978B1 (enExample) |
| PT (2) | PT1580207E (enExample) |
| RU (1) | RU2298017C2 (enExample) |
| WO (1) | WO2003002625A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391585A (zh) * | 2011-10-08 | 2012-03-28 | 中国石油化工股份有限公司 | 一种透明瓶用聚丙烯材料及其制备方法 |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE60129939T2 (de) * | 2001-06-27 | 2008-05-15 | Borealis Technology Oy | Verfahren zur Herstellung einer Polymerfolie die ein statistisches Propylencopolymer enthält |
| US7579408B2 (en) | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
| US7622529B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
| US7714071B2 (en) | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
| US7671106B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
| US7863379B2 (en) | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
| US7514517B2 (en) | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
| US7671131B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
| DE602005009648D1 (de) * | 2005-01-14 | 2008-10-23 | Borealis Polymers Oy | Heterophasische Polymerzusammensetzung und Verfahren zu ihrer Herstellung |
| WO2006095762A1 (ja) * | 2005-03-08 | 2006-09-14 | Du Pont/Mitsui Polychemicals Co. Ltd. | 太陽電池封止材 |
| ZA200707883B (en) * | 2005-03-17 | 2008-12-31 | Dow Global Technologies Inc | Thermoplastic vulcanizate comprising interpolymers ethylene/alpha-olefins |
| CA2601233A1 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/alpha-olefins |
| CN101175778B (zh) | 2005-05-12 | 2011-12-07 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯-乙烯共聚物和它们的制备方法 |
| EP1801157B1 (en) * | 2005-12-22 | 2010-09-22 | Borealis Technology Oy | Polypropylene composition comprising a propylene copolymer component |
| US7977435B2 (en) * | 2006-07-12 | 2011-07-12 | Lin Chon-Yie | Propylene polymer compositions and processes for making the same |
| BRPI0713834B1 (pt) * | 2006-07-28 | 2018-12-26 | Basell Poliolefine Italia Srl | polímeros de propileno |
| EP1980577A1 (en) * | 2007-04-10 | 2008-10-15 | Borealis Technology OY | Pipes comprising ß-nucleated propylene copolymers |
| ES2354383T5 (es) * | 2007-08-10 | 2021-06-21 | Borealis Tech Oy | Artículo que comprende una composición de polipropileno |
| PL2072587T3 (pl) * | 2007-12-20 | 2020-11-02 | Borealis Technology Oy | Powlekane rury o ulepszonych właściwościach mechanicznych w wysokich temperaturach i sposób ich wytwarzania |
| WO2010034515A1 (en) | 2008-09-29 | 2010-04-01 | Borealis Ag | Polyolefin composition |
| EP2174965B1 (en) * | 2008-10-08 | 2013-05-29 | Borealis AG | Preparation of propylene copolymer with dynamically operated reactor |
| CN102203179B (zh) * | 2008-10-27 | 2013-09-11 | 北欧化工公司 | 具有高刚度和透明度的挤出吹塑成型瓶子 |
| EP2350186B1 (en) | 2008-10-27 | 2013-02-20 | Borealis AG | Extrusion blown molded bottles with high stiffness and transparency |
| CN102224173B (zh) * | 2008-11-21 | 2013-11-06 | 北欧化工公司 | 用于改进无规聚丙烯粉末流动性的方法 |
| EP2199650A1 (en) * | 2008-12-19 | 2010-06-23 | Borealis AG | Layer for pipes made of multimodal polyethylene composition |
| US8507717B2 (en) * | 2008-12-31 | 2013-08-13 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| KR101060012B1 (ko) * | 2009-06-02 | 2011-08-29 | 주식회사 효성 | 폴리프로필렌 랜덤 공중합체의 제조방법 |
| EP2338930A1 (en) | 2009-12-23 | 2011-06-29 | Borealis AG | Blownfilm grade showing superior stiffness, transparency and processing behaviour |
| EP2338931A1 (en) | 2009-12-23 | 2011-06-29 | Borealis AG | Blown grade showing superior stiffness, transparency and processing behaviour |
| EP2386604B1 (en) * | 2010-04-20 | 2018-11-28 | Borealis AG | Polypropylene bottles |
| PL2561016T3 (pl) | 2010-04-21 | 2015-10-30 | Borealis Ag | Kompozycja kopolimeru propylenowo-1-heksenowego o niskiej temperaturze zgrzewania |
| EP2380926B1 (en) | 2010-04-26 | 2017-06-21 | Borealis AG | Masterbatch for improving stiffness and transparency of a random propylene copolymer |
| CN102453181A (zh) * | 2010-10-29 | 2012-05-16 | 中国石油化工股份有限公司 | 一种丙烯乙烯无规共聚物 |
| CN102453186B (zh) * | 2010-10-29 | 2016-04-27 | 中国石油化工股份有限公司 | 一种丙烯乙烯无规共聚物的制备方法 |
| CN102453179A (zh) * | 2010-10-29 | 2012-05-16 | 中国石油化工股份有限公司 | 一种丙烯无规共聚物 |
| EP2487203B2 (en) | 2011-02-14 | 2020-11-25 | Borealis AG | Sealing propylene copolymer |
| CA2830286C (en) | 2011-03-18 | 2020-03-10 | Ineos Manufacturing Belgium Nv | Propylene-ethylene random copolymer |
| EP2736930B1 (en) * | 2011-07-28 | 2016-04-06 | W.R. Grace & Co.-Conn. | Propylene/ethylene copolymer film for heat seal |
| CN103130939A (zh) * | 2013-03-18 | 2013-06-05 | 中国石油化工股份有限公司 | 一种丙烯/1-丁烯无规共聚物的生产方法 |
| AU2014243188B2 (en) | 2013-03-26 | 2016-05-12 | Borealis Ag | Propylene copolymer with high impact properties |
| BR112015028319B8 (pt) * | 2013-05-22 | 2021-07-06 | Borealis Ag | copolímero de propileno, artigo moldado por injeção, embalagem com pequena espessura e processo de produção do copolímero |
| PT2999722T (pt) * | 2013-05-22 | 2018-11-26 | Borealis Ag | Polipropileno para aplicações de películas |
| ES2646195T3 (es) | 2013-05-29 | 2017-12-12 | Abu Dhabi Polymers Co. Ltd (Borouge) Llc. | Polipropileno bimodal para películas hechas por colada o una película metalizada en donde el polipropileno comprende dos fracciones que difieren en el contenido de comonómeros |
| RU2637930C2 (ru) * | 2013-06-26 | 2017-12-08 | Бореалис Аг | Сополимер пропилена для бутылок, изготавливаемых пневмоформованием с экструзией |
| KR102227838B1 (ko) * | 2013-10-29 | 2021-03-12 | 더블유.알. 그레이스 앤드 캄파니-콘. | 파이프에 적합한 프로필렌 에틸렌 랜덤 공중합체 |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US9593179B2 (en) | 2014-02-07 | 2017-03-14 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| CZ27700U1 (cs) * | 2014-10-15 | 2015-01-12 | Pipelife Czech S.R.O. | Termoplastický kompozit a trubka z něho vyrobená |
| US20190127890A1 (en) * | 2016-04-22 | 2019-05-02 | Basell Poliolefine Italia S.R.L. | Propylene terpolymer for filament for 3d printer |
| EP3445793B1 (en) * | 2016-04-22 | 2020-01-01 | Basell Poliolefine Italia S.r.l. | Propylene based filament for 3d printer |
| WO2018069025A1 (en) * | 2016-10-11 | 2018-04-19 | Basell Poliolefine Italia S.R.L. | Propylene based filament for 3d printer |
| EP3609931A4 (en) * | 2017-04-12 | 2020-12-23 | W.R. Grace & Co.-Conn. | PROCESS FOR THE PRODUCTION OF LOW VOC PROPYLENE COPOLYMERS |
| US11390700B2 (en) * | 2017-05-18 | 2022-07-19 | Borealis Ag | Propylene-ethylene random copolymer with improved irradiation resistance |
| CN107151390B (zh) * | 2017-06-09 | 2020-03-03 | 湖北远大天天明制药有限公司 | 一种多相丙烯共聚物及其作为贮藏容器中的应用 |
| WO2019241063A1 (en) * | 2018-06-11 | 2019-12-19 | W.R. Grace & Co.-Conn. | Propylene-ethylene copolymer compositions suitable for hot fill packaging of foodstuffs |
| EP3870423A4 (en) | 2018-10-26 | 2022-07-20 | W. R. Grace & Co.-Conn | Polypropylene random copolymer composition for cold and hot water pipe applications |
| WO2020099566A1 (en) | 2018-11-15 | 2020-05-22 | Borealis Ag | Propylene butene copolymer |
| CN113195623B (zh) | 2018-11-15 | 2024-02-06 | 博里利斯股份公司 | 组合物 |
| SG11202102319WA (en) | 2018-11-15 | 2021-04-29 | Abu Dhabi Polymers Co Ltd Borouge | Polymer composition for blow molding applications |
| WO2020099563A1 (en) | 2018-11-15 | 2020-05-22 | Borealis Ag | Propylene butene copolymer |
| CN110437359A (zh) * | 2019-07-03 | 2019-11-12 | 联泓新材料科技股份有限公司 | 一种奶茶杯用的聚丙烯的制备方法 |
| CN113183452B (zh) * | 2021-06-09 | 2022-08-02 | 中国科学院空间应用工程与技术中心 | 一种机械性能可变的多材料复杂结构4d打印方法及产品 |
| WO2023004039A1 (en) * | 2021-07-22 | 2023-01-26 | Braskem America, Inc. | Polypropylene polymers for powder bed fusion based additive manufacturing |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63159412A (ja) * | 1986-12-23 | 1988-07-02 | Mitsubishi Kasei Corp | プロピレン共重合体の製造方法 |
| JPS63168414A (ja) * | 1986-12-29 | 1988-07-12 | Mitsubishi Kasei Corp | プロピレン共重合体の製造法 |
| CA2102542A1 (en) * | 1992-11-12 | 1994-05-13 | Thaddeus W. Klimek | Gas-phase process for producing copolymer of propylene and ethylene and polyolefin films made therefrom |
| US5587436A (en) * | 1992-11-12 | 1996-12-24 | Quantum Chemical Corporation | Process for controlling the polymerization of propylene and ethylene and copolymer products |
| US5331047A (en) * | 1993-02-17 | 1994-07-19 | Himont Incorporated | Olefin polymer films |
| CA2116081C (en) * | 1993-12-17 | 2005-07-26 | Ann Louise Mccormack | Breathable, cloth-like film/nonwoven composite |
| DE19606510A1 (de) * | 1996-02-22 | 1997-08-28 | Hoechst Ag | Hochmolekulares Polypropylen mit breiter Molmassenverteilung |
| CA2262468A1 (en) * | 1996-09-04 | 1998-03-12 | Exxon Chemical Patents, Inc. | Improved propylene polymers for oriented films |
| US6583227B2 (en) * | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
| US5962537A (en) | 1997-05-06 | 1999-10-05 | Exxon Research And Engineering Co | Multizone downcomer for slurry hydrocarbon syntheses process |
| FI104824B (fi) * | 1997-06-24 | 2000-04-14 | Borealis As | Menetelmä propeenin terpolymeerien aikaansaamiseksi |
| FI111848B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| FI111846B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi |
| FI111847B (fi) * | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä propeenin kopolymeerien valmistamiseksi |
| JP4037468B2 (ja) * | 1997-06-24 | 2008-01-23 | ボレアリス エー／エス | プロピレンを含む異相ポリマーの製造方法 |
| JP3378517B2 (ja) * | 1997-12-11 | 2003-02-17 | 住友化学工業株式会社 | プロピレン系重合体、その製造方法およびそれから得られる発泡成形体 |
| JPH11255824A (ja) * | 1998-03-11 | 1999-09-21 | Japan Polychem Corp | 放射線照射用食品容器 |
| EP0982328B1 (en) * | 1998-08-25 | 2003-07-23 | Idemitsu Petrochemical Co., Ltd. | Propylene resin compositions, process for the preparation thereof, and use thereof. |
| WO2000012573A1 (en) * | 1998-09-01 | 2000-03-09 | Idemitsu Petrochemical Co., Ltd. | Propylene random copolymer, propylene resin composition, film of these, and multilayered propylene resin laminate |
| EP1270627B1 (en) * | 2001-06-27 | 2005-01-12 | Borealis Technology Oy | Propylene polymer resin with improved properties |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391585A (zh) * | 2011-10-08 | 2012-03-28 | 中国石油化工股份有限公司 | 一种透明瓶用聚丙烯材料及其制备方法 |
| CN102391585B (zh) * | 2011-10-08 | 2013-06-26 | 中国石油化工股份有限公司 | 一种透明瓶用聚丙烯材料及其制备方法 |
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