JP2021113307A - エチレンビニルアルコール共重合体樹脂組成物並びにそのフィルム及び多層構造体 - Google Patents
エチレンビニルアルコール共重合体樹脂組成物並びにそのフィルム及び多層構造体 Download PDFInfo
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- JP2021113307A JP2021113307A JP2020215845A JP2020215845A JP2021113307A JP 2021113307 A JP2021113307 A JP 2021113307A JP 2020215845 A JP2020215845 A JP 2020215845A JP 2020215845 A JP2020215845 A JP 2020215845A JP 2021113307 A JP2021113307 A JP 2021113307A
- Authority
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- Japan
- Prior art keywords
- resin composition
- evoh
- vinyl alcohol
- fluorine
- ethylene vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 title claims abstract description 228
- 239000011342 resin composition Substances 0.000 title claims abstract description 115
- 239000002245 particle Substances 0.000 claims abstract description 81
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000011737 fluorine Substances 0.000 claims abstract description 71
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 71
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052796 boron Inorganic materials 0.000 claims abstract description 28
- 229920002313 fluoropolymer Polymers 0.000 claims description 51
- 238000002844 melting Methods 0.000 claims description 36
- 230000008018 melting Effects 0.000 claims description 36
- 239000010410 layer Substances 0.000 claims description 21
- -1 polypropylene Polymers 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 10
- 150000001639 boron compounds Chemical class 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 abstract description 192
- 239000008188 pellet Substances 0.000 abstract description 26
- 239000010408 film Substances 0.000 description 62
- 239000004811 fluoropolymer Substances 0.000 description 50
- 230000000052 comparative effect Effects 0.000 description 28
- 238000000034 method Methods 0.000 description 28
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 20
- 239000005977 Ethylene Substances 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 15
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 13
- 239000000523 sample Substances 0.000 description 12
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 238000001556 precipitation Methods 0.000 description 9
- 241000251468 Actinopterygii Species 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910021538 borax Inorganic materials 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 6
- 235000010338 boric acid Nutrition 0.000 description 6
- 229960002645 boric acid Drugs 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 229910001873 dinitrogen Inorganic materials 0.000 description 6
- 235000010339 sodium tetraborate Nutrition 0.000 description 6
- 239000004327 boric acid Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229920000609 methyl cellulose Polymers 0.000 description 5
- 239000001923 methylcellulose Substances 0.000 description 5
- 235000010981 methylcellulose Nutrition 0.000 description 5
- 238000007127 saponification reaction Methods 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- AUTNMGCKBXKHNV-UHFFFAOYSA-P diazanium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [NH4+].[NH4+].O1B([O-])OB2OB([O-])OB1O2 AUTNMGCKBXKHNV-UHFFFAOYSA-P 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- HKFZDVPCCOOGEV-UHFFFAOYSA-N nickel(3+);borate Chemical compound [Ni+3].[O-]B([O-])[O-] HKFZDVPCCOOGEV-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 150000004291 polyenes Chemical class 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 3
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 3
- QGBLCIBATKETJC-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;manganese(2+) Chemical compound [Mn+2].O1B([O-])OB2OB([O-])OB1O2 QGBLCIBATKETJC-UHFFFAOYSA-N 0.000 description 2
- DOVLHZIEMGDZIW-UHFFFAOYSA-N [Cu+3].[O-]B([O-])[O-] Chemical compound [Cu+3].[O-]B([O-])[O-] DOVLHZIEMGDZIW-UHFFFAOYSA-N 0.000 description 2
- XLLZUKPXODPNPP-UHFFFAOYSA-N [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] XLLZUKPXODPNPP-UHFFFAOYSA-N 0.000 description 2
- BUWURQPWRDROFU-UHFFFAOYSA-N [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] BUWURQPWRDROFU-UHFFFAOYSA-N 0.000 description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 2
- XBJJRSFLZVLCSE-UHFFFAOYSA-N barium(2+);diborate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]B([O-])[O-].[O-]B([O-])[O-] XBJJRSFLZVLCSE-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005674 electromagnetic induction Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- ZPPSOOVFTBGHBI-UHFFFAOYSA-N lead(2+);oxido(oxo)borane Chemical compound [Pb+2].[O-]B=O.[O-]B=O ZPPSOOVFTBGHBI-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VPOLVWCUBVJURT-UHFFFAOYSA-N pentadecasodium;pentaborate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] VPOLVWCUBVJURT-UHFFFAOYSA-N 0.000 description 2
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 2
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- YTCHAEAIYHLXBK-UHFFFAOYSA-N 2-chloro-1,1,3,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=C(Cl)C(F)(F)F YTCHAEAIYHLXBK-UHFFFAOYSA-N 0.000 description 1
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- YAMJITULHOEKMI-UHFFFAOYSA-N B([O-])([O-])[O-].[Ag+3] Chemical compound B([O-])([O-])[O-].[Ag+3] YAMJITULHOEKMI-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- GABQNAFEZZDSCM-RMKNXTFCSA-N Cinnamyl anthranilate Chemical compound NC1=CC=CC=C1C(=O)OC\C=C\C1=CC=CC=C1 GABQNAFEZZDSCM-RMKNXTFCSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- 241000976924 Inca Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BKIFLZBXPJKAJF-UHFFFAOYSA-N OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N Chemical compound OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N BKIFLZBXPJKAJF-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- QFVJLAYKIQBTGJ-UHFFFAOYSA-N [Cu+2].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [Cu+2].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] QFVJLAYKIQBTGJ-UHFFFAOYSA-N 0.000 description 1
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 description 1
- XVDCMYGYCHKSOH-UHFFFAOYSA-N [K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] XVDCMYGYCHKSOH-UHFFFAOYSA-N 0.000 description 1
- MZMIWABCFXURCX-UHFFFAOYSA-N [Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].OB(O)[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].OB(O)[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] MZMIWABCFXURCX-UHFFFAOYSA-N 0.000 description 1
- CSPKQASYQIUQRF-UHFFFAOYSA-N [Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical compound [Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[Ni+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] CSPKQASYQIUQRF-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- CQLZEWXXRJJDKG-UHFFFAOYSA-N azanium;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluorodecanoate Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CQLZEWXXRJJDKG-UHFFFAOYSA-N 0.000 description 1
- ACOIWNYPCCHUDF-UHFFFAOYSA-N barium(2+);tetraborate Chemical compound [Ba+2].[Ba+2].[Ba+2].[Ba+2].[Ba+2].[Ba+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] ACOIWNYPCCHUDF-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- YISOXLVRWFDIKD-UHFFFAOYSA-N bismuth;borate Chemical compound [Bi+3].[O-]B([O-])[O-] YISOXLVRWFDIKD-UHFFFAOYSA-N 0.000 description 1
- 229910001730 borate mineral Inorganic materials 0.000 description 1
- 239000010429 borate mineral Substances 0.000 description 1
- WUXDZHVEKQZJSQ-UHFFFAOYSA-N cadmium(2+);tetraborate Chemical compound [Cd+2].[Cd+2].[Cd+2].[Cd+2].[Cd+2].[Cd+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] WUXDZHVEKQZJSQ-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- WEZJBAOYGIDDLB-UHFFFAOYSA-N cobalt(3+);borate Chemical compound [Co+3].[O-]B([O-])[O-] WEZJBAOYGIDDLB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 description 1
- HQYGGVLSRVLMEE-UHFFFAOYSA-N dimagnesium dioxidoboranyloxy(dioxido)borane Chemical compound [Mg+2].[Mg+2].[O-]B([O-])OB([O-])[O-] HQYGGVLSRVLMEE-UHFFFAOYSA-N 0.000 description 1
- KTDLRMKJADTUIF-UHFFFAOYSA-N dodecasilver;tetraborate Chemical compound [Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[Ag+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] KTDLRMKJADTUIF-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
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- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 1
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- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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Abstract
Description
本出願の特許請求の範囲は、2019年12月30日に出願された「エチレンビニルアルコールペレット及びそのフィルム」と題する米国特許出願第16/729,984号の優先権を主張するものであり、且つ本出願は当該出願の一部継続出願であり、その全内容は参照によりここに組み込まれる。
本発明は、エチレンビニルアルコール共重合体(ethylene−vinyl alcohol,EVOH)樹脂組成物及びそのペレットに関するものである。エチレンビニルアルコール共重合体樹脂組成物は粒子を有しており、特に含フッ素粒子を有している。EVOH樹脂組成物は、10〜450ppmのホウ素含有量を有し得る。本発明はさらに、エチレンビニルアルコール共重合体樹脂組成物及び/又はペレットにより形成された、フィルム及び多層構造体を開示する。
オートクレーブを回分反応器として使用し、実施例フッ素ポリマーAを調製した。オートクレーブの内容積は約20Lであり、電磁誘導撹拌装置が設置されている。オートクレーブに窒素ガス(N2)を十分に充填し、その後に減圧した窒素ガスを5回充填した。
同様のオートクレーブを使用して実施例フッ素ポリマーBを調製し、且つ実施例フッ素ポリマーAと同じ方法に従って設置を行った。オートクレーブは同様に減圧した窒素ガスの充填を5回繰り返した。
実施例フッ素ポリマーAの調製に用いたのと同様のオートクレーブ及び誘導撹拌装置を使用して、実施例フッ素ポリマーCを調製した。オートクレーブに窒素ガスを十分に充填し、且つ3Lの組成物を加えた。当該組成物には脱酸素純水及び乳化剤として30gのノナデカフルオロデカン酸アンモニウムが含有されている。オートクレーブ内の組成物を60℃まで加熱して、380rpmで攪拌した。
容積が約3Lのオートクレーブを回分反応器として使用し、実施例フッ素ポリマーDを調製した。オートクレーブは電磁誘導撹拌装置を備えている。936gの脱イオン水、0.36gのメチルセルロース、360gのVDF、0.3gのt−ブチルパーオキシピバレート(tert−butyl peroxypivalate)、0.36gのピロリン酸ナトリウム、0.36gの酸性ピロリン酸ナトリウム及び1.8gの炭酸ジエチルのバッチをオートクレーブにセットして加え、10℃で30分間撹拌した後、45℃で140分間加熱した。
△Tab=|(A−B)|/(A又はB)小さいほう
△Tbc=|(B−C)|/(B又はC)小さいほう
△Tac=|(A−C)|/(A又はC)小さいほう
110 含フッ素粒子
120 コーティング層
Claims (13)
- エチレンビニルアルコール共重合体と、
1種類以上の含フッ素粒子と、
ホウ素化合物と、を含み、10〜450ppmのホウ素含有量を有する、エチレンビニルアルコール共重合体樹脂組成物。 - さらに、第1融点温度及び第2融点温度の2つの融点温度を少なくとも含む、請求項1に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 前記第1融点温度は約100℃〜約140℃である、請求項2に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 前記第2融点温度は約150℃〜約195℃である、請求項2又は3に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 前記1種類以上の含フッ素粒子はフッ化ポリマーを含む、請求項1から4のいずれか1項に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 前記含フッ素粒子は、約1.5〜約47wt%のフッ素含有量を含み、前記フッ素含有量は炭素、酸素及びフッ素元素の総重量に基づいている、請求項1から5のいずれか1項に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 各前記含フッ素粒子の粒径は直径又は主軸長さが20μm未満である、請求項1から6のいずれか1項に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 各前記含フッ素粒子の粒径は直径又は主軸長さが0.3〜約18μmである、請求項7に記載のエチレンビニルアルコール共重合体樹脂組成物。
- ホウ素含有量は20〜350ppmである、請求項1から8のいずれか1項に記載のエチレンビニルアルコール共重合体樹脂組成物。
- 請求項1から9のいずれか1項に記載のエチレンビニルアルコール共重合体樹脂組成物を含み、ISO 179−1に基づくシャルピー衝撃強度(Charpy impact strength)は、23℃下で少なくとも2.5KJ/m2であり、ISO 527−2に基づく破断点伸びは、23℃下で少なくとも18%である、フィルム。
- 前記破断点伸びは少なくとも20%である、請求項10に記載のフィルム。
- (a)請求項1から9のいずれか1項に記載のエチレンビニルアルコール共重合体樹脂組成物により形成された少なくとも1つの層と、
(b)少なくとも1つのポリマー層と、
(c)少なくとも1つの粘着剤層と、を含む、多層構造体。 - 前記ポリマー層は、低密度ポリエチレン層、ポリエチレングラフト無水マレイン酸層、ポリプロピレン層、ナイロン層及びそれらの組み合わせで組成されたグループから選択されている、請求項12に記載の多層構造体。
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US16/729,984 | 2019-12-30 | ||
US16/729,984 US10711124B1 (en) | 2019-12-30 | 2019-12-30 | Ethylene vinyl alcohol pellets as well as films thereof |
US16/877,555 US10982084B1 (en) | 2019-12-30 | 2020-05-19 | Ethylene vinyl alcohol copolymer resin composition as well as films and multi-layer structures thereof |
US16/877,570 | 2020-05-19 | ||
US16/877,555 | 2020-05-19 | ||
US16/877,570 US10961375B1 (en) | 2019-12-30 | 2020-05-19 | Ethylene vinyl alcohol copolymer resin composition as well as films and multi-layer structures thereof |
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CN113121908A (zh) | 2021-07-16 |
CN112574498A (zh) | 2021-03-30 |
BR102020026505A2 (pt) | 2021-07-13 |
EP3845597A1 (en) | 2021-07-07 |
SG10202013100UA (en) | 2021-07-29 |
KR20210086958A (ko) | 2021-07-09 |
CN112574498B (zh) | 2022-04-01 |
TW202124565A (zh) | 2021-07-01 |
JP2021109970A (ja) | 2021-08-02 |
JP7231603B2 (ja) | 2023-03-01 |
JP2023168356A (ja) | 2023-11-24 |
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