JP2020517562A - 粒子システムと方法 - Google Patents
粒子システムと方法 Download PDFInfo
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- JP2020517562A JP2020517562A JP2019556712A JP2019556712A JP2020517562A JP 2020517562 A JP2020517562 A JP 2020517562A JP 2019556712 A JP2019556712 A JP 2019556712A JP 2019556712 A JP2019556712 A JP 2019556712A JP 2020517562 A JP2020517562 A JP 2020517562A
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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Abstract
Description
本願は、2017年4月20日に出願された米国仮出願第62/487,795号、2017年8月28日に出願された米国仮出願第62/551,059号、および2017年8月28日に出願された米国仮出願第62/551,072号の利益を主張する。これらはそれぞれ参照により本書に完全に組み込まれる。
など)を有する場合がある。1または複数の炭素粒子は、本明細書に記載の1または複数の他の特性と組み合わせてそのような構造を有してもよい。
は、本明細書に記載される1または複数の他の特性と組み合わせてそのような純度を有し得る。
[実施例1]
炭素粒子は、炭化水素注入器が2つの同心電極の中心に挿入される図4に示されたものと同様のセットアップを使用して製造される。注入器の先端は、電極の平面から14インチ上にあり、電極は650kWで動作している。電極間の環内の水素流量は90Nm3/時(標準立方メートル/時)で、電極の外側のシールドフローは242Nm3/時である。天然ガスは88kg/時間の割合で注入される。メタン変換率に基づくカーボンナノ粒子の収率は95%を超えている。
炭素粒子は、炭化水素注入器が2つの同心電極の中心に挿入される図4に示されたものと同様のセットアップを使用して製造される。注入器の先端は、電極の平面から14インチ上にあり、電極は850kWで動作している。電極間の環内の水素流量は235nm3/時(標準立方メートル/時)で、電極の外側のシールドフローは192nm3/時である。天然ガスは103kg/時間の割合で注入される。メタン変換率に基づくカーボンナノ粒子の収率は94%を超えている。
Claims (164)
- 炭素粒子を生成するためのシステムであって、
1または複数の材料の流れの中で少なくとも1つの材料の流れを加熱する熱発生器、および
前記1または複数の材料の流れから前記炭素粒子を生成する反応器であって、前記炭素粒子が(i)約0.05%未満の灰、約5ppm未満の325メッシュグリット、またはそれらの組み合わせの純度、(ii)約3.0ナノメートル(nm)より大きい格子定数(Lc)、および(iii)約0.35nm未満のグラファイトの002ピークの格子間隔(d002)を有する反応器
を備えるシステム。 - 前記炭素粒子が約0.3%未満の硫黄を備える、請求項1に記載のシステム。
- 前記炭素粒子が約50ppm以下の硫黄を備える、請求項2に記載のシステム。
- 前記炭素粒子が約10ppm以下の硫黄を備える、請求項3に記載のシステム。
- 前記炭素粒子が約0.03%以下の灰を備える、請求項1に記載のシステム。
- 前記炭素粒子が約0.01%以下の灰を備える、請求項5に記載のシステム。
- 前記炭素反応器が前記熱発生器を備える、請求項1に記載のシステム。
- 前記熱発生器は、電気エネルギーで前記少なくとも1つの材料の流れを加熱する、請求項1に記載のシステム。
- 前記炭素粒子が、約15m2/g(グラム当たり平方メートル)から約300m2/gの表面積を有する、請求項1に記載のシステム。
- 前記炭素粒子がカーボンブラックを含む、請求項1に記載のシステム。
- 前記炭素粒子は、約1ppm以下の325メッシュグリットを備える、請求項1に記載のシステム。
- 炭素粒子の製造方法であって、
熱伝達ガスを加熱することと、
前記炭素粒子を生成するために、前記熱伝達ガスと炭化水素原料を混合することであって、前記炭素粒子は、(a)前記炭素粒子の圧縮されたフタル酸ジブチル(CDBP)吸収の約1.3倍以下であるフタル酸ジブチル(DBP)吸収、または(b)約15m2/g(平方メートル/グラム)から約300m2/gの表面積、および純度が約0.05%未満の灰および/または約5ppm未満の325メッシュグリットである、混合することと
を含む方法。 - 前記炭素粒子および水素ガスを生成するために、前記熱伝達ガスを前記炭化水素原料と混合することをさらに含む、請求項12に記載の方法。
- 前記加熱の下流で前記熱伝達ガスを前記炭化水素原料と混合することをさらに含む、請求項12に記載の方法。
- 前記熱伝達ガスが約60%を超える水素を備える、請求項12に記載の方法。
- 前記熱伝達ガスが水素である、請求項15に記載の方法。
- 前記炭化水素原料が少なくとも約70重量%のメタン、エタン、プロパンまたはそれらの混合物を備える、請求項12に記載の方法。
- 前記炭素粒子がカーボンブラックを含む、請求項12に記載の方法。
- 前記加熱することは、電気エネルギーで加熱することを含む、請求項12に記載の方法。
- 前記加熱することは、電気アークにより加熱することを含む、請求項19に記載の方法。
- 前記炭素粒子が約0.03%以下の灰を備える、請求項12に記載の方法。
- 前記炭素粒子が約0.01%以下の灰を備える、請求項21に記載の方法。
- 前記炭素粒子が、約1ppm以下の325メッシュグリットを備える、請求項12に記載の方法。
- (i)油ペレット化、または(ii)蒸留水および無灰バインダーによるペレット化を使用して前記炭素粒子をペレット化することをさらに含む、請求項12に記載の方法。
- 前記無灰バインダーが糖である、請求項24に記載の方法。
- 前記炭素粒子が約0.4%以下の酸素を備える、請求項12に記載の方法。
- 前記炭素粒子が約99%以上の炭素を備える、請求項12に記載の方法。
- 前記炭素粒子が約0.4%未満の水素を備える、請求項12に記載の方法。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項12に記載の方法。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項29に記載の方法。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項12に記載の方法。
- 前記WSPが約5mJ/m2未満である、請求項31に記載の方法。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項12に記載の方法。
- 前記炭素粒子の圧縮されたフタル酸ジブチル(CDBP)吸収の約1.3倍以下であるフタル酸ジブチル(DBP)吸収を有する炭素粒子。
- 前記粒子がカーボンブラックである、請求項34に記載の炭素粒子。
- DBPとCDBPの比が、参照カーボンブラックのDBPとCDBPの比の約95%以下である、請求項35に記載の炭素粒子。
- 前記粒子が約15m2/g(グラム当たり平方メートル)から約300m2/gの表面積を有する、請求項34に記載の炭素粒子。
- 前記炭素粒子が約1nmより大きいLcを有する、請求項34に記載の炭素粒子。
- 前記炭素粒子が約3nm以上のLcを有する、請求項38に記載の炭素粒子。
- 前記炭素粒子が約4nmより大きいLcを有する、請求項39に記載の炭素粒子。
- 前記炭素粒子は、約3.0nmより大きいLc、約0.35nmより小さいd002、またはそれらの組み合わせを有する、請求項34に記載の炭素粒子。
- 前記炭素粒子が、LaまたはLcに関して約3nmから約20nmの結晶化度を有する、請求項34に記載の炭素粒子。
- 前記DBPが前記CDBPの約1.1倍以下である、請求項34に記載の炭素粒子。
- 前記炭素粒子が約0.3重量%未満の硫黄を備える、請求項34に記載の炭素粒子。
- 前記炭素粒子が約0.4重量%以下の酸素を備える、請求項34に記載の炭素粒子。
- 前記炭素粒子が約99重量%以上の炭素を備える、請求項34に記載の炭素粒子。
- 前記炭素粒子が約0.4重量%未満の水素を備える、請求項34に記載の炭素粒子。
- 前記炭素粒子が、参照カーボンブラックよりも低い水素含有量を有する、請求項34に記載の炭素粒子。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項34に記載の炭素粒子。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項49に記載の炭素粒子。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項34に記載の炭素粒子。
- 前記WSPが約5mJ/m2未満である、請求項51に記載の炭素粒子。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項34に記載の炭素粒子。
- (i)約15m2/g(平方メートル/グラム)から約300m2/gの表面積、および(ii)純度が約0.05%未満の灰、および約5ppm未満の325メッシュグリット、またはその組み合わせを有する炭素粒子。
- 前記炭素粒子がカーボンブラック粒子を備える、請求項54に記載の炭素粒子。
- 前記炭素粒子は、約3.0nmよりも大きいLc、約0.35nmよりも小さいd002、約0.3%よりも少ない硫黄、またはそれらの任意の組み合わせを有する、請求項54に記載の炭素粒子。
- 前記炭素粒子は、約3.0nmよりも大きいLc、約0.35nmよりも小さいd002、約10ppmよりも少ない硫黄、またはそれらの任意の組み合わせを有する、請求項56に記載の炭素粒子。
- 前記炭素粒子のトートが約99%以上である、請求項54に記載の炭素粒子。
- (i)約19m2/gから約50m2/gの窒素表面積(N2SA)および約55ml/100gから約131ml/100gのフタル酸ジブチル(DBP)吸収を有する、請求項54に記載の炭素粒子。
- (i)約23m2/gから約35m2/gの窒素表面積(N2SA)および約59ml/100gから約71ml/100gのフタル酸ジブチル(DBP)吸収、または(ii)約19m2/gから約39m2/gのN2SAおよび約55ml/100gから約75ml/100gのDBPを有する、請求項54に記載の炭素粒子。
- (i)約29m2/gから約41m2/gの窒素表面積(N2SA)および約84ml/100gから約96ml/100gのフタル酸ジブチル(DBP)吸収、または(ii)約25m2/gから約45m2/gのN2SAおよび約80ml/100gから約100ml/100gのDBPを有する、請求項54に記載の炭素粒子。
- (i)約34m2/gから約46m2/gの窒素表面積(N2SA)および約115ml/100gから約127ml/100gのフタル酸ジブチル(DBP)吸収、または(ii)約30m2/gから約50m2/gのN2SAおよび約111ml/100gから約131ml/100gのDBPを有する、請求項54に記載の炭素粒子。
- 前記炭素粒子が約0.03%以下の灰を備える、請求項54に記載の炭素粒子。
- 前記炭素粒子が約0.01%以下の灰を備える、請求項63に記載の炭素粒子。
- 前記炭素粒子が約1ppm以下の325メッシュグリットを備える、請求項54に記載の炭素粒子。
- 前記炭素粒子が約0.4%以下の酸素を備える、請求項54に記載の炭素粒子。
- 前記炭素粒子が約99%以上の炭素を備える、請求項54に記載の炭素粒子。
- 前記炭素粒子が約0.4%未満の水素を備える、請求項54に記載の炭素粒子。
- 前記炭素粒子が、参照カーボンブラックよりも低い水素含有量を有する、請求項54に記載の炭素粒子。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項54に記載の炭素粒子。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項70に記載の炭素粒子。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項54に記載の炭素粒子。
- 前記WSPが約5mJ/m2未満である、請求項72に記載の炭素粒子。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項54に記載の炭素粒子。
- (i)約15平方メートル/グラム(m2/g)以上の窒素表面積(N2SA)および(ii)約5ppm未満の硫黄を有する炭素粒子。
- N2SAが約23m2/gから約35m2/gであり、フタル酸ジブチル(DBP)吸収が約59ml/100gから約71ml/100gである、請求項75に記載の炭素粒子。
- 前記炭素粒子が約約1重量ppm未満の硫黄を備える、請求項75に記載の炭素粒子。
- 前記N2SAが約300m2/g以下である、請求項75に記載の炭素粒子。
- 前記N2SAが約20m2/g以上である、請求項75に記載の炭素粒子。
- 前記炭素粒子が約0.4%以下の酸素を備える、請求項75に記載の炭素粒子。
- 前記炭素粒子が約99%以上の炭素を備える、請求項75に記載の炭素粒子。
- 前記炭素粒子が約0.4%未満の水素を備える、請求項75に記載の炭素粒子。
- 前記炭素粒子が、参照カーボンブラックよりも低い水素含有量を有する、請求項75に記載の炭素粒子。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項75に記載の炭素粒子。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項84に記載の炭素粒子。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項75に記載の炭素粒子。
- 前記WSPが約5mJ/m2未満である、請求項86に記載の炭素粒子。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項75に記載の炭素粒子。
- 請求項75に記載の前記炭素粒子を備えるゴム。
- 請求項89に記載の前記ゴムを備えるタイヤ。
- 請求項75に記載の前記炭素粒子を備える塗料。
- 請求項75に記載の前記炭素粒子を備えるコーティング。
- 請求項75に記載の前記炭素粒子を備えるエラストマー複合体。
- 請求項75に記載の前記炭素粒子を備えるポリマー。
- 請求項75に記載の前記炭素粒子を備えるインク。
- 粒子を生成するためのシステムであって、
1または複数の材料の流れの中の少なくとも1つの材料の流れを電気的に加熱する熱発生器、
1または複数の材料の流れの少なくとも1つから硫黄不純物を除去するフィルタ、および
前記1または複数の材料の流れから前記粒子を生成する反応器
を含むシステム。 - 前記粒子が炭素粒子を備える、請求項96に記載のシステム。
- 前記炭素粒子がカーボンブラックを含む、請求項97に記載のシステム。
- 前記粒子が約0.3%未満の硫黄を備える、請求項96に記載のシステム。
- 前記粒子が約50百万分率(ppm)未満の硫黄を備える、請求項99に記載のシステム。
- 前記粒子が約10ppm未満の硫黄を備える、請求項100に記載のシステム。
- 前記粒子が約5ppm未満の硫黄を備える、請求項101に記載のシステム。
- 前記粒子が約1ppm未満の硫黄を備える、請求項102に記載のシステム。
- 前記1または複数の材料の流れが原料流を含み、前記フィルタが前記原料流から硫黄不純物を除去する、請求項96に記載のシステム。
- 前記フィルタは、原料注入器に連結される、請求項96に記載のシステム。
- 前記フィルタは、前記原料注入器の入口に連結される、請求項105に記載のシステム。
- 前記粒子が約15平方メートル/グラム(m2/g)以上の窒素表面積(N2SA)を有し、約5重量ppm未満の硫黄を備える、請求項96に記載のシステム。
- 前記熱発生器はプラズマ発生器である、請求項96に記載のシステム。
- ラジエーターホース、自動車用押出成形品、中電圧電力ケーブルのケーブルフラッディング/絶縁、またはシールであるポリマー製品であって、
(a)純度が約0.05%未満の灰、および約5ppm未満の325メッシュグリット、またはその組み合わせ;約3.0ナノメートル(nm)より大きい格子定数(Lc);グラファイトの002ピークの格子間隔(d002)が約0.35nm未満;
(b)前記炭素粒子の圧縮されたフタル酸ジブチル(CDBP)吸収の約1.3倍以下のフタル酸ジブチル(DBP)吸収;
(c)約15m2/g(平方メートル/グラム)から約300m2/gの表面積;および、純度が約0.05%未満の灰、約5ppm未満の325メッシュグリット、またはそれらの組み合わせ、または
(d)窒素表面積(N2SA)が1グラム当たり約15平方メートル(m2/g)以上で、硫黄が約5ppm未満
を有する炭素粒子を含むポリマー製品。 - 前記DBPが前記CDBPの約1.1倍以下である、請求項109に記載のポリマー製品。
- 前記炭素粒子が約1重量ppm以下の325メッシュグリットを備える、請求項109に記載のポリマー製品。
- 前記炭素粒子が、約10m2/gから約30m2/gの窒素表面積(N2SA)および約70ml/100gから約120ml/100gの構造を有し、参照カーボンブラックを備えるポリマー製品と比較すると、(i)加工性の向上または改善、(ii)成形性の向上または改善、(iii)電気抵抗率の増加、(iv)分散の強化または改善、(v)押出の強化または改善、および/または(vi)生強度の増加を有する、請求項109に記載のポリマー製品。
- 前記N2SAが約15m2/gから約20m2/gであり、前記構造が約80ml/100gから約100ml/100gである、請求項112に記載のポリマー。
- 前記ポリマー製品が前記ラジエーターホースである、請求項112に記載のポリマー製品。
- 前記炭素粒子が、約17m2/gから約51m2/gの窒素表面積(N2SA)および約108ml/100gから約133ml/100gの構造を有し、参照カーボンブラックを備えるポリマー製品と比較すると、(i)表面の欠陥/欠陥の減少、(ii)虹色の減少、(iii)寸法安定性の向上または改善、(iv)分散の向上または改善、(v)押出特性の向上または改善、(v)押出平滑性の向上または改善、および/または(vi)生強度の向上を有する、請求項109に記載のポリマー製品。
- 前記N2SAが約20m2/gから約50m2/gであり、前記構造が約110ml/100gから約130ml/100gである、請求項115に記載のポリマー製品。
- 前記ポリマー製品が前記自動車用押出物である、請求項115に記載のポリマー製品。
- 前記炭素粒子が、約30m2/gから約50m2/gの窒素表面積(N2SA)および約111ml/100g以上の構造を有し、参照カーボンブラックを備えるポリマー製品と比較すると、(i)加工性の向上または改善、(ii)剥離の向上または改善、(iii)清浄度の向上、(iv)分散の強化または改善、(v)押出の強化または改善、および/または(vi)ケーブル寿命の向上または改善を有する、請求項109に記載のポリマー製品。
- 前記N2SAが約30m2/gから約50m2/gであり、前記構造が約150ml/100g以上である、請求項118に記載のポリマー製品。
- 前記ポリマー製品が、中電圧電力ケーブル用の前記ケーブルフラッディング/絶縁体である、請求項118に記載のポリマー製品。
- 前記炭素粒子が約2m2/gから約50m2/gの窒素表面積(N2SA)および約33ml/100gから約131ml/100gの構造を有し、参照カーボンブラックを備えるポリマー製品と比較して、(i)熱熟成物理特性の向上または改善、および/または(ii)屈曲サイクルおよび亀裂発生に対する耐性によって測定される動的能力の向上または改善を有する、請求項109に記載のポリマー製品。
- 前記N2SAが約20m2/gから約40m2/gであり、前記構造が約45ml/100gから約95ml/100gである、請求項121に記載のポリマー製品。
- 前記ポリマー製品が前記シールである、請求項121に記載のポリマー製品。
- 前記ポリマー製品がEPDMゴムを備える、請求項109に記載のポリマー製品。
- 前記炭素粒子が約0.4%以下の酸素を備える、請求項109に記載のポリマー製品。
- 前記炭素粒子が約99%以上の炭素を備える、請求項109に記載のポリマー製品。
- 前記炭素粒子が約0.4%未満の水素を備える、請求項109に記載のポリマー製品。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項109に記載のポリマー製品。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項128に記載のポリマー製品。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項109に記載のポリマー製品。
- 前記WSPが約5mJ/m2未満である、請求項130に記載のポリマー製品。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項109に記載のポリマー製品。
- 成形されるポリマー製品であって、
a.純度が約0.05%未満の灰、および約5ppm未満の325メッシュグリット、またはその組み合わせ;約3.0ナノメートル(nm)より大きい格子定数(Lc);グラファイトの002ピークの格子間隔(d002)が約0.35nm未満;
b.前記炭素粒子の圧縮されたフタル酸ジブチル(CDBP)吸収の約1.3倍以下のフタル酸ジブチル(DBP)吸収;
c.約15m2/g(平方メートル/グラム)から約300m2/gの表面積;および、純度が約0.05%未満の灰、約5ppm未満の325メッシュグリット、またはそれらの組み合わせ、または
d.窒素表面積(N2SA)が1グラム当たり約15平方メートル(m2/g)以上で、硫黄が約5ppm未満
を有する炭素粒子を含むポリマー製品。 - 前記炭素粒子が約2m2/gから約50m2/gの窒素表面積(N2SA)および約33ml/100gから約131ml/100gの構造を有し、参照カーボンブラックを備えるポリマー製品と比較して、(i)強化されたまたは改善された金型流動性、(ii)長い金型寿命、(iii)研磨化合物の量の減少、(iv)動的環境での長い寿命、(v)亀裂の発生が少ないこと、および/または(vi)破損が少ないことを有する、請求項133に記載のポリマー製品。
- 前記N2SAが約22m2/gから約45m2/gであり、前記構造が約42ml/100gから約100ml/100gである、請求項134に記載のポリマー。
- 前記炭素粒子が約0.4%以下の酸素を備える、請求項133に記載のポリマー製品。
- 前記炭素粒子が約99%以上の炭素を備える、請求項133に記載のポリマー製品。
- 前記炭素粒子が約0.4%未満の水素を備える、請求項133に記載のポリマー製品。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項133に記載のポリマー製品。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項139に記載のポリマー製品。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項133に記載のポリマー製品。
- 前記WSPが約5mJ/m2未満である、請求項141に記載のポリマー製品。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項133に記載のポリマー製品。
- ラジエーターホース、自動車用押出成形品、中電圧電力ケーブルのケーブルフラッディング/絶縁、またはシールであるポリマー製品であって、3.0nmを超えるLcの炭素粒子を含むポリマー製品。
- 前記炭素粒子が約0.3重量%未満の硫黄を備える、請求項144に記載のポリマー製品。
- 前記炭素粒子が約0.1重量%未満の硫黄を備える、請求項145に記載のポリマー製品。
- 前記炭素粒子が重量基準で約50百万分率(ppm)未満の硫黄を備える、請求項146に記載のポリマー製品。
- 前記炭素粒子が約10重量%以下の硫黄を備える、請求項147に記載のポリマー製品。
- 前記炭素粒子が約1重量ppm未満の硫黄を備える、請求項148に記載のポリマー製品。
- 前記炭素粒子が約0.03重量%以下の灰を備える、請求項144に記載のポリマー製品。
- 前記炭素粒子が約0.01重量%以下の灰を備える、請求項150に記載のポリマー製品。
- 前記炭素粒子が約5重量%ppm以下の325メッシュグリットを備える、請求項144に記載のポリマー製品。
- DBPとCDBPの比が、参照カーボンブラックのDBPとCDBPの比の約95%以下である、請求項144に記載のポリマー製品。
- 前記Lcが約4nmより大きい、請求項144に記載のポリマー製品。
- 前記炭素粒子がカーボンブラック粒子である、請求項144に記載のポリマー製品。
- 前記炭素粒子が約0.35nm未満のd002を有する、請求項144に記載のポリマー製品。
- 前記炭素粒子が約0.4重量%以下の酸素を備える、請求項144に記載のポリマー製品。
- 前記炭素粒子が約0.4重量%未満の水素を備える、請求項144に記載のポリマー製品。
- 前記炭素粒子が、前記炭素粒子の表面積1平方メートル当たり約0.5ml(ミリリットル)未満の水を含む相対湿度80%の空気から水を吸着する親和性を有する、請求項144に記載のポリマー製品。
- 相対湿度80%の空気から水を吸着する前記親和性が、前記炭素粒子の表面積1平方メートル当たり約0.05ml未満の水である、請求項159に記載のポリマー製品。
- 前記炭素粒子が、約0〜約8mJ/m2の水拡散圧力(WSP)を有する、請求項144に記載のポリマー製品。
- 前記WSPが約5mJ/m2未満である、請求項161に記載のポリマー製品。
- 前記炭素粒子が、約0.5μmol/m2以下の総表面酸基含有量を有する、請求項154に記載のポリマー製品。
- 前記ポリマー製品がEPDMゴムを備える、請求項154に記載のポリマー製品。
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US11760884B2 (en) | 2023-09-19 |
US20200291237A1 (en) | 2020-09-17 |
CN115637064A (zh) | 2023-01-24 |
KR20190138862A (ko) | 2019-12-16 |
WO2018195460A1 (en) | 2018-10-25 |
CN115746586A (zh) | 2023-03-07 |
EP3612600A4 (en) | 2021-01-27 |
CA3060576A1 (en) | 2018-10-25 |
CN110799602A (zh) | 2020-02-14 |
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