SG195420A1 - High energy gas flow tyre pyrolysis using rf inductive plasma in combination with lf induction heating. - Google Patents

High energy gas flow tyre pyrolysis using rf inductive plasma in combination with lf induction heating. Download PDF

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Publication number
SG195420A1
SG195420A1 SG2012042222A SG2012042222A SG195420A1 SG 195420 A1 SG195420 A1 SG 195420A1 SG 2012042222 A SG2012042222 A SG 2012042222A SG 2012042222 A SG2012042222 A SG 2012042222A SG 195420 A1 SG195420 A1 SG 195420A1
Authority
SG
Singapore
Prior art keywords
plasma
pyrolysis
induction
induction heating
gas flow
Prior art date
Application number
SG2012042222A
Inventor
Hiang Mong Tan
Tiam Kwei Tan
Original Assignee
Ael Enviro Asia Pte Ltd
Hiang Mong Tan
Tiam Kwei Tan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ael Enviro Asia Pte Ltd, Hiang Mong Tan, Tiam Kwei Tan filed Critical Ael Enviro Asia Pte Ltd
Priority to SG2012042222A priority Critical patent/SG195420A1/en
Priority to PCT/SG2013/000239 priority patent/WO2013184074A1/en
Priority to SG2014012199A priority patent/SG2014012199A/en
Publication of SG195420A1 publication Critical patent/SG195420A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/482Preparation from used rubber products, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/485Preparation involving the use of a plasma or of an electric arc
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B19/00Heating of coke ovens by electrical means
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/06Continuous processes
    • C10J3/18Continuous processes using electricity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • C10K1/028Dust removal by electrostatic precipitation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/033Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment comminuting or crushing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D11/00Arrangement of elements for electric heating in or on furnaces
    • F27D11/06Induction heating, i.e. in which the material being heated, or its container or elements embodied therein, form the secondary of a transformer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B2017/0424Specific disintegrating techniques; devices therefor
    • B29B2017/0496Pyrolysing the materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2305/00Use of metals, their alloys or their compounds, as reinforcement
    • B29K2305/08Transition metals
    • B29K2305/12Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2030/00Pneumatic or solid tyres or parts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/123Heating the gasifier by electromagnetic waves, e.g. microwaves
    • C10J2300/1238Heating the gasifier by electromagnetic waves, e.g. microwaves by plasma
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643Conversion of synthesis gas to energy
    • C10J2300/165Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/40Gasification
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2204/00Supplementary heating arrangements
    • F23G2204/20Supplementary heating arrangements using electric energy
    • F23G2204/201Plasma
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • F23G2206/202Waste heat recuperation using the heat in association with another installation with an internal combustion engine
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • F23G2206/203Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/28Plastics or rubber like materials
    • F23G2209/281Tyres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00Subject matter not provided for in other groups of this subclass
    • F27D99/0001Heating elements or systems
    • F27D99/0006Electric heating elements or system
    • F27D2099/0031Plasma-torch heating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Abstract

HIGH ENERGY GAS FLOW TYRE PYROLYSIS USING RF INDUCTIVE PLASMA IN COMBINATION WITH IF INDUCTION HEATINGAbstractThe present invention relates to a High Energy Gas Flow Tyre Pyrolysis using our technology of RF Inductive Plasma in combination with LF Induction Heating, which controls both the atmosphere and temperature of the pyrolysis process to convert waste tyres to energy. Our technology involves the use of an RF induced plasma torch coupled with careful process design parameters, operational flexibility, and an oxygen-deprived atmosphere where the pyrolysis occurs. RF torch plasma is a much more flexible pyrolysis technique because the hot plasma field is formed by passing gas through an RF induction coil. This allows different gasses to be used to control the end result and also eliminates the need to shut down the reactor to replace electrodes. The pyrolysis takes place in oxygen starved and high heat atmosphere that does not allow, in the alternate, destroys the ability for dioxins, furans, and other hazardous by-products to be produced. The different gas compositions from the tyre pyrolysis, unlike the solid fraction, are not only affected by the reaction temperature but also by the process dwell times, type of plasma gas and type of carrier gas. This variability of inputs provides the ability to produce a range of quantities of the output constituents. Combine with Induction heating, this is designed to provide high temperature to a conduit tube attached to the RF Plasma outlet. The induction heating is accomplished using this conduit tube as the heat sink. The tube then radiates and convectively heats the passing gasses, liquids and solids. This tube operates at relatively high temperatures (9009 C). Since this invention includes an RF plasma torch in-line with an LF Induction heater. The LF Induction Heater will have an angle. This will create a fluidized bath and will allow the variation of the rubber particle dwell time. This added dwell time breaks down any heavy oils leaving the Plasma torch in long chain hydrocarbon gasses that are used to increase the heating value of the syngas to produce energy from waste tyres. FIGURE 1
SG2012042222A 2012-06-07 2012-06-07 High energy gas flow tyre pyrolysis using rf inductive plasma in combination with lf induction heating. SG195420A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SG2012042222A SG195420A1 (en) 2012-06-07 2012-06-07 High energy gas flow tyre pyrolysis using rf inductive plasma in combination with lf induction heating.
PCT/SG2013/000239 WO2013184074A1 (en) 2012-06-07 2013-06-07 Plasma pyrolysis system and method for tyres
SG2014012199A SG2014012199A (en) 2012-06-07 2013-06-07 Plasma pyrolysis system and method for tyres

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SG2012042222A SG195420A1 (en) 2012-06-07 2012-06-07 High energy gas flow tyre pyrolysis using rf inductive plasma in combination with lf induction heating.

Publications (1)

Publication Number Publication Date
SG195420A1 true SG195420A1 (en) 2013-12-30

Family

ID=54256892

Family Applications (2)

Application Number Title Priority Date Filing Date
SG2012042222A SG195420A1 (en) 2012-06-07 2012-06-07 High energy gas flow tyre pyrolysis using rf inductive plasma in combination with lf induction heating.
SG2014012199A SG2014012199A (en) 2012-06-07 2013-06-07 Plasma pyrolysis system and method for tyres

Family Applications After (1)

Application Number Title Priority Date Filing Date
SG2014012199A SG2014012199A (en) 2012-06-07 2013-06-07 Plasma pyrolysis system and method for tyres

Country Status (2)

Country Link
SG (2) SG195420A1 (en)
WO (1) WO2013184074A1 (en)

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US11939477B2 (en) 2014-01-30 2024-03-26 Monolith Materials, Inc. High temperature heat integration method of making carbon black
US10138378B2 (en) 2014-01-30 2018-11-27 Monolith Materials, Inc. Plasma gas throat assembly and method
US10100200B2 (en) 2014-01-30 2018-10-16 Monolith Materials, Inc. Use of feedstock in carbon black plasma process
US10370539B2 (en) 2014-01-30 2019-08-06 Monolith Materials, Inc. System for high temperature chemical processing
US9574086B2 (en) 2014-01-31 2017-02-21 Monolith Materials, Inc. Plasma reactor
RU2016135213A (en) 2014-01-31 2018-03-05 Монолит Матириалз, Инк. PLASMA BURNER DESIGN
EP3253904B1 (en) 2015-02-03 2020-07-01 Monolith Materials, Inc. Regenerative cooling method and apparatus
CA3032246C (en) 2015-07-29 2023-12-12 Monolith Materials, Inc. Dc plasma torch electrical power design method and apparatus
US10808097B2 (en) 2015-09-14 2020-10-20 Monolith Materials, Inc. Carbon black from natural gas
US10472572B1 (en) 2016-04-07 2019-11-12 Foret Plasma Labs, Llc Method and apparatus for treating organic matter
MX2018013161A (en) 2016-04-29 2019-06-24 Monolith Mat Inc Torch stinger method and apparatus.
US11149148B2 (en) 2016-04-29 2021-10-19 Monolith Materials, Inc. Secondary heat addition to particle production process and apparatus
EP3592810A4 (en) 2017-03-08 2021-01-27 Monolith Materials, Inc. Systems and methods of making carbon particles with thermal transfer gas
CA3060576A1 (en) 2017-04-20 2018-10-25 Monolith Materials, Inc. Carbon particles with low sulfur, ash and grit impurities
WO2019084200A1 (en) 2017-10-24 2019-05-02 Monolith Materials, Inc. Particle systems and methods
DE102021205776A1 (en) 2021-06-08 2022-12-08 Continental Reifen Deutschland Gmbh Process for producing carbon black from waste
WO2023132784A1 (en) * 2022-01-06 2023-07-13 Global Enviro Holding Pte. Ltd. Method and apparatus for tire recycling
US11811542B1 (en) 2022-06-01 2023-11-07 NDSL, Inc. Galvanic isolation circuitry and associated low power wakeup methods

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CA2300602C (en) * 1999-10-21 2008-11-18 Hebco International Inc. High purity carbon black composition in the form of a powder obtained by pyrolysis of a solid carbonizable material, process thereof
UA84945C2 (en) * 2007-01-24 2008-12-10 Григорий Абрамович Березин method and device of utilization of TYREs
US20110062013A1 (en) * 2007-02-27 2011-03-17 Plasco Energy Group Inc. Multi-Zone Carbon Conversion System with Plasma Melting

Also Published As

Publication number Publication date
WO2013184074A1 (en) 2013-12-12
SG2014012199A (en) 2014-04-28

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