JP2020503426A5 - - Google Patents
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- Publication number
- JP2020503426A5 JP2020503426A5 JP2019551765A JP2019551765A JP2020503426A5 JP 2020503426 A5 JP2020503426 A5 JP 2020503426A5 JP 2019551765 A JP2019551765 A JP 2019551765A JP 2019551765 A JP2019551765 A JP 2019551765A JP 2020503426 A5 JP2020503426 A5 JP 2020503426A5
- Authority
- JP
- Japan
- Prior art keywords
- epoxy
- thiol
- component
- curable
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003573 thiols Chemical class 0.000 claims 20
- 239000004593 Epoxy Substances 0.000 claims 18
- 239000011342 resin composition Substances 0.000 claims 17
- 239000003822 epoxy resin Substances 0.000 claims 10
- 229920000647 polyepoxide Polymers 0.000 claims 10
- 229920006295 polythiol Polymers 0.000 claims 5
- 238000000034 method Methods 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- 150000007656 barbituric acids Chemical class 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 150000002118 epoxides Chemical group 0.000 claims 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 2
- 229920003986 novolac Polymers 0.000 claims 2
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 2
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 1
- KAJBSGLXSREIHP-UHFFFAOYSA-N 2,2-bis[(2-sulfanylacetyl)oxymethyl]butyl 2-sulfanylacetate Chemical compound SCC(=O)OCC(CC)(COC(=O)CS)COC(=O)CS KAJBSGLXSREIHP-UHFFFAOYSA-N 0.000 claims 1
- HAQZWTGSNCDKTK-UHFFFAOYSA-N 2-(3-sulfanylpropanoyloxy)ethyl 3-sulfanylpropanoate Chemical compound SCCC(=O)OCCOC(=O)CCS HAQZWTGSNCDKTK-UHFFFAOYSA-N 0.000 claims 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims 1
- RUDUCNPHDIMQCY-UHFFFAOYSA-N [3-(2-sulfanylacetyl)oxy-2,2-bis[(2-sulfanylacetyl)oxymethyl]propyl] 2-sulfanylacetate Chemical compound SCC(=O)OCC(COC(=O)CS)(COC(=O)CS)COC(=O)CS RUDUCNPHDIMQCY-UHFFFAOYSA-N 0.000 claims 1
- JOBBTVPTPXRUBP-UHFFFAOYSA-N [3-(3-sulfanylpropanoyloxy)-2,2-bis(3-sulfanylpropanoyloxymethyl)propyl] 3-sulfanylpropanoate Chemical compound SCCC(=O)OCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS JOBBTVPTPXRUBP-UHFFFAOYSA-N 0.000 claims 1
- 125000002723 alicyclic group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 229930003836 cresol Natural products 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- -1 glycidyl ether ester Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 229920005672 polyolefin resin Polymers 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662433325P | 2016-12-13 | 2016-12-13 | |
| US62/433,325 | 2016-12-13 | ||
| PCT/IB2017/057663 WO2018109617A1 (en) | 2016-12-13 | 2017-12-05 | Epoxy stabilization using substituted barbituric acids |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020503426A JP2020503426A (ja) | 2020-01-30 |
| JP2020503426A5 true JP2020503426A5 (https=) | 2021-01-21 |
| JP7019715B2 JP7019715B2 (ja) | 2022-02-15 |
Family
ID=60782289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019551765A Active JP7019715B2 (ja) | 2016-12-13 | 2017-12-05 | 置換バルビツール酸を使用するエポキシ安定化 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11584823B2 (https=) |
| EP (2) | EP3822298A1 (https=) |
| JP (1) | JP7019715B2 (https=) |
| KR (1) | KR20190093583A (https=) |
| CN (1) | CN110072907B (https=) |
| WO (1) | WO2018109617A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3555169A1 (en) | 2016-12-13 | 2019-10-23 | 3M Innovative Properties Company | Epoxy stabilization using acid-coated nitrogen-containing catalysts, particles, and methods |
| EP3583151B1 (en) | 2017-02-15 | 2021-06-09 | 3M Innovative Properties Company | Epoxy stabilization using metal nanoparticles and nitrogen-containing catalysts, and methods |
| WO2019053646A1 (en) * | 2017-09-15 | 2019-03-21 | 3M Innovative Properties Company | ADHESIVE FILM COMPRISING A (METH) ACRYLATE MATRIX COMPRISING A CURABLE EPOXY / THIOL RESIN COMPOSITION, RIBBON AND METHOD |
| CN112739738A (zh) | 2018-09-25 | 2021-04-30 | 3M创新有限公司 | 包含含脲二酮的材料和可热活化的胺的聚合物材料、两部分组合物以及方法 |
| US20240336725A1 (en) * | 2021-07-30 | 2024-10-10 | 3M Innovative Properties Company | Curable, one-part, dual-stage thiol-ene-epoxy liquid adhesives and methods |
| CN116239720B (zh) * | 2023-02-06 | 2024-05-31 | 四川大学 | 具有双重碱基面识别Hg2+的温敏性线性高分子材料及其制备方法 |
| US11911748B1 (en) | 2023-03-01 | 2024-02-27 | King Faisal University | Modified homogeneous dinuclear transition metal-organic frameworks |
| US11773124B1 (en) | 2023-03-08 | 2023-10-03 | King Faisal University | Homoliptic dinuclear complexes of palladium (II) with diaroyldihydrazone succinate ligand as highly effective catalyst for cross coupling reactions |
| WO2025200154A1 (en) | 2024-03-29 | 2025-10-02 | 3M Innovative Properties Company | Two-part epoxy composition comprising thiol curative, and catalyst |
| WO2026062466A1 (en) | 2024-09-17 | 2026-03-26 | 3M Innovative Properties Company | Curable adhesive compositions with a low dielectric constant |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1593791A1 (de) | 1966-05-04 | 1970-10-01 | Ciba Geigy | Latente Haerter und stabile hitzegehaertete Epoxydmassen |
| US3496250A (en) | 1967-02-21 | 1970-02-17 | Borg Warner | Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers |
| NL6904873A (https=) * | 1968-04-29 | 1969-10-31 | ||
| JPS5657820A (en) | 1979-10-18 | 1981-05-20 | Semedain Kk | Curable epoxy resin composition |
| JPS6072917A (ja) | 1983-09-30 | 1985-04-25 | Ajinomoto Co Inc | エポキシ樹脂用潜在性硬化剤 |
| JPS61159417A (ja) | 1984-12-29 | 1986-07-19 | Semedain Kk | 硬化性エポキシ樹脂組成物 |
| EP0193068A1 (en) | 1985-02-18 | 1986-09-03 | Asahi Kasei Kogyo Kabushiki Kaisha | One liquid type epoxy resin composition |
| DE3789337T2 (de) | 1986-08-29 | 1994-08-11 | Nippon Zeon Co | Vulkanisierbare Elastomerzusammensetzung. |
| JPH0794588B2 (ja) | 1987-03-07 | 1995-10-11 | 日本ゼオン株式会社 | アクリレ−ト系エラストマ−加硫組成物 |
| IE891601L (en) | 1989-05-18 | 1990-11-18 | Loctite Ireland Ltd | Latent hardeners for epoxy resin compositions |
| US5439746A (en) * | 1991-09-09 | 1995-08-08 | Kabushiki Kaisha Toshiba | Epoxy resin-basin composite material |
| DE69318369T2 (de) | 1992-10-22 | 1999-01-28 | Ajinomoto Co., Inc., Tokio/Tokyo | Polythiol-Epoxidharz-Mischung mit längerer Verarbeitungszeit |
| US5464910A (en) | 1993-12-22 | 1995-11-07 | Shikoku Chemicals Corporation | Epoxy resin adduct combined with a borate ester and phenolic compound |
| US6653371B1 (en) | 1998-01-16 | 2003-11-25 | Barry E. Burns | One-part curable composition of polyepoxide, polythiol, latent hardener and solid organic acid |
| CN1165592C (zh) * | 1998-01-16 | 2004-09-08 | 洛克泰特(R&D)有限公司 | 可固化的环氧基组合物 |
| US6359039B1 (en) | 1998-04-28 | 2002-03-19 | Industrial Technology Research Institute | Mixing barbituric acid-modified BMI with MEK solution of epoxy resin and elastomer |
| JP3882374B2 (ja) | 1999-02-12 | 2007-02-14 | 味の素株式会社 | 導電性樹脂組成物 |
| EP1291390A4 (en) | 2000-05-29 | 2004-08-25 | Ajinomoto Kk | CONDUCTIVE RESIN COMPOSITION |
| US6872762B2 (en) | 2000-07-13 | 2005-03-29 | Loctite (R&D) Limited | Epoxy resin composition with solid organic acid |
| TW538318B (en) | 2000-11-03 | 2003-06-21 | Ind Tech Res Inst | Photo-sensitive composition |
| WO2005070991A1 (ja) | 2004-01-22 | 2005-08-04 | Ajinomoto Co., Inc. | 一液性エポキシ樹脂組成物 |
| US20100105795A1 (en) * | 2005-02-01 | 2010-04-29 | Henkel Corporation | Liquid Stable Thiol-Acrylate/Vinyl Ether Compositions |
| CN101210077B (zh) * | 2006-12-28 | 2010-07-14 | 财团法人工业技术研究院 | 无卤耐高温组合物 |
| JP4561937B2 (ja) | 2008-11-07 | 2010-10-13 | 横浜ゴム株式会社 | 1液型熱硬化性エポキシ樹脂組成物 |
| EP2412361A1 (en) * | 2010-07-29 | 2012-02-01 | 3M Innovative Properties Company | Kit of parts, method of producing and use thereof |
| EP2635619A1 (en) | 2010-11-05 | 2013-09-11 | Henkel Ireland Limited | Epoxy-thiol compositions with improved stability |
| TWI586749B (zh) * | 2010-11-19 | 2017-06-11 | 漢高日本股份有限公司 | 單組分環氧樹脂組成物 |
| CN103282401A (zh) | 2011-01-05 | 2013-09-04 | 纳美仕有限公司 | 树脂组合物 |
| KR102229770B1 (ko) * | 2014-03-17 | 2021-03-18 | 나믹스 가부시끼가이샤 | 수지 조성물 |
| DE102015113352A1 (de) * | 2014-09-23 | 2016-03-24 | Fischerwerke Gmbh & Co. Kg | Befestigungssysteme mit feinteiligen Füllstoffen |
| CA2976436A1 (en) | 2015-02-13 | 2016-08-18 | 3M Innovative Properties Company | Cold-tolerant sealants and components thereof |
| WO2019053646A1 (en) * | 2017-09-15 | 2019-03-21 | 3M Innovative Properties Company | ADHESIVE FILM COMPRISING A (METH) ACRYLATE MATRIX COMPRISING A CURABLE EPOXY / THIOL RESIN COMPOSITION, RIBBON AND METHOD |
-
2017
- 2017-12-05 US US16/467,570 patent/US11584823B2/en active Active
- 2017-12-05 EP EP20216492.7A patent/EP3822298A1/en active Pending
- 2017-12-05 KR KR1020197016970A patent/KR20190093583A/ko not_active Ceased
- 2017-12-05 EP EP17818294.5A patent/EP3555170B1/en active Active
- 2017-12-05 JP JP2019551765A patent/JP7019715B2/ja active Active
- 2017-12-05 CN CN201780077373.0A patent/CN110072907B/zh active Active
- 2017-12-05 WO PCT/IB2017/057663 patent/WO2018109617A1/en not_active Ceased
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