JP2018501949A5 - - Google Patents
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- Publication number
- JP2018501949A5 JP2018501949A5 JP2017526562A JP2017526562A JP2018501949A5 JP 2018501949 A5 JP2018501949 A5 JP 2018501949A5 JP 2017526562 A JP2017526562 A JP 2017526562A JP 2017526562 A JP2017526562 A JP 2017526562A JP 2018501949 A5 JP2018501949 A5 JP 2018501949A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- metal
- molecular sieve
- scr
- nox adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 claims 88
- 229910052751 metal Inorganic materials 0.000 claims 42
- 239000002184 metal Substances 0.000 claims 42
- 239000002808 molecular sieve Substances 0.000 claims 35
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 35
- 238000001179 sorption measurement Methods 0.000 claims 23
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 20
- 239000000758 substrate Substances 0.000 claims 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 14
- 229910052684 Cerium Inorganic materials 0.000 claims 10
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 10
- 229910052763 palladium Inorganic materials 0.000 claims 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 8
- 229910017052 cobalt Inorganic materials 0.000 claims 8
- 239000010941 cobalt Substances 0.000 claims 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 8
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 8
- 229910052725 zinc Inorganic materials 0.000 claims 8
- 239000011701 zinc Substances 0.000 claims 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 7
- 229910052742 iron Inorganic materials 0.000 claims 7
- 229910052750 molybdenum Inorganic materials 0.000 claims 7
- 239000011733 molybdenum Substances 0.000 claims 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 7
- 229910052721 tungsten Inorganic materials 0.000 claims 7
- 239000010937 tungsten Substances 0.000 claims 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 6
- 239000002131 composite material Substances 0.000 claims 6
- 229910052802 copper Inorganic materials 0.000 claims 6
- 239000010949 copper Substances 0.000 claims 6
- 229910052709 silver Inorganic materials 0.000 claims 6
- 239000004332 silver Substances 0.000 claims 6
- 229910052723 transition metal Inorganic materials 0.000 claims 6
- 150000003624 transition metals Chemical class 0.000 claims 6
- 239000010953 base metal Substances 0.000 claims 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 4
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 4
- 229910052804 chromium Inorganic materials 0.000 claims 4
- 239000011651 chromium Substances 0.000 claims 4
- 229910052746 lanthanum Inorganic materials 0.000 claims 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 4
- 239000000463 material Substances 0.000 claims 4
- 150000002739 metals Chemical class 0.000 claims 4
- 229910052759 nickel Inorganic materials 0.000 claims 4
- 229910052758 niobium Inorganic materials 0.000 claims 4
- 239000010955 niobium Substances 0.000 claims 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- 229910021536 Zeolite Inorganic materials 0.000 claims 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 3
- 238000001354 calcination Methods 0.000 claims 3
- 230000003197 catalytic effect Effects 0.000 claims 3
- 238000001035 drying Methods 0.000 claims 3
- 238000001125 extrusion Methods 0.000 claims 3
- 239000004071 soot Substances 0.000 claims 3
- 239000010457 zeolite Substances 0.000 claims 3
- 229910052726 zirconium Inorganic materials 0.000 claims 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- -1 VIB metals Chemical class 0.000 claims 2
- 239000003463 adsorbent Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910021529 ammonia Inorganic materials 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims 2
- 229910052676 chabazite Inorganic materials 0.000 claims 2
- 229910052733 gallium Inorganic materials 0.000 claims 2
- 229910052738 indium Inorganic materials 0.000 claims 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 2
- 229910052741 iridium Inorganic materials 0.000 claims 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229910052680 mordenite Inorganic materials 0.000 claims 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- 229910052702 rhenium Inorganic materials 0.000 claims 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 2
- 229910052707 ruthenium Inorganic materials 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 239000011135 tin Substances 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 229910006404 SnO 2 Inorganic materials 0.000 claims 1
- 229910010413 TiO 2 Inorganic materials 0.000 claims 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims 1
- 229910052675 erionite Inorganic materials 0.000 claims 1
- 229910001657 ferrierite group Inorganic materials 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021157548A JP7314225B2 (ja) | 2014-11-19 | 2021-09-28 | 低温排出制御のためのｓｃｒとｐｎａの組み合わせ |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462081894P | 2014-11-19 | 2014-11-19 | |
| US62/081,894 | 2014-11-19 | ||
| PCT/GB2015/053498 WO2016079507A1 (en) | 2014-11-19 | 2015-11-18 | Combining scr with pna for low temperature emission control |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021157548A Division JP7314225B2 (ja) | 2014-11-19 | 2021-09-28 | 低温排出制御のためのｓｃｒとｐｎａの組み合わせ |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018501949A JP2018501949A (ja) | 2018-01-25 |
| JP2018501949A5 true JP2018501949A5 (enExample) | 2018-12-27 |
| JP7249099B2 JP7249099B2 (ja) | 2023-03-30 |
Family
ID=54771146
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017526562A Active JP7249099B2 (ja) | 2014-11-19 | 2015-11-18 | 低温排出制御のためのｓｃｒとｐｎａの組み合わせ |
| JP2021157548A Active JP7314225B2 (ja) | 2014-11-19 | 2021-09-28 | 低温排出制御のためのｓｃｒとｐｎａの組み合わせ |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021157548A Active JP7314225B2 (ja) | 2014-11-19 | 2021-09-28 | 低温排出制御のためのｓｃｒとｐｎａの組み合わせ |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10179329B2 (enExample) |
| EP (1) | EP3221032B1 (enExample) |
| JP (2) | JP7249099B2 (enExample) |
| KR (1) | KR102444558B1 (enExample) |
| CN (1) | CN107106982B (enExample) |
| BR (1) | BR112017010317B1 (enExample) |
| DE (1) | DE102015119913A1 (enExample) |
| GB (1) | GB2535274B (enExample) |
| RU (1) | RU2702578C2 (enExample) |
| WO (1) | WO2016079507A1 (enExample) |
Families Citing this family (70)
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| GB2539745B (en) * | 2015-02-26 | 2017-05-24 | Johnson Matthey Plc | Palladium-MAZ zeolite passive NOx adsorber and use thereof |
| CA2989729A1 (en) * | 2015-06-16 | 2016-12-22 | Basf Se | Scr-catalyzed soot filter with integrated lean nox trap catalyst for use in passive selective catalytic reduction |
| GB2551936B (en) | 2015-07-02 | 2019-07-31 | Johnson Matthey Plc | Passive NOx Adsorber |
| GB201521123D0 (en) | 2015-11-30 | 2016-01-13 | Johnson Matthey Plc | Diesel oxidation catalyst having a capture region for exhaust gas impurities |
| RU2019100972A (ru) | 2016-06-17 | 2020-07-17 | Басф Корпорейшн | Палладиевый дизельный катализатор окисления |
| EP3493901A4 (en) * | 2016-07-29 | 2020-03-11 | BASF Corporation | RUTHENIUM IMPREGNATED ZERO DIOXIDE CATALYST |
| WO2018054929A1 (en) * | 2016-09-20 | 2018-03-29 | Umicore Ag & Co. Kg | Diesel particle filter |
| EP3296009B1 (de) * | 2016-09-20 | 2019-03-27 | Umicore AG & Co. KG | Partikelfilter mit scr-aktiver beschichtung |
| CA3041422A1 (en) * | 2016-10-24 | 2018-05-03 | Basf Corporation | Integrated scr catalyst and lnt for nox abatement |
| CN110099731A (zh) * | 2016-12-20 | 2019-08-06 | 优美科股份公司及两合公司 | 含有氧化钒和含有铁的分子筛的scr催化剂装置 |
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| CN106732755B (zh) * | 2016-12-23 | 2019-03-05 | 中节能万润股份有限公司 | 一种分子筛-多元氧化物复合整体挤出式脱硝催化剂的制备方法 |
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| CN110102337A (zh) * | 2019-06-06 | 2019-08-09 | 安徽纳蓝环保科技有限公司 | 一种复合铜基scr分子筛催化剂的制备方法 |
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- 2015-11-18 US US14/944,273 patent/US10179329B2/en active Active
- 2015-11-18 CN CN201580070171.4A patent/CN107106982B/zh active Active
- 2015-11-18 BR BR112017010317-6A patent/BR112017010317B1/pt active IP Right Grant
- 2015-11-18 EP EP15804184.8A patent/EP3221032B1/en active Active
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