JP2016537483A - 分散ウレタン変性ポリイソシアヌレートを含有する揺変性ポリオール組成物 - Google Patents
分散ウレタン変性ポリイソシアヌレートを含有する揺変性ポリオール組成物 Download PDFInfo
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- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/08—Processes
- C08G18/16—Catalysts
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/08—Processes
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
- C08G18/3281—Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4845—Polyethers containing oxyethylene units and other oxyalkylene units containing oxypropylene or higher oxyalkylene end groups
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- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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Abstract
Description
80部のポリオールVIII、20部の80/20TDI、及び0.05部の第四級アンモニウムイソシアネート三量化触媒を組み合わせて、45℃で数時間撹拌する。結果として生じたプレポリマーのイソシアネート含有量は3.6%である。85部の結果として生じたプレポリマーを、次いで、15部のポリオールIXと組み合わせて、その混合物をイソシアネート含有量が0.1重量%未満まで低減されるまで反応させる。結果として生じた生成物は、プレポリマーAである。
プレポリマーCを、50重量部のポリオールVIIと50部の80/20TDIとを組み合わせて、その混合物を、密封容器中で、室温で数時間撹拌することによって作製する。モノオール及び80/20TDIの量に基づいた理論上のイソシアネート含有量(ビウレット、尿素、アロフォネート、またはイソシアヌレート形成を考慮せず)は、23.6%である。生成物の測定されたイソシアネート含有量は16%であり、これはイソシアヌレート(おそらくはビウレット、尿素、及び/またはアロフォネート)形成が、ポリオールVII中の酢酸カリウムの存在によって生じていることを示す。
プレポリマーEを、80重量部のポリオールVIII、0.05部のイソシアネート三量化触媒、及び20部の80/20TDIを組み合わせて、その混合物を密封容器中で、イソシアネート含有量が2.4%まで減少するまで50℃で撹拌することによって作製する。
実施例9を、室温での撹拌下で、79部のポリオールIII、2部のポリオールVIII、0.05部の第四級アンモニウムイソシアネート三量化触媒、及び11.7部のTDI80/20のブレンドを4分間事前に反応させることによって行う。次いで、9部のポリオールIX及び0.1部のカルボン酸亜鉛を添加して、その反応物質を5分間撹拌する。粒径及び粘度測定を、前述のように行う。結果を、表4に報告する。
Claims (16)
- 液体ベースポリオール中のポリウレタン−イソシアヌレート粒子の揺変性分散体。
- 前記液体ベースポリオールが、少なくとも200のヒドロキシル当量、及び1分子当たり少なくとも2個のヒドロキシル基の平均公称ヒドロキシル官能価を有する、請求項1に記載の前記揺変性分散体。
- 前記ポリウレタン−イソシアヌレート粒子が、イソシアヌレート三量化触媒の存在下での、最大80のヒドロキシル当量及び1分子当たり2〜6個のヒドロキシル基を有する低当量ポリオールと、1つ以上のポリイソシアネート化合物との反応生成物を含む、請求項1または2に記載の前記揺変性分散体。
- 前記低当量ポリオールが、アミノアルコールを含む、請求項3に記載の前記揺変性分散体。
- 前記低当量ポリオールが、トリエタノールアミンまたは75〜99.9%のトリエタノールアミンを含有する混合物である、請求項4に記載の前記揺変性分散体。
- 前記ポリイソシアネート化合物が、トルエンジイソシアネートまたはMDIを含む、請求項3〜5のいずれかに記載の前記揺変性分散体。
- 前記ポリウレタン−イソシアヌレート粒子が、前記分散体の重量の5〜35パーセントを構成する、請求項1〜6のいずれかに記載の前記揺変性分散体。
- 前記粒子が、20nm〜1μmのサイズを有する少なくとも1つの画分を有する多峰性である、請求項1〜7のいずれかに記載の前記揺変性分散体。
- 20℃で少なくとも100Pa・sの最小せん断時の粘度を有する、請求項1〜8のいずれかに記載の前記揺変性分散体。
- 請求項1〜9のいずれかに記載の前記揺変性分散体を作製する方法であって、イソシアヌレート三量化触媒及びベースポリエーテルポリオールの存在下で、低当量ポリオールを1つ以上のポリイソシアネート化合物と反応させて、前記ベースポリオール中に分散されたポリウレタン−イソシアヌレート粒子を形成することを含む、前記方法。
- 前記低当量ポリオール、前記1つ以上のポリイソシアネート化合物、前記イソシアヌレート三量化触媒、及び前記ベースポリエーテルポリオールの撹拌された混合物を形成し、前記ベースポリエーテルポリオール及び前記イソシアネート三量化触媒の存在下で、前記低当量ポリオールを前記ポリイソシアネート化合物(複数可)と反応させて、前記ベースポリオール中に分散されたポリウレタン−イソシアヌレート粒子を形成することによって実施される、請求項10に記載の前記方法。
- 前記低当量ポリオールが、最大80のヒドロキシル当量、及び1分子当たり2〜6個のヒドロキシル基を有し、前記ベースポリエーテルポリオールが、少なくとも200のヒドロキシル当量を有する、請求項10または11に記載の前記方法。
- 前記反応ステップが、イソシアネートまたはイソシアネート反応性基を含有するプレポリマーの存在下で実施される、請求項10〜12のいずれかに記載の前記方法。
- 請求項1〜9のいずれかに記載の前記揺変性分散体を作製する方法であって、イソシアヌレート三量化触媒、イソシアヌレート基及びイソシアネートまたはイソシアネート反応性基を有するプレポリマー、ならびにベースポリエーテルポリオールの存在下で、低当量ポリオールを1つ以上のポリイソシアネート化合物と反応させて、前記ベースポリオール中に分散されたポリウレタン−イソシアヌレート粒子を形成することを含む、前記方法。
- 請求項1〜9のいずれかに記載の前記揺変性分散体と、ヒドロキシル基と反応する少なくとも1つの硬化剤とを含む、硬化性樹脂組成物。
- 配合コーティング、配合シーラント、または配合接着剤である、請求項15に記載の前記硬化性樹脂組成物。
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US201361877287P | 2013-09-13 | 2013-09-13 | |
US201361877290P | 2013-09-13 | 2013-09-13 | |
US61/877,290 | 2013-09-13 | ||
US61/877,287 | 2013-09-13 | ||
PCT/US2014/055267 WO2015038830A1 (en) | 2013-09-13 | 2014-09-11 | Thixotropic polyol compositions containing dispersed urethane-modified polyisocyanurates |
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JP2019165340A Pending JP2020023698A (ja) | 2013-09-13 | 2019-09-11 | 分散ウレタン変性ポリイソシアヌレートを含有する揺変性ポリオール組成物 |
JP2021175115A Pending JP2022009533A (ja) | 2013-09-13 | 2021-10-27 | 分散ウレタン変性ポリイソシアヌレートを含有する揺変性ポリオール組成物 |
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JP2021175115A Pending JP2022009533A (ja) | 2013-09-13 | 2021-10-27 | 分散ウレタン変性ポリイソシアヌレートを含有する揺変性ポリオール組成物 |
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US (1) | US9840579B2 (ja) |
EP (1) | EP3044246B1 (ja) |
JP (3) | JP6985796B2 (ja) |
CN (1) | CN105683237B (ja) |
AU (1) | AU2014318649B2 (ja) |
BR (1) | BR112016004952B1 (ja) |
MX (1) | MX2016002958A (ja) |
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JP6447557B2 (ja) * | 2016-03-24 | 2019-01-09 | 日亜化学工業株式会社 | 発光装置の製造方法 |
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EP3044246A1 (en) | 2016-07-20 |
MX2016002958A (es) | 2016-06-10 |
EP3044246B1 (en) | 2019-11-13 |
AU2014318649B2 (en) | 2017-09-07 |
AU2014318649A1 (en) | 2016-04-21 |
CN105683237A (zh) | 2016-06-15 |
JP6985796B2 (ja) | 2021-12-22 |
US20160208041A1 (en) | 2016-07-21 |
JP2022009533A (ja) | 2022-01-14 |
BR112016004952A8 (pt) | 2020-02-11 |
BR112016004952B1 (pt) | 2021-07-20 |
US9840579B2 (en) | 2017-12-12 |
CN105683237B (zh) | 2019-02-22 |
JP2020023698A (ja) | 2020-02-13 |
WO2015038830A1 (en) | 2015-03-19 |
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