JP2015502252A5 - - Google Patents
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- JP2015502252A5 JP2015502252A5 JP2014546273A JP2014546273A JP2015502252A5 JP 2015502252 A5 JP2015502252 A5 JP 2015502252A5 JP 2014546273 A JP2014546273 A JP 2014546273A JP 2014546273 A JP2014546273 A JP 2014546273A JP 2015502252 A5 JP2015502252 A5 JP 2015502252A5
- Authority
- JP
- Japan
- Prior art keywords
- exchange
- rare earth
- catalyst according
- magnesium
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 claims description 31
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 30
- 239000010457 zeolite Substances 0.000 claims description 24
- 229910021536 Zeolite Inorganic materials 0.000 claims description 23
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 23
- 150000002910 rare earth metals Chemical class 0.000 claims description 21
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 20
- 239000002808 molecular sieve Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- -1 rare earth compound Chemical class 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000004005 microsphere Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 229910052621 halloysite Inorganic materials 0.000 claims description 2
- 235000011167 hydrochloric acid Nutrition 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229910001562 pearlite Inorganic materials 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 17
- 239000006185 dispersion Substances 0.000 claims 13
- 159000000003 magnesium salts Chemical group 0.000 claims 8
- 238000000034 method Methods 0.000 claims 6
- 238000001354 calcination Methods 0.000 claims 5
- 238000010304 firing Methods 0.000 claims 5
- 230000004048 modification Effects 0.000 claims 5
- 238000012986 modification Methods 0.000 claims 5
- 150000003863 ammonium salts Chemical class 0.000 claims 4
- 239000002270 dispersing agent Substances 0.000 claims 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- 239000004927 clay Substances 0.000 claims 3
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 3
- 239000002002 slurry Substances 0.000 claims 3
- 239000011734 sodium Substances 0.000 claims 3
- 229910052708 sodium Inorganic materials 0.000 claims 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- 238000004523 catalytic cracking Methods 0.000 claims 2
- 239000000295 fuel oil Substances 0.000 claims 2
- 229910052746 lanthanum Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000002243 precursor Substances 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 238000005406 washing Methods 0.000 claims 2
- 229910017119 AlPO Inorganic materials 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- 239000004113 Sepiolite Substances 0.000 claims 1
- 244000275012 Sesbania cannabina Species 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims 1
- 235000019341 magnesium sulphate Nutrition 0.000 claims 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 229910052624 sepiolite Inorganic materials 0.000 claims 1
- 235000019355 sepiolite Nutrition 0.000 claims 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- 238000003756 stirring Methods 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 241000219782 Sesbania Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110419856.9 | 2011-12-15 | ||
| CN201110419856.9A CN103157506B (zh) | 2011-12-15 | 2011-12-15 | 一种高轻收重油催化裂化催化剂及其制备方法 |
| PCT/CN2012/000507 WO2013086766A1 (zh) | 2011-12-15 | 2012-04-13 | 一种高轻收重油催化裂化催化剂及其制备方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015502252A JP2015502252A (ja) | 2015-01-22 |
| JP2015502252A5 true JP2015502252A5 (https=) | 2015-03-26 |
| JP5996667B2 JP5996667B2 (ja) | 2016-09-21 |
Family
ID=48581341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014546273A Active JP5996667B2 (ja) | 2011-12-15 | 2012-04-13 | 高軽質収率の重質油接触分解触媒およびその製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9889439B2 (https=) |
| JP (1) | JP5996667B2 (https=) |
| CN (1) | CN103157506B (https=) |
| AU (1) | AU2012351265B2 (https=) |
| CA (1) | CA2862131C (https=) |
| SG (1) | SG11201404087VA (https=) |
| WO (1) | WO2013086766A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103157506B (zh) | 2011-12-15 | 2015-09-23 | 中国石油天然气股份有限公司 | 一种高轻收重油催化裂化催化剂及其制备方法 |
| CN103394365B (zh) * | 2013-07-16 | 2015-08-05 | 常州大学 | 一种用于苯酚对位烷基化过程催化剂的制备方法 |
| CN104888840A (zh) * | 2015-01-14 | 2015-09-09 | 任丘市华北石油科林环保有限公司 | 一种高骨架硅铝比原位晶化fcc重油转化助剂的制备方法 |
| CN104923282B (zh) * | 2015-06-25 | 2017-08-15 | 湖北赛因化工有限公司 | 一种高稀土含量原位晶化催化剂的超稳化处理方法 |
| JP7163298B2 (ja) * | 2017-02-21 | 2022-10-31 | 中国石油化工股▲ふん▼有限公司 | マグネシウム改質ｙ型分子篩、その生成方法、およびそれを含む触媒 |
| CN109304209B (zh) * | 2017-07-28 | 2021-07-30 | 中国石油天然气股份有限公司 | 一种多产汽油催化裂化催化剂及其制备方法 |
| CN109304210B (zh) * | 2017-07-28 | 2022-02-01 | 中国石油天然气股份有限公司 | 一种裂化焦化蜡油多产柴油的催化裂化催化剂制备方法 |
| CN109304205B (zh) * | 2017-07-28 | 2021-11-02 | 中国石油天然气股份有限公司 | 一种提高焦炭选择性的催化裂化催化剂及其制备方法 |
| CN109304206B (zh) * | 2017-07-28 | 2021-08-31 | 中国石油天然气股份有限公司 | 一种裂化焦化蜡油多产汽油的催化裂化催化剂制备方法 |
| CN109304212B (zh) * | 2017-07-28 | 2021-09-28 | 中国石油天然气股份有限公司 | 一种催化裂化催化剂及其制备方法 |
| CN108097288A (zh) * | 2017-12-09 | 2018-06-01 | 北京惠尔三吉绿色化学科技有限公司 | 一种制备稀土y型分子筛的方法 |
| CN110193375A (zh) * | 2018-02-26 | 2019-09-03 | 中国石油天然气股份有限公司 | 一种镁盐沉淀改性y型分子筛的制备方法 |
| CN110652998B (zh) * | 2018-06-29 | 2021-01-08 | 中国石油化工股份有限公司 | 一种多产异构烃的高稳定性改性y型分子筛及其制备方法 |
| AU2019296817B2 (en) | 2018-06-29 | 2024-04-11 | China Petroleum & Chemical Corporation | Modified Y-type molecular sieve, catalytic cracking catalyst including same, and preparation and use thereof |
| CN111686790A (zh) * | 2019-03-12 | 2020-09-22 | 中国石油天然气股份有限公司 | 一种低液化气产率催化裂化汽油辛烷值助剂及其制备方法 |
| CN111744536A (zh) * | 2019-03-27 | 2020-10-09 | 中国石油化工股份有限公司 | 一种含稀土和镁的催化材料及其制备方法 |
| CN111744528B (zh) * | 2019-03-27 | 2023-04-07 | 中国石油化工股份有限公司 | 一种多金属修饰的复合材料的制备方法 |
| CN112108173B (zh) * | 2019-06-21 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种降低柴油收率的催化剂制备方法 |
| CN112717985B (zh) * | 2019-10-28 | 2023-04-07 | 中国石油化工股份有限公司 | 一种滤渣及其制备方法以及一种催化裂化催化剂及其制备方法 |
| CN112808298B (zh) * | 2019-11-18 | 2023-07-11 | 中国石油化工股份有限公司 | 含多级孔y型分子筛的催化剂及其制备方法 |
| CN112808297B (zh) * | 2019-11-18 | 2023-07-14 | 中国石油化工股份有限公司 | 固体酸烷基化催化剂及其制备方法 |
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| CN114132977B (zh) * | 2021-11-30 | 2022-12-20 | 华中科技大学 | 一种天然水体净化剂及其制备方法和应用 |
| CN115055203B (zh) * | 2022-07-20 | 2024-10-18 | 成都蓉澄石化科技有限公司 | 一种重油催化裂化催化剂 |
| CN116062772B (zh) * | 2022-12-08 | 2025-03-28 | 汕头大学 | 一种泡沫状分子筛及用其制备的正构烷烃临氢异构催化剂 |
| CN118831635B (zh) * | 2023-04-23 | 2026-01-27 | 中国石油天然气股份有限公司 | 一种抗钒催化裂化催化剂的制备方法 |
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| CN100344374C (zh) * | 2004-08-13 | 2007-10-24 | 中国石油化工股份有限公司 | 一种稀土y分子筛及其制备方法 |
| CN1322928C (zh) | 2004-08-13 | 2007-06-27 | 中国石油化工股份有限公司 | 一种降低催化裂化汽油烯烃含量的裂化催化剂 |
| CN100357399C (zh) * | 2005-03-31 | 2007-12-26 | 中国石油化工股份有限公司 | 一种裂化催化剂的制备方法 |
| CN100497175C (zh) | 2005-10-31 | 2009-06-10 | 中国石油化工股份有限公司 | 一种提高超稳y型沸石稀土含量的方法 |
| CN101088613B (zh) * | 2006-06-14 | 2010-08-25 | 中国石油化工股份有限公司 | 一种rey分子筛的制备方法 |
| CN101190416B (zh) * | 2006-12-01 | 2011-06-15 | 石大卓越科技股份有限公司 | 一种催化裂化催化剂及其制备方法 |
| CN101210187B (zh) * | 2006-12-27 | 2011-09-14 | 中国石油化工股份有限公司 | 一种重油裂化催化剂的制备方法 |
| CN101284243B (zh) * | 2007-04-12 | 2011-04-20 | 中国石油化工股份有限公司 | 一种催化裂化催化剂 |
| CN101676027B (zh) * | 2008-09-19 | 2012-10-10 | 中国石油化工股份有限公司 | 一种石油烃裂化催化剂 |
| CN102029177B (zh) * | 2009-09-28 | 2012-07-18 | 中国石油化工股份有限公司 | 一种裂化催化剂及其制备方法 |
| CN102133542A (zh) | 2010-01-27 | 2011-07-27 | 华东理工大学 | 一种复合型催化裂化催化剂及其制备方法 |
| CN102125870B (zh) | 2010-12-15 | 2013-01-16 | 卓润生 | 一种重质油催化裂化催化剂的制备方法 |
| CN103157506B (zh) | 2011-12-15 | 2015-09-23 | 中国石油天然气股份有限公司 | 一种高轻收重油催化裂化催化剂及其制备方法 |
-
2011
- 2011-12-15 CN CN201110419856.9A patent/CN103157506B/zh active Active
-
2012
- 2012-04-13 AU AU2012351265A patent/AU2012351265B2/en active Active
- 2012-04-13 JP JP2014546273A patent/JP5996667B2/ja active Active
- 2012-04-13 CA CA2862131A patent/CA2862131C/en active Active
- 2012-04-13 SG SG11201404087VA patent/SG11201404087VA/en unknown
- 2012-04-13 US US14/364,652 patent/US9889439B2/en active Active
- 2012-04-13 WO PCT/CN2012/000507 patent/WO2013086766A1/zh not_active Ceased
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