AU2012351265B2 - High light received heavy oil catalytic cracking catalyst and preparation method therefor - Google Patents

High light received heavy oil catalytic cracking catalyst and preparation method therefor Download PDF

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Publication number
AU2012351265B2
AU2012351265B2 AU2012351265A AU2012351265A AU2012351265B2 AU 2012351265 B2 AU2012351265 B2 AU 2012351265B2 AU 2012351265 A AU2012351265 A AU 2012351265A AU 2012351265 A AU2012351265 A AU 2012351265A AU 2012351265 B2 AU2012351265 B2 AU 2012351265B2
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exchange
rare earth
molecular sieve
magnesium
preparation
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AU2012351265A1 (en
Inventor
Jinjun CAI
Gengzhen CAO
Hongchang Duan
Xionghou Gao
Xiaoliang HUANG
Di Li
Xueli Li
Zhengguo Tan
Chenxi Zhang
Haitao Zhang
Yunfeng Zheng
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Petrochina Co Ltd
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Petrochina Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J2029/062—Mixtures of different aluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
AU2012351265A 2011-12-15 2012-04-13 High light received heavy oil catalytic cracking catalyst and preparation method therefor Active AU2012351265B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201110419856.9 2011-12-15
CN201110419856.9A CN103157506B (zh) 2011-12-15 2011-12-15 一种高轻收重油催化裂化催化剂及其制备方法
PCT/CN2012/000507 WO2013086766A1 (zh) 2011-12-15 2012-04-13 一种高轻收重油催化裂化催化剂及其制备方法

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AU2012351265A1 AU2012351265A1 (en) 2014-08-07
AU2012351265B2 true AU2012351265B2 (en) 2016-03-31

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US (1) US9889439B2 (https=)
JP (1) JP5996667B2 (https=)
CN (1) CN103157506B (https=)
AU (1) AU2012351265B2 (https=)
CA (1) CA2862131C (https=)
SG (1) SG11201404087VA (https=)
WO (1) WO2013086766A1 (https=)

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CN103157506B (zh) 2011-12-15 2015-09-23 中国石油天然气股份有限公司 一种高轻收重油催化裂化催化剂及其制备方法
CN103394365B (zh) * 2013-07-16 2015-08-05 常州大学 一种用于苯酚对位烷基化过程催化剂的制备方法
CN104888840A (zh) * 2015-01-14 2015-09-09 任丘市华北石油科林环保有限公司 一种高骨架硅铝比原位晶化fcc重油转化助剂的制备方法
CN104923282B (zh) * 2015-06-25 2017-08-15 湖北赛因化工有限公司 一种高稀土含量原位晶化催化剂的超稳化处理方法
JP7163298B2 (ja) * 2017-02-21 2022-10-31 中国石油化工股▲ふん▼有限公司 マグネシウム改質ｙ型分子篩、その生成方法、およびそれを含む触媒
CN109304209B (zh) * 2017-07-28 2021-07-30 中国石油天然气股份有限公司 一种多产汽油催化裂化催化剂及其制备方法
CN109304210B (zh) * 2017-07-28 2022-02-01 中国石油天然气股份有限公司 一种裂化焦化蜡油多产柴油的催化裂化催化剂制备方法
CN109304205B (zh) * 2017-07-28 2021-11-02 中国石油天然气股份有限公司 一种提高焦炭选择性的催化裂化催化剂及其制备方法
CN109304206B (zh) * 2017-07-28 2021-08-31 中国石油天然气股份有限公司 一种裂化焦化蜡油多产汽油的催化裂化催化剂制备方法
CN109304212B (zh) * 2017-07-28 2021-09-28 中国石油天然气股份有限公司 一种催化裂化催化剂及其制备方法
CN108097288A (zh) * 2017-12-09 2018-06-01 北京惠尔三吉绿色化学科技有限公司 一种制备稀土y型分子筛的方法
CN110193375A (zh) * 2018-02-26 2019-09-03 中国石油天然气股份有限公司 一种镁盐沉淀改性y型分子筛的制备方法
CN110652998B (zh) * 2018-06-29 2021-01-08 中国石油化工股份有限公司 一种多产异构烃的高稳定性改性y型分子筛及其制备方法
AU2019296817B2 (en) 2018-06-29 2024-04-11 China Petroleum & Chemical Corporation Modified Y-type molecular sieve, catalytic cracking catalyst including same, and preparation and use thereof
CN111686790A (zh) * 2019-03-12 2020-09-22 中国石油天然气股份有限公司 一种低液化气产率催化裂化汽油辛烷值助剂及其制备方法
CN111744536A (zh) * 2019-03-27 2020-10-09 中国石油化工股份有限公司 一种含稀土和镁的催化材料及其制备方法
CN111744528B (zh) * 2019-03-27 2023-04-07 中国石油化工股份有限公司 一种多金属修饰的复合材料的制备方法
CN112108173B (zh) * 2019-06-21 2023-06-30 中国石油天然气股份有限公司 一种降低柴油收率的催化剂制备方法
CN112717985B (zh) * 2019-10-28 2023-04-07 中国石油化工股份有限公司 一种滤渣及其制备方法以及一种催化裂化催化剂及其制备方法
CN112808298B (zh) * 2019-11-18 2023-07-11 中国石油化工股份有限公司 含多级孔y型分子筛的催化剂及其制备方法
CN112808297B (zh) * 2019-11-18 2023-07-14 中国石油化工股份有限公司 固体酸烷基化催化剂及其制备方法
CN111686786B (zh) * 2020-06-05 2023-05-16 中国石油天然气集团有限公司 酸性和孔结构可调控的杂原子改性y型沸石及其制备方法
CN114132977B (zh) * 2021-11-30 2022-12-20 华中科技大学 一种天然水体净化剂及其制备方法和应用
CN115055203B (zh) * 2022-07-20 2024-10-18 成都蓉澄石化科技有限公司 一种重油催化裂化催化剂
CN116062772B (zh) * 2022-12-08 2025-03-28 汕头大学 一种泡沫状分子筛及用其制备的正构烷烃临氢异构催化剂
CN118831635B (zh) * 2023-04-23 2026-01-27 中国石油天然气股份有限公司 一种抗钒催化裂化催化剂的制备方法

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AU2012351265A1 (en) 2014-08-07
CN103157506B (zh) 2015-09-23
CA2862131C (en) 2018-03-13
US9889439B2 (en) 2018-02-13
CA2862131A1 (en) 2013-06-20
JP2015502252A (ja) 2015-01-22
JP5996667B2 (ja) 2016-09-21
CN103157506A (zh) 2013-06-19
WO2013086766A1 (zh) 2013-06-20
SG11201404087VA (en) 2014-10-30
US20150011378A1 (en) 2015-01-08

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