JP2015500194A - 高い亀裂発生閾値を有するイオン交換可能なガラス - Google Patents
高い亀裂発生閾値を有するイオン交換可能なガラス Download PDFInfo
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- alkali aluminosilicate
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- 239000011521 glass Substances 0.000 title claims abstract description 189
- 230000000977 initiatory effect Effects 0.000 title claims description 23
- 239000005358 alkali aluminosilicate glass Substances 0.000 claims abstract description 148
- 238000005342 ion exchange Methods 0.000 claims abstract description 36
- 238000007373 indentation Methods 0.000 claims abstract description 32
- 239000011734 sodium Substances 0.000 claims description 62
- 229910052708 sodium Inorganic materials 0.000 claims description 47
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 45
- 229910052760 oxygen Inorganic materials 0.000 claims description 44
- 229910052796 boron Inorganic materials 0.000 claims description 27
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 26
- 229910001409 divalent cation oxide Inorganic materials 0.000 claims description 26
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 25
- 229910052700 potassium Inorganic materials 0.000 claims description 25
- 239000011591 potassium Substances 0.000 claims description 25
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 22
- 150000002500 ions Chemical group 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 16
- 229910052792 caesium Inorganic materials 0.000 claims description 15
- 229910052701 rubidium Inorganic materials 0.000 claims description 15
- 229910001408 cation oxide Inorganic materials 0.000 claims description 7
- 238000005728 strengthening Methods 0.000 claims description 4
- 238000005336 cracking Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 description 70
- 238000007906 compression Methods 0.000 description 36
- 230000006835 compression Effects 0.000 description 36
- 229910021645 metal ion Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000003513 alkali Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 229910001423 beryllium ion Inorganic materials 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910017119 AlPO Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910006404 SnO 2 Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- -1 but not limited to Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000006025 fining agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- IBIRZFNPWYRWOG-UHFFFAOYSA-N phosphane;phosphoric acid Chemical compound P.OP(O)(O)=O IBIRZFNPWYRWOG-UHFFFAOYSA-N 0.000 description 2
- 239000005341 toughened glass Substances 0.000 description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 238000007545 Vickers hardness test Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910001491 alkali aluminosilicate Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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Abstract
Description
i. 0.6<[M2O3(モル%)/RXO(モル%)]<1.4;または
ii. 1.3<[(P2O5+R2O)/M2O3]≦2.3;
であり、式中M2O3=Al2O3+B2O3であり、RXOが、アルカリアルミノケイ酸ガラス中に存在する一価および二価のカチオン酸化物の合計であり、R2Oがアルカリアルミノケイ酸ガラス中に存在する一価カチオン酸化物の合計である、アルカリアルミノケイ酸ガラスを含む。一部の実施形態において、ガラスは0.6<[M2O3(モル%)/RXO(モル%)]<1.4を満たす。一部の実施形態において、ガラスは0.6<[M2O3(モル%)/RXO(モル%)]<1を満たす。一部の実施形態において、ガラスは1.3<[(P2O5+R2O)/M2O3]≦2.3を満たす。一部の実施形態において、ガラスは1.5<[(P2O5+R2O)/M2O3]≦2.0を満たす。一部の実施形態において、アルカリアルミノケイ酸ガラスは1モル%未満のK2Oをさらに含んでいる。一部の実施形態において、アルカリアルミノケイ酸ガラスは、さらに、1モル%未満のB2O3を含む。一部の実施形態において、一価および二価のカチオン酸化物は、Li2O、Na2O、K2O、Rb2O、Cs2O、MgO、CaO、SrO、BaOおよびZnOからなる群から選択される。一部の実施形態において、アルカリアルミノケイ酸ガラスは、410℃で少なくとも約2.4×10−10cm2/sのカリウム/ナトリウム相互拡散係数を有する。一部の実施形態において、カリウム/ナトリウム相互拡散係数は、約2.4×10−10cm2/s〜約1.5×10−9cm2の範囲内にある。一部の実施形態において、ガラスは、その表面から層深さまで延在する圧縮層を有し、ここで圧縮層は少なくとも約300MPaの圧縮応力下にある。一部の実施形態において、ガラスは、少なくとも約7kgfのビッカース圧子圧入亀裂発生荷重を有する。一部の実施形態において、ガラスは少なくとも約12kgfのビッカース圧子圧入亀裂発生荷重を有する。
i. 0.6<[M2O3(モル%)/RXO(モル%)]<1.4;または
ii. 1.3<[(P2O5+R2O)/M2O3]≦2.3;
であり、式中M2O3=Al2O3+B2O3であり、RXOが、アルカリアルミノケイ酸ガラス中に存在する一価および二価のカチオン酸化物の合計であり、R2Oがアルカリアルミノケイ酸ガラス中に存在する一価カチオン酸化物の合計であるアルカリアルミノケイ酸ガラスを提供するステップと;最大約24時間の時限中イオン交換浴中にアルカリアルミノケイ酸ガラスを浸漬して、アルカリアルミノケイ酸ガラスの表面から少なくとも10μmの層深さまで延在する圧縮層を形成するステップとを含む、アルカリアルミノケイ酸ガラスを強化する方法を含んでいる。一部の実施形態において、ガラスは0.6<[M2O3(モル%)/RXO(モル%)]<1.4を満たす。一部の実施形態において、ガラスは0.6<[M2O3(モル%)/RXO(モル%)]<1を満たす。一部の実施形態において、ガラスは1.3<[(P2O5+R2O)/M2O3]≦2.3を満たす。一部の実施形態において、ガラスは1.5<[(P2O5+R2O)/M2O3]≦2.0を満たす。一部の実施形態において、アルカリアルミノケイ酸ガラスは1モル%未満のK2Oを含む。一部の実施形態において、アルカリアルミノケイ酸ガラスは、1モル%未満のB2O3を含む。一部の実施形態において、圧縮層は少なくとも約300MPaの圧縮応力下にある。一部の実施形態において、イオン交換ガラスは、少なくとも約7kgfのビッカース圧子圧入亀裂発生荷重を有する。一部の実施形態において、イオン交換ガラスは少なくとも約12kgfのビッカース圧子圧入亀裂発生荷重を有する。
i. 0.6<[M2O3(モル%)/RXO(モル%)]<1.4;または
ii. 1.3<[(P2O5+R2O)/M2O3]≦2.3;
であり、式中M2O3=Al2O3+B2O3であり、RXOが、アルカリアルミノケイ酸ガラス中に存在する一価および二価のカチオン酸化物の合計であり、R2Oがアルカリアルミノケイ酸ガラス中に存在する一価カチオン酸化物の合計であるアルカリアルミノケイ酸ガラスを提供するステップと;最大約24時間の時限中イオン交換浴中にアルカリアルミノケイ酸ガラスを浸漬して、アルカリアルミノケイ酸ガラスの表面から少なくとも10μmの層深さまで延在する圧縮層を形成するステップとを含む。一部の実施形態において、ガラスは0.6<[M2O3(モル%)/RXO(モル%)]<1.4を満たす。一部の実施形態において、ガラスは0.6<[M2O3(モル%)/RXO(モル%)]<1を満たす。一部の実施形態において、ガラスは1.3<[(P2O5+R2O)/M2O3]≦2.3を満たす。一部の実施形態において、ガラスは1.5<[(P2O5+R2O)/M2O3]≦2.0を満たす。一部の実施形態において、アルカリアルミノケイ酸ガラスは1モル%未満のK2Oを含んでいる。一部の実施形態において、アルカリアルミノケイ酸ガラスは、1モル%未満のB2O3を含む。一部の実施形態において、圧縮層は少なくとも約300MPaの圧縮応力下にある。一部の実施形態において、イオン交換ガラスは、少なくとも約7kgfのビッカース圧子圧入亀裂発生荷重を有する。一部の実施形態において、イオン交換ガラスは少なくとも約12kgfのビッカース圧子圧入亀裂発生荷重を有する。一部の実施形態において、圧縮層は表面から、少なくとも70μmの層深さまで延在する。
0.75≦[(P2O5(モル%)+R2O(モル%))/M2O3(モル%)]≦1.3
(式中、M2O3=Al2O3+B2O3)。
[(Al2O3(モル%)+B2O3(モル%))/(Σ改質酸化物(モル%))]<1.0
一部の実施形態において、ガラスはガラス構造を可能にするのに充分なP2O5を有することができ、ここでP2O5はむしろ構造中に存在するかまたはMPO4に加えて存在する。一部の実施形態において、このような構造は、1.24超の[(P2O5(モル%)+R2O(モル%))/M2O3(モル%)]比により表現されてよく、式中M2O3=Al2O3+B2O3であり、P2O5は4モル%以上であり、R2Oはアルカリアルミノケイ酸ガラス中に存在する二価のカチオン酸化物の合計である。一部の実施形態において、本明細書中に記載のガラスは、4モル%超のP2O5を含み、ここで[(P2O5(モル%)+R2O(モル%))/M2O3(モル%)]の比は1.24超であり、式中M2O3=Al2O3+B2O3であり、ここでR2Oは、アルカリアルミノケイ酸ガラス中に存在する二価のカチオン酸化物の合計である。一部の実施形態において、[(P2O5(モル%)+R2O(モル%))/M2O3(モル%)]の比は1.3超である。一部の実施形態において、この比は1.24≦[(P2O5(モル%)+R2O(モル%))/M2O3(モル%)]≦2.8である。一部の実施形態において、本明細書中に記載のガラスおよびガラス物品は4モル%超のP2O5を含み、
S≦[(P2O5(モル%)+R2O(モル%))/M2O3(モル%)]≦V
の比で表現される。式中、Sは独立して約1.5、1.45、1.4、1.35、1.3、1.25、1.24、1.2または1.15であり、Vは独立して約2.0、2.05、2.1、2.15、2.2、2.25、2.3、2.35、2.4、2.45、2.5、2.55、2.6、2.65、2.7、2.75または2.8である。
Claims (10)
- 少なくとも約4%のP2O5を含むアルカリアルミノケイ酸ガラスにおいて、少なくとも約10μmの層深さまでイオン交換されていること;および、
i. 0.6<[M2O3(モル%)/RXO(モル%)]<1.4;または
ii. 1.3<[(P2O5+R2O)/M2O3]≦2.3;
であり、式中M2O3=Al2O3+B2O3であり、RXOが、前記アルカリアルミノケイ酸ガラス中に存在する一価および二価のカチオン酸化物の合計であり、R2Oが前記アルカリアルミノケイ酸ガラス中に存在する一価カチオン酸化物の合計であることを特徴とする、アルカリアルミノケイ酸ガラス。 - 前記ガラスが、下記式
1.5<[(P2O5+R2O)/M2O3]≦2.0
を満たすことを特徴とする請求項1に記載のアルカリアルミノケイ酸ガラス。 - 1モル%未満のK2Oまたは1モル%未満のB2O3をさらに含み、前記一価および二価のカチオン酸化物が、Li2O、Na2O、K2O、Rb2O、Cs2O、MgO、CaO、SrO、BaOおよびZnOからなる群から選択されることを特徴とする請求項1または2に記載のアルカリアルミノケイ酸ガラス。
- 前記アルカリアルミノケイ酸ガラスが約40モル%〜約70モル%のSiO2と;約11モル%〜約25モル%のAl2O3と;約4モル%〜約15モル%のP2O5と;約13モル%〜約25モル%のNa2Oとを含むことを特徴とする請求項1〜3のいずれか1項に記載のアルカリアルミノケイ酸ガラス。
- 前記アルカリアルミノケイ酸ガラスが約50モル%〜約65モル%のSiO2と;約14モル%〜約20モル%のAl2O3と;約4モル%〜約10モル%のP2O5と;約14モル%〜約20モル%のNa2Oと;任意選択で1モル%未満のK2Oまたは1モル%未満のB2O3とを含むことを特徴とする請求項4に記載のアルカリアルミノケイ酸ガラス。
- カリウム/ナトリウム相互拡散係数が、410℃で約2.4×10−10cm2/s〜約6×10−10cm2/sの範囲内にあるか;または前記ガラスが前記ガラスの表面から前記層深さまで延在する圧縮層を有すること、および前記圧縮層が少なくとも約300MPaの圧縮応力下にあるか;または前記イオン交換ガラスが少なくとも約12kgfのビッカース圧子圧入亀裂発生荷重を有することを特徴とする請求項1〜5のいずれか1項に記載のアルカリアルミノケイ酸ガラス。
- アルカリアルミノケイ酸ガラスを強化する方法において、
a.請求項1〜6のいずれか1項に記載のアルカリアルミノケイ酸ガラスを提供するステップと;
b.最大約24時間の時限中イオン交換浴中に前記アルカリアルミノケイ酸ガラスを浸漬して、前記アルカリアルミノケイ酸ガラスの表面から少なくとも10μmの層深さまで延在する圧縮層を形成するステップと;
を含む方法。 - 前記ガラスが、下記式
1.5<[(P2O5+R2O)/M2O3]≦2.0
を満たすことを特徴とする請求項7に記載の方法。 - 前記アルカリアルミノケイ酸ガラスが1モル%未満のK2Oまたは1モル%未満のB2O3を含むことおよび、前記一価および二価のカチオン酸化物がLi2O、Na2O、K2O、Rb2O、Cs2O、MgO、CaO、SrO、BaOおよびZnOからなる群から選択されていることを特徴とする請求項7または8に記載の方法。
- 前記ガラスの前記カリウム/ナトリウム相互拡散係数が410℃で約2.4×10−10cm2/s〜約6×10−10cm2/sの範囲内にあるか;または前記ガラスが前記ガラスの表面から前記層深さまで延在する圧縮層を有すること、および前記圧縮層が少なくとも約300MPaの圧縮応力下にあるか;または前記イオン交換ガラスが少なくとも約12kgfのビッカース圧子圧入亀裂発生荷重を有することを特徴とする請求項7〜9のいずれか1項に記載のアルカリアルミノケイ酸ガラス。
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CN107810110B (zh) | 2015-06-26 | 2020-03-10 | 康宁股份有限公司 | 具有高表面强度的玻璃 |
US9701569B2 (en) | 2015-07-21 | 2017-07-11 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
TWI758263B (zh) | 2015-11-19 | 2022-03-21 | 美商康寧公司 | 顯示螢幕保護器 |
CN108290775A (zh) | 2015-11-23 | 2018-07-17 | 康宁股份有限公司 | 从玻璃基材去除无机涂层 |
JP2019501101A (ja) * | 2015-12-08 | 2019-01-17 | コーニング インコーポレイテッド | S字応力プロファイル及び生成方法 |
KR20240019400A (ko) | 2015-12-11 | 2024-02-14 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함하는 융합-형성가능한 유리계 제품 |
KR20180095559A (ko) | 2015-12-17 | 2018-08-27 | 코닝 인코포레이티드 | 빠른 확산을 갖는 이온 교환 가능한 유리 |
TWI736571B (zh) | 2016-01-08 | 2021-08-21 | 美商康寧公司 | 具固有耐損性之可化學強化的鋰鋁矽酸鹽玻璃 |
JP6923555B2 (ja) | 2016-01-12 | 2021-08-18 | コーニング インコーポレイテッド | 薄厚熱強化及び化学強化ガラス系物品 |
DE102016101066B3 (de) | 2016-01-21 | 2017-02-23 | Schott Ag | Verfahren zur Herstellung eines vorzugsweise nicht eingefärbten glaskeramischen Materials mit geringem Streulichtanteil sowie verfahrensgemäß hergestelltes glaskeramisches Material und dessen Verwendung |
US11795102B2 (en) | 2016-01-26 | 2023-10-24 | Corning Incorporated | Non-contact coated glass and related coating system and method |
US11597672B2 (en) | 2016-03-09 | 2023-03-07 | Corning Incorporated | Cold forming of complexly curved glass articles |
KR20240033166A (ko) | 2016-04-08 | 2024-03-12 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함하는 유리-계 제품 |
US10271442B2 (en) * | 2016-04-08 | 2019-04-23 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
US11453612B2 (en) * | 2016-04-20 | 2022-09-27 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
JP6948349B2 (ja) | 2016-05-31 | 2021-10-13 | コーニング インコーポレイテッド | ガラス物品用偽造防止対策 |
US11198639B2 (en) | 2016-06-13 | 2021-12-14 | Corning Incorporated | Multicolored photosensitive glass-based parts and methods of manufacture |
DE102016211065B4 (de) | 2016-06-21 | 2019-09-05 | Schott Ag | Transparenter, vorzugsweise eingefärbter Glaskeramikartikel mit geringem Streulichtanteil und hoher Festigkeit sowie Verfahren zu seiner Herstellung und seine Verwendung |
CN107540214B (zh) * | 2016-06-24 | 2020-06-05 | 成都光明光电股份有限公司 | 光学玻璃、光学预制件和光学元件 |
KR102456592B1 (ko) | 2016-06-28 | 2022-10-19 | 코닝 인코포레이티드 | 장식 및 디스플레이 커버 적용(application)을 위한 커브드(curved) 몰딩된(molded) 플라스틱 표면에 대한 얇은 강화된 유리의 적층(laminating) |
US10483101B2 (en) | 2016-06-30 | 2019-11-19 | Corning Incorporated | Glass-based article with engineered stress distribution and method of making same |
US11607958B2 (en) | 2016-07-05 | 2023-03-21 | Corning Incorporated | Cold-formed glass article and assembly process thereof |
CN109476530A (zh) * | 2016-07-28 | 2019-03-15 | 康宁股份有限公司 | 具有抗光致暗化性的玻璃 |
CN115403280B (zh) | 2016-10-25 | 2024-03-19 | 康宁公司 | 用于显示器的冷成形玻璃积层 |
EP3686004B1 (en) | 2017-01-03 | 2021-12-08 | Corning Incorporated | Vehicle interior systems having a curved cover glass and a display |
US11016590B2 (en) | 2017-01-03 | 2021-05-25 | Corning Incorporated | Vehicle interior systems having a curved cover glass and display or touch panel and methods for forming the same |
EP3571170B1 (en) | 2017-01-18 | 2022-08-31 | Corning Incorporated | Coated glass-based articles with engineered stress profiles and methods of manufacture |
TWI749160B (zh) * | 2017-01-31 | 2021-12-11 | 美商康寧公司 | 具有工程應力分佈的塗層玻璃基底製品及包含其之消費性電子產品 |
KR102558993B1 (ko) | 2017-05-15 | 2023-07-24 | 코닝 인코포레이티드 | 윤곽 유리 제품 및 그 제조 방법 |
US11332011B2 (en) | 2017-07-18 | 2022-05-17 | Corning Incorporated | Cold forming of complexly curved glass articles |
US20190030861A1 (en) | 2017-07-27 | 2019-01-31 | Corning Incorporated | Composite laminate with high depth of compression |
CN111065609A (zh) | 2017-08-24 | 2020-04-24 | 康宁股份有限公司 | 具有改进的回火能力的玻璃 |
KR102669222B1 (ko) | 2017-09-12 | 2024-05-24 | 코닝 인코포레이티드 | 장식용 유리 상에 터치 패널을 포함하는 디스플레이용 데드프론트 및 관련 방법 |
US11065960B2 (en) | 2017-09-13 | 2021-07-20 | Corning Incorporated | Curved vehicle displays |
TW202340816A (zh) | 2017-09-13 | 2023-10-16 | 美商康寧公司 | 用於顯示器的基於光導器的無電面板、相關的方法及載具內部系統 |
CN107651837B (zh) * | 2017-09-27 | 2021-03-26 | 东旭光电科技股份有限公司 | 一种用于保护显示器件的玻璃组合物及其制备方法 |
US11523527B2 (en) | 2017-10-03 | 2022-12-06 | Corning Incorporated | Glass-based articles having crack resistant stress profiles |
US11655184B2 (en) | 2017-10-10 | 2023-05-23 | Corning Incorporated | Glass-based articles with sections of different thicknesses |
CN111433019B (zh) | 2017-10-10 | 2023-10-13 | 康宁股份有限公司 | 具有改进的可靠性的弯曲覆盖玻璃的交通工具内部系统及其形成方法 |
NL2020896B1 (en) * | 2018-05-08 | 2019-11-14 | Corning Inc | Water-containing glass-based articles with high indentation cracking threshold |
WO2019103469A1 (en) | 2017-11-21 | 2019-05-31 | Corning Precision Materials Co., Ltd. | Aspheric mirror for head-up display system and methods for forming the same |
WO2019108774A1 (en) | 2017-11-29 | 2019-06-06 | Corning Incorporated | Methods of making coated glass-based parts |
JP7407707B2 (ja) | 2017-11-30 | 2024-01-04 | コーニング インコーポレイテッド | 非球面ミラーを真空成形するシステム及び方法 |
WO2019108840A1 (en) | 2017-11-30 | 2019-06-06 | Corning Incorporated | Glass-based articles having stress profiles with high stored energy and methods of manufacture |
KR102605341B1 (ko) | 2017-11-30 | 2023-11-24 | 코닝 인코포레이티드 | 곡선형 미러를 성형하기 위한 진공 몰드 장치, 시스템, 및 방법 |
TWI785156B (zh) | 2017-11-30 | 2022-12-01 | 美商康寧公司 | 具有高熱膨脹係數及對於熱回火之優先破裂行為的非離子交換玻璃 |
EP3765425B1 (en) | 2018-03-13 | 2023-11-08 | Corning Incorporated | Vehicle interior systems having a crack resistant curved cover glass and methods for forming the same |
WO2019191480A1 (en) | 2018-03-29 | 2019-10-03 | Corning Incorporated | Glasses having high fracture toughness |
TW202005928A (zh) | 2018-06-01 | 2020-02-01 | 美商康寧公司 | 低翹曲、強化製品及製作該製品之非對稱離子交換方法 |
CN110605274B (zh) | 2018-06-15 | 2022-12-27 | 康宁股份有限公司 | 玻璃基材加工方法 |
EP3818022A1 (en) | 2018-07-05 | 2021-05-12 | Corning Incorporated | Asymmetric ion-exchange methods of making strengthened articles with asymmetric surfaces |
DE102018116464A1 (de) | 2018-07-06 | 2020-01-09 | Schott Ag | Chemisch vorspannbare, korrosionsstabile Gläser |
DE102018116460A1 (de) | 2018-07-06 | 2020-01-09 | Schott Ag | Hoch beständige und chemisch vorspannbare Gläser |
DE102018116483A1 (de) | 2018-07-06 | 2020-01-09 | Schott Ag | Chemisch vorspannbare Gläser mit hoher chemischer Resistenz und Rißbeständigkeit |
DE102019117498B4 (de) | 2018-07-06 | 2024-03-28 | Schott Ag | Gläser mit verbesserter Ionenaustauschbarkeit |
WO2020018284A1 (en) | 2018-07-16 | 2020-01-23 | Corning Incorporated | Vehicle interior systems having a cold-bent glass substrate and methods for forming the same |
MA50738B1 (fr) | 2018-08-16 | 2021-05-31 | Anuvia Plant Nutrients Holdings Llc | Revêtements inorganiques réactifs pour engrais agricoles |
CN109020192A (zh) * | 2018-10-17 | 2018-12-18 | 科立视材料科技有限公司 | 一种具有高应变点、可快速离子交换和耐弱酸性的锌磷铝硅酸盐玻璃 |
WO2020102147A2 (en) | 2018-11-16 | 2020-05-22 | Corning Incorporated | Laminated glass articles comprising a hydrogen-containing glass core layer and methods of forming the same |
TW202026257A (zh) | 2018-11-16 | 2020-07-16 | 美商康寧公司 | 用於透過蒸氣處理而強化之玻璃成分及方法 |
CN111204989A (zh) | 2018-11-22 | 2020-05-29 | 康宁股份有限公司 | 低翘曲的强化制品以及制造其的不对称离子交换方法 |
CN111348837A (zh) | 2018-12-20 | 2020-06-30 | 康宁股份有限公司 | 强化制品、强化玻璃制品以及制造强化制品的方法 |
WO2020231961A1 (en) | 2019-05-16 | 2020-11-19 | Corning Incorporated | Glass compositions and methods with steam treatment haze resistance |
EP3771695A1 (en) | 2019-07-31 | 2021-02-03 | Corning Incorporated | Method and system for cold-forming glass |
DE102019121147A1 (de) | 2019-08-05 | 2021-02-11 | Schott Ag | Scheibenförmiger, chemisch vorgespannter Glasartikel und Verfahren zu dessen Herstellung |
WO2021023757A1 (de) | 2019-08-05 | 2021-02-11 | Schott Ag | Scheibenförmiger, chemisch vorgespannter oder chemisch vorspannbarer glasartikel und verfahren zu dessen herstellung |
DE102019121146A1 (de) | 2019-08-05 | 2021-02-11 | Schott Ag | Heißgeformter chemisch vorspannbarer Glasartikel mit geringem Kristallanteil, insbesondere scheibenförmiger chemisch vorspannbarer Glasartikel, sowie Verfahren und Vorrichtung zu seiner Herstellung |
WO2021025981A1 (en) | 2019-08-06 | 2021-02-11 | Corning Incorporated | Glass laminate with buried stress spikes to arrest cracks and methods of making the same |
US11584681B2 (en) | 2019-11-26 | 2023-02-21 | Corning Incorporated | Ion exchangeable alkali aluminosilicate glass compositions having improved mechanical durability |
CN114981224A (zh) * | 2019-11-27 | 2022-08-30 | 康宁股份有限公司 | 具有高中心张力的高断裂韧性玻璃 |
US11772361B2 (en) | 2020-04-02 | 2023-10-03 | Corning Incorporated | Curved glass constructions and methods for forming same |
GB202012825D0 (en) | 2020-05-12 | 2020-09-30 | Corning Inc | Fusion formable and steam strengthenable glass compositions with platinum compatibility |
KR20230109717A (ko) | 2020-11-30 | 2023-07-20 | 코닝 인코포레이티드 | 압축 상단 층이 있는 유리 폴리머 적층 |
CN112707639A (zh) * | 2020-12-30 | 2021-04-27 | 清远南玻节能新材料有限公司 | 锂铝硅酸盐玻璃、强化玻璃及其制备方法和电子产品 |
CN113149428B (zh) * | 2021-04-30 | 2022-09-09 | 科立视材料科技有限公司 | 一种高铝玻璃、高铝钢化玻璃及其制备方法 |
DE202021103861U1 (de) | 2021-07-20 | 2021-10-04 | Schott Ag | Scheibenförmiger, chemisch vorgespannter oder chemisch vorspannbarer Glasartikel |
CN117957204A (zh) * | 2021-07-29 | 2024-04-30 | 康宁公司 | 低模量可离子交换玻璃组合物 |
WO2023211731A1 (en) | 2022-04-28 | 2023-11-02 | Corning Incorporated | Impact-resistant glass-polymer laminates and sensors incorporating the same |
WO2024118320A1 (en) | 2022-11-28 | 2024-06-06 | Corning Incorporated | Composite articles with impact-resistant glass-polymer layers and damage-resistant glass laminate layers and methods of making the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3357876A (en) * | 1965-01-19 | 1967-12-12 | Pittsburgh Plate Glass Co | Method of strengthening a glass article by ion exchange |
US3433611A (en) * | 1965-09-09 | 1969-03-18 | Ppg Industries Inc | Strengthening glass by multiple alkali ion exchange |
JP2004102210A (ja) * | 2002-07-16 | 2004-04-02 | Asahi Glass Co Ltd | ガラス、光導波路製造方法および光導波路 |
Family Cites Families (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6410825A (ja) | 1963-11-21 | 1965-05-24 | ||
US3356477A (en) | 1963-12-04 | 1967-12-05 | Pittsburgh Plate Glass Co | Method of increasing stain resistance of a glass body subjected to an ion exchange strengthening set-up |
US3485647A (en) * | 1964-12-18 | 1969-12-23 | Corning Glass Works | Glass article and method of production |
US3495963A (en) | 1965-04-13 | 1970-02-17 | Ppg Industries Inc | Simultaneous staining and strengthening of glass |
NL6808826A (ja) * | 1967-07-01 | 1969-01-03 | ||
US3998617A (en) * | 1968-10-24 | 1976-12-21 | Jenaer Glaswerk Schott & Gen. | Method of improving the mechanical strength of glass |
US3728095A (en) | 1971-02-16 | 1973-04-17 | Owens Illinois Inc | Chemically-strengthened glass-encapsulated glass articles and process therefor |
GB1367903A (en) | 1971-07-12 | 1974-09-25 | Pilkington Brothers Ltd | Photochromic glasses |
AT339523B (de) * | 1973-09-21 | 1977-10-25 | Jenaer Glaswerk Schott & Gen | Glaskeramik fur zahnfullmassen |
US4108674A (en) | 1974-02-01 | 1978-08-22 | Jenaer Glaswerk Schott & Gen. | Phototropic optical glass |
US4055703A (en) | 1975-08-15 | 1977-10-25 | Ppg Industries, Inc. | Ion exchange strengthened glass containing P2 O5 |
US4053679A (en) * | 1975-08-15 | 1977-10-11 | Ppg Industries, Inc. | Chemically strengthened opal glass |
GB1540471A (en) | 1976-01-30 | 1979-02-14 | Pilkington Brothers Ltd | Photochromic glasses |
US4042405A (en) * | 1976-03-18 | 1977-08-16 | American Optical Corporation | High strength ophthalmic lens |
US4059454A (en) * | 1976-06-16 | 1977-11-22 | Corning Glass Works | Green colored glasses |
US4125404A (en) | 1976-11-05 | 1978-11-14 | Corning Glass Works | Photochromic glasses exhibiting dichroism, birefringence and color adaptation |
SU823326A1 (ru) | 1979-07-30 | 1981-04-23 | Государственный Научно-Исследовательскийинститут Стекла | Глушеное стекло |
SU925886A1 (ru) | 1980-07-09 | 1982-05-07 | Государственный научно-исследовательский институт стекла | Глушеное стекло |
DE3204625C2 (de) | 1982-02-10 | 1986-07-10 | Schott Glaswerke, 6500 Mainz | Alumosilico-Phosphat-Brillenglas mit einer Abbezahl über 46, mit einem Brechungsindex über 1,56 und einer sehr niedrigen Dichte |
US4726981A (en) | 1985-06-10 | 1988-02-23 | Corning Glass Works | Strengthened glass articles and method for making |
JPH01167245A (ja) | 1987-12-24 | 1989-06-30 | Central Glass Co Ltd | 化学強化用ガラス組成物 |
DE4423794C1 (de) * | 1994-07-01 | 1996-02-08 | Ivoclar Ag | Zr0¶2¶-haltige Glaskeramik, Verfahren zu deren Herstellung sowie deren Verwendung |
CN1207086A (zh) * | 1996-09-04 | 1999-02-03 | 保谷株式会社 | 信息记录介质基片用玻璃及玻璃基片 |
JP3219705B2 (ja) | 1996-11-14 | 2001-10-15 | 株式会社オハラ | 磁気情報記憶媒体用ガラスセラミックス基板 |
JPH10236891A (ja) * | 1997-02-28 | 1998-09-08 | Kawasaki Steel Corp | コークス炉炭化室コーティング剤及びその施工方法 |
JPH1167245A (ja) | 1997-08-21 | 1999-03-09 | Toshiba Corp | 燃料電池の保持電解質管理方法 |
JP3311308B2 (ja) | 1998-03-03 | 2002-08-05 | 株式会社オハラ | 垂直磁気記録媒体用ガラスセラミックス基板 |
JP2000086283A (ja) * | 1998-09-08 | 2000-03-28 | Ohara Inc | 発光性ガラス |
JP2001076336A (ja) * | 1999-09-08 | 2001-03-23 | Hoya Corp | 情報記録媒体用ガラス基板およびそれを用いた情報記録媒体 |
SG99350A1 (en) * | 2000-02-17 | 2003-10-27 | Hoya Corp | Glass for cathode-ray tube, strengthened glass, method for the production thereof and use thereof |
US6743743B2 (en) * | 2001-01-29 | 2004-06-01 | Hoya Corporation | Optical glass |
US6753279B2 (en) * | 2001-10-30 | 2004-06-22 | Corning Incorporated | Glass composition for display panels |
CN1450010A (zh) * | 2002-04-09 | 2003-10-22 | 碧悠国际光电股份有限公司 | 光学玻璃 |
JP4933863B2 (ja) | 2005-10-25 | 2012-05-16 | 株式会社オハラ | 結晶化ガラスおよび結晶化ガラスの製造方法 |
JP2008050182A (ja) * | 2006-08-23 | 2008-03-06 | Nippon Sheet Glass Co Ltd | ガラス組成物およびその製造方法 |
KR101221834B1 (ko) * | 2006-10-10 | 2013-01-15 | 니폰 덴키 가라스 가부시키가이샤 | 강화 유리 기판 |
JP4755135B2 (ja) | 2007-04-27 | 2011-08-24 | 株式会社オハラ | 結晶化ガラス |
CN101679105B (zh) | 2007-06-07 | 2015-06-17 | 日本电气硝子株式会社 | 强化玻璃基板及其制造方法 |
JP2009007194A (ja) * | 2007-06-27 | 2009-01-15 | Ohara Inc | ガラス組成物 |
EP2252558A4 (en) | 2008-02-08 | 2014-08-27 | Corning Inc | DAMAGING RESISTANT, CHEMICALLY PREVENTED PROTECTIVE GLASS |
JP5583606B2 (ja) | 2008-02-26 | 2014-09-03 | コーニング インコーポレイテッド | ケイ酸塩ガラス用の清澄剤 |
JP5614607B2 (ja) * | 2008-08-04 | 2014-10-29 | 日本電気硝子株式会社 | 強化ガラスおよびその製造方法 |
CN102123960A (zh) * | 2008-08-21 | 2011-07-13 | 康宁股份有限公司 | 用于电子设备的耐久性玻璃机壳/封罩 |
US8341976B2 (en) * | 2009-02-19 | 2013-01-01 | Corning Incorporated | Method of separating strengthened glass |
WO2010131659A1 (ja) | 2009-05-13 | 2010-11-18 | 旭硝子株式会社 | 固体撮像素子パッケージ用カバーガラス |
JP5659544B2 (ja) * | 2009-07-03 | 2015-01-28 | 旭硝子株式会社 | 情報記録媒体基板用ガラス、情報記録媒体用ガラス基板および磁気ディスク |
US8326777B2 (en) * | 2009-07-31 | 2012-12-04 | Yahoo! Inc. | Supplementing a trained model using incremental data in making item recommendations |
US8802581B2 (en) | 2009-08-21 | 2014-08-12 | Corning Incorporated | Zircon compatible glasses for down draw |
US20110081396A1 (en) | 2009-09-09 | 2011-04-07 | The Ohio State University Research Foundation | Glass ceramic scaffolds with complex topography |
JP5645099B2 (ja) * | 2009-09-09 | 2014-12-24 | 日本電気硝子株式会社 | 強化ガラス |
US8759238B2 (en) | 2010-05-27 | 2014-06-24 | Corning Incorporated | Ion exchangeable glasses |
US9346703B2 (en) * | 2010-11-30 | 2016-05-24 | Corning Incorporated | Ion exchangable glass with deep compressive layer and high damage threshold |
US8889575B2 (en) * | 2011-05-31 | 2014-11-18 | Corning Incorporated | Ion exchangeable alkali aluminosilicate glass articles |
US10280112B2 (en) | 2011-08-19 | 2019-05-07 | Corning Incorporated | Ion exchanged glass with high resistance to sharp contact failure and articles made therefrom |
BR112014011561A2 (pt) * | 2011-11-16 | 2017-05-09 | Corning Inc | vidro de troca iônica com alto limiar de iniciação de craqueamento |
TWI635063B (zh) * | 2013-11-26 | 2018-09-11 | 康寧公司 | 具有抗微生物效果之含磷玻璃 |
US9517968B2 (en) * | 2014-02-24 | 2016-12-13 | Corning Incorporated | Strengthened glass with deep depth of compression |
CN106232543A (zh) * | 2014-02-27 | 2016-12-14 | 康宁股份有限公司 | 用于三维成形的可离子交换玻璃制品 |
-
2012
- 2012-11-15 BR BR112014011561A patent/BR112014011561A2/pt not_active IP Right Cessation
- 2012-11-15 US US13/678,013 patent/US9156724B2/en active Active
- 2012-11-15 CN CN201280067101.XA patent/CN104114503A/zh active Pending
- 2012-11-15 CN CN201910294436.9A patent/CN110002745B/zh active Active
- 2012-11-15 KR KR1020147016419A patent/KR102036799B1/ko active IP Right Grant
- 2012-11-15 US US13/677,805 patent/US8765262B2/en active Active
- 2012-11-15 JP JP2014542460A patent/JP6527330B2/ja active Active
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3357876A (en) * | 1965-01-19 | 1967-12-12 | Pittsburgh Plate Glass Co | Method of strengthening a glass article by ion exchange |
US3433611A (en) * | 1965-09-09 | 1969-03-18 | Ppg Industries Inc | Strengthening glass by multiple alkali ion exchange |
JP2004102210A (ja) * | 2002-07-16 | 2004-04-02 | Asahi Glass Co Ltd | ガラス、光導波路製造方法および光導波路 |
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JP2018509366A (ja) * | 2015-02-26 | 2018-04-05 | コーニング インコーポレイテッド | 軟化点が低い、高速イオン交換可能な無ホウ素ガラス |
KR102562301B1 (ko) * | 2015-02-26 | 2023-08-01 | 코닝 인코포레이티드 | 낮은 연화점을 갖는 빠른 이온 교환 가능한 붕소-없는 유리 |
JP2019503330A (ja) * | 2016-01-13 | 2019-02-07 | コーニング インコーポレイテッド | 極薄の割れにくいガラスおよびその製造方法 |
US11286203B2 (en) | 2016-01-13 | 2022-03-29 | Corning Incorporated | Ultra-thin, non-frangible glass and methods of making |
US11767252B2 (en) | 2016-01-21 | 2023-09-26 | AGC Inc. | Chemically strengthened glass, and glass for chemical strengthening |
US10370287B2 (en) | 2016-01-21 | 2019-08-06 | AGC Inc. | Chemically strengthened glass, and glass for chemical strengthening |
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US10472272B2 (en) | 2016-01-21 | 2019-11-12 | AGC Inc. | Chemically strengthened glass, and glass for chemical strengthening |
US11059744B2 (en) | 2016-06-14 | 2021-07-13 | Corning Incorporated | Glasses having improved drop performance |
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JP7198325B2 (ja) | 2016-06-14 | 2022-12-28 | コーニング インコーポレイテッド | 落下性能が改善されたガラス |
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KR20190020028A (ko) * | 2016-06-14 | 2019-02-27 | 코닝 인코포레이티드 | 향상된 낙하 성능을 갖는 유리 |
JP2020520337A (ja) * | 2017-05-16 | 2020-07-09 | トンシュー テクノロジー グループ カンパニー リミテッドTunghsu Technology Group Co., Ltd. | ガラス用組成物及びガラス、並びにその製造方法及び応用 |
JP6995885B2 (ja) | 2017-05-16 | 2022-01-17 | トンシュー テクノロジー グループ カンパニー リミテッド | ガラス用組成物及びガラス、並びにその製造方法及び使用 |
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US11708295B2 (en) | 2017-05-16 | 2023-07-25 | Tunghsu Technology Group Co., Ltd. | Composition for glass, glass, preparation method and application thereof |
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