JP2013543217A - 塩化物を含有する支持溶液に基づくレドックスフロー電池 - Google Patents
塩化物を含有する支持溶液に基づくレドックスフロー電池 Download PDFInfo
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title description 29
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 42
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 150000002500 ions Chemical class 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 12
- GNZKCLSXDUXHNG-UHFFFAOYSA-N Vanadium cation Chemical compound [V+] GNZKCLSXDUXHNG-UHFFFAOYSA-N 0.000 claims description 9
- 239000000243 solution Substances 0.000 abstract description 99
- 239000011259 mixed solution Substances 0.000 abstract description 6
- 239000000460 chlorine Substances 0.000 description 80
- 150000001768 cations Chemical class 0.000 description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 24
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 24
- 239000012528 membrane Substances 0.000 description 18
- 229910052801 chlorine Inorganic materials 0.000 description 17
- 239000003792 electrolyte Substances 0.000 description 17
- 239000007789 gas Substances 0.000 description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 12
- 229910002804 graphite Inorganic materials 0.000 description 11
- 239000010439 graphite Substances 0.000 description 11
- VLOPEOIIELCUML-UHFFFAOYSA-L vanadium(2+);sulfate Chemical compound [V+2].[O-]S([O-])(=O)=O VLOPEOIIELCUML-UHFFFAOYSA-L 0.000 description 11
- 229920000557 Nafion® Polymers 0.000 description 10
- 238000002484 cyclic voltammetry Methods 0.000 description 10
- 229920003295 Radel® Polymers 0.000 description 7
- AVXLRFJKHPHWLZ-UHFFFAOYSA-K S(=O)(=O)([O-])[O-].[Cl-].[V+3] Chemical compound S(=O)(=O)([O-])[O-].[Cl-].[V+3] AVXLRFJKHPHWLZ-UHFFFAOYSA-K 0.000 description 7
- 229910021550 Vanadium Chloride Inorganic materials 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000013112 stability test Methods 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 239000008151 electrolyte solution Substances 0.000 description 5
- 229940021013 electrolyte solution Drugs 0.000 description 5
- -1 halogen ions Chemical class 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000002918 waste heat Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical class C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000006479 redox reaction Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000003077 quantum chemistry computational method Methods 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910001456 vanadium ion Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000003011 anion exchange membrane Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000005595 deprotonation Effects 0.000 description 1
- 238000010537 deprotonation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/08—Fuel cells with aqueous electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
- H01M2300/0011—Sulfuric acid-based
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
Abstract
Description
本発明は、米国エネルギー省によって付与された契約番号DE-AC0576RL01830の下で連邦政府の支援を受けてなされたものである。連邦政府は本発明の一定の権利を有する。
本発明は、2010年9月28日に出願された米国特許出願第12/892,693号(「Redox Flow Batteries Based on Supporting Solutions Containing Chloride」)の優先権を主張する。
2. 2.5VS 6HCl:2.5MのV, 2.5MのSO4 2-, 6MのCl-; 3VS6HCl:3MのV, 3MのSO4 2-, 6MのCl-; 1.6V 4.5S:1.6MのV, 4.5MのSO4 2-
Claims (19)
- バナジウム系レドックスフロー電池システムであり、陽極液が支持溶液中のV2+およびV3+を含み、陰極液が支持溶液中のV4+およびV5+を含み、前記支持溶液がClを含むことを特徴とするシステム。
- 前記支持溶液が、SO4 2-イオンとCl-イオンの混合物を含む請求項1に記載のシステム。
- Cl-対SO4 2-の濃度比が、1:100〜100:1の範囲である請求項2に記載のシステム。
- Cl-対SO4 2-の濃度比が、1:10〜10:1の範囲である請求項2に記載のシステム。
- Cl-対SO4 2-の濃度比が、1:3〜3:1の範囲である請求項2に記載のシステム。
- 前記陰極液が、VO2Cl(H2O)2を含む請求項1に記載のシステム。
- 運転中のセル温度が、40℃より高い請求項1に記載のシステム。
- 運転中のセル温度が、-35℃〜60℃の範囲である請求項1に記載のシステム。
- 前記セル温度を能動的に調節する熱管理装置を有さない請求項8に記載のシステム。
- 運転中の充電状態条件が、0%超100%未満である請求項1に記載のシステム。
- バナジウムカチオン濃度が、0.5Mより高い請求項1に記載のシステム。
- バナジウムカチオン濃度が、1.7Mより高い請求項1に記載のシステム。
- バナジウムカチオン濃度が、2.5Mより高い請求項1に記載のシステム。
- 支持溶液を有するレドックスフロー電池システムであり、該支持溶液がSO4 2-イオンとCl-イオンの混合物を含むシステム。
- Cl-対SO4 2-の濃度比が、1:100〜100:1の範囲である請求項14に記載のシステム。
- Cl-対SO4 2-の濃度比が、1:10〜10:1の範囲である請求項14に記載のシステム。
- Cl-対SO4 2-の濃度比が、1:3〜3:1の範囲である請求項14に記載のシステム。
- Fe/Cr系である請求項14に記載のシステム。
- 支持溶液を備えるレドックスフロー電池システムであり、該支持溶液がSO4 2-イオンとF-イオンの混合物を含むことを特徴とするシステム。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/892,693 | 2010-09-28 | ||
US12/892,693 US8628880B2 (en) | 2010-09-28 | 2010-09-28 | Redox flow batteries based on supporting solutions containing chloride |
PCT/US2011/039626 WO2012047320A1 (en) | 2010-09-28 | 2011-06-08 | Redox flow batteries based on supporting solutions containing chloride |
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JP2013543217A true JP2013543217A (ja) | 2013-11-28 |
JP6266344B2 JP6266344B2 (ja) | 2018-01-24 |
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JP2013530141A Active JP6266344B2 (ja) | 2010-09-28 | 2011-06-08 | 塩化物を含有する支持溶液に基づくレドックスフロー電池 |
JP2017184337A Active JP6581635B2 (ja) | 2010-09-28 | 2017-09-26 | 塩化物を含有する支持溶液に基づくレドックスフロー電池 |
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Country Status (8)
Country | Link |
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US (5) | US8628880B2 (ja) |
EP (1) | EP2622675A4 (ja) |
JP (2) | JP6266344B2 (ja) |
KR (2) | KR20150091179A (ja) |
CN (2) | CN103125041B (ja) |
AU (1) | AU2011312833B2 (ja) |
CA (1) | CA2812928C (ja) |
WO (1) | WO2012047320A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2016524280A (ja) * | 2013-05-16 | 2016-08-12 | ユナイテッド テクノロジーズ コーポレイションUnited Technologies Corporation | 最大水ドメインクラスターサイズを有する水和イオン交換膜を備えるフローバッテリ |
JP2017535035A (ja) * | 2014-10-06 | 2017-11-24 | バッテル メモリアル インスティチュート | 全バナジウム硫酸酸性レドックスフローバッテリーシステム |
JP2018133263A (ja) * | 2017-02-16 | 2018-08-23 | 株式会社ギャラキシー | フロー型電池の電池活物質液 |
WO2019124300A1 (ja) * | 2017-12-19 | 2019-06-27 | 昭和電工株式会社 | 電解液およびレドックスフロー電池 |
WO2019212053A1 (ja) * | 2018-05-02 | 2019-11-07 | 昭和電工株式会社 | レドックスフロー電池の運転方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
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US8785023B2 (en) * | 2008-07-07 | 2014-07-22 | Enervault Corparation | Cascade redox flow battery systems |
US7820321B2 (en) * | 2008-07-07 | 2010-10-26 | Enervault Corporation | Redox flow battery system for distributed energy storage |
US9960443B2 (en) | 2010-09-28 | 2018-05-01 | Battelle Memorial Institute | Redox flow batteries having multiple electroactive elements |
US8628880B2 (en) | 2010-09-28 | 2014-01-14 | Battelle Memorial Institute | Redox flow batteries based on supporting solutions containing chloride |
US8916281B2 (en) | 2011-03-29 | 2014-12-23 | Enervault Corporation | Rebalancing electrolytes in redox flow battery systems |
US8980484B2 (en) | 2011-03-29 | 2015-03-17 | Enervault Corporation | Monitoring electrolyte concentrations in redox flow battery systems |
WO2012162383A1 (en) | 2011-05-23 | 2012-11-29 | University Of Kentucky Research Foundation | Flow battery |
KR20140083027A (ko) * | 2011-10-14 | 2014-07-03 | 이머지 파워 시스템스 인코포레이티드 | 바나듐 플로우 셀 |
CN102881933B (zh) * | 2012-10-23 | 2014-12-24 | 山西金能世纪科技有限公司 | 全钒液流电池电解液 |
US8993183B2 (en) | 2012-12-31 | 2015-03-31 | Enervault Corporation | Operating a redox flow battery with a negative electrolyte imbalance |
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US9077011B2 (en) | 2015-07-07 |
JP6266344B2 (ja) | 2018-01-24 |
KR20130122626A (ko) | 2013-11-07 |
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CN105938912A (zh) | 2016-09-14 |
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JP2018032632A (ja) | 2018-03-01 |
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CA2812928C (en) | 2018-02-27 |
AU2011312833A1 (en) | 2013-03-07 |
AU2011312833B2 (en) | 2014-12-04 |
CA2812928A1 (en) | 2012-04-12 |
JP6581635B2 (ja) | 2019-09-25 |
CN103125041B (zh) | 2016-10-19 |
US8628880B2 (en) | 2014-01-14 |
EP2622675A1 (en) | 2013-08-07 |
CN103125041A (zh) | 2013-05-29 |
US9123931B2 (en) | 2015-09-01 |
US9819039B2 (en) | 2017-11-14 |
US20140199607A1 (en) | 2014-07-17 |
EP2622675A4 (en) | 2014-06-25 |
US20120077079A1 (en) | 2012-03-29 |
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