JP2013542308A5 - - Google Patents
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- JP2013542308A5 JP2013542308A5 JP2013538851A JP2013538851A JP2013542308A5 JP 2013542308 A5 JP2013542308 A5 JP 2013542308A5 JP 2013538851 A JP2013538851 A JP 2013538851A JP 2013538851 A JP2013538851 A JP 2013538851A JP 2013542308 A5 JP2013542308 A5 JP 2013542308A5
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- reactor
- aqueous medium
- dispersion
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 claims description 43
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- 239000004094 surface-active agent Substances 0.000 claims description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- 229920002313 fluoropolymer Polymers 0.000 claims description 26
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 22
- 239000004811 fluoropolymer Substances 0.000 claims description 22
- 239000012736 aqueous medium Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 14
- 230000006641 stabilisation Effects 0.000 claims description 9
- 238000011105 stabilization Methods 0.000 claims description 9
- 239000003505 polymerization initiator Substances 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 9
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 229920001973 fluoroelastomer Polymers 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- -1 perfluoro Chemical group 0.000 description 2
- 229920005548 perfluoropolymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229920002009 Pluronic® 31R1 Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41162210P | 2010-11-09 | 2010-11-09 | |
| US61/411,622 | 2010-11-09 | ||
| US201161498806P | 2011-06-20 | 2011-06-20 | |
| US61/498,806 | 2011-06-20 | ||
| PCT/US2011/059972 WO2012064841A1 (en) | 2010-11-09 | 2011-11-09 | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013542308A JP2013542308A (ja) | 2013-11-21 |
| JP2013542308A5 true JP2013542308A5 (https=) | 2014-12-25 |
| JP6109073B2 JP6109073B2 (ja) | 2017-04-05 |
Family
ID=45034187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013538851A Active JP6109073B2 (ja) | 2010-11-09 | 2011-11-09 | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
Country Status (5)
| Country | Link |
|---|---|
| US (4) | US9255164B2 (https=) |
| EP (2) | EP3539995B1 (https=) |
| JP (1) | JP6109073B2 (https=) |
| CN (2) | CN103201300B (https=) |
| WO (1) | WO2012064841A1 (https=) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103201300B (zh) | 2010-11-09 | 2016-11-09 | 纳幕尔杜邦公司 | 使用烃表面活性剂的含氟单体的含水聚合 |
| US9574027B2 (en) | 2013-03-11 | 2017-02-21 | The Chemours Company Fc, Llc | Fluoropolymer resin treatment employing sorbent to reduce fluoropolymer resin discoloration |
| JP6269671B2 (ja) * | 2013-07-18 | 2018-01-31 | 旭硝子株式会社 | 含フッ素重合体水性分散液の製造方法、含フッ素重合体水性分散液および含フッ素重合体 |
| US9676929B2 (en) * | 2013-11-26 | 2017-06-13 | The Chemours Company Fc, Llc | Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer |
| US20180201775A1 (en) * | 2015-07-09 | 2018-07-19 | Arkema Inc. | Compositions based on semi-crystalline fluorinated polymer and nucleating agent useful for preparing high gloss coatings |
| CN110461883B (zh) | 2017-03-31 | 2021-11-30 | 大金工业株式会社 | 含氟聚合物的制造方法、聚合用表面活性剂和表面活性剂的使用 |
| CN110446695A (zh) | 2017-03-31 | 2019-11-12 | 大金工业株式会社 | 烷基硫酸酯或其盐 |
| WO2019031617A1 (ja) | 2017-08-10 | 2019-02-14 | ダイキン工業株式会社 | 精製ポリテトラフルオロエチレン水性分散液の製造方法、改質ポリテトラフルオロエチレン粉末の製造方法、ポリテトラフルオロエチレン成形体の製造方法、及び、組成物 |
| SG11202000862YA (en) | 2017-08-10 | 2020-02-27 | Daikin Ind Ltd | Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition |
| CN111356738B (zh) | 2017-11-30 | 2022-07-26 | 惠普发展公司，有限责任合伙企业 | 用于三维打印的抗聚结剂 |
| JP7014976B2 (ja) | 2017-12-25 | 2022-02-15 | ダイキン工業株式会社 | ポリテトラフルオロエチレン粉末の製造方法 |
| US12583947B2 (en) | 2018-03-07 | 2026-03-24 | Daikin Industries, Ltd. | Method for producing fluoropolymer |
| WO2020022355A1 (ja) | 2018-07-23 | 2020-01-30 | ダイキン工業株式会社 | ポリテトラフルオロエチレン及び延伸体 |
| JP7277799B2 (ja) * | 2018-10-03 | 2023-05-19 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| CN112739728B (zh) | 2018-10-03 | 2023-03-10 | 大金工业株式会社 | 聚四氟乙烯的制造方法 |
| CN112771006A (zh) | 2018-10-03 | 2021-05-07 | 大金工业株式会社 | 从排水除去含氟化合物的方法 |
| CN113366034B (zh) | 2019-02-01 | 2022-11-11 | 大金工业株式会社 | 聚四氟乙烯的制造方法 |
| EP3922435A4 (en) | 2019-02-07 | 2022-11-02 | Daikin Industries, Ltd. | Composition, stretched body and method of manufacturing thereof |
| WO2020213691A1 (ja) * | 2019-04-16 | 2020-10-22 | ダイキン工業株式会社 | フルオロポリマー粉末の製造方法 |
| WO2020218618A1 (ja) | 2019-04-26 | 2020-10-29 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法 |
| JP7236004B2 (ja) | 2019-04-26 | 2023-03-09 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法及びフルオロポリマー水性分散液 |
| CN114096573A (zh) | 2019-07-16 | 2022-02-25 | 大金工业株式会社 | 含氟弹性体的制造方法和组合物 |
| EP4006063A4 (en) * | 2019-07-23 | 2023-10-25 | Daikin Industries, Ltd. | METHOD FOR PRODUCING A FLUROPOLYMER, POLYTETRAFLUORETHYLENE COMPOSITION AND POLYTETRAFLUORETHYLENE POWDER |
| EP4039716A4 (en) | 2019-10-03 | 2023-10-25 | Daikin Industries, Ltd. | Polytetrafluoroethylene and method for producing same |
| CA3151436A1 (en) * | 2019-10-11 | 2021-04-15 | Rajeev Chauhan | Process for preparing fluoropolymers and fluoroelastomers in presence of a non fluorinated sulfonate type hydrocarbon containing surfactant thereof |
| EP4063405A4 (en) * | 2019-11-19 | 2024-01-10 | Daikin Industries, Ltd. | PROCESS FOR PRODUCING POLYTETRAFLUOROETHYLENE |
| JP6989792B2 (ja) | 2019-12-25 | 2022-01-12 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| WO2021149022A1 (en) * | 2020-01-24 | 2021-07-29 | Gujarat Fluorochemicals Limited | Process for polymerizing fluoromonomers using a combination of fluorinated and non-fluorinated surfactant |
| KR20230009876A (ko) | 2020-05-14 | 2023-01-17 | 구자라트 플루오로케미칼스 리미티드 | 플루오르화 및 비-플루오르화 계면활성제의 조합을 사용한 플루오로단량체 중합 방법 |
| EP4186957A4 (en) * | 2020-07-21 | 2024-07-24 | Agc Inc. | Water- and oil-repelling agent composition, method for producing same, and article |
| WO2022072693A1 (en) | 2020-10-01 | 2022-04-07 | The Chemours Company Fc, Llc | Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers |
| WO2022196804A1 (ja) | 2021-03-18 | 2022-09-22 | ダイキン工業株式会社 | フッ素樹脂の製造方法、フッ素樹脂および水性分散液 |
| JP7360066B2 (ja) | 2021-03-31 | 2023-10-12 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| TW202530278A (zh) | 2021-03-31 | 2025-08-01 | 日商大金工業股份有限公司 | 氟樹脂組成物、及成形體 |
| CN117043262A (zh) | 2021-03-31 | 2023-11-10 | 大金工业株式会社 | 氟树脂组合物和成型体 |
| JP7323833B2 (ja) | 2021-03-31 | 2023-08-09 | ダイキン工業株式会社 | フッ素樹脂組成物の製造方法、フッ素樹脂組成物、及び、成形体 |
| WO2023059320A1 (en) * | 2021-10-06 | 2023-04-13 | Surface Technology, Inc. | Composite ptfe plating |
| WO2023191061A1 (ja) | 2022-03-31 | 2023-10-05 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| KR102932815B1 (ko) | 2023-01-18 | 2026-03-05 | 다이킨 고교 가부시키가이샤 | 전기 화학 디바이스용 합제 자립막, 전극, 및 전기 화학 디바이스 |
| WO2024154805A1 (ja) | 2023-01-18 | 2024-07-25 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、固体二次電池用バインダー、電解質層用合剤、電極合剤、電極、及び、固体二次電池 |
| JP7583340B2 (ja) | 2023-01-18 | 2024-11-14 | ダイキン工業株式会社 | 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス |
| JP7538458B2 (ja) | 2023-01-18 | 2024-08-22 | ダイキン工業株式会社 | ポリテトラフルオロエチレン組成物 |
| WO2024154803A1 (ja) | 2023-01-18 | 2024-07-25 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| CN121646623A (zh) | 2023-08-08 | 2026-03-10 | Ａｇｃ株式会社 | 含氟聚合物的制造方法、水性分散液、粒子和组合物 |
| JP7804869B2 (ja) * | 2023-08-08 | 2026-01-23 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液、粒子、及び組成物 |
| JP7741457B2 (ja) | 2024-01-18 | 2025-09-18 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| WO2025154806A1 (ja) | 2024-01-18 | 2025-07-24 | ダイキン工業株式会社 | 電気化学デバイス、組成物、電極合剤、電極、及び、二次電池 |
| EP4657572A1 (en) | 2024-01-18 | 2025-12-03 | Daikin Industries, Ltd. | Composition, electrochemical device binder, electrode mixture, electrode, and secondary battery |
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