JP2013542308A5 - - Google Patents
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- JP2013542308A5 JP2013542308A5 JP2013538851A JP2013538851A JP2013542308A5 JP 2013542308 A5 JP2013542308 A5 JP 2013542308A5 JP 2013538851 A JP2013538851 A JP 2013538851A JP 2013538851 A JP2013538851 A JP 2013538851A JP 2013542308 A5 JP2013542308 A5 JP 2013542308A5
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- reactor
- aqueous medium
- dispersion
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 claims description 43
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- 239000004094 surface-active agent Substances 0.000 claims description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- 229920002313 fluoropolymer Polymers 0.000 claims description 26
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 22
- 239000004811 fluoropolymer Substances 0.000 claims description 22
- 239000012736 aqueous medium Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 14
- 230000006641 stabilisation Effects 0.000 claims description 9
- 238000011105 stabilization Methods 0.000 claims description 9
- 239000003505 polymerization initiator Substances 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 9
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 229920001973 fluoroelastomer Polymers 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- -1 perfluoro Chemical group 0.000 description 2
- 229920005548 perfluoropolymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229920002009 Pluronic® 31R1 Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41162210P | 2010-11-09 | 2010-11-09 | |
| US61/411,622 | 2010-11-09 | ||
| US201161498806P | 2011-06-20 | 2011-06-20 | |
| US61/498,806 | 2011-06-20 | ||
| PCT/US2011/059972 WO2012064841A1 (en) | 2010-11-09 | 2011-11-09 | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013542308A JP2013542308A (ja) | 2013-11-21 |
| JP2013542308A5 true JP2013542308A5 (https=) | 2014-12-25 |
| JP6109073B2 JP6109073B2 (ja) | 2017-04-05 |
Family
ID=45034187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013538851A Active JP6109073B2 (ja) | 2010-11-09 | 2011-11-09 | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
Country Status (5)
| Country | Link |
|---|---|
| US (4) | US9255164B2 (https=) |
| EP (2) | EP2638081B1 (https=) |
| JP (1) | JP6109073B2 (https=) |
| CN (2) | CN103201300B (https=) |
| WO (1) | WO2012064841A1 (https=) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6109073B2 (ja) * | 2010-11-09 | 2017-04-05 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
| US9574027B2 (en) | 2013-03-11 | 2017-02-21 | The Chemours Company Fc, Llc | Fluoropolymer resin treatment employing sorbent to reduce fluoropolymer resin discoloration |
| JP6269671B2 (ja) * | 2013-07-18 | 2018-01-31 | 旭硝子株式会社 | 含フッ素重合体水性分散液の製造方法、含フッ素重合体水性分散液および含フッ素重合体 |
| JP6622209B2 (ja) * | 2013-11-26 | 2019-12-18 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用 |
| US20180201775A1 (en) * | 2015-07-09 | 2018-07-19 | Arkema Inc. | Compositions based on semi-crystalline fluorinated polymer and nucleating agent useful for preparing high gloss coatings |
| CN110446695A (zh) | 2017-03-31 | 2019-11-12 | 大金工业株式会社 | 烷基硫酸酯或其盐 |
| CN113667247A (zh) * | 2017-03-31 | 2021-11-19 | 大金工业株式会社 | 包含含氟聚合物的组合物及其成型体 |
| RU2766151C2 (ru) | 2017-08-10 | 2022-02-08 | Дайкин Индастриз, Лтд. | Способ производства водной жидкой дисперсии очищенного политетрафторэтилена, способ производства модифицированного порошкообразного политетрафторэтилена, способ производства формованного тела из политетрафторэтилена и композиция |
| CN110997735B (zh) | 2017-08-10 | 2024-03-01 | 大金工业株式会社 | 精制聚四氟乙烯水性分散液的制造方法、改性聚四氟乙烯粉末的制造方法、聚四氟乙烯成型体的制造方法以及组合物 |
| WO2019108200A1 (en) * | 2017-11-30 | 2019-06-06 | Hewlett-Packard Development Company, L.P. | Anti-coalescing agent for three-dimensional printing |
| WO2019131633A1 (ja) | 2017-12-25 | 2019-07-04 | ダイキン工業株式会社 | ポリテトラフルオロエチレン粉末の製造方法 |
| WO2019172382A1 (ja) | 2018-03-07 | 2019-09-12 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| EP3828208A4 (en) * | 2018-07-23 | 2022-07-13 | Daikin Industries, Ltd. | POLYTETRAFLUORETHYLENE AND STRETCHED BODY |
| CN112771006A (zh) | 2018-10-03 | 2021-05-07 | 大金工业株式会社 | 从排水除去含氟化合物的方法 |
| EP3862368A4 (en) | 2018-10-03 | 2022-06-29 | Daikin Industries, Ltd. | Polytetrafluoroethylene production method |
| JP7277799B2 (ja) * | 2018-10-03 | 2023-05-19 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| US20220119561A1 (en) * | 2019-02-01 | 2022-04-21 | Daikin Industries, Ltd. | Method for producing polytetrafluoroethylene |
| JP7104354B2 (ja) | 2019-02-07 | 2022-07-21 | ダイキン工業株式会社 | 組成物、延伸体及びその製造方法 |
| CN113661184A (zh) * | 2019-04-16 | 2021-11-16 | 大金工业株式会社 | 含氟聚合物粉末的制造方法 |
| JP7564452B2 (ja) | 2019-04-26 | 2024-10-09 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法 |
| JP7236004B2 (ja) | 2019-04-26 | 2023-03-09 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法及びフルオロポリマー水性分散液 |
| US20220267483A1 (en) | 2019-07-16 | 2022-08-25 | Daikin Industries, Ltd. | Method for producing fluorine-containing elastomer, and composition |
| CN118146427A (zh) | 2019-07-23 | 2024-06-07 | 大金工业株式会社 | 含氟聚合物的制造方法、聚四氟乙烯组合物和聚四氟乙烯粉末 |
| WO2021066189A1 (ja) | 2019-10-03 | 2021-04-08 | ダイキン工業株式会社 | ポリテトラフルオロエチレンおよびその製造方法 |
| MX2022004325A (es) * | 2019-10-11 | 2022-09-19 | Gujarat Fluorochemicals Ltd | Proceso para preparar fluoropolímeros y fluoroelastómeros en presencia de un hidrocarburo de tipo sulfonato no fluorado que contiene tensioactivo. |
| JP7417131B2 (ja) * | 2019-11-19 | 2024-01-18 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| JP6989792B2 (ja) | 2019-12-25 | 2022-01-12 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| WO2021149022A1 (en) * | 2020-01-24 | 2021-07-29 | Gujarat Fluorochemicals Limited | Process for polymerizing fluoromonomers using a combination of fluorinated and non-fluorinated surfactant |
| EP4126977A1 (en) | 2020-05-14 | 2023-02-08 | Gujarat Fluorochemicals Limited | Process for polymerizing fluoromonomers using a combination of fluorinated and non-fluorinated surfactant |
| EP4186957A4 (en) * | 2020-07-21 | 2024-07-24 | Agc Inc. | Water- and oil-repelling agent composition, method for producing same, and article |
| CN116234794A (zh) * | 2020-10-01 | 2023-06-06 | 科慕埃弗西有限公司 | 含氟聚合物的水性聚合反应中的低反应性烃分散剂 |
| CN117015557A (zh) | 2021-03-18 | 2023-11-07 | 大金工业株式会社 | 氟树脂的制造方法、氟树脂和水性分散液 |
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| WO2022211067A1 (ja) | 2021-03-31 | 2022-10-06 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| JP7323832B2 (ja) | 2021-03-31 | 2023-08-09 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| KR20230160917A (ko) | 2021-03-31 | 2023-11-24 | 다이킨 고교 가부시키가이샤 | 불소 수지 조성물의 제조 방법, 불소 수지 조성물 및 성형체 |
| US20230106833A1 (en) * | 2021-10-06 | 2023-04-06 | Surface Technology, Inc | Composite PTFE plating |
| JP7785034B2 (ja) | 2022-03-31 | 2025-12-12 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| JP7560797B2 (ja) | 2023-01-18 | 2024-10-03 | ダイキン工業株式会社 | 電気化学デバイス用合剤自立膜、電極、及び、電気化学デバイス |
| EP4481860A4 (en) | 2023-01-18 | 2025-07-23 | Daikin Ind Ltd | MIXTURE FOR ELECTROCHEMICAL DEVICE, MIXTURE SHEET FOR ELECTROCHEMICAL DEVICE, ELECTRODE, AND ELECTROCHEMICAL DEVICE |
| EP4525095A4 (en) | 2023-01-18 | 2026-04-08 | Daikin Ind Ltd | Tetrafluoroethylene polymer composition, binder for semiconductor secondary batteries, electrolyte layer mixture, electrode mixture, electrode and semiconductor secondary battery |
| CN120530158A (zh) | 2023-01-18 | 2025-08-22 | 大金工业株式会社 | 聚四氟乙烯组合物 |
| EP4471908A4 (en) | 2023-01-18 | 2025-10-01 | Daikin Ind Ltd | TETRAFLUOROETHYLENE-BASED POLYMER COMPOSITION, BINDER FOR ELECTROCHEMICAL DEVICE, MIXTURE FOR ELECTRODE, ELECTRODE, AND SECONDARY BATTERY |
| JP7804869B2 (ja) * | 2023-08-08 | 2026-01-23 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液、粒子、及び組成物 |
| JP7800762B2 (ja) * | 2023-08-08 | 2026-01-16 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液、粒子及び組成物 |
| JP7741457B2 (ja) | 2024-01-18 | 2025-09-18 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| JP7719418B1 (ja) | 2024-01-18 | 2025-08-06 | ダイキン工業株式会社 | 組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| EP4645423A1 (en) | 2024-01-18 | 2025-11-05 | Daikin Industries, Ltd. | Electrochemical device, composition, electrode mixture, electrode, and secondary battery |
Family Cites Families (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA878571A (en) | 1971-08-17 | H. Porter Verleon | Dispersion polymerization of tetrafluoroethylene | |
| US2559752A (en) | 1951-03-06 | 1951-07-10 | Du Pont | Aqueous colloidal dispersions of polymers |
| BE563881A (https=) | 1957-01-11 | |||
| US3000892A (en) | 1959-11-16 | 1961-09-19 | Paul A J Janssen | 1-aroylalkyl-4-aroylpiperazines |
| US3037953A (en) | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3271341A (en) | 1961-08-07 | 1966-09-06 | Du Pont | Aqueous colloidal dispersions of polymer |
| US3282875A (en) | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| US3391099A (en) | 1966-04-25 | 1968-07-02 | Du Pont | Polymerization process |
| DE2015279A1 (de) | 1969-04-01 | 1970-10-08 | E.I. du Pont de Nemours and'Company, Wilmington, Del. (V.St.A.) | Dispersionspolymerisation von Tetrafluoräthylen |
| DE2037028C2 (de) | 1970-07-25 | 1982-07-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung fluorhaltiger Copolymerisate |
| US4036802A (en) | 1975-09-24 | 1977-07-19 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer fine powder resin |
| US4098978A (en) | 1975-11-12 | 1978-07-04 | The B. F. Goodrich Company | Process for emulsion polymerization of vinylidene halides and product thereof |
| US4342675A (en) * | 1978-06-16 | 1982-08-03 | E. I. Du Pont De Nemours And Company | Process for preparing aqueous dispersion of polytetrafluoroethylene |
| US4358545A (en) | 1980-06-11 | 1982-11-09 | The Dow Chemical Company | Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000 |
| US4463144A (en) | 1980-09-10 | 1984-07-31 | Asahi Glass Company Ltd. | Process for producing propylene-tetrafluoroethylene copolymer |
| US4552631A (en) | 1983-03-10 | 1985-11-12 | E. I. Du Pont De Nemours And Company | Reinforced membrane, electrochemical cell and electrolysis process |
| US4469846A (en) * | 1983-05-20 | 1984-09-04 | E. I. Du Pont De Nemours And Company | Core/shell fluoropolymer compositions |
| US4940525A (en) | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| JP3172983B2 (ja) | 1993-09-20 | 2001-06-04 | ダイキン工業株式会社 | ビニリデンフルオライド系重合体の水性分散液およびその製法 |
| DE4335705A1 (de) | 1993-10-20 | 1995-04-27 | Hoechst Ag | Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung |
| IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
| US5637748A (en) | 1995-03-01 | 1997-06-10 | E. I. Du Pont De Nemours And Company | Process for synthesizing fluorinated nitrile compounds |
| US5955556A (en) * | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| US5969067A (en) | 1996-09-13 | 1999-10-19 | E.I. Dupont De Nemours And Company | Phosphorus-containing fluoromonomers and polymers thereof |
| US5866711A (en) | 1996-09-13 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Fluorocyanate and fluorocarbamate monomers and polymers thereof |
| US6512063B2 (en) | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| EP1392744B1 (en) | 2001-05-02 | 2008-07-09 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| US6833414B2 (en) * | 2002-02-12 | 2004-12-21 | Arkema Inc. | Cross-linkable aqueous fluoropolymer based dispersions containing silanes |
| US6824872B2 (en) * | 2002-04-23 | 2004-11-30 | Laurel Products Llc | Surface-treating fluoropolymer powders using atmospheric plasma |
| WO2003106556A1 (ja) * | 2002-05-20 | 2003-12-24 | ダイキン工業株式会社 | 含フッ素樹脂水性分散体組成物及び含フッ素水性塗料組成物 |
| JP2006504844A (ja) | 2002-10-31 | 2006-02-09 | スリーエム イノベイティブ プロパティズ カンパニー | フッ化オレフィンと炭化水素オレフィンとのコポリマーを製造するための、乳化剤非含有水性乳化重合 |
| JP4433145B2 (ja) * | 2003-02-12 | 2010-03-17 | 日東電工株式会社 | 光学部材用粘着剤組成物、光学部材用粘着剤層、粘着型光学部材および画像表示装置 |
| US6841616B2 (en) | 2003-03-28 | 2005-01-11 | Arkema Inc. | Polymerization of halogen-containing monomers using siloxane surfactant |
| US6869997B2 (en) | 2003-05-06 | 2005-03-22 | Arkema, Inc. | Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant |
| JP2004359870A (ja) | 2003-06-05 | 2004-12-24 | Daikin Ind Ltd | 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液 |
| US7589234B2 (en) | 2003-07-02 | 2009-09-15 | Daikin Industries, Ltd. | Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer |
| WO2005007745A1 (ja) * | 2003-07-18 | 2005-01-27 | Kaneka Corporation | 硬化性組成物 |
| US20050090613A1 (en) | 2003-10-22 | 2005-04-28 | Daikin Industries, Ltd. | Process for preparing fluorine-containing polymer latex |
| ATE529451T1 (de) * | 2003-11-17 | 2011-11-15 | 3M Innovative Properties Co | Wässrige ptfe-dispersionen mit einem niedrigen gehalt an fluorierten emulgatoren |
| JP4100431B2 (ja) | 2003-12-25 | 2008-06-11 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| US7122610B2 (en) | 2004-04-27 | 2006-10-17 | Arkema Inc. | Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants |
| JP2006111722A (ja) * | 2004-10-14 | 2006-04-27 | Daikin Ind Ltd | 含フッ素重合体の製造方法 |
| US20060178472A1 (en) * | 2005-02-10 | 2006-08-10 | Johnson David W | Process for producing low fluorosurfactant-containing aqueous fluoropolymer dispersions with controlled pH |
| US8338518B2 (en) | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| US8080621B2 (en) | 2005-06-10 | 2011-12-20 | Arkema Inc. | Aqueous process for making fluoropolymers |
| US20060281845A1 (en) | 2005-06-10 | 2006-12-14 | Ramin Amin-Sanayei | Aqueous process for making fluoropolymers |
| US7671112B2 (en) | 2005-07-15 | 2010-03-02 | 3M Innovative Properties Company | Method of making fluoropolymer dispersion |
| GB0514398D0 (en) | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant |
| GB0514387D0 (en) | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant |
| ES2611988T3 (es) | 2005-08-08 | 2017-05-11 | Arkema Inc. | Polimerización de fluoropolímeros usando tensioactivos no fluorados |
| US8124699B2 (en) | 2005-08-08 | 2012-02-28 | Arkema Inc. | Polymerization of fluoropolymers using alkyl phosphonate surfactants |
| CN100558753C (zh) | 2005-10-17 | 2009-11-11 | 旭硝子株式会社 | 聚四氟乙烯水性乳化液、由其制得的聚四氟乙烯细粉和多孔体 |
| WO2007046377A1 (ja) | 2005-10-20 | 2007-04-26 | Asahi Glass Company, Limited | 溶融成形可能なフッ素樹脂の製造方法 |
| JP5141256B2 (ja) | 2005-10-20 | 2013-02-13 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液およびその製品 |
| EP1942118B1 (en) | 2005-10-26 | 2013-09-11 | Asahi Glass Company, Limited | Fluororesin with low fluorine-containing emulsifier residual and method for producing same |
| EP1948706B1 (en) | 2005-11-18 | 2012-09-19 | E.I. Du Pont De Nemours And Company | Core/shell polymer |
| US7728087B2 (en) * | 2005-12-23 | 2010-06-01 | 3M Innovative Properties Company | Fluoropolymer dispersion and method for making the same |
| US20070282044A1 (en) | 2006-05-31 | 2007-12-06 | Robert John Cavanaugh | Concentrated fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents |
| WO2008019155A1 (en) | 2006-08-11 | 2008-02-14 | The University Of North Carolina At Chapel Hill | Process of fluoromonomer polymerization |
| WO2008060462A1 (en) | 2006-11-09 | 2008-05-22 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and siloxane surfactant |
| JP5439186B2 (ja) * | 2006-11-09 | 2014-03-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合 |
| EP2079766B1 (en) | 2006-11-09 | 2011-05-18 | E.I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomer using polymerization agent comprising high molecular weight fluoropolyether acid or salt and fluoropolyether acid or salt surfactant |
| US7521513B2 (en) * | 2006-11-29 | 2009-04-21 | Dupont Performance Elastomers Llc | Semi-batch process for producing fluoroelastomers |
| US20080262177A1 (en) | 2006-12-19 | 2008-10-23 | Lyons Donald F | Process for producing fluoroelastomers |
| US20080146757A1 (en) | 2006-12-19 | 2008-06-19 | Lyons Donald F | Process for producing fluoroelastomers |
| US7694203B2 (en) * | 2007-07-03 | 2010-04-06 | Sun Microsystems, Inc. | On-chip samplers for asynchronously triggered events |
| WO2009013214A1 (en) * | 2007-07-20 | 2009-01-29 | Solvay Solexis S.P.A. | Process for polymer dispersions |
| EP2274345B1 (en) | 2008-04-07 | 2017-01-04 | Arkema Inc. | Polymerization of fluoropolymers using polycaprolactone |
| US9192915B2 (en) * | 2008-05-10 | 2015-11-24 | Brigham Young University | Porous composite particulate materials, methods of making and using same, and related apparatuses |
| US8153738B2 (en) | 2008-12-23 | 2012-04-10 | E I Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| WO2011024856A1 (ja) | 2009-08-28 | 2011-03-03 | ダイキン工業株式会社 | 含フッ素重合体の製造方法 |
| WO2011024857A1 (ja) | 2009-08-28 | 2011-03-03 | ダイキン工業株式会社 | 含フッ素重合体の製造方法 |
| CN101787091B (zh) * | 2010-01-18 | 2011-08-24 | 上海三爱富新材料股份有限公司 | 一种含氟聚合物水性分散乳液及其制备方法 |
| EP3533811B1 (en) | 2010-11-09 | 2021-08-11 | The Chemours Company FC, LLC | Nucleation in aqueous polymerization of fluoromonomer |
| JP6109073B2 (ja) | 2010-11-09 | 2017-04-05 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
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- 2011-11-09 WO PCT/US2011/059972 patent/WO2012064841A1/en not_active Ceased
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