JP2013511465A - 炭素‐炭素複合材料におけるｃｎｔ浸出繊維 - Google Patents
炭素‐炭素複合材料におけるｃｎｔ浸出繊維 Download PDFInfo
- Publication number
- JP2013511465A JP2013511465A JP2012540115A JP2012540115A JP2013511465A JP 2013511465 A JP2013511465 A JP 2013511465A JP 2012540115 A JP2012540115 A JP 2012540115A JP 2012540115 A JP2012540115 A JP 2012540115A JP 2013511465 A JP2013511465 A JP 2013511465A
- Authority
- JP
- Japan
- Prior art keywords
- carbon
- cnt
- carbon fiber
- cnts
- fiber material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title description 189
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical class [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 title description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 762
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 478
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 462
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 456
- 239000004917 carbon fiber Substances 0.000 claims abstract description 454
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 407
- 239000000463 material Substances 0.000 claims abstract description 356
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 288
- 239000002131 composite material Substances 0.000 claims abstract description 189
- 238000000576 coating method Methods 0.000 claims abstract description 141
- 239000011248 coating agent Substances 0.000 claims abstract description 130
- 230000004888 barrier function Effects 0.000 claims abstract description 109
- 239000011159 matrix material Substances 0.000 claims abstract description 105
- 238000004519 manufacturing process Methods 0.000 claims abstract description 46
- 239000002243 precursor Substances 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000004804 winding Methods 0.000 claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims description 163
- 238000000034 method Methods 0.000 claims description 137
- 230000008569 process Effects 0.000 claims description 102
- 238000002386 leaching Methods 0.000 claims description 63
- 238000005229 chemical vapour deposition Methods 0.000 claims description 59
- 238000000280 densification Methods 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 19
- 239000011347 resin Substances 0.000 claims description 19
- 238000000197 pyrolysis Methods 0.000 claims description 16
- -1 nano-onions Substances 0.000 claims description 13
- 239000003607 modifier Substances 0.000 claims description 11
- 238000003763 carbonization Methods 0.000 claims description 7
- 239000005011 phenolic resin Substances 0.000 claims description 7
- 239000002717 carbon nanostructure Substances 0.000 claims description 6
- 239000011253 protective coating Substances 0.000 claims description 6
- 239000002759 woven fabric Substances 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 239000002019 doping agent Substances 0.000 claims description 5
- 150000004767 nitrides Chemical class 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 150000001247 metal acetylides Chemical class 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 4
- 238000004046 wet winding Methods 0.000 claims description 4
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 3
- 239000010432 diamond Substances 0.000 claims description 3
- 239000002121 nanofiber Substances 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims description 3
- 229910003460 diamond Inorganic materials 0.000 claims description 2
- 229910003472 fullerene Inorganic materials 0.000 claims description 2
- 229910021389 graphene Inorganic materials 0.000 claims description 2
- 229910052752 metalloid Inorganic materials 0.000 claims description 2
- 150000002738 metalloids Chemical class 0.000 claims description 2
- 239000002102 nanobead Substances 0.000 claims description 2
- 239000002159 nanocrystal Substances 0.000 claims description 2
- 239000002113 nanodiamond Substances 0.000 claims description 2
- 239000002060 nanoflake Substances 0.000 claims description 2
- 239000002106 nanomesh Substances 0.000 claims description 2
- 239000002078 nanoshell Substances 0.000 claims description 2
- 239000002070 nanowire Substances 0.000 claims description 2
- 229910021332 silicide Inorganic materials 0.000 claims description 2
- 238000005979 thermal decomposition reaction Methods 0.000 claims 2
- 239000002657 fibrous material Substances 0.000 abstract description 41
- 238000004513 sizing Methods 0.000 description 52
- 239000003795 chemical substances by application Substances 0.000 description 48
- 230000015572 biosynthetic process Effects 0.000 description 47
- 239000007789 gas Substances 0.000 description 42
- 210000002381 plasma Anatomy 0.000 description 42
- 238000003786 synthesis reaction Methods 0.000 description 42
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
- 238000007605 air drying Methods 0.000 description 28
- 239000000243 solution Substances 0.000 description 28
- 238000012545 processing Methods 0.000 description 27
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 238000010924 continuous production Methods 0.000 description 19
- 239000000047 product Substances 0.000 description 18
- 239000002904 solvent Substances 0.000 description 18
- 230000006870 function Effects 0.000 description 16
- 238000009832 plasma treatment Methods 0.000 description 16
- 229910052723 transition metal Inorganic materials 0.000 description 16
- 239000000758 substrate Substances 0.000 description 15
- 150000003624 transition metals Chemical class 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000002105 nanoparticle Substances 0.000 description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 230000009286 beneficial effect Effects 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000003618 dip coating Methods 0.000 description 12
- 239000011261 inert gas Substances 0.000 description 12
- 239000002048 multi walled nanotube Substances 0.000 description 11
- 230000008859 change Effects 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 9
- 239000011521 glass Substances 0.000 description 9
- 229910052734 helium Inorganic materials 0.000 description 9
- 239000001307 helium Substances 0.000 description 9
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000012783 reinforcing fiber Substances 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 8
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 8
- 229910002804 graphite Inorganic materials 0.000 description 8
- 239000010439 graphite Substances 0.000 description 8
- 238000002955 isolation Methods 0.000 description 8
- 229910010271 silicon carbide Inorganic materials 0.000 description 8
- 239000002109 single walled nanotube Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000003993 interaction Effects 0.000 description 7
- 239000002071 nanotube Substances 0.000 description 7
- 150000003839 salts Chemical group 0.000 description 7
- 238000001878 scanning electron micrograph Methods 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 229910021524 transition metal nanoparticle Inorganic materials 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- 238000007865 diluting Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000005684 electric field Effects 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 229920002239 polyacrylonitrile Polymers 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000004071 soot Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 238000009827 uniform distribution Methods 0.000 description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000011269 tar Substances 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 238000003917 TEM image Methods 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 229910052810 boron oxide Inorganic materials 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000011162 core material Substances 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000002079 double walled nanotube Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000007306 functionalization reaction Methods 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910001374 Invar Inorganic materials 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000009730 filament winding Methods 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 229910021344 molybdenum silicide Inorganic materials 0.000 description 2
- 229940031182 nanoparticles iron oxide Drugs 0.000 description 2
- 125000002524 organometallic group Chemical class 0.000 description 2
- 239000011295 pitch Substances 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- SBEQWOXEGHQIMW-UHFFFAOYSA-N silicon Chemical compound [Si].[Si] SBEQWOXEGHQIMW-UHFFFAOYSA-N 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229910021341 titanium silicide Inorganic materials 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 230000005483 Hooke's law Effects 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- JXOOCQBAIRXOGG-UHFFFAOYSA-N [B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[Al] Chemical compound [B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[Al] JXOOCQBAIRXOGG-UHFFFAOYSA-N 0.000 description 1
- TWRSDLOICOIGRH-UHFFFAOYSA-N [Si].[Si].[Hf] Chemical compound [Si].[Si].[Hf] TWRSDLOICOIGRH-UHFFFAOYSA-N 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 description 1
- 230000002457 bidirectional effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910021387 carbon allotrope Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000005490 dry winding Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000011554 ferrofluid Substances 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 239000002783 friction material Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- WHJFNYXPKGDKBB-UHFFFAOYSA-N hafnium;methane Chemical compound C.[Hf] WHJFNYXPKGDKBB-UHFFFAOYSA-N 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical compound N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 description 1
- 229920006391 phthalonitrile polymer Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 description 1
- 229910021342 tungsten silicide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 238000013316 zoning Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/83—Carbon fibres in a carbon matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/178—Opening; Filling
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62844—Coating fibres
- C04B35/62847—Coating fibres with oxide ceramics
- C04B35/62849—Silica or silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62886—Coating the powders or the macroscopic reinforcing agents by wet chemical techniques
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/145—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/24—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/10—Filled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/421—Boron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5252—Fibers having a specific pre-form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/526—Fibers characterised by the length of the fibers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5264—Fibers characterised by the diameter of the fibers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5284—Hollow fibers, e.g. nanotubes
- C04B2235/5288—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/614—Gas infiltration of green bodies or pre-forms
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2008—Fabric composed of a fiber or strand which is of specific structural definition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
- Y10T442/2984—Coated or impregnated carbon or carbonaceous fiber fabric
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Textile Engineering (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Ceramic Products (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26380509P | 2009-11-23 | 2009-11-23 | |
| US61/263,805 | 2009-11-23 | ||
| US12/945,768 | 2010-11-12 | ||
| US12/945,768 US20110124253A1 (en) | 2009-11-23 | 2010-11-12 | Cnt-infused fibers in carbon-carbon composites |
| PCT/US2010/057520 WO2011063298A1 (en) | 2009-11-23 | 2010-11-19 | Cnt-infused fibers in carbon-carbon composites |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013511465A true JP2013511465A (ja) | 2013-04-04 |
| JP2013511465A5 JP2013511465A5 (enExample) | 2013-12-19 |
Family
ID=44060049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012540115A Pending JP2013511465A (ja) | 2009-11-23 | 2010-11-19 | 炭素‐炭素複合材料におけるｃｎｔ浸出繊維 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20110124253A1 (enExample) |
| EP (1) | EP2478749A4 (enExample) |
| JP (1) | JP2013511465A (enExample) |
| KR (1) | KR20120101639A (enExample) |
| CN (1) | CN102598875A (enExample) |
| AU (1) | AU2010321762A1 (enExample) |
| BR (1) | BR112012007628A2 (enExample) |
| CA (1) | CA2774403A1 (enExample) |
| WO (1) | WO2011063298A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014530964A (ja) * | 2011-09-07 | 2014-11-20 | テイジン・アラミド・ビー．ブイ． | 低抵抗率、高弾性率、および／または高熱伝導率を有するカーボンナノチューブ繊維、ならびに、繊維紡糸ドープを用いた紡糸による当該繊維の製造方法 |
| JP2016084547A (ja) * | 2014-10-23 | 2016-05-19 | ニッタ株式会社 | 複合素材および強化繊維 |
| JP2018086808A (ja) * | 2016-11-29 | 2018-06-07 | 日産自動車株式会社 | 炭素繊維強化プラスチック構造体の製造方法及び製造装置 |
| JPWO2018225271A1 (ja) * | 2017-06-09 | 2019-12-26 | 日産自動車株式会社 | 複合材料の成形方法 |
Families Citing this family (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
| CN102461361A (zh) | 2009-04-24 | 2012-05-16 | 应用纳米结构方案公司 | 并入cnt的emi屏蔽复合材料和涂层 |
| US8664573B2 (en) | 2009-04-27 | 2014-03-04 | Applied Nanostructured Solutions, Llc | CNT-based resistive heating for deicing composite structures |
| US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| US8665581B2 (en) | 2010-03-02 | 2014-03-04 | Applied Nanostructured Solutions, Llc | Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof |
| EP2543052B1 (en) | 2010-03-02 | 2019-11-27 | Applied NanoStructured Solutions, LLC | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US9475709B2 (en) | 2010-08-25 | 2016-10-25 | Lockheed Martin Corporation | Perforated graphene deionization or desalination |
| US9017854B2 (en) | 2010-08-30 | 2015-04-28 | Applied Nanostructured Solutions, Llc | Structural energy storage assemblies and methods for production thereof |
| CA2782976A1 (en) | 2010-09-23 | 2012-03-29 | Applied Nanostructured Solutions, Llc | Cnt-infused fiber as a self shielding wire for enhanced power transmission line |
| US9127732B2 (en) * | 2011-05-27 | 2015-09-08 | Honeywell International Inc. | Rigidization of porous preform prior to densification |
| US20130022658A1 (en) * | 2011-07-23 | 2013-01-24 | Synos Technology, Inc. | Depositing material with antimicrobial properties on permeable substrate using atomic layer deposition |
| US9893363B2 (en) | 2011-10-17 | 2018-02-13 | Lockheed Martin Corporation | High surface area flow battery electrodes |
| US8822057B2 (en) | 2011-10-17 | 2014-09-02 | Lockheed Martin Corporation | High surface area flow battery electrodes |
| RU2475463C1 (ru) * | 2011-11-23 | 2013-02-20 | Закрытое акционерное общество "ГрАВИОНИКС-К" (ЗАО "ГрАВИОНИКС-К") | Способ модифицирования поверхности неорганического волокна, модифицированное волокно и композиционный материал |
| KR101349161B1 (ko) * | 2012-02-07 | 2014-01-10 | 현대자동차주식회사 | 금속-탄소나노튜브 코팅 유리섬유와 그라파이트를 함유한 고분자 나노복합재 및 그 제조 방법 |
| US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
| US10017852B2 (en) | 2016-04-14 | 2018-07-10 | Lockheed Martin Corporation | Method for treating graphene sheets for large-scale transfer using free-float method |
| US10980919B2 (en) | 2016-04-14 | 2021-04-20 | Lockheed Martin Corporation | Methods for in vivo and in vitro use of graphene and other two-dimensional materials |
| US9834809B2 (en) | 2014-02-28 | 2017-12-05 | Lockheed Martin Corporation | Syringe for obtaining nano-sized materials for selective assays and related methods of use |
| US9744617B2 (en) | 2014-01-31 | 2017-08-29 | Lockheed Martin Corporation | Methods for perforating multi-layer graphene through ion bombardment |
| US10653824B2 (en) | 2012-05-25 | 2020-05-19 | Lockheed Martin Corporation | Two-dimensional materials and uses thereof |
| US10376845B2 (en) | 2016-04-14 | 2019-08-13 | Lockheed Martin Corporation | Membranes with tunable selectivity |
| CN103663414A (zh) * | 2012-09-03 | 2014-03-26 | 国家纳米科学中心 | 一种石墨烯海绵的制备方法 |
| WO2014039509A2 (en) | 2012-09-04 | 2014-03-13 | Ocv Intellectual Capital, Llc | Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media |
| US20140093728A1 (en) * | 2012-09-28 | 2014-04-03 | Applied Nanostructured Solutions, Llc | Carbon nanostructures and methods of making the same |
| TWI509119B (zh) | 2012-12-03 | 2015-11-21 | Ind Tech Res Inst | 碳纖維複合材料及其製法 |
| US9107292B2 (en) * | 2012-12-04 | 2015-08-11 | Applied Nanostructured Solutions, Llc | Carbon nanostructure-coated fibers of low areal weight and methods for producing the same |
| RU2523483C1 (ru) * | 2012-12-21 | 2014-07-20 | Федеральное государственное бюджетное научное учреждение "Технологический институт сверхтвердых и новых углеродных материалов" (ФГБНУ ТИСНУМ) | Способ упрочнения углеродного волокна |
| US9592475B2 (en) | 2013-03-12 | 2017-03-14 | Lockheed Martin Corporation | Method for forming perforated graphene with uniform aperture size |
| CN105121339B (zh) * | 2013-04-24 | 2018-11-09 | 霓达株式会社 | 复合材料及成形品 |
| CN103321093B (zh) * | 2013-05-31 | 2015-07-29 | 陕西科技大学 | 一种硼化锆改性纸基摩擦材料的制备方法 |
| US20140356613A1 (en) * | 2013-05-31 | 2014-12-04 | Materials Sciences Corporation | Carbon nanotube studded carbon fiber tow and matrix prepreg |
| US9572918B2 (en) | 2013-06-21 | 2017-02-21 | Lockheed Martin Corporation | Graphene-based filter for isolating a substance from blood |
| US9550701B2 (en) | 2013-07-25 | 2017-01-24 | Honeywell International Inc. | Carbon-carbon composites including isotropic carbon encapsulating layer and methods of forming the same |
| CN104418604A (zh) * | 2013-08-21 | 2015-03-18 | 甘肃郝氏炭纤维有限公司 | 一种管类碳/碳复合材料快速制备方法 |
| US20150075667A1 (en) | 2013-09-19 | 2015-03-19 | Lockheed Martin Corporation | Carbon macrotubes and methods for making the same |
| CN103601535B (zh) * | 2013-11-05 | 2015-04-22 | 陕西科技大学 | 碳/碳复合材料SiC–CrB复合外涂层的制备方法 |
| KR20160142820A (ko) | 2014-01-31 | 2016-12-13 | 록히드 마틴 코포레이션 | 브로드 이온 필드를 사용한 2차원 물질 천공 |
| AU2015210875A1 (en) | 2014-01-31 | 2016-09-15 | Lockheed Martin Corporation | Processes for forming composite structures with a two-dimensional material using a porous, non-sacrificial supporting layer |
| CN106232205A (zh) | 2014-03-12 | 2016-12-14 | 洛克希德马丁公司 | 由有孔石墨烯形成的分离膜 |
| CN104129779A (zh) * | 2014-06-27 | 2014-11-05 | 桂林浩新科技服务有限公司 | 一种制备含石墨烯的纳米纸的方法 |
| GB201412656D0 (en) * | 2014-07-16 | 2014-08-27 | Imp Innovations Ltd | Process |
| WO2016019143A1 (en) | 2014-07-30 | 2016-02-04 | General Nano Llc | Carbon nanotube sheet structure and method for its making |
| WO2017136806A1 (en) | 2016-02-04 | 2017-08-10 | General Nano Llc | Carbon nanotube sheet structure and method for its making |
| CN107073408A (zh) | 2014-09-02 | 2017-08-18 | 洛克希德马丁公司 | 基于二维膜材料的血液透析膜和血液过滤膜及其应用方法 |
| US10047614B2 (en) | 2014-10-09 | 2018-08-14 | Rolls-Royce Corporation | Coating system including alternating layers of amorphous silica and amorphous silicon nitride |
| US10280770B2 (en) | 2014-10-09 | 2019-05-07 | Rolls-Royce Corporation | Coating system including oxide nanoparticles in oxide matrix |
| GB201421827D0 (en) * | 2014-12-09 | 2015-01-21 | Short Brothers Plc | Fibre-reinforced components including nanostructures |
| JP6701093B2 (ja) * | 2014-12-26 | 2020-05-27 | 昭和電工株式会社 | レドックスフロー電池用電極およびレドックスフロー電池 |
| US10703680B2 (en) * | 2015-05-25 | 2020-07-07 | Apple Inc. | Fiber-reinforced ceramic matrix composite for electronic devices |
| WO2016205788A1 (en) * | 2015-06-18 | 2016-12-22 | General Nano Llc | Lightweight electromagnetic shielding structure |
| US9725803B2 (en) | 2015-07-02 | 2017-08-08 | Goodrich Corporation | Method of forming borides in carbon composites |
| CA2994549A1 (en) | 2015-08-05 | 2017-02-09 | Lockheed Martin Corporation | Perforatable sheets of graphene-based material |
| CA2994664A1 (en) | 2015-08-06 | 2017-02-09 | Lockheed Martin Corporation | Nanoparticle modification and perforation of graphene |
| RU2612247C1 (ru) * | 2015-11-12 | 2017-03-03 | Федеральное государственное бюджетное учреждение науки Институт металлоорганической химии им. Г.А. Разуваева Российской академии наук (ИМХ РАН) | Способ получения гибридного материала на основе многостенных углеродных нанотрубок с покрытием карбида титана |
| US10758936B2 (en) | 2015-12-08 | 2020-09-01 | The Boeing Company | Carbon nanomaterial composite sheet and method for making the same |
| US9970497B2 (en) * | 2015-12-18 | 2018-05-15 | Goodrich Corporation | Systems and methods for carbon-carbon materials incorporating yttrium and zirconium compounds |
| CN105439592B (zh) * | 2016-01-11 | 2017-09-01 | 山东理工大学 | 合脂分散硼化钨碳化硅‑碳纤维摩擦材料的制备方法 |
| CN105693262B (zh) * | 2016-01-14 | 2018-10-09 | 西北工业大学 | 石墨烯/碳纳米管界面的纤维增强陶瓷基复合材料及制备方法 |
| JP2019519756A (ja) | 2016-04-14 | 2019-07-11 | ロッキード・マーチン・コーポレーション | 欠陥形成または欠陥修復をその場で監視して制御する方法 |
| EP3442697A4 (en) | 2016-04-14 | 2020-03-18 | Lockheed Martin Corporation | SELECTIVE INTERFACE REDUCTION OF GRAPH DEFECTS |
| KR20190018410A (ko) | 2016-04-14 | 2019-02-22 | 록히드 마틴 코포레이션 | 흐름 통로들을 갖는 2차원 막 구조들 |
| US10813257B2 (en) * | 2016-09-05 | 2020-10-20 | Nec Corporation | Electromagnetic wave absorbing material |
| CN108530098B (zh) * | 2017-03-06 | 2022-04-08 | 海南大学 | 一种块体碳增强体/碳复合材料及其制备方法 |
| CN109676951B (zh) | 2017-10-18 | 2021-03-09 | 财团法人工业技术研究院 | 纤维复合材料及其制法 |
| US10272651B1 (en) | 2017-10-18 | 2019-04-30 | Industrial Technology Research Institute | Fiber composite and manufacturing method thereof |
| CA3017081C (en) * | 2017-11-16 | 2022-09-06 | The Boeing Company | Carbon nanomaterial composite sheet and method for making the same |
| US10934219B2 (en) * | 2017-12-20 | 2021-03-02 | Raytheon Technologies Corporation | Method of increasing the uniformity of chemical vapor deposition on fibrous material through the imposition of pressure waves |
| US11053168B2 (en) * | 2018-03-20 | 2021-07-06 | Goodrich Corporation | Systems and methods for carbon structures incorporating silicon carbide |
| US20200113020A1 (en) * | 2018-10-05 | 2020-04-09 | Serendipity Technologies Llc | Low power high-efficiency heating element |
| CN109206146B (zh) * | 2018-11-28 | 2021-12-31 | 西安工程大学 | 碳纤维/纳米纤维协同强韧陶瓷基复合材料及其制备方法 |
| CN109811327B (zh) * | 2019-01-22 | 2021-03-16 | 陕西科技大学 | 一种纳米界面层/碳纳米管-c/c复合材料及其制备方法 |
| CN109650381B (zh) * | 2019-02-15 | 2022-04-05 | 湖南医家智烯新材料科技有限公司 | 一种海胆状石墨烯及其制备方法 |
| CN111805935B (zh) | 2019-04-11 | 2022-01-07 | 财团法人工业技术研究院 | 纤维复合结构 |
| CN110304932B (zh) * | 2019-08-11 | 2021-11-02 | 西南石油大学 | 一种具有HfB2界面的Cf/SiC复合材料的制备方法 |
| CN110862267A (zh) * | 2019-12-03 | 2020-03-06 | 广西汇元锰业有限责任公司 | 一种石墨烯掺杂c/c复合材料及其制备方法 |
| JP7319205B2 (ja) * | 2020-01-29 | 2023-08-01 | 日本碍子株式会社 | 緻密質複合材料、その製法、接合体及び半導体製造装置用部材 |
| CN111499338B (zh) * | 2020-04-27 | 2021-11-26 | 江苏优格曼航空科技有限公司 | 一种高比强度通风机用复合材料叶片的制备方法 |
| US12346020B2 (en) * | 2021-02-12 | 2025-07-01 | Taiwan Semiconductor Manufacturing Co., Ltd. | Optical assembly with coating and methods of use |
| CN113480321B (zh) * | 2021-05-07 | 2022-09-13 | 西北工业大学 | 一种核壳结构碳纳米管增强碳/碳复合材料及制备方法 |
| CN113463246B (zh) * | 2021-06-15 | 2022-11-29 | 上海大学绍兴研究院 | 一种碳纤维预制体及其制备方法和碳纤维预制体的致密化方法 |
| CN113636854A (zh) * | 2021-08-30 | 2021-11-12 | 江西信达航科新材料科技有限公司 | 一种沉积碳纳米管的碳碳复合材料 |
| EP4180405A1 (en) * | 2021-11-15 | 2023-05-17 | Arkema France | High temperature composites and methods for preparing high temperature composites |
| WO2023084306A1 (en) * | 2021-11-15 | 2023-05-19 | Arkema France | High temperature composites and methods for preparing high temperature composites |
| CN115611660B (zh) * | 2022-10-12 | 2023-05-30 | 南京工程学院 | 一种c/c复合材料表面抗1600℃风洞燃气冲刷涂层及其制备方法和应用 |
| CN118580092A (zh) * | 2024-06-28 | 2024-09-03 | 西北工业大学 | 一种碳纤维/碳纳米管纤维复合碳基材料及其制备方法和应用 |
| CN118791320B (zh) * | 2024-09-13 | 2024-12-27 | 富优特(山东)新材料科技有限公司 | 铁离子掺杂改性提高碳碳复合材料力学性能的方法 |
| CN118834083B (zh) * | 2024-09-23 | 2024-12-27 | 富优特(山东)新材料科技有限公司 | 一种硼掺杂提升碳碳复合材料耐磨性的方法 |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS627668A (ja) * | 1985-07-03 | 1987-01-14 | 三菱化学株式会社 | 炭素繊維強化炭素複合材 |
| JPS63242537A (ja) * | 1987-02-25 | 1988-10-07 | アエロスパシアル・ソシエテ・ナシオナル・アンデユストリエル | マトリックス及び炭素の強化ファイバーを備えた複合材料とその製造方法 |
| JPH04149068A (ja) * | 1990-10-09 | 1992-05-22 | Tokai Carbon Co Ltd | 炭素繊維強化炭素複合材製二重中空円筒体 |
| JPH04300247A (ja) * | 1990-12-05 | 1992-10-23 | Toyo Tanso Kk | 耐酸化性炭素材 |
| JPH05306167A (ja) * | 1992-05-01 | 1993-11-19 | Nippon Steel Corp | 短繊維強化ｃ／ｃコンポジットの製造方法 |
| JPH07165927A (ja) * | 1991-03-06 | 1995-06-27 | Hercules Inc | 炭素―炭素複合体の内部酸化抑制のための無機酸化物 |
| JP2004002182A (ja) * | 2002-03-25 | 2004-01-08 | Mitsubishi Gas Chem Co Inc | 配向性カーボンナノチューブ膜およびその製造方法 |
| JP2005538026A (ja) * | 2002-09-12 | 2005-12-15 | スネクマ・プロピュルシオン・ソリド | 耐火繊維の３次元繊維構造体、これを調製する方法、および耐熱構造複合材料への適用 |
| JP2007119318A (ja) * | 2005-10-31 | 2007-05-17 | Shinshu Univ | カーボンナノチューブを含有する炭素繊維強化炭素複合材料 |
| JP2007523033A (ja) * | 2004-01-30 | 2007-08-16 | サーントル ナシオナル ドゥ ラ ルシェルシェ シャーンティフィク（セーエンヌエールエス） | 支持体に結合させたカーボンナノチューブ及びそれを含む複合体の製造方法 |
| JP2007314421A (ja) * | 1996-06-27 | 2007-12-06 | Toyo Tanso Kk | 単結晶引き上げ用ルツボ |
| WO2008085634A1 (en) * | 2007-01-03 | 2008-07-17 | Lockheed Martin Corporation | Cnt-infused fiber and method therefor |
| JP2009535530A (ja) * | 2006-05-02 | 2009-10-01 | ロール インコーポレイテッド | ナノ補強材を用いた複合材料中に用いられる補強繊維トウの修飾 |
| JP2011512315A (ja) * | 2008-02-20 | 2011-04-21 | コミサリア ア レネルジー アトミック エ オ ゼネルジー アルテルナティブ | 炭素基板または金属基板上でのカーボンナノチューブの成長 |
Family Cites Families (98)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3736162A (en) * | 1972-02-10 | 1973-05-29 | Ceskoslovenska Akademie Ved | Cements containing mineral fibers of high corrosion resistance |
| DE3507419A1 (de) * | 1985-03-02 | 1986-09-04 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von verbundstoffen aus metallen und elektrisch leitfaehigen polymeren |
| US4837073A (en) * | 1987-03-30 | 1989-06-06 | Allied-Signal Inc. | Barrier coating and penetrant providing oxidation protection for carbon-carbon materials |
| US5130194A (en) * | 1988-02-22 | 1992-07-14 | The Boeing Company | Coated ceramic fiber |
| US4894293A (en) * | 1988-03-10 | 1990-01-16 | Texas Instruments Incorporated | Circuit system, a composite metal material for use therein, and a method for making the material |
| US5227238A (en) * | 1988-11-10 | 1993-07-13 | Toho Rayon Co., Ltd. | Carbon fiber chopped strands and method of production thereof |
| DE68914120T2 (de) * | 1988-11-29 | 1994-09-01 | Tonen Corp | Verfahren zur Oberflächenbehandlung von Verstärkungsfasern mit Sulfonen und die so erhaltenen oberflächenbehandelten Fasern. |
| WO1991014294A1 (fr) * | 1990-03-16 | 1991-09-19 | Ricoh Co., Ltd. | Electrolyte solide, element electrochimique comprenant cette substance et procede de production |
| US5225265A (en) * | 1991-12-06 | 1993-07-06 | Basf Aktiengesellschaft | Environmentally durable lightning strike protection materials for composite structures |
| US20020085974A1 (en) * | 1992-01-15 | 2002-07-04 | Hyperion Catalysis International, Inc. | Surface treatment of carbon microfibers |
| US5744075A (en) * | 1995-05-19 | 1998-04-28 | Martin Marietta Energy Systems, Inc. | Method for rapid fabrication of fiber preforms and structural composite materials |
| US6683783B1 (en) * | 1997-03-07 | 2004-01-27 | William Marsh Rice University | Carbon fibers formed from single-wall carbon nanotubes |
| US20080063585A1 (en) * | 1997-03-07 | 2008-03-13 | William Marsh Rice University, A Texas University | Fullerene nanotube compositions |
| EP0933343B1 (en) * | 1998-01-29 | 2003-06-25 | Coi Ceramics, Inc. | Method for producing sized, coated ceramic fibers |
| JP3540602B2 (ja) * | 1998-05-13 | 2004-07-07 | 古河電気工業株式会社 | 低風圧電線 |
| US6346189B1 (en) * | 1998-08-14 | 2002-02-12 | The Board Of Trustees Of The Leland Stanford Junior University | Carbon nanotube structures made using catalyst islands |
| WO2000034964A1 (en) * | 1998-12-05 | 2000-06-15 | Energy Storage Systems Pty. Ltd. | A charge storage device |
| US6265466B1 (en) * | 1999-02-12 | 2001-07-24 | Eikos, Inc. | Electromagnetic shielding composite comprising nanotubes |
| US6221154B1 (en) * | 1999-02-18 | 2001-04-24 | City University Of Hong Kong | Method for growing beta-silicon carbide nanorods, and preparation of patterned field-emitters by chemical vapor depositon (CVD) |
| US7132161B2 (en) * | 1999-06-14 | 2006-11-07 | Energy Science Laboratories, Inc. | Fiber adhesive material |
| US6913075B1 (en) * | 1999-06-14 | 2005-07-05 | Energy Science Laboratories, Inc. | Dendritic fiber material |
| US20050181209A1 (en) * | 1999-08-20 | 2005-08-18 | Karandikar Prashant G. | Nanotube-containing composite bodies, and methods for making same |
| US6790425B1 (en) * | 1999-10-27 | 2004-09-14 | Wiliam Marsh Rice University | Macroscopic ordered assembly of carbon nanotubes |
| FR2805179B1 (fr) * | 2000-02-23 | 2002-09-27 | Centre Nat Rech Scient | Procede d'obtention de fibres et de rubans macroscopiques a partir de particules colloidales, et notamment de nanotubes de carbone |
| DE60107057T2 (de) * | 2000-03-07 | 2005-11-10 | Dsm Ip Assets B.V. | Wärmehärtende harzzusammensetzung einer radikalisch härtbaren harzmischung und kohlenstofffasern |
| JP4757369B2 (ja) * | 2000-05-08 | 2011-08-24 | パナソニック株式会社 | 角形アルカリ蓄電池、並びにこれを用いた単位電池及び組電池 |
| NO321272B1 (no) * | 2000-05-31 | 2006-04-10 | Aker Kvaerner Subsea As | Strekklegeme |
| JP3981566B2 (ja) * | 2001-03-21 | 2007-09-26 | 守信 遠藤 | 膨張炭素繊維体の製造方法 |
| US6986853B2 (en) * | 2001-03-26 | 2006-01-17 | Eikos, Inc. | Carbon nanotube fiber-reinforced composite structures for EM and lightning strike protection |
| CA2442310A1 (en) * | 2001-03-26 | 2002-10-03 | Eikos, Inc. | Coatings containing carbon nanotubes |
| US6382120B1 (en) * | 2001-05-02 | 2002-05-07 | Fred Aivars Keire | Seamed sail and method of manufacture |
| US7033485B2 (en) * | 2001-05-11 | 2006-04-25 | Koppers Industries Of Delaware, Inc. | Coal tar and hydrocarbon mixture pitch production using a high efficiency evaporative distillation process |
| JP4207398B2 (ja) * | 2001-05-21 | 2009-01-14 | 富士ゼロックス株式会社 | カーボンナノチューブ構造体の配線の製造方法、並びに、カーボンナノチューブ構造体の配線およびそれを用いたカーボンナノチューブデバイス |
| WO2002095097A1 (en) * | 2001-05-21 | 2002-11-28 | Trustees Of Boston College, The | Varied morphology carbon nanotubes and methods for their manufacture |
| US6762237B2 (en) * | 2001-06-08 | 2004-07-13 | Eikos, Inc. | Nanocomposite dielectrics |
| TW561102B (en) * | 2001-10-22 | 2003-11-11 | Hrl Lab Llc | Preparing composites by using resins |
| JP2005509533A (ja) * | 2001-11-19 | 2005-04-14 | ユニヴェルシテ ラヴァル | 放電加工用電極及び放電加工方法 |
| WO2003049219A1 (en) * | 2001-11-30 | 2003-06-12 | The Trustees Of Boston College | Coated carbon nanotube array electrodes |
| US6921462B2 (en) * | 2001-12-17 | 2005-07-26 | Intel Corporation | Method and apparatus for producing aligned carbon nanotube thermal interface structure |
| FR2836119B1 (fr) * | 2002-02-20 | 2004-05-28 | Jean Marie Finot | Perfectionnements apportes aux mats en carbone |
| US6934600B2 (en) * | 2002-03-14 | 2005-08-23 | Auburn University | Nanotube fiber reinforced composite materials and method of producing fiber reinforced composites |
| JP3962376B2 (ja) * | 2002-03-14 | 2007-08-22 | カーボン ナノテクノロジーズ インコーポレーテッド | 極性重合体及び単層壁炭素ナノチューブを含有する複合体材料 |
| US7405854B2 (en) * | 2002-03-21 | 2008-07-29 | Cornell Research Foundation, Inc. | Fibrous micro-composite material |
| US7378075B2 (en) * | 2002-03-25 | 2008-05-27 | Mitsubishi Gas Chemical Company, Inc. | Aligned carbon nanotube films and a process for producing them |
| US6905667B1 (en) * | 2002-05-02 | 2005-06-14 | Zyvex Corporation | Polymer and method for using the polymer for noncovalently functionalizing nanotubes |
| US6852410B2 (en) * | 2002-07-01 | 2005-02-08 | Georgia Tech Research Corporation | Macroscopic fiber comprising single-wall carbon nanotubes and acrylonitrile-based polymer and process for making the same |
| US6979947B2 (en) * | 2002-07-09 | 2005-12-27 | Si Diamond Technology, Inc. | Nanotriode utilizing carbon nanotubes and fibers |
| JP4619130B2 (ja) * | 2002-11-27 | 2011-01-26 | ウィリアム・マーシュ・ライス・ユニバーシティ | 官能基化カーボンナノチューブポリマー複合体および放射線との相互作用 |
| US7372880B2 (en) * | 2002-12-20 | 2008-05-13 | Alnair Labs Corporation | Optical pulse lasers |
| US7074294B2 (en) * | 2003-04-17 | 2006-07-11 | Nanosys, Inc. | Structures, systems and methods for joining articles and materials and uses therefor |
| WO2004096512A2 (en) * | 2003-04-29 | 2004-11-11 | Sampson James K | Autoclave molding system for carbon composite materials |
| FR2854409B1 (fr) * | 2003-04-30 | 2005-06-17 | Centre Nat Rech Scient | Procede d'obtention de fibres a haute teneur en particules colloidales et fibres composites obtenues |
| CA2434447A1 (fr) * | 2003-06-27 | 2004-12-27 | Eduardo Ruiz | Fabrication des composites par un procede d'injection flexible au moyen d'un moule a double chambre ou a chambres multiples |
| US20050062024A1 (en) * | 2003-08-06 | 2005-03-24 | Bessette Michael D. | Electrically conductive pressure sensitive adhesives, method of manufacture, and use thereof |
| US6935679B2 (en) * | 2003-09-03 | 2005-08-30 | Mack Trucks, Inc. | Modular cab, sleeper and roof structural assembly for a truck-tractor vehicle |
| US20050119371A1 (en) * | 2003-10-15 | 2005-06-02 | Board Of Trustees Of Michigan State University | Bio-based epoxy, their nanocomposites and methods for making those |
| US7354877B2 (en) * | 2003-10-29 | 2008-04-08 | Lockheed Martin Corporation | Carbon nanotube fabrics |
| US7628041B2 (en) * | 2004-02-27 | 2009-12-08 | Alcatel-Lucent Usa Inc. | Carbon particle fiber assembly technique |
| US7972743B2 (en) * | 2004-03-12 | 2011-07-05 | Nagaoka University Of Technology | Membrane electrode assembly, method for producing the same, and solid state polymer fuel cell |
| CN1296436C (zh) * | 2004-06-07 | 2007-01-24 | 清华大学 | 一种基于碳纳米管的复合材料的制备方法 |
| FR2877262B1 (fr) * | 2004-10-29 | 2007-04-27 | Centre Nat Rech Scient Cnrse | Fibres composites et fibres dissymetriques a partir de nanotubes de carbonne et de particules colloidales |
| CN105696139B (zh) * | 2004-11-09 | 2019-04-16 | 得克萨斯大学体系董事会 | 纳米纤维纱线、带和板的制造和应用 |
| US7729100B2 (en) * | 2004-11-11 | 2010-06-01 | Gamesa Innovation & Technology, S.L. | Lightning conductor system for wind generator blades comprising carbon fibre laminates |
| US7309830B2 (en) * | 2005-05-03 | 2007-12-18 | Toyota Motor Engineering & Manufacturing North America, Inc. | Nanostructured bulk thermoelectric material |
| US7387578B2 (en) * | 2004-12-17 | 2008-06-17 | Integran Technologies Inc. | Strong, lightweight article containing a fine-grained metallic layer |
| CN1796334A (zh) * | 2004-12-27 | 2006-07-05 | 陈瑾惠 | 碳/碳复合材料及其制造方法 |
| WO2007061428A2 (en) * | 2004-12-27 | 2007-05-31 | The Regents Of The University Of California | Components and devices formed using nanoscale materials and methods of production |
| US20080286546A1 (en) * | 2005-05-03 | 2008-11-20 | Nanocomp Technologies, Inc. | Continuous glassy carbon composite materials reinforced with carbon nanotubes and methods of manufacturing same |
| US8313723B2 (en) * | 2005-08-25 | 2012-11-20 | Nanocarbons Llc | Activated carbon fibers, methods of their preparation, and devices comprising activated carbon fibers |
| US8148276B2 (en) * | 2005-11-28 | 2012-04-03 | University Of Hawaii | Three-dimensionally reinforced multifunctional nanocomposites |
| FR2893939B1 (fr) * | 2005-11-29 | 2008-02-22 | Snecma Propulsion Solide Sa | Protection contre l'oxydation de materiaux composites contenant du carbone |
| KR101007621B1 (ko) * | 2005-11-30 | 2011-01-12 | 시마네켄 | 미크론 사이즈 및 나노 사이즈의 탄소섬유를 모두 함유하는금속기 복합재료 |
| US20090186214A1 (en) * | 2006-05-17 | 2009-07-23 | University Of Dayton | Method of growing carbon nanomaterials on various substrates |
| US8679630B2 (en) * | 2006-05-17 | 2014-03-25 | Purdue Research Foundation | Vertical carbon nanotube device in nanoporous templates |
| EP2385016B1 (en) * | 2006-05-19 | 2018-08-08 | Massachusetts Institute of Technology | Continuous process for the production of nanostructures |
| CN100591613C (zh) * | 2006-08-11 | 2010-02-24 | 清华大学 | 碳纳米管复合材料及其制造方法 |
| WO2008027530A1 (en) * | 2006-09-01 | 2008-03-06 | Seldon Technologies, Llc | Nanostructured materials comprising support fibers coated with metal containing compounds and methods of using the same |
| US7919151B2 (en) * | 2006-12-14 | 2011-04-05 | General Electric Company | Methods of preparing wetting-resistant surfaces and articles incorporating the same |
| US8951631B2 (en) * | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused metal fiber materials and process therefor |
| US9233850B2 (en) * | 2007-04-09 | 2016-01-12 | Nanotek Instruments, Inc. | Nano-scaled graphene plate films and articles |
| FR2918081B1 (fr) * | 2007-06-27 | 2009-09-18 | Cabinet Hecke Sa | Procede d'impregnation de fibres continues par une matrice polymerique composite renfermant un polymere thermoplastique |
| US7883050B2 (en) * | 2007-06-28 | 2011-02-08 | The Boeing Company | Composites with integrated multi-functional circuits |
| GB0712820D0 (en) * | 2007-07-03 | 2007-08-08 | Dunlop Aerospace Ltd | Carbon-carbon composite |
| US20090081383A1 (en) * | 2007-09-20 | 2009-03-26 | Lockheed Martin Corporation | Carbon Nanotube Infused Composites via Plasma Processing |
| US20090081441A1 (en) * | 2007-09-20 | 2009-03-26 | Lockheed Martin Corporation | Fiber Tow Comprising Carbon-Nanotube-Infused Fibers |
| JP5026209B2 (ja) * | 2007-09-27 | 2012-09-12 | 富士フイルム株式会社 | カーボンナノチューブ架橋体 |
| US20090126783A1 (en) * | 2007-11-15 | 2009-05-21 | Rensselaer Polytechnic Institute | Use of vertical aligned carbon nanotube as a super dark absorber for pv, tpv, radar and infrared absorber application |
| US9725314B2 (en) * | 2008-03-03 | 2017-08-08 | Performancy Polymer Solutions, Inc. | Continuous process for the production of carbon nanofiber reinforced continuous fiber preforms and composites made therefrom |
| US20110026494A1 (en) * | 2008-03-27 | 2011-02-03 | Kyocera Corporation | Wireless communication apparatus and communication apparatus |
| US20110159270A9 (en) * | 2008-06-02 | 2011-06-30 | Texas A & M University System | Carbon nanotube fiber-reinforced polymer composites having improved fatigue durability and methods for production thereof |
| US8574710B2 (en) * | 2008-10-10 | 2013-11-05 | Nano Terra Inc. | Anti-reflective coatings comprising ordered layers of nanowires and methods of making and using the same |
| US8664573B2 (en) * | 2009-04-27 | 2014-03-04 | Applied Nanostructured Solutions, Llc | CNT-based resistive heating for deicing composite structures |
| US8299159B2 (en) * | 2009-08-17 | 2012-10-30 | Laird Technologies, Inc. | Highly thermally-conductive moldable thermoplastic composites and compositions |
| US20110089958A1 (en) * | 2009-10-19 | 2011-04-21 | Applied Nanostructured Solutions, Llc | Damage-sensing composite structures |
| US20110123735A1 (en) * | 2009-11-23 | 2011-05-26 | Applied Nanostructured Solutions, Llc | Cnt-infused fibers in thermoset matrices |
| US9167736B2 (en) * | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| US8999453B2 (en) * | 2010-02-02 | 2015-04-07 | Applied Nanostructured Solutions, Llc | Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom |
| CA2782976A1 (en) * | 2010-09-23 | 2012-03-29 | Applied Nanostructured Solutions, Llc | Cnt-infused fiber as a self shielding wire for enhanced power transmission line |
-
2010
- 2010-11-12 US US12/945,768 patent/US20110124253A1/en not_active Abandoned
- 2010-11-19 EP EP10832300.7A patent/EP2478749A4/en not_active Withdrawn
- 2010-11-19 CA CA 2774403 patent/CA2774403A1/en not_active Abandoned
- 2010-11-19 JP JP2012540115A patent/JP2013511465A/ja active Pending
- 2010-11-19 WO PCT/US2010/057520 patent/WO2011063298A1/en not_active Ceased
- 2010-11-19 KR KR20127011099A patent/KR20120101639A/ko not_active Withdrawn
- 2010-11-19 AU AU2010321762A patent/AU2010321762A1/en not_active Abandoned
- 2010-11-19 CN CN2010800488138A patent/CN102598875A/zh active Pending
- 2010-11-19 BR BR112012007628A patent/BR112012007628A2/pt not_active IP Right Cessation
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS627668A (ja) * | 1985-07-03 | 1987-01-14 | 三菱化学株式会社 | 炭素繊維強化炭素複合材 |
| JPS63242537A (ja) * | 1987-02-25 | 1988-10-07 | アエロスパシアル・ソシエテ・ナシオナル・アンデユストリエル | マトリックス及び炭素の強化ファイバーを備えた複合材料とその製造方法 |
| JPH04149068A (ja) * | 1990-10-09 | 1992-05-22 | Tokai Carbon Co Ltd | 炭素繊維強化炭素複合材製二重中空円筒体 |
| JPH04300247A (ja) * | 1990-12-05 | 1992-10-23 | Toyo Tanso Kk | 耐酸化性炭素材 |
| JPH07165927A (ja) * | 1991-03-06 | 1995-06-27 | Hercules Inc | 炭素―炭素複合体の内部酸化抑制のための無機酸化物 |
| JPH05306167A (ja) * | 1992-05-01 | 1993-11-19 | Nippon Steel Corp | 短繊維強化ｃ／ｃコンポジットの製造方法 |
| JP2007314421A (ja) * | 1996-06-27 | 2007-12-06 | Toyo Tanso Kk | 単結晶引き上げ用ルツボ |
| JP2004002182A (ja) * | 2002-03-25 | 2004-01-08 | Mitsubishi Gas Chem Co Inc | 配向性カーボンナノチューブ膜およびその製造方法 |
| JP2005538026A (ja) * | 2002-09-12 | 2005-12-15 | スネクマ・プロピュルシオン・ソリド | 耐火繊維の３次元繊維構造体、これを調製する方法、および耐熱構造複合材料への適用 |
| JP2007523033A (ja) * | 2004-01-30 | 2007-08-16 | サーントル ナシオナル ドゥ ラ ルシェルシェ シャーンティフィク（セーエンヌエールエス） | 支持体に結合させたカーボンナノチューブ及びそれを含む複合体の製造方法 |
| JP2007119318A (ja) * | 2005-10-31 | 2007-05-17 | Shinshu Univ | カーボンナノチューブを含有する炭素繊維強化炭素複合材料 |
| JP2009535530A (ja) * | 2006-05-02 | 2009-10-01 | ロール インコーポレイテッド | ナノ補強材を用いた複合材料中に用いられる補強繊維トウの修飾 |
| WO2008085634A1 (en) * | 2007-01-03 | 2008-07-17 | Lockheed Martin Corporation | Cnt-infused fiber and method therefor |
| JP2010531934A (ja) * | 2007-01-03 | 2010-09-30 | ロッキード マーティン コーポレーション | カーボン・ナノチューブを浸出したファイバとその製造方法 |
| JP2011512315A (ja) * | 2008-02-20 | 2011-04-21 | コミサリア ア レネルジー アトミック エ オ ゼネルジー アルテルナティブ | 炭素基板または金属基板上でのカーボンナノチューブの成長 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014530964A (ja) * | 2011-09-07 | 2014-11-20 | テイジン・アラミド・ビー．ブイ． | 低抵抗率、高弾性率、および／または高熱伝導率を有するカーボンナノチューブ繊維、ならびに、繊維紡糸ドープを用いた紡糸による当該繊維の製造方法 |
| JP2016084547A (ja) * | 2014-10-23 | 2016-05-19 | ニッタ株式会社 | 複合素材および強化繊維 |
| JP2018086808A (ja) * | 2016-11-29 | 2018-06-07 | 日産自動車株式会社 | 炭素繊維強化プラスチック構造体の製造方法及び製造装置 |
| JPWO2018225271A1 (ja) * | 2017-06-09 | 2019-12-26 | 日産自動車株式会社 | 複合材料の成形方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102598875A (zh) | 2012-07-18 |
| US20110124253A1 (en) | 2011-05-26 |
| KR20120101639A (ko) | 2012-09-14 |
| CA2774403A1 (en) | 2011-05-26 |
| AU2010321762A1 (en) | 2012-04-05 |
| WO2011063298A1 (en) | 2011-05-26 |
| BR112012007628A2 (pt) | 2016-08-23 |
| EP2478749A4 (en) | 2013-07-17 |
| EP2478749A1 (en) | 2012-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2013511465A (ja) | 炭素‐炭素複合材料におけるｃｎｔ浸出繊維 | |
| JP5701907B2 (ja) | 強化送電線のセルフシールドワイヤとしてのｃｎｔ浸出繊維 | |
| JP5823403B2 (ja) | Ｃｎｔ導入炭素繊維材料及びその製造プロセス | |
| US8951631B2 (en) | CNT-infused metal fiber materials and process therefor | |
| JP5744008B2 (ja) | 複合材料構造体を除氷するためのｃｎｔベース抵抗加熱 | |
| AU2010321535B2 (en) | CNT-infused fibers in thermoset matrices | |
| US20120189846A1 (en) | Cnt-infused ceramic fiber materials and process therefor | |
| US20110297892A1 (en) | Cnt-infused fibers in thermoplastic matrices | |
| JP2013509503A5 (enExample) | ||
| JP2014508370A (ja) | 強化送電線のセルフシールドワイヤとしてのｃｎｔ浸出繊維 | |
| JP2014508370A5 (enExample) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131028 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131028 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140919 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141104 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150130 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150303 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20150728 |