JP2013506722A - ポリウレタンフォームからの放出量の低減方法 - Google Patents

ポリウレタンフォームからの放出量の低減方法 Download PDF

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Publication number
JP2013506722A
JP2013506722A JP2012531265A JP2012531265A JP2013506722A JP 2013506722 A JP2013506722 A JP 2013506722A JP 2012531265 A JP2012531265 A JP 2012531265A JP 2012531265 A JP2012531265 A JP 2012531265A JP 2013506722 A JP2013506722 A JP 2013506722A
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weight
parts
component
isocyanate
components
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JP2012531265A
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Japanese (ja)
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ペーター・ハース
グンドルフ・ヤコブス
スヴェン・マイヤー−アーレンス
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Covestro Deutschland AG
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Bayer MaterialScience AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3834—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing hydrazide or semi-carbazide groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/24—Derivatives of hydrazine
    • C08K5/26—Semicarbazides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2290/00—Compositions for creating anti-fogging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
JP2012531265A 2009-09-30 2010-09-18 ポリウレタンフォームからの放出量の低減方法 Pending JP2013506722A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009047846A DE102009047846A1 (de) 2009-09-30 2009-09-30 Verfahren zur Erniedrigung von Emissionen eines Polyurethanschaumstoffes
DE102009047846.9 2009-09-30
PCT/EP2010/005741 WO2011038846A1 (de) 2009-09-30 2010-09-18 Verfahren zur erniedrigung von emissionen eines polyurethanschaumstoffes

Publications (1)

Publication Number Publication Date
JP2013506722A true JP2013506722A (ja) 2013-02-28

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Application Number Title Priority Date Filing Date
JP2012531265A Pending JP2013506722A (ja) 2009-09-30 2010-09-18 ポリウレタンフォームからの放出量の低減方法

Country Status (12)

Country Link
US (1) US20120184639A1 (enExample)
EP (1) EP2483324B1 (enExample)
JP (1) JP2013506722A (enExample)
CN (1) CN102574973B (enExample)
CA (1) CA2775606A1 (enExample)
DE (1) DE102009047846A1 (enExample)
ES (1) ES2544884T3 (enExample)
IN (1) IN2012DN02754A (enExample)
MX (1) MX2012003255A (enExample)
PL (1) PL2483324T3 (enExample)
RU (1) RU2549875C2 (enExample)
WO (1) WO2011038846A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015526558A (ja) * 2012-08-16 2015-09-10 ハンツマン ペトロケミカル エルエルシーＨｕｎｔｓｍａｎ Ｐｅｔｒｏｃｈｅｍｉｃａｌ ＬＬＣ 組成物
CN110023365A (zh) * 2016-12-05 2019-07-16 科思创德国股份有限公司 丙烯酸酯和丙烯酰胺用于减少聚氨酯泡沫体的排放的用途
JP2022500510A (ja) * 2018-08-02 2022-01-04 ダウ グローバル テクノロジーズ エルエルシー ポリウレタン発泡体のアルデヒド排出量を減少させるための方法
JP2022541617A (ja) * 2019-07-24 2022-09-26 エボニック オペレーションズ ゲーエムベーハー ポリウレタン系の製造

Families Citing this family (17)

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MX2010005069A (es) * 2009-05-27 2010-11-26 Bayer Materialscience Ag Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida.
US10066047B2 (en) 2012-02-02 2018-09-04 Covestro Llc Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams
EP2922886B1 (de) * 2012-11-23 2017-10-04 Covestro Deutschland AG Verfahren zur herstellung von flexiblen polyurethan- weichschaumstoffen mit hohem komfort und niedrigen hystereseverlusten
EP2762510B1 (de) 2013-02-01 2018-11-21 Covestro Deutschland AG Verbundelemente mit einem kern aus emissionsarmem polyurethan sowie verfahren zu deren herstellung
CN104744726B (zh) * 2013-12-27 2017-09-05 奕益实业有限公司 用于提升有机材料耐候性的稳定剂及经其改性的聚合物
US10766994B2 (en) * 2014-12-31 2020-09-08 Huntsman Petrochemical Llc Reduction of aldehydes in amine catalysts
US10590231B2 (en) * 2015-05-28 2020-03-17 Basf Se Polyurethanes with reduced aldehyde emission
WO2016196643A1 (en) * 2015-06-01 2016-12-08 Air Products And Chemicals, Inc. Reactive amine catalysts for polyurethane applications
WO2016201615A1 (en) 2015-06-16 2016-12-22 Air Products And Chemicals, Inc. Aldehyde scavengers for polyurethane foams
US10696777B2 (en) * 2015-06-16 2020-06-30 Evonik Operations Gmbh Aldehyde scavengers mixtures for polyurethane foams
EP3411420B1 (en) * 2016-02-05 2020-06-17 Huntsman International LLC Method for the reduction of aldehyde emission in polyurethane foam
WO2018148898A1 (en) * 2017-02-16 2018-08-23 Dow Global Technologies Llc Polyurethane foams having reduced aldehyde emissions
BR112019017144A2 (pt) * 2017-02-20 2020-04-14 Dow Global Technologies Llc poliuretano que tem emissões de aldeído reduzidas
CN108274678B (zh) * 2018-01-24 2020-09-08 盐城申呈汽车配件有限公司 一种汽车座椅头枕的成型方法
EP3617246A1 (en) * 2018-09-03 2020-03-04 Covestro Deutschland AG Nco-terminated polyurethane prepolymer and preparation method thereof
WO2020016124A1 (en) * 2018-07-16 2020-01-23 Covestro Deutschland Ag Nco-terminated polyurethane prepolymer and preparation method thereof
JP7247320B2 (ja) * 2018-08-02 2023-03-28 ダウ グローバル テクノロジーズ エルエルシー ポリウレタン発泡体のアルデヒド排出量を減少させるための方法

Family Cites Families (15)

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DE1694142C3 (de) 1967-03-25 1975-10-23 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Schaumstoffen
DE1720768A1 (de) 1968-01-02 1971-07-15 Bayer Ag Kunststoffe auf Isocyanatbasis und Verfahren zu ihrer Herstellung
CA1043948A (en) * 1974-05-17 1978-12-05 Manfred Dahm Process for the production of polyurethane foams
DE2550796C3 (de) * 1975-11-12 1987-04-16 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von stabilen Dispersionen
US4107102A (en) * 1976-01-05 1978-08-15 Bayer Aktiengesellschaft Highly elastic polyurethane foams and process for making them
DE2638759A1 (de) * 1976-08-27 1978-03-09 Bayer Ag Loesungen von polyisocyanat-polyadditionsprodukten
DE2732292A1 (de) 1977-07-16 1979-02-01 Bayer Ag Verfahren zur herstellung von polyurethankunststoffen
DE2832253A1 (de) 1978-07-22 1980-01-31 Bayer Ag Verfahren zur herstellung von formschaumstoffen
DE3435070A1 (de) 1984-09-25 1986-04-03 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von gegebenenfalls geschaeumten polyurethanen, die mit einem anderen werkstoff verbunden oder konfektioniert worden sind
DE3827595A1 (de) 1988-08-13 1990-02-22 Bayer Ag Verfahren zur herstellung von urethangruppen ausweisenden polyharnstoff-elastomeren
DE10258046A1 (de) 2002-12-11 2004-06-24 Basf Ag Verfahren zur Erniedrigung von Emissionen aus Polyurethanschaumstoffen
DE102004001746A1 (de) * 2004-01-13 2005-08-04 Bayer Materialscience Ag Polyetherester als Flammschutzmittel für Polyurethanweichschaumstoffe
WO2007126107A1 (ja) * 2006-04-25 2007-11-08 Kansai Paint Co., Ltd. 複層塗膜形成方法
WO2009114329A2 (en) * 2008-03-07 2009-09-17 Dow Global Technologies Inc. Polyurethanes having low levels of aldehyde emissions
JP5583112B2 (ja) * 2008-03-20 2014-09-03 ハンツマン ペトロケミカル エルエルシー アミン中のアルデヒドの還元

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015526558A (ja) * 2012-08-16 2015-09-10 ハンツマン ペトロケミカル エルエルシーＨｕｎｔｓｍａｎ Ｐｅｔｒｏｃｈｅｍｉｃａｌ ＬＬＣ 組成物
JP2017014516A (ja) * 2012-08-16 2017-01-19 ハンツマン ペトロケミカル エルエルシーＨｕｎｔｓｍａｎ Ｐｅｔｒｏｃｈｅｍｉｃａｌ ＬＬＣ 組成物
US10308754B2 (en) 2012-08-16 2019-06-04 Huntsman Petrochemical Llc Composition
CN110023365A (zh) * 2016-12-05 2019-07-16 科思创德国股份有限公司 丙烯酸酯和丙烯酰胺用于减少聚氨酯泡沫体的排放的用途
JP2019535885A (ja) * 2016-12-05 2019-12-12 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ ポリウレタンフォームの放出を低減するためのアクリル酸エステルおよびアミドの使用
CN110023365B (zh) * 2016-12-05 2022-06-10 科思创德国股份有限公司 丙烯酸酯和丙烯酰胺用于减少聚氨酯泡沫体的排放的用途
JP2022500510A (ja) * 2018-08-02 2022-01-04 ダウ グローバル テクノロジーズ エルエルシー ポリウレタン発泡体のアルデヒド排出量を減少させるための方法
JP7232317B2 (ja) 2018-08-02 2023-03-02 ダウ グローバル テクノロジーズ エルエルシー ポリウレタン発泡体のアルデヒド排出量を減少させるための方法
JP2022541617A (ja) * 2019-07-24 2022-09-26 エボニック オペレーションズ ゲーエムベーハー ポリウレタン系の製造
JP7554813B2 (ja) 2019-07-24 2024-09-20 エボニック オペレーションズ ゲーエムベーハー ポリウレタン系の製造

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Publication number Publication date
EP2483324A1 (de) 2012-08-08
DE102009047846A1 (de) 2011-03-31
CN102574973B (zh) 2014-09-24
PL2483324T3 (pl) 2015-11-30
MX2012003255A (es) 2012-04-10
RU2549875C2 (ru) 2015-05-10
RU2012117413A (ru) 2013-11-10
US20120184639A1 (en) 2012-07-19
EP2483324B1 (de) 2015-06-17
CN102574973A (zh) 2012-07-11
IN2012DN02754A (enExample) 2015-09-18
ES2544884T3 (es) 2015-09-04
CA2775606A1 (en) 2011-04-07
WO2011038846A1 (de) 2011-04-07

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