RU2549875C2 - Способ снижения эмиссий полиуретанового пенопласта - Google Patents
Способ снижения эмиссий полиуретанового пенопласта Download PDFInfo
- Publication number
- RU2549875C2 RU2549875C2 RU2012117413/04A RU2012117413A RU2549875C2 RU 2549875 C2 RU2549875 C2 RU 2549875C2 RU 2012117413/04 A RU2012117413/04 A RU 2012117413/04A RU 2012117413 A RU2012117413 A RU 2012117413A RU 2549875 C2 RU2549875 C2 RU 2549875C2
- Authority
- RU
- Russia
- Prior art keywords
- weight
- compounds
- parts
- components
- component
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 20
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 18
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 18
- 229920003023 plastic Polymers 0.000 title abstract description 6
- 239000004033 plastic Substances 0.000 title abstract description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 54
- 150000001875 compounds Chemical class 0.000 claims abstract description 44
- 239000012948 isocyanate Substances 0.000 claims abstract description 24
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 21
- 239000000654 additive Substances 0.000 claims abstract description 16
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 13
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000003993 interaction Effects 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 3
- -1 cell regulators Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 10
- 239000004604 Blowing Agent Substances 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 5
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 150000003672 ureas Chemical class 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 230000003712 anti-aging effect Effects 0.000 claims description 2
- 230000003385 bacteriostatic effect Effects 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 230000001408 fungistatic effect Effects 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 239000002683 reaction inhibitor Substances 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 239000012190 activator Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 230000005012 migration Effects 0.000 abstract description 3
- 238000013508 migration Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- 239000006260 foam Substances 0.000 description 10
- 229920002635 polyurethane Polymers 0.000 description 9
- 239000004814 polyurethane Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 150000003077 polyols Chemical class 0.000 description 7
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 125000004149 thio group Chemical group *S* 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- AXFVIWBTKYFOCY-UHFFFAOYSA-N 1-n,1-n,3-n,3-n-tetramethylbutane-1,3-diamine Chemical compound CN(C)C(C)CCN(C)C AXFVIWBTKYFOCY-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- YSAANLSYLSUVHB-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]ethanol Chemical compound CN(C)CCOCCO YSAANLSYLSUVHB-UHFFFAOYSA-N 0.000 description 1
- 229940105325 3-dimethylaminopropylamine Drugs 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 1
- MAVAPODDHKKXIY-UHFFFAOYSA-N NNC(Nc(cc1)ccc1NNC(Nc1ccccc1)=O)=O Chemical compound NNC(Nc(cc1)ccc1NNC(Nc1ccccc1)=O)=O MAVAPODDHKKXIY-UHFFFAOYSA-N 0.000 description 1
- AVKHCKXGKPAGEI-UHFFFAOYSA-N Phenicarbazide Chemical compound NC(=O)NNC1=CC=CC=C1 AVKHCKXGKPAGEI-UHFFFAOYSA-N 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- NLUNLVTVUDIHFE-UHFFFAOYSA-N cyclooctylcyclooctane Chemical compound C1CCCCCCC1C1CCCCCCC1 NLUNLVTVUDIHFE-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000005597 hydrazone group Chemical group 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000013518 molded foam Substances 0.000 description 1
- JWIXXKMOAUUTIQ-UHFFFAOYSA-N n',n'-dimethylpropane-1,3-diamine;urea Chemical compound NC(N)=O.CN(C)CCCN JWIXXKMOAUUTIQ-UHFFFAOYSA-N 0.000 description 1
- SBOJXQVPLKSXOG-UHFFFAOYSA-N o-amino-hydroxylamine Chemical class NON SBOJXQVPLKSXOG-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229960001206 phenicarbazide Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
- C08G18/3834—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing hydrazide or semi-carbazide groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
- C08K5/26—Semicarbazides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2290/00—Compositions for creating anti-fogging
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2350/00—Acoustic or vibration damping material
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009047846A DE102009047846A1 (de) | 2009-09-30 | 2009-09-30 | Verfahren zur Erniedrigung von Emissionen eines Polyurethanschaumstoffes |
| DE102009047846.9 | 2009-09-30 | ||
| PCT/EP2010/005741 WO2011038846A1 (de) | 2009-09-30 | 2010-09-18 | Verfahren zur erniedrigung von emissionen eines polyurethanschaumstoffes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012117413A RU2012117413A (ru) | 2013-11-10 |
| RU2549875C2 true RU2549875C2 (ru) | 2015-05-10 |
Family
ID=43014481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012117413/04A RU2549875C2 (ru) | 2009-09-30 | 2010-09-18 | Способ снижения эмиссий полиуретанового пенопласта |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20120184639A1 (enExample) |
| EP (1) | EP2483324B1 (enExample) |
| JP (1) | JP2013506722A (enExample) |
| CN (1) | CN102574973B (enExample) |
| CA (1) | CA2775606A1 (enExample) |
| DE (1) | DE102009047846A1 (enExample) |
| ES (1) | ES2544884T3 (enExample) |
| IN (1) | IN2012DN02754A (enExample) |
| MX (1) | MX2012003255A (enExample) |
| PL (1) | PL2483324T3 (enExample) |
| RU (1) | RU2549875C2 (enExample) |
| WO (1) | WO2011038846A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2738375C2 (ru) * | 2016-02-05 | 2020-12-11 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Способ снижения эмиссии альдегида в полиуретановой пене |
| RU2783442C2 (ru) * | 2017-12-18 | 2022-11-14 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Композиция с пониженной эмиссией альдегидов |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2010005069A (es) * | 2009-05-27 | 2010-11-26 | Bayer Materialscience Ag | Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida. |
| US10066047B2 (en) | 2012-02-02 | 2018-09-04 | Covestro Llc | Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams |
| EP2703421A1 (en) * | 2012-08-28 | 2014-03-05 | Huntsman Petrochemical LLC | A composition for making foams with reduced aldehyde emission |
| EP2922886B1 (de) * | 2012-11-23 | 2017-10-04 | Covestro Deutschland AG | Verfahren zur herstellung von flexiblen polyurethan- weichschaumstoffen mit hohem komfort und niedrigen hystereseverlusten |
| PL2762510T3 (pl) | 2013-02-01 | 2019-05-31 | Covestro Deutschland Ag | Elementy kompozytowe z rdzeniem z niskoemisyjnego poliuretanu oraz sposób ich wytwarzania |
| CN104744726B (zh) * | 2013-12-27 | 2017-09-05 | 奕益实业有限公司 | 用于提升有机材料耐候性的稳定剂及经其改性的聚合物 |
| JP6778196B2 (ja) * | 2014-12-31 | 2020-10-28 | ハンツマン ペトロケミカル エルエルシーＨｕｎｔｓｍａｎ Ｐｅｔｒｏｃｈｅｍｉｃａｌ ＬＬＣ | アミン触媒中のアルデヒドの削減 |
| BR112017025021A2 (pt) * | 2015-05-28 | 2018-08-07 | Basf Se | ?processo para a produção de poliuretanos, poliuretano e uso de um poliuretano? |
| ES3050629T3 (en) * | 2015-06-01 | 2025-12-22 | Evonik Operations Gmbh | Reactive amine catalysts for polyurethane applications |
| MX2017016191A (es) | 2015-06-16 | 2018-04-24 | Evonik Degussa Gmbh | Eliminadores de aldehido para espumas de poliuretano. |
| US10696777B2 (en) * | 2015-06-16 | 2020-06-30 | Evonik Operations Gmbh | Aldehyde scavengers mixtures for polyurethane foams |
| EP3330307A1 (de) * | 2016-12-05 | 2018-06-06 | Covestro Deutschland AG | Verwendung von acrylsäureestern und amiden zur erniedrigung von emissionen eines polyurethanschaumstoffes |
| US20210130562A1 (en) * | 2017-02-16 | 2021-05-06 | Dow Global Technologies., Llc | Polyurethane foams having reduced aldehyde emissions |
| BR112019017144A2 (pt) * | 2017-02-20 | 2020-04-14 | Dow Global Technologies Llc | poliuretano que tem emissões de aldeído reduzidas |
| CN108274678B (zh) * | 2018-01-24 | 2020-09-08 | 盐城申呈汽车配件有限公司 | 一种汽车座椅头枕的成型方法 |
| EP3617246A1 (en) * | 2018-09-03 | 2020-03-04 | Covestro Deutschland AG | Nco-terminated polyurethane prepolymer and preparation method thereof |
| WO2020016124A1 (en) * | 2018-07-16 | 2020-01-23 | Covestro Deutschland Ag | Nco-terminated polyurethane prepolymer and preparation method thereof |
| EP3830160B1 (en) * | 2018-08-02 | 2025-06-25 | Dow Global Technologies LLC | Methods for reducing aldehyde emissions in polyurethane foams |
| US11603428B2 (en) | 2018-08-02 | 2023-03-14 | Dow Global Technologies Llc | Methods for reducing aldehyde emissions in polyurethane foams |
| WO2021013607A1 (de) * | 2019-07-24 | 2021-01-28 | Evonik Operations Gmbh | Herstellung von polyurethansystemen |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107102A (en) * | 1976-01-05 | 1978-08-15 | Bayer Aktiengesellschaft | Highly elastic polyurethane foams and process for making them |
| EP1428847A1 (de) * | 2002-12-11 | 2004-06-16 | Basf Aktiengesellschaft | Verfahren zur Erniedrigung von Emissionen aus Polyurethanschaumstoffen |
| RU2005100197A (ru) * | 2004-01-13 | 2006-06-20 | Байер МатириальСайенс АГ (DE) | Мягкий полиуретановый пенопласт согласно стандарту fmvss 302 и его применение |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1694142C3 (de) | 1967-03-25 | 1975-10-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Schaumstoffen |
| DE1720768A1 (de) | 1968-01-02 | 1971-07-15 | Bayer Ag | Kunststoffe auf Isocyanatbasis und Verfahren zu ihrer Herstellung |
| NL180113C (nl) * | 1974-05-17 | 1987-01-02 | Bayer Ag | Werkwijze ter bereiding van opgeschuimde polyurethanmaterialen alsmede gevormd voortbrengsel. |
| DE2550796C3 (de) * | 1975-11-12 | 1987-04-16 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von stabilen Dispersionen |
| DE2638759A1 (de) * | 1976-08-27 | 1978-03-09 | Bayer Ag | Loesungen von polyisocyanat-polyadditionsprodukten |
| DE2732292A1 (de) | 1977-07-16 | 1979-02-01 | Bayer Ag | Verfahren zur herstellung von polyurethankunststoffen |
| DE2832253A1 (de) | 1978-07-22 | 1980-01-31 | Bayer Ag | Verfahren zur herstellung von formschaumstoffen |
| DE3435070A1 (de) | 1984-09-25 | 1986-04-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von gegebenenfalls geschaeumten polyurethanen, die mit einem anderen werkstoff verbunden oder konfektioniert worden sind |
| DE3827595A1 (de) | 1988-08-13 | 1990-02-22 | Bayer Ag | Verfahren zur herstellung von urethangruppen ausweisenden polyharnstoff-elastomeren |
| CN101432082B (zh) * | 2006-04-25 | 2011-10-05 | 关西涂料株式会社 | 形成多层涂膜的方法 |
| WO2009114329A2 (en) * | 2008-03-07 | 2009-09-17 | Dow Global Technologies Inc. | Polyurethanes having low levels of aldehyde emissions |
| CN102924675B (zh) * | 2008-03-20 | 2015-07-29 | 亨斯迈石油化学有限责任公司 | 减少胺中的醛的方法 |
-
2009
- 2009-09-30 DE DE102009047846A patent/DE102009047846A1/de not_active Withdrawn
-
2010
- 2010-09-18 IN IN2754DEN2012 patent/IN2012DN02754A/en unknown
- 2010-09-18 CA CA2775606A patent/CA2775606A1/en not_active Abandoned
- 2010-09-18 JP JP2012531265A patent/JP2013506722A/ja active Pending
- 2010-09-18 CN CN201080044006.9A patent/CN102574973B/zh not_active Expired - Fee Related
- 2010-09-18 RU RU2012117413/04A patent/RU2549875C2/ru not_active IP Right Cessation
- 2010-09-18 US US13/498,979 patent/US20120184639A1/en not_active Abandoned
- 2010-09-18 EP EP10763601.1A patent/EP2483324B1/de not_active Not-in-force
- 2010-09-18 WO PCT/EP2010/005741 patent/WO2011038846A1/de not_active Ceased
- 2010-09-18 ES ES10763601.1T patent/ES2544884T3/es active Active
- 2010-09-18 MX MX2012003255A patent/MX2012003255A/es active IP Right Grant
- 2010-09-18 PL PL10763601T patent/PL2483324T3/pl unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107102A (en) * | 1976-01-05 | 1978-08-15 | Bayer Aktiengesellschaft | Highly elastic polyurethane foams and process for making them |
| EP1428847A1 (de) * | 2002-12-11 | 2004-06-16 | Basf Aktiengesellschaft | Verfahren zur Erniedrigung von Emissionen aus Polyurethanschaumstoffen |
| RU2005100197A (ru) * | 2004-01-13 | 2006-06-20 | Байер МатириальСайенс АГ (DE) | Мягкий полиуретановый пенопласт согласно стандарту fmvss 302 и его применение |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2738375C2 (ru) * | 2016-02-05 | 2020-12-11 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Способ снижения эмиссии альдегида в полиуретановой пене |
| RU2783442C2 (ru) * | 2017-12-18 | 2022-11-14 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Композиция с пониженной эмиссией альдегидов |
Also Published As
| Publication number | Publication date |
|---|---|
| PL2483324T3 (pl) | 2015-11-30 |
| WO2011038846A1 (de) | 2011-04-07 |
| JP2013506722A (ja) | 2013-02-28 |
| ES2544884T3 (es) | 2015-09-04 |
| MX2012003255A (es) | 2012-04-10 |
| CA2775606A1 (en) | 2011-04-07 |
| EP2483324A1 (de) | 2012-08-08 |
| US20120184639A1 (en) | 2012-07-19 |
| RU2012117413A (ru) | 2013-11-10 |
| IN2012DN02754A (enExample) | 2015-09-18 |
| EP2483324B1 (de) | 2015-06-17 |
| DE102009047846A1 (de) | 2011-03-31 |
| CN102574973A (zh) | 2012-07-11 |
| CN102574973B (zh) | 2014-09-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102574973B (zh) | 减少聚氨酯泡沫的释放物的方法 | |
| CA2670190C (en) | Process for lowering emissions of a polyurethane foam | |
| DK3205680T3 (en) | AGE-RESISTANT AND EMISSION-POWERFUL MATTRESSES AND / OR CUSHIONS | |
| JP5550450B2 (ja) | 放出の少ない軟質ポリウレタンフォームの製造方法 | |
| CA2864245A1 (en) | Additive for adjusting the glass transition temperature of visco-elastic polyurethane soft foams | |
| US9701804B2 (en) | Method for producing flexible polyurethane foams | |
| US20130190414A1 (en) | Additive composition useful for controlling the foam properties in the production of flexible polyurethane foams containing polyols based on renewable raw materials | |
| CN104736585A (zh) | 制备基于聚酯多元醇的聚氨酯软质泡沫材料的方法 | |
| US20160264757A1 (en) | Antioxidants for producing low-emission pur systems | |
| US20210139634A1 (en) | Use of acrylic acid esters and amides for reducing emissions of a polyurethane foam | |
| CN103249752B (zh) | 制备柔性聚氨酯泡沫的方法 | |
| CA2689510C (en) | Reactive amine catalysts for polyurethane foam | |
| US9328196B2 (en) | Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups | |
| JP7034143B2 (ja) | ポリウレタンフォームのアルデヒド放出を軽減する方法 | |
| CN114026145A (zh) | 作为hr泡沫中可并入的催化剂的胺起始的多元醇 | |
| US20130345330A1 (en) | Method for producing flexible polyurethane foams | |
| EP4658698A1 (en) | Process for manufacturing polyurethane foam |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20190919 |