JP2012193448A - ステンレス鋼と樹脂の複合体及びその製造方法 - Google Patents
ステンレス鋼と樹脂の複合体及びその製造方法 Download PDFInfo
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- JP2012193448A JP2012193448A JP2012037224A JP2012037224A JP2012193448A JP 2012193448 A JP2012193448 A JP 2012193448A JP 2012037224 A JP2012037224 A JP 2012037224A JP 2012037224 A JP2012037224 A JP 2012037224A JP 2012193448 A JP2012193448 A JP 2012193448A
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- stainless steel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14795—Porous or permeable material, e.g. foam
- B29C2045/14803—Porous or permeable material, e.g. foam the injected material entering minute pores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C2045/1486—Details, accessories and auxiliary operations
- B29C2045/14868—Pretreatment of the insert, e.g. etching, cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
- B29K2705/08—Transition metals
- B29K2705/12—Iron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249955—Void-containing component partially impregnated with adjacent component
Abstract
【解決手段】本発明に係るステンレス鋼と樹脂の複合体は、陽極酸化処理によって、平均内径が100〜500nmである無数の微細孔を有する膜層により表面が被覆されている形状化されたステンレス鋼基材と、結晶型熱可塑性樹脂を主成分とし、且つ射出成形によって前記表面の微細孔内に嵌め込まれて、前記ステンレス鋼基材と一体に接合される樹脂部材と、を備える。
【選択図】図2
Description
13 樹脂部材
100 ステンレス鋼と樹脂の複合体
112 膜層
114 微細孔
Claims (9)
- 陽極酸化処理によって、平均内径が100〜500nmである無数の微細孔を有する膜層により表面が被覆されている、形状化されたステンレス鋼基材と、
結晶型熱可塑性樹脂を主成分とし、且つ射出成形によって前記表面の微細孔内に嵌め込まれて前記ステンレス鋼基材と一体に接合される樹脂部材と、
を備えることを特徴とするステンレス鋼と樹脂の複合体。 - 前記膜層の輪郭曲線の算術の平均高さ(Ra)は0.2〜1.0μmで、輪郭曲線の最大高さ(Rz)は2.5〜5.0μmで、且つ前記膜層が輪郭曲線要素の平均長さ(RSm)が30〜50μmである粗度を有することを特徴とする請求項1に記載のステンレス鋼と樹脂の複合体。
- 前記樹脂部材は、ポリフェニレンスルフィドを主成分とし、且つその中には重量比が25重量%〜35重量%のガラス繊維が添加されていることを特徴とする請求項1から2の何れか一項に記載のステンレス鋼と樹脂の複合体。
- ステンレス鋼基材の表面に形成された前記膜層は、主に鉄(Fe)、クロム(Cr)、ニッケル(Ni)及び酸素(O)元素により構成されることを特徴とする請求項1から3の何れか一項に記載のステンレス鋼と樹脂の複合体。
- 形状化されたステンレス鋼基材を用意する工程と、
前記ステンレス鋼基材を活性化処理して、その表面に形成された自然酸化物皮膜を除く工程と、
活性化処理を経た前記ステンレス鋼基材に対して、陽極酸化処理を行うことによって、前記ステンレス鋼基材の表面に平均内径が100〜500nmである無数の微細孔を有する膜層を形成する工程と、
陽極酸化処理を経た前記ステンレス鋼基材を射出成形金型内にインサートして、前記ステンレス鋼基材の膜層に向かって溶融した結晶型熱可塑性樹脂を注入し、且つ前記溶融樹脂を前記ステンレス鋼基材の表面に形成された微細孔に侵入させた状態で、前記溶融樹脂を硬化して樹脂部材を成形する工程と、
を備えることを特徴とするステンレス鋼と樹脂の複合体の製造方法。 - 前記活性化処理は、前記ステンレス鋼基材を室温下で硫酸或いは塩酸を含有する水溶液に1〜2分浸漬することであり、硫酸溶液の場合、前記硫酸の質量濃度が15%〜35%であることを特徴とする請求項5に記載のステンレス鋼と樹脂の複合体の製造方法。
- 前記陽極酸化処理は、前記ステンレス鋼基材を陽極とし、チタン板を陰極とし、硝酸、三価の塩化鉄及び添加剤を含有する酸性電解液を通電して行うことを特徴とする請求項5に記載のステンレス鋼と樹脂の複合体の製造方法。
- 前記酸性電解液において、硝酸の質量濃度が1%〜10%であり、三価の塩化鉄の質量濃度が10%〜100%であり、前記ステンレス鋼基材を通過する電流の密度は1〜10A/dm2であり、陽極酸化する時に必要とする通電時間は1〜3分であり、且つ陽極酸化している間の前記酸性電解液の温度は15〜60℃に保たれることを特徴とする請求項7に記載のステンレス鋼と樹脂の複合体の製造方法。
- 前記添加剤は、体積濃度が1〜10g/Lのチオカルバミド或いは体積濃度が4〜40g/Lの酒石酸カリウムナトリウムであることを特徴とする請求項7に記載のステンレス鋼と樹脂の複合体の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011100603575A CN102672878A (zh) | 2011-03-14 | 2011-03-14 | 不锈钢与树脂的复合体及其制造方法 |
CN201110060357.5 | 2011-03-14 |
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JP2012193448A true JP2012193448A (ja) | 2012-10-11 |
JP5766135B2 JP5766135B2 (ja) | 2015-08-19 |
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JP2012037224A Active JP5766135B2 (ja) | 2011-03-14 | 2012-02-23 | ステンレス鋼と樹脂の複合体の製造方法 |
Country Status (5)
Country | Link |
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US (1) | US8784981B2 (ja) |
EP (1) | EP2500156A1 (ja) |
JP (1) | JP5766135B2 (ja) |
CN (1) | CN102672878A (ja) |
TW (1) | TWI464053B (ja) |
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JP2016503835A (ja) * | 2012-12-28 | 2016-02-08 | ビーワイディー カンパニー リミテッドByd Company Limited | ステンレス鋼−樹脂複合体及びそれを調製する方法 |
US9770884B2 (en) | 2012-02-24 | 2017-09-26 | Shenzhen Byd Auto R&D Company Limited | Metal-resin composite and method for producing the same |
US9783894B2 (en) | 2012-05-28 | 2017-10-10 | Byd Company Limited | Metal composite and method of preparing the same, metal-resin composite and method of preparing the same |
US9802388B2 (en) | 2012-02-24 | 2017-10-31 | Shenzhen Byd Auto R&D Company Limited | Aluminum alloy resin composite and method of preparing the same |
US9809895B2 (en) | 2012-02-24 | 2017-11-07 | Shenzhen Byd Auto R&D Company Limited | Method of preparing aluminum alloy resin composite and aluminum alloy-resin composite obtainable by the same |
US9808974B2 (en) | 2012-02-24 | 2017-11-07 | Shenzhen Byd Auto R&D Company Limited | Method of preparing aluminum alloy resin composite and aluminum alloy-resin composite obtainable by the same |
WO2017209011A1 (ja) * | 2016-05-31 | 2017-12-07 | 三井化学株式会社 | 金属/樹脂複合構造体、金属部材および金属部材の製造方法 |
US9862131B2 (en) | 2012-02-24 | 2018-01-09 | Byd Company Limited | Method for integrally molding metal and resin and metal-resin composite structure obtainable by the same |
US9889588B2 (en) | 2012-02-24 | 2018-02-13 | Shenzhen Byd Auto R&D Company Limited | Method for integrally molding metal and resin and metal-resin composite structure obtainable by the same |
WO2019050039A1 (ja) * | 2017-09-08 | 2019-03-14 | ジオネーション株式会社 | 樹脂金属接合体及びその製造方法 |
JP2019183194A (ja) * | 2018-04-03 | 2019-10-24 | ジオネーション株式会社 | 樹脂炭素鋼接合体及びその製造法 |
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WO2017209011A1 (ja) * | 2016-05-31 | 2017-12-07 | 三井化学株式会社 | 金属/樹脂複合構造体、金属部材および金属部材の製造方法 |
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JP7042740B2 (ja) | 2016-05-31 | 2022-03-28 | 三井化学株式会社 | 金属/樹脂複合構造体、金属部材および金属部材の製造方法 |
KR20220053036A (ko) * | 2016-05-31 | 2022-04-28 | 미쯔이가가꾸가부시끼가이샤 | 금속/수지 복합 구조체, 금속 부재 및 금속 부재의 제조 방법 |
CN109195791A (zh) * | 2016-05-31 | 2019-01-11 | 三井化学株式会社 | 金属/树脂复合结构体、金属构件及金属构件的制造方法 |
WO2019050039A1 (ja) * | 2017-09-08 | 2019-03-14 | ジオネーション株式会社 | 樹脂金属接合体及びその製造方法 |
JP2019049023A (ja) * | 2017-09-08 | 2019-03-28 | ジオネーション株式会社 | 樹脂金属接合体及びその製造方法 |
KR20200085269A (ko) | 2017-09-08 | 2020-07-14 | 토아덴카 코., 엘티디. | 수지 금속 접합체 및 그 제조 방법 |
KR102330886B1 (ko) * | 2017-09-08 | 2021-11-24 | 토아덴카 코., 엘티디. | 수지 금속 접합체 및 그 제조 방법 |
JP2019183194A (ja) * | 2018-04-03 | 2019-10-24 | ジオネーション株式会社 | 樹脂炭素鋼接合体及びその製造法 |
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TW201236861A (en) | 2012-09-16 |
US20120237755A1 (en) | 2012-09-20 |
EP2500156A1 (en) | 2012-09-19 |
JP5766135B2 (ja) | 2015-08-19 |
CN102672878A (zh) | 2012-09-19 |
TWI464053B (zh) | 2014-12-11 |
US8784981B2 (en) | 2014-07-22 |
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