JP2012166421A - 遮熱性合わせ構造体の製造方法、遮熱性合わせ構造体、合わせ構造体用透明積層フィルム - Google Patents
遮熱性合わせ構造体の製造方法、遮熱性合わせ構造体、合わせ構造体用透明積層フィルム Download PDFInfo
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- JP2012166421A JP2012166421A JP2011028322A JP2011028322A JP2012166421A JP 2012166421 A JP2012166421 A JP 2012166421A JP 2011028322 A JP2011028322 A JP 2011028322A JP 2011028322 A JP2011028322 A JP 2011028322A JP 2012166421 A JP2012166421 A JP 2012166421A
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Abstract
【解決手段】透明高分子フィルムの少なくとも一方面に、有機分を含有する金属酸化物層と金属層とが積層されてなる積層構造部を有し、前記積層構造部に前記金属層を分断する幅30μm以下の溝部が形成された透明積層フィルム12を、2枚の透明基材14,14で挟み、圧力を加えて2枚の透明基材14,14を透明積層フィルム12を介して貼り合わせるとともに、前記圧力により透明積層フィルム12の金属層の分断化を進行させて全体の表面抵抗値を上げるようにした。
【選択図】図1
Description
上記金属酸化物としては、具体的には、例えば、チタンの酸化物、亜鉛の酸化物、インジウムの酸化物、スズの酸化物、インジウムとスズとの酸化物、マグネシウムの酸化物、アルミニウムの酸化物、ジルコニウムの酸化物、ニオブの酸化物、セリウムの酸化物などを例示することができる。これらは1種または2種以上含まれていても良い。また、これら金属酸化物は、2種以上の金属酸化物が複合した複酸化物であっても良い。
金属層の金属としては、具体的には、例えば、銀、金、白金、銅、アルミニウム、クロム、チタン、亜鉛、スズ、ニッケル、コバルト、ニオブ、タンタル、タングステン、ジルコニウム、鉛、パラジウム、インジウムなどの金属や、これら金属の合金などを例示することができる。これらは1種または2種以上含まれていても良い。
本フィルムにおいて、バリア層は、主として、金属層を構成する元素が、金属酸化物層中へ拡散するのを抑制するバリア的な機能を有している。また、金属酸化物層と金属層との間に介在することで、両者の密着性の向上にも寄与しうる。
実施例に用いた透明積層フィルムは、以下の7層積層構造部を有する透明積層フィルムとした。すなわち、ゾル−ゲル法及びUV照射によるTiO2層(1層目)│金属Ti層/Ag−Cu合金層/金属Ti層が、後酸化されて形成された層(2層目)│ゾル−ゲル法及びUV照射によるTiO2層(3層目)│金属Ti層/Ag−Cu合金層/金属Ti層が、後酸化されて形成された層(4層目)│ゾル−ゲル法及びUV照射によるTiO2層(5層目)│金属Ti層/Ag−Cu合金層/金属Ti層が、後酸化されて形成された層(6層目)│ゾル−ゲル法及びUV照射によるTiO2層(7層目)が、両面に易接着層が形成されたPETフィルムの一方の易接着層上に順に積層された積層構造部を有している。なお、上記金属Ti層が後酸化されて形成されたものが、バリア層に該当する。バリア層は、合金層に付随する薄膜層として、合金層に含めて積層数を数えている。また、上記後酸化は、具体的には、熱酸化である。7層積層構造部の表面には、保護層を備えている。
以下、上記透明積層フィルム(溝部有り)の具体的な作製手順を示す。
先ず、ゾル−ゲル法によるTiO2層の形成に使用するコーティング液を調製した。すなわち、チタンアルコキシドとして、テトラ−n−ブトキシチタン4量体(日本曹達(株)製、「B4」)と、紫外線吸収性のキレートを形成する添加剤として、アセチルアセトンとを、n−ブタノールとイソプロピルアルコールとの混合溶媒に配合し、これを攪拌機を用いて10分間混合することにより、コーティング液を調製した。この際、テトラ−n−ブトキシチタン4量体/アセチルアセトン/n−ブタノール/イソプロピルアルコールの配合は、それぞれ6.75質量%/3.38質量%/59.87質量%/30.00質量%とした。
透明高分子フィルムとして、易接着層が両面に形成された厚み50μmのポリエチレンテレフタレートフィルム(東洋紡績(株)製、「コスモシャイン(登録商標)A4300」)(以下、「PETフィルム」という。)を用い、この両面に易接着層が形成されたPETフィルムの一方の易接着層上に、1層目として、TiO2層を以下の手順により成膜した。
作製した上記の溝部を有する透明積層フィルムを2枚のポリビニルブチラール膜(厚み380μm)で挟み、さらにポリビニルブチラール膜の外側から2枚のガラス板(厚み2mm)で挟んで得られる積層体をオートクレーブ内に入れ、135℃×13kgf/cm2×20分の条件下で処理することにより、合わせガラス化を行った。これにより、実施例1〜4の合わせガラスを作製した。合わせガラス化を行ったことにより、金属層の分断化を進行させた。
透明高分子フィルムとして、易接着層が片面に形成された厚み50μmのポリエチレンテレフタレートフィルム(東洋紡績(株)製、「コスモシャイン(登録商標)A4100」)(以下、「PETフィルム」という。)を用い、このPETフィルムの易接着層面側とは反対側の面(PET面)側に7層積層構造の薄膜層を成膜した以外は実施例と同様にして、比較例1の透明積層フィルム(溝部無し)を作製した。また、比較例1の透明積層フィルム(溝部無し)を用いて実施例と同様に合わせガラス化を行うことにより、比較例1の合わせガラスを作製した。
<表面抵抗値の測定>
DELCOM社製「非接触抵抗率計 Model 717H」を用いて、透明積層フィルムおよび合わせガラスのそれぞれについて、表面抵抗値を測定した。より具体的には、透明積層フィルムおよび合わせガラスのそれぞれについて、160mm角の範囲を9分割し、9点で表面抵抗値を測定し、その最大値、最小値、平均値を求めた。
JIS R3212に準拠して、合わせガラスの可視光線透過率を求めた。
日射遮蔽性の評価のため、ISO13837に準拠して、合わせガラスの太陽光全透過率を求めた。
12 透明積層フィルム
14 透明基材
16 接着層
Claims (16)
- 透明高分子フィルムの少なくとも一方面に、有機分を含有する金属酸化物層と金属層とが積層されてなる積層構造部を有し、前記積層構造部に前記金属層を分断する幅30μm以下の溝部が形成された透明積層フィルムを、2枚の透明基材で挟み、圧力を加えて前記2枚の透明基材を前記透明積層フィルムを介して貼り合わせるとともに、前記圧力により前記透明積層フィルムの金属層の分断化を進行させて全体の表面抵抗値を上げることを特徴とする遮熱性合わせ構造体の製造方法。
- 前記溝部の形成は、前記有機分を含有する金属酸化物層を形成する出発原料を反応させ、その反応過程で前記積層構造部に生じた応力によって亀裂を発生させることにより行われることを特徴とする請求項1に記載の遮熱性合わせ構造体の製造方法。
- 前記有機分はゾル−ゲル法による出発原料の残存分であり、前記溝部の形成は、酸素、オゾンおよび水から選択される1種または2種以上を含む雰囲気下にて、前記積層構造部に対してその表面からエネルギーを与える手順を含むことを特徴とする請求項1または2に記載の遮熱性合わせ構造体の製造方法。
- 前記溝部の形成は、前記積層構造部の表面をレーザー加工することにより行われることを特徴とする請求項1に記載の遮熱性合わせ構造体の製造方法。
- 前記溝部の形成は、フィルムの延伸により行われることを特徴とする請求項1に記載の遮熱性合わせ構造体の製造方法。
- 前記延伸は二軸延伸であることを特徴とする請求項5に記載の遮熱性合わせ構造体の製造方法。
- 前記溝部の形成は、易接着層を介して前記透明高分子フィルムの少なくとも一方面に前記積層構造部を形成することにより行われることを特徴とする請求項1または2に記載の遮熱性合わせ構造体の製造方法。
- 前記有機分を含有する金属酸化物層は、ゾルゲル硬化時に光エネルギーを用いるゾル−ゲル法により形成することを特徴とする請求項1から7のいずれか1項に記載の遮熱性合わせ構造体の製造方法。
- 前記金属層の少なくとも一方面に、金属酸化物より主に構成されるバリア層を形成することを特徴とする請求項1から8のいずれか1項に記載の遮熱性合わせ構造体の製造方法。
- 前記金属酸化物層は、チタン酸化物層であることを特徴とする請求項1から9のいずれか1項に記載の遮熱性合わせ構造体の製造方法。
- 前記金属層は、銀層または銀合金層であることを特徴とする請求項1から10のいずれか1項に記載の遮熱性合わせ構造体の製造方法。
- 前記バリア層は、チタン酸化物より主に構成されることを特徴とする請求項9から11のいずれか1項に記載の遮熱性合わせ構造体の製造方法。
- 前記バリア層の形成は、金属Ti層を後酸化することにより行われる、または、部分酸化されたチタン酸化物層を後酸化することにより行われることを特徴とする請求項9から12のいずれか1項に記載の遮熱性合わせ構造体の製造方法。
- 請求項1から13のいずれか1項に記載の製造方法により得られる遮熱性合わせ構造体。
- 透明高分子フィルムの少なくとも一方面に、有機分を含有する金属酸化物層と金属層とが積層されてなる積層構造部を有し、前記積層構造部に前記金属層を分断する幅30μm以下の溝部が形成された透明積層フィルムが、2枚の透明基材で挟まれており、圧力が加えられて前記2枚の透明基材が前記透明積層フィルムを介して貼り合わされているとともに、前記圧力により前記透明積層フィルムの金属層の分断化を進行させたことにより全体の表面抵抗値が500Ω/□以上に設定されていることを特徴とする遮熱性合わせ構造体。
- 圧力を加えて貼り合わされる2枚の透明基材の間に配置される透明積層フィルムであって、
透明高分子フィルムの少なくとも一方面に、有機分を含有する金属酸化物層と金属層とが積層されてなる積層構造部を有し、
前記積層構造部には、前記金属層を分断する幅30μm以下の溝部が形成されており、
表面抵抗値が10Ω/□以上に設定されていることを特徴とする合わせ構造体用透明積層フィルム。
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