JP2011511429A5 - - Google Patents
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- Publication number
- JP2011511429A5 JP2011511429A5 JP2010546004A JP2010546004A JP2011511429A5 JP 2011511429 A5 JP2011511429 A5 JP 2011511429A5 JP 2010546004 A JP2010546004 A JP 2010546004A JP 2010546004 A JP2010546004 A JP 2010546004A JP 2011511429 A5 JP2011511429 A5 JP 2011511429A5
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- cobalt
- hydroxide
- particles
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010941 cobalt Substances 0.000 claims description 67
- 229910017052 cobalt Inorganic materials 0.000 claims description 67
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 67
- 239000002245 particle Substances 0.000 claims description 40
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 36
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 27
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
- 229910052759 nickel Inorganic materials 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 239000007800 oxidant agent Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 8
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 6
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 6
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical group NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 5
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000004913 activation Effects 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 13
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 8
- 230000008595 infiltration Effects 0.000 description 5
- 238000001764 infiltration Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- SPIFDSWFDKNERT-UHFFFAOYSA-N nickel;hydrate Chemical compound O.[Ni] SPIFDSWFDKNERT-UHFFFAOYSA-N 0.000 description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 5
- 229910018916 CoOOH Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- -1 alkali metal persulfate Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6507908P | 2008-02-07 | 2008-02-07 | |
| US61/065,079 | 2008-02-07 | ||
| US12/365,658 | 2009-02-04 | ||
| US12/365,658 US8043748B2 (en) | 2008-02-07 | 2009-02-04 | Pasted nickel hydroxide electrode for rechargeable nickel-zinc batteries |
| PCT/US2009/033265 WO2009100248A1 (en) | 2008-02-07 | 2009-02-05 | Pasted nickel hydroxide electrode for rechargeable nickel-zinc batteries |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011511429A JP2011511429A (ja) | 2011-04-07 |
| JP2011511429A5 true JP2011511429A5 (enExample) | 2015-01-29 |
| JP5719175B2 JP5719175B2 (ja) | 2015-05-13 |
Family
ID=40939155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010546004A Active JP5719175B2 (ja) | 2008-02-07 | 2009-02-05 | 充電式ニッケル−亜鉛バッテリ用のペーストされた水酸化ニッケル電極 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US8043748B2 (enExample) |
| EP (1) | EP2250691A1 (enExample) |
| JP (1) | JP5719175B2 (enExample) |
| KR (1) | KR20100114516A (enExample) |
| CN (1) | CN101939863B (enExample) |
| WO (1) | WO2009100248A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7829221B2 (en) * | 2000-11-10 | 2010-11-09 | Powergenix Systems, Inc. | Cobalt containing positive electrode formulation for a nickel-zinc cell |
| US8703330B2 (en) * | 2005-04-26 | 2014-04-22 | Powergenix Systems, Inc. | Nickel zinc battery design |
| US8048566B2 (en) * | 2008-02-07 | 2011-11-01 | Powergenix Systems, Inc. | Nickel hydroxide electrode for rechargeable batteries |
| KR101839158B1 (ko) * | 2009-10-13 | 2018-03-15 | 파워지닉스 시스템즈, 인코포레이티드 | 양성 캔을 포함하는 원통형 니켈-아연 전지 |
| US9425456B2 (en) * | 2012-02-07 | 2016-08-23 | Ovonic Battery Company, Inc. | Rechargeable battery cell with improved high temperature performance |
| US8703336B2 (en) | 2012-03-21 | 2014-04-22 | The Gillette Company | Metal-doped nickel oxide active materials |
| US9028564B2 (en) | 2012-03-21 | 2015-05-12 | The Gillette Company | Methods of making metal-doped nickel oxide active materials |
| US9570741B2 (en) | 2012-03-21 | 2017-02-14 | Duracell U.S. Operations, Inc. | Metal-doped nickel oxide active materials |
| US9248501B1 (en) * | 2012-11-05 | 2016-02-02 | The United States Of America As Represented By The Secretary Of The Navy | Method for additive manufacturing using pH and potential controlled powder solidification |
| CN104995782A (zh) | 2013-01-14 | 2015-10-21 | 鲍尔热尼系统公司 | 用于可再充电碱性蓄电池的膏状氢氧化镍电极和添加剂 |
| CN103159264B (zh) * | 2013-03-18 | 2015-05-20 | 昆明理工大学 | 一种纯固相法制备锂离子电池正极材料nca的方法 |
| US10407790B1 (en) | 2015-03-23 | 2019-09-10 | The Government Of The United States Of America, As Represented By The Secretary Of The Navy | Method of electrochemically-driven coated material synthesis |
| KR101589471B1 (ko) * | 2015-06-02 | 2016-01-28 | 에스티비 주식회사 | 에멀션 처리된 활물질을 이용한 극판과 이를 포함하는 Ni-MH 전지 |
| FR3070544B1 (fr) * | 2017-08-30 | 2023-01-27 | Centre Nat Rech Scient | Electrode a reseau multiple de collecte de courant |
| US11437655B2 (en) * | 2018-03-15 | 2022-09-06 | Energizer Brands, Llc | Long-chain surfactants for improving battery performance |
| CN110444821B (zh) * | 2019-08-01 | 2022-06-03 | 武汉理工大学 | 基于三维电极的柔性微型碱性锌电池的制备方法 |
| JP7735277B2 (ja) | 2020-01-23 | 2025-09-08 | デュラセル、ユーエス、オペレーションズ、インコーポレーテッド | アルカリニッケル酸化物の酸化的脱リチウム化 |
| US20230074320A1 (en) * | 2021-09-06 | 2023-03-09 | Mohammad Shafikul Huq | System and method for recharagable battery module by combining cells of varying sizes |
| CN115020699B (zh) * | 2022-08-09 | 2022-12-13 | 国联汽车动力电池研究院有限责任公司 | 一种低钴或无钴正极材料及其制备方法和应用 |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1223014A (en) * | 1967-02-28 | 1971-02-17 | Int Nickel Ltd | Bipolar plates for nickel-zinc accumulators |
| US3961985A (en) * | 1973-03-10 | 1976-06-08 | Tokyo Shibaura Electric Co., Ltd. | Nickel-zinc cell |
| US3870564A (en) * | 1973-03-30 | 1975-03-11 | Tokyo Shibaura Electric Co | Alkaline cell |
| JPS5461B2 (enExample) * | 1973-11-21 | 1979-01-05 | ||
| CS167146B1 (enExample) * | 1974-05-21 | 1976-04-29 | ||
| DE2452064C3 (de) * | 1974-11-02 | 1981-06-19 | Varta Batterie Ag, 3000 Hannover | Gasdicht verschlossener alkalischer Akkumulator |
| JPS54163324A (en) | 1978-06-15 | 1979-12-25 | Yardney Electric Corp | Activated material for pressswrought nickel electrode |
| JPS5629345A (en) | 1979-08-18 | 1981-03-24 | Mitsubishi Electric Corp | Division of wafer |
| US5168018A (en) | 1990-05-17 | 1992-12-01 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing zinc-alkaline batteries |
| US5215836A (en) * | 1991-07-18 | 1993-06-01 | Electrochimica Corporation | Alkaline galvanic cells |
| US5523182A (en) * | 1992-11-12 | 1996-06-04 | Ovonic Battery Company, Inc. | Enhanced nickel hydroxide positive electrode materials for alkaline rechargeable electrochemical cells |
| JPH0737609A (ja) | 1993-07-23 | 1995-02-07 | Matsushita Electric Ind Co Ltd | アルカリ蓄電池 |
| US5556720A (en) | 1994-08-18 | 1996-09-17 | Energy Research Corporation | Sealed zinc secondary battery and zinc electrode therefor |
| JP3527594B2 (ja) * | 1995-11-16 | 2004-05-17 | 松下電器産業株式会社 | アルカリ蓄電池およびその製造法 |
| US6040007A (en) * | 1996-06-19 | 2000-03-21 | Tanaka Chemical Corporation | Nickel hydroxide particles having an α- or β-cobalt hydroxide coating layer for use in alkali batteries and a process for producing the nickel hydroxide |
| JP3246345B2 (ja) * | 1996-08-21 | 2002-01-15 | 松下電器産業株式会社 | アルカリ蓄電池用ニッケル正極とこれを用いたニッケル・水素蓄電池 |
| US6261720B1 (en) | 1996-09-20 | 2001-07-17 | Matsushita Electric Industrial Co., Ltd. | Positive electrode active material for alkaline storage batteries |
| US7393612B2 (en) * | 1996-12-17 | 2008-07-01 | Toshiba Battery Co., Ltd. | Electrodes, alkaline secondary battery, and method for manufacturing alkaline secondary battery |
| US6566008B2 (en) * | 1997-01-30 | 2003-05-20 | Sanyo Electric Co., Ltd. | Sealed alkaline storage battery |
| JP3205276B2 (ja) * | 1997-02-14 | 2001-09-04 | 古河電池株式会社 | アルカリ二次電池用正極活物質の製造法、ペースト式ニッケル極、アルカリ二次電池並びにその製造法 |
| JP2953463B2 (ja) | 1997-09-10 | 1999-09-27 | 松下電器産業株式会社 | アルカリ蓄電池用正極活物質とその製造方法 |
| JP2947284B2 (ja) * | 1997-12-26 | 1999-09-13 | 松下電器産業株式会社 | アルカリ蓄電池用非焼結式正極およびこれを用いたアルカリ蓄電池 |
| JPH11238508A (ja) * | 1998-02-23 | 1999-08-31 | Matsushita Electric Ind Co Ltd | アルカリ蓄電池用ニッケル正極および製造方法 |
| JP4747233B2 (ja) | 1998-04-07 | 2011-08-17 | 株式会社Ｇｓユアサ | アルカリ蓄電池 |
| JP2000058062A (ja) | 1998-06-05 | 2000-02-25 | Japan Storage Battery Co Ltd | アルカリ蓄電池用非焼結式ニッケル正極 |
| JP2000003707A (ja) * | 1998-06-16 | 2000-01-07 | Matsushita Electric Ind Co Ltd | アルカリ蓄電池 |
| US6436575B1 (en) * | 1998-11-13 | 2002-08-20 | Moltech Power Systems, Inc. | Pasted positive electrode and process for its production |
| FR2788887B1 (fr) * | 1999-01-27 | 2001-04-20 | Conseil Et De Prospective Scie | Generateurs electrochimiques secondaires alcalins a anode de zinc |
| JP3429741B2 (ja) * | 2000-03-24 | 2003-07-22 | 松下電器産業株式会社 | アルカリ蓄電池用ペースト型正極およびニッケル水素蓄電池 |
| JP2001357845A (ja) * | 2000-06-16 | 2001-12-26 | Canon Inc | ニッケル系二次電池及び該二次電池の製造方法 |
| DE60143829D1 (de) | 2000-06-30 | 2011-02-24 | Sanyo Electric Co | Nickelelektrode für alkalische Speicherbatterie und alkalische Speicherbatterie |
| JP3558590B2 (ja) * | 2000-07-14 | 2004-08-25 | 松下電器産業株式会社 | アルカリ蓄電池用正極活物質の製造方法 |
| US7829221B2 (en) * | 2000-11-10 | 2010-11-09 | Powergenix Systems, Inc. | Cobalt containing positive electrode formulation for a nickel-zinc cell |
| CA2325640A1 (en) * | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Positive and negative interactive electrode formulation for a zinc-containing cell having an alkaline elelctrolyte |
| JP4608128B2 (ja) | 2000-11-15 | 2011-01-05 | パナソニック株式会社 | コバルト化合物およびその製造方法ならびにそれを用いたアルカリ蓄電池用正極板およびアルカリ蓄電池 |
| CN1307739C (zh) * | 2001-03-05 | 2007-03-28 | 株式会社汤浅 | 镍氢电池的制造方法 |
| EP1371103A2 (en) * | 2001-03-15 | 2003-12-17 | Jeffrey Phillips | Methods for production of zinc oxide electrodes for alkaline batteries |
| US6617072B2 (en) * | 2001-11-27 | 2003-09-09 | Ovonic Battery Company, Inc. | Positive active electrode composition with graphite additive |
| CN100416891C (zh) * | 2002-07-25 | 2008-09-03 | 株式会社东芝 | 非水电解质二次电池 |
| EP1542298A4 (en) * | 2002-08-30 | 2008-02-27 | Toshiba Battery | PRIMARY CELL WITH POSITIVE ELECTRODE MATERIAL IN COMPOUND BASED ON NICKEL |
| CN1187270C (zh) * | 2003-07-01 | 2005-02-02 | 福建南平南孚電池有限公司 | 羟基氧化镍的制备方法 |
| JP2005056733A (ja) | 2003-08-06 | 2005-03-03 | Matsushita Electric Ind Co Ltd | アルカリ電池、ならびにアルカリ電池用正極活物質の製造方法 |
| EP1699099A4 (en) | 2003-11-06 | 2008-12-24 | Panasonic Corp | ALKALIBATTERY AND MATERIAL FOR THE POSITIVE ELECTRODE OF AN ALKALIBATTERY |
| US8048566B2 (en) * | 2008-02-07 | 2011-11-01 | Powergenix Systems, Inc. | Nickel hydroxide electrode for rechargeable batteries |
-
2009
- 2009-02-04 US US12/365,658 patent/US8043748B2/en active Active
- 2009-02-05 JP JP2010546004A patent/JP5719175B2/ja active Active
- 2009-02-05 CN CN200980104394.2A patent/CN101939863B/zh active Active
- 2009-02-05 WO PCT/US2009/033265 patent/WO2009100248A1/en not_active Ceased
- 2009-02-05 EP EP09708105A patent/EP2250691A1/en not_active Withdrawn
- 2009-02-05 KR KR1020107017542A patent/KR20100114516A/ko not_active Ceased
-
2011
- 2011-09-30 US US13/250,217 patent/US20120018669A1/en not_active Abandoned
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