JP2011088958A - 表面保護用粘着シート - Google Patents
表面保護用粘着シート Download PDFInfo
- Publication number
- JP2011088958A JP2011088958A JP2009241717A JP2009241717A JP2011088958A JP 2011088958 A JP2011088958 A JP 2011088958A JP 2009241717 A JP2009241717 A JP 2009241717A JP 2009241717 A JP2009241717 A JP 2009241717A JP 2011088958 A JP2011088958 A JP 2011088958A
- Authority
- JP
- Japan
- Prior art keywords
- pressure
- sensitive adhesive
- polyester
- adhesive sheet
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 159
- 229920000728 polyester Polymers 0.000 claims abstract description 177
- 239000002253 acid Substances 0.000 claims abstract description 58
- 239000000203 mixture Substances 0.000 claims abstract description 57
- 239000010410 layer Substances 0.000 claims abstract description 51
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 34
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical group CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 18
- 239000000539 dimer Substances 0.000 claims abstract description 16
- 125000003827 glycol group Chemical group 0.000 claims abstract description 14
- 230000009477 glass transition Effects 0.000 claims abstract description 8
- 230000001070 adhesive effect Effects 0.000 claims description 73
- 239000000853 adhesive Substances 0.000 claims description 60
- 125000001931 aliphatic group Chemical group 0.000 claims description 16
- 238000003860 storage Methods 0.000 claims description 11
- 150000007513 acids Chemical class 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 24
- 239000000758 substrate Substances 0.000 abstract description 4
- 230000003373 anti-fouling effect Effects 0.000 abstract description 2
- 230000000630 rising effect Effects 0.000 abstract 1
- -1 D-lactide Chemical compound 0.000 description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 30
- 229920005989 resin Polymers 0.000 description 28
- 239000011347 resin Substances 0.000 description 28
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 17
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 17
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 14
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 239000005056 polyisocyanate Substances 0.000 description 13
- 229920001228 polyisocyanate Polymers 0.000 description 13
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 230000007423 decrease Effects 0.000 description 11
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 10
- 239000002028 Biomass Substances 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 239000012790 adhesive layer Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 150000002430 hydrocarbons Chemical group 0.000 description 7
- 229960000448 lactic acid Drugs 0.000 description 7
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 7
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 7
- 239000002685 polymerization catalyst Substances 0.000 description 7
- 230000001681 protective effect Effects 0.000 description 7
- 150000003505 terpenes Chemical class 0.000 description 7
- 235000007586 terpenes Nutrition 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 239000004310 lactic acid Substances 0.000 description 6
- 235000014655 lactic acid Nutrition 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 6
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 6
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 5
- 239000012948 isocyanate Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 238000007259 addition reaction Methods 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000002723 alicyclic group Chemical group 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- 239000013638 trimer Substances 0.000 description 4
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 3
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920000747 poly(lactic acid) Polymers 0.000 description 3
- 239000004626 polylactic acid Substances 0.000 description 3
- 229920006381 polylactic acid film Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 2
- JVYDLYGCSIHCMR-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanoic acid Chemical compound CCC(CO)(CO)C(O)=O JVYDLYGCSIHCMR-UHFFFAOYSA-N 0.000 description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 2
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 description 2
- YWVFNWVZBAWOOY-UHFFFAOYSA-N 4-methylcyclohexane-1,2-dicarboxylic acid Chemical compound CC1CCC(C(O)=O)C(C(O)=O)C1 YWVFNWVZBAWOOY-UHFFFAOYSA-N 0.000 description 2
- 229920006353 Acrylite® Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 229930182843 D-Lactic acid Natural products 0.000 description 2
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229940022769 d- lactic acid Drugs 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229920000587 hyperbranched polymer Polymers 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- VAWFFNJAPKXVPH-UHFFFAOYSA-N naphthalene-1,6-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC2=CC(C(=O)O)=CC=C21 VAWFFNJAPKXVPH-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000582 polyisocyanurate Polymers 0.000 description 2
- 239000011495 polyisocyanurate Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- JJTUDXZGHPGLLC-ZXZARUISSA-N (3r,6s)-3,6-dimethyl-1,4-dioxane-2,5-dione Chemical compound C[C@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-ZXZARUISSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical class O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- DTZHXCBUWSTOPO-UHFFFAOYSA-N 1-isocyanato-4-[(4-isocyanato-3-methylphenyl)methyl]-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(CC=2C=C(C)C(N=C=O)=CC=2)=C1 DTZHXCBUWSTOPO-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- LHOBKFFUEUQRQX-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,5-diol Chemical compound OCC(C)CC(C)(C)CO LHOBKFFUEUQRQX-UHFFFAOYSA-N 0.000 description 1
- IVIDDMGBRCPGLJ-UHFFFAOYSA-N 2,3-bis(oxiran-2-ylmethoxy)propan-1-ol Chemical compound C1OC1COC(CO)COCC1CO1 IVIDDMGBRCPGLJ-UHFFFAOYSA-N 0.000 description 1
- OJRJDENLRJHEJO-UHFFFAOYSA-N 2,4-diethylpentane-1,5-diol Chemical compound CCC(CO)CC(CC)CO OJRJDENLRJHEJO-UHFFFAOYSA-N 0.000 description 1
- ZRPKEUVFESZUKX-UHFFFAOYSA-N 2-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=CC=C1C(O)=O ZRPKEUVFESZUKX-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- LBTDHCQNAQRHCE-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)cyclohexyl]oxyethanol Chemical compound OCCOC1CCC(OCCO)CC1 LBTDHCQNAQRHCE-UHFFFAOYSA-N 0.000 description 1
- MUHNBZQOTATUGE-UHFFFAOYSA-N 2-[4-[2-[4-(2-hydroxyethoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxyethanol Chemical compound C1CC(OCCO)CCC1C(C)(C)C1CCC(OCCO)CC1 MUHNBZQOTATUGE-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 1
- QJQZRLXDLORINA-UHFFFAOYSA-N 2-cyclohexylethanol Chemical compound OCCC1CCCCC1 QJQZRLXDLORINA-UHFFFAOYSA-N 0.000 description 1
- WVQHODUGKTXKQF-UHFFFAOYSA-N 2-ethyl-2-methylhexane-1,1-diol Chemical compound CCCCC(C)(CC)C(O)O WVQHODUGKTXKQF-UHFFFAOYSA-N 0.000 description 1
- BRSICLJIUFXBCB-UHFFFAOYSA-N 2-methyloctane-1,1-diol Chemical compound CCCCCCC(C)C(O)O BRSICLJIUFXBCB-UHFFFAOYSA-N 0.000 description 1
- 125000003504 2-oxazolinyl group Chemical class O1C(=NCC1)* 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JOIXGDNGAXHWPO-UHFFFAOYSA-N 3,5-dihydroxycyclohexane-1-carboxylic acid Chemical compound OC1CC(O)CC(C(O)=O)C1 JOIXGDNGAXHWPO-UHFFFAOYSA-N 0.000 description 1
- NILOCPBMTIJETB-UHFFFAOYSA-N 3-[4-(3-hydroxypropyl)cyclohexyl]propan-1-ol Chemical compound OCCCC1CCC(CCCO)CC1 NILOCPBMTIJETB-UHFFFAOYSA-N 0.000 description 1
- FDSDHQKRZOBZLX-UHFFFAOYSA-N 3-ethylpentane-1,5-diol Chemical compound OCCC(CC)CCO FDSDHQKRZOBZLX-UHFFFAOYSA-N 0.000 description 1
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 description 1
- DBXBTMSZEOQQDU-UHFFFAOYSA-N 3-hydroxyisobutyric acid Chemical compound OCC(C)C(O)=O DBXBTMSZEOQQDU-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- ZJFCVUTYZHUNSW-UHFFFAOYSA-N 3-octadecyloxolane-2,5-dione Chemical compound CCCCCCCCCCCCCCCCCCC1CC(=O)OC1=O ZJFCVUTYZHUNSW-UHFFFAOYSA-N 0.000 description 1
- ZFXXWASURZZDSI-UHFFFAOYSA-N 3-octylpentane-1,5-diol Chemical compound CCCCCCCCC(CCO)CCO ZFXXWASURZZDSI-UHFFFAOYSA-N 0.000 description 1
- WBJFJKPHFOAHPA-UHFFFAOYSA-N 3-propylpentane-1,5-diol Chemical compound CCCC(CCO)CCO WBJFJKPHFOAHPA-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- WXQZLPFNTPKVJM-UHFFFAOYSA-N 4-[(4-hydroxycyclohexyl)methyl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1CC1CCC(O)CC1 WXQZLPFNTPKVJM-UHFFFAOYSA-N 0.000 description 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 description 1
- WPSWDCBWMRJJED-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;oxirane Chemical compound C1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 WPSWDCBWMRJJED-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- JJTUDXZGHPGLLC-IMJSIDKUSA-N 4511-42-6 Chemical compound C[C@@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-IMJSIDKUSA-N 0.000 description 1
- HWIOZYQYVYQVSP-UHFFFAOYSA-N 5-(2-hydroxyethoxy)benzene-1,3-dicarboxylic acid Chemical compound OCCOC1=CC(C(O)=O)=CC(C(O)=O)=C1 HWIOZYQYVYQVSP-UHFFFAOYSA-N 0.000 description 1
- ZCBVLVPFQVVJHY-UHFFFAOYSA-N 5-(2-hydroxyethoxy)cyclohexane-1,3-dicarboxylic acid Chemical compound OCCOC1CC(C(O)=O)CC(C(O)=O)C1 ZCBVLVPFQVVJHY-UHFFFAOYSA-N 0.000 description 1
- QDSZMNWAEWRDKM-UHFFFAOYSA-N 5-acetyloxybenzene-1,3-dicarboxylic acid Chemical compound CC(=O)OC1=CC(C(O)=O)=CC(C(O)=O)=C1 QDSZMNWAEWRDKM-UHFFFAOYSA-N 0.000 description 1
- FAXWWNPNOMJCBJ-UHFFFAOYSA-N 5-hydroxycyclohexane-1,3-dicarboxylic acid Chemical compound OC1CC(C(O)=O)CC(C(O)=O)C1 FAXWWNPNOMJCBJ-UHFFFAOYSA-N 0.000 description 1
- JVERADGGGBYHNP-UHFFFAOYSA-N 5-phenylbenzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(=O)O)=CC(C=2C=CC=CC=2)=C1C(O)=O JVERADGGGBYHNP-UHFFFAOYSA-N 0.000 description 1
- XVMSFILGAMDHEY-UHFFFAOYSA-N 6-(4-aminophenyl)sulfonylpyridin-3-amine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=N1 XVMSFILGAMDHEY-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- IIGAAOXXRKTFAM-UHFFFAOYSA-N N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C Chemical class N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C IIGAAOXXRKTFAM-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 1
- XDODWINGEHBYRT-UHFFFAOYSA-N [2-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCCC1CO XDODWINGEHBYRT-UHFFFAOYSA-N 0.000 description 1
- LUSFFPXRDZKBMF-UHFFFAOYSA-N [3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCC(CO)C1 LUSFFPXRDZKBMF-UHFFFAOYSA-N 0.000 description 1
- MQEJZVCGHIZWAB-UHFFFAOYSA-N [4-(hydroxymethoxy)cyclohexyl]oxymethanol Chemical compound OCOC1CCC(OCO)CC1 MQEJZVCGHIZWAB-UHFFFAOYSA-N 0.000 description 1
- YSJLUXHGNVDCMD-UHFFFAOYSA-N [4-[2-[4-(hydroxymethoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxymethanol Chemical compound C1CC(OCO)CCC1C(C)(C)C1CCC(OCO)CC1 YSJLUXHGNVDCMD-UHFFFAOYSA-N 0.000 description 1
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical class OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001541 aziridines Chemical class 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- GWZCCUDJHOGOSO-UHFFFAOYSA-N diphenic acid Chemical compound OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O GWZCCUDJHOGOSO-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- VLTJQUYPGHDYFR-UHFFFAOYSA-N methyl 3,5-bis(2-hydroxyethoxy)benzoate Chemical compound COC(=O)C1=CC(OCCO)=CC(OCCO)=C1 VLTJQUYPGHDYFR-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- JAYXSROKFZAHRQ-UHFFFAOYSA-N n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC=CC=1)CC1CO1 JAYXSROKFZAHRQ-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- YLLIGHVCTUPGEH-UHFFFAOYSA-M potassium;ethanol;hydroxide Chemical compound [OH-].[K+].CCO YLLIGHVCTUPGEH-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- 229940057402 undecyl alcohol Drugs 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
- C08G18/428—Lactides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/40—Compositions for pressure-sensitive adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2896—Adhesive compositions including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
【解決手段】少なくとも、乳酸単位、二塩基酸単位、及びグリコール単位を含有するポリエステル、及び架橋剤を含有するポリエステル系粘着剤組成物より形成される粘着剤層を、支持体の少なくとも片面に設けた表面保護用粘着シートであって、前記二塩基酸単位が、ダイマー酸を含有し、前記ポリエステルが、示差走査熱量計を用いて昇温速度20℃/分で測定した際のガラス転移温度が−70〜−20℃であり、重量平均分子量が2万〜20万であり、前記ポリエステル系粘着剤組成物の水酸基価が、20〜60mgKOH/gであり、前記粘着剤層のゲル分率が、85〜99重量%であることを特徴とする表面保護用粘着シート。
【選択図】なし
Description
1,2−シクロヘキシルジイソシアネート、1,3−シクロヘキシルジイソシアネート、1,4−シクロヘキシルジイソシアネートなどのシクロヘキシルジイソシアネート、1,2−シクロペンチルジイソシアネート、1,3−シクロペンチルジイソシアネートなどのシクロペンチルジイソシアネート、水素添加キシリレンジイソシアネート、水素添加トリレンジイソシアネート、水素添加ジフェニルメタンジイソシアネート、水素添加テトラメチルキシレンジイソシアネート、4,4’−ジシクヘキシルメタンジイソシアネートなどが挙げられる。
撹拌機、温度計、流出用冷却機を装備した反応缶内に、ダイマー酸86部、セバシン酸10部、1,3−プロピレングリコール30部、トリメチロールプロパン0.4部、DL−ラクチド50部、及び重合触媒であるテトラブチルチタネートを0.014部、オクチル酸錫を0.014部配合し、窒素雰囲気の常圧下で、5時間かけて250℃まで昇温させた後、1時間反応させ、留出する水を系外に除去し、エステル化反応を行った。更に、30分かけて、10mmHgまで減圧し、250℃で30分間、初期重合を行った。更に、1mmHgまで30分間かけて減圧し、250℃で、後期重合を行い、ポリエステルAを得た。
ダイマー酸100部、セバシン酸5.6部、ネオペンチルグリコール20部、トリメチロールプロパン1.0重量部、DL−ラクチド21部、および重合触媒であるテトラブチルチタネートを0.014部、オクチル酸錫を0.014部を用いて、ポリエステルAと同様にして、ポリエステルBを得た。
ダイマー酸100部、セバシン酸11部、1,3−プロピレングリコール17部、トリメチロールプロパン10.8重量部、および重合触媒であるテトラブチルチタネートを0.014部、オクチル酸錫を0.014部を用いて、ポリエステルAと同様にして、ポリエステルCを得た。
撹拌機、温度計、流出用冷却機を装備した反応缶内に、DL−ラクチド100部、ε−カプロラクトン53部、ネオペンチルグリコール0.2部、及び重合触媒であるテトラブチルチタネートを0.010部、オクチル酸錫を0.010部配合し、窒素雰囲気の常圧下で、5時間かけて180℃まで昇温させた後、更に3時間反応させた。ついで、30分かけて、10mmHgまで減圧し、更に1mmHgまで30分間かけて減圧し、180℃で重合を行いながら、残留ラクチドの除去も行い、ポリエステルDを得た。
DL−ラクチド100部、ε−カプロラクトン118部、エチレングリコール0.2部、及び重合触媒であるテトラブチルチタネートを0.010部、オクチル酸錫を0.010部用いて、ポリエステルDと同様にして、ポリエステルEを得た。
<実施例1>
ポリエステルAを92部、乾燥した分岐型ポリエステルオリゴマー(Perstorp社製、ハイパーブランチポリマー Boltorn H20、水酸基価500mgKOH/g、重量平均分子量2100)8部を、メチルエチルケトン(MEK)117部と酢酸エチル117部の混合溶媒に溶解した後、架橋剤として、ポリイソシアヌレート(日本ポリウレタン社製、コロネートHK)10部、触媒としてジオクチルスズジウラレート(東京ファインケミカル社製、エンビライザーOL−1)0.1部を配合し、この混合物を乾燥後の厚みが5μmになるように、支持体としての厚さが25μmのポリ乳酸フィルム(ユニチカ社製「テラマック」)上に塗布し、80℃で3分間乾燥後、剥離処理したポリエチレンテレフタレートフィルムの剥離処理面に組成物層を貼り合わせ、更に50℃で5日間放置し、粘着シートを得た。
分岐型ポリエステルオリゴマー(Perstorp社製、ハイパーブランチポリマー Boltorn H40、水酸基価490mgKOH/g、重量平均分子量5100)8部配合した以外は、実施例1と同様の方法で、粘着シートを得た。
ポリエステルAの代わりに、ポリエステルBを92部配合した以外は、実施例1と同様の方法で、粘着シートを得た。
ポリエステルAを100部配合し、分岐型ポリエステルオリゴマーを配合しなかった以外は、実施例1と同様の方法にて、粘着シートを得た。
ポリエステルAの代わりにポリエステルDを100部配合し、触媒を配合しなかった以外は、比較例1と同様の方法にて、粘着シートを得た。
ポリエステルAの代わりにポリエステルEを100部配合した以外は、比較例1と同様の方法にて、粘着シートを得た。
ポリエステルAの代わりにポリエステルCを92部配合した以外は、実施例1と同様の方法にて、粘着シートを得た。
ポリエステルをクロロホルムDに溶解し、ヴァリアン社製核磁気共鳴分析計(NMR)400−MRを用いて、1H−NMR分析を行うことにより、ポリエステルの組成を解析した。
数平均分子量(Mn)及び重量平均分子量(Mw)は、ポリエステル、又は、ポリエステル及び分岐型ポリエステルオリゴマーの混合物約0.2gをシャーレに採取し、120℃×2時間、乾燥させ溶剤を除去した。ついで、前記シャーレ上のポリエステル層(又はポリエステル及び分岐型ポリエステルオリゴマーの混合物層)0.01gを秤量して、テトラヒドロフラン(THF)10gに添加し、24時間放置して溶解した。この溶液をゲル・パーミエイション・クロマトグラフィ(GPC)法を用い、標準ポリスチレンにより作成した検量線から、それぞれの分子量を測定した。
(測定条件)
装置名:東ソー社製、HLC−8220GPC
サンプル濃度:0.1重量%(THF溶液)
サンプル注入量:20μl
溶離液:THF
流速:0.300ml/min
測定(カラム)温度:40℃
カラム: サンプルカラム;TSKguardcolumn SuperHZ−L(1本)+TSKgel SuperHZM−M(2本)、リファレンスカラム;TSKgel SuperH−RC(1本)、東ソー製
検出器:示差屈折計(RI)
示差走査熱量計(装置名:DSC−220、セイコーインスツルメント社製)を用い、測定条件として、測定試料5mgをアルミパンに入れ、温度条件:−120〜150℃、昇温速度:20℃/分にて測定し、ガラス転移温度(Tg:℃)を測定した。
250ml三角フラスコに試料として、ポリエステル又はポリエステル系粘着剤組成物を約0.5g採取し、重量を測定した。ついで、無水酢酸と無水ピリジンを1:10(質量比)に調整・混合した溶液20.00mlを採取し、前記三角フラスコに入れ、冷却器を取り付けて、20分間、攪拌しながら還流させた後、室温まで冷却した。更に、前記三角フラスコ内に冷却器を通じてアセトン20ml、蒸留水20mlを加えた。これにフェノールフタレイン指示薬を入れて、1.00N(規定)の水酸化ナトリウム水溶液により、滴定した。なお、別途測定したブランク(試料を含まない)の測定結果を差し引き、水酸基価(mgKOH/g)を算出した。
試料として、ポリエステル又はポリエステル系粘着剤組成物0.2gを20mlのクロロホルムに溶解し、指示薬としてフェノールフタレインを用いて、0.1N(規定)の水酸化カリウムエタノール溶液で滴定し、酸価(mgKOH/g)を算出した。
使用原料全体の重量に対する植物由来の使用原料の重量割合を算出したものを、バイオマス度(%)として、評価した。
バイオマス度(%)=100×(植物由来の使用原料の重量)/(使用原料全体の重量)
剥離ライナー(三菱化学ポリエステル社製、MRF38、厚さ38μm)上に、粘着剤層を形成し、前記粘着剤層を厚さ3mm、直径8mmφに調製し、これを試験用サンプルとした。次いで、レオメトリックス社製粘弾性試験機ARESを用い直径7. 9mmのパラレルプレート(せん断試験用)で試験用サンプルを挟み込み、周波数1Hzの周波数のせん断歪みを与え、23℃における貯蔵弾性率(G’:Pa)を測定した。
ポリ乳酸フィルム(ユニチカ社製、テラマット、厚さ25μm)上に、厚さ50μmに調製した粘着剤層を貼り合せ、縦100mm×横20mmの試験用サンプルを作製した。次いで、前記試験用サンプルを、アクリル板(三菱レイヨン社製、アクリライト、厚さ2mm)上に、2kg圧で、ローラーで1往復して貼りあわせ(圧着して)、JIS C2107に準拠して引張速度300mm/minで、粘着力(N/20mm)を測定した。なお、23℃におけるアクリル板に対する剥離角度180°、引張速度300mm/min.の初期粘着力が、0.1〜0.5N/20mmであることが好ましく、より好ましくは、0.2〜0.4N/20mmである。初期粘着力が0.1N/20mm未満であると、被着体に対する粘着力が十分ではなく、使用中に剥離する恐れがあり、一方、0.5N/20mmを超えると、粘着力が高くなりすぎて、表面保護用粘着シートとして使用後、剥離する際に被着体に糊残りが生じたり、支持体(基材)が破損する恐れがあり好ましくない。
前記初期粘着力の際と同様にして得られた試験用サンプルを、40℃で30日保存した後、更に23℃で6時間静置後、前記初期粘着力の際と同様の方法にて、加熱保存後の粘着力を測定した。前記粘着力としては、0.1〜1.0N/20mmであることが好ましく、より好ましくは、0.3〜0.5N/20mmである。粘着力が0.1N/20mm未満であると、粘着力が十分ではなく、使用中に剥離する恐れがあり、一方、1.0N/20mmを超えると、表面保護用粘着シートとして使用後、剥離する際に被着体に糊残りが生じたり、支持体(基材)が破損する恐れがあり好ましくない。
ポリ乳酸フィルム(ユニチカ社製、テラマット、厚さ25μm)に、粘着剤組成物溶液を塗布乾燥して、厚さ5μmの粘着剤層を形成して粘着シートとし、これを10mm×30mmにカットした黒色のアクリル板(三菱レイヨン社製、アクリライト(黒)、厚さ2 mm)に、2kg圧のラミネータに1回通して、貼り合せて(圧着して)、試験用サンプルとした。前記試験用サンプルを、80℃雰囲気下で3日間放置後、23℃雰囲気下で4時間放置後、手で試料を剥離し、暗室内で粘着シートを剥離した後の被着体に、蛍光灯を照らして、目視にて、被着体表面の表面汚染の有無を確認した。
実施例及び比較例で得られた粘着シート(粘着剤層の厚さは50μm)を5cm×5cm角に切り出した。切り出したサンプルを、重さがわかっているテフロン(登録商標)シートで包み、重量を秤量し、トルエン中に23℃で7日間放置して、サンプル中のゾル分を抽出した。その後、120℃で2時間乾燥し、乾燥後の重量を秤量した。ゲル分率を下記の式にて算出した。
ゲル分率(%)=(乾燥後の重量−テフロンシート重量)/(乾燥前の重量−テフロンシート重量)×100
Claims (10)
- 少なくとも、乳酸単位、二塩基酸単位、及びグリコール単位を含有するポリエステル、及び架橋剤を含有するポリエステル系粘着剤組成物より形成される粘着剤層を、支持体の少なくとも片面に設けた表面保護用粘着シートであって、
前記二塩基酸単位が、ダイマー酸を含有し、
前記ポリエステルが、示差走査熱量計を用いて昇温速度20℃/分で測定した際のガラス転移温度が−70〜−20℃であり、重量平均分子量が2万〜20万であり、
前記ポリエステル系粘着剤組成物の水酸基価が、20〜60mgKOH/gであり、
前記粘着剤層のゲル分率が、85〜99重量%であることを特徴とする表面保護用粘着シート。 - 前記ポリエステルが、前記乳酸単位を10〜50モル%含有し、前記乳酸単位以外の成分を50〜90モル%含有し、
前記二塩基酸単位とグリコール単位のモル比が、1:0.8〜1:1.2であることを特徴とする請求項1記載の表面保護用粘着シート。 - 更に、前記二塩基酸単位が、ダイマー酸以外の脂肪族二塩基酸を含有することを特徴とする請求項1又は2記載の表面保護用粘着シート。
- 前記ポリエステルが、前記乳酸単位、二塩基酸単位、及びグリコール単位以外の成分として、3官能以上のカルボン酸及び/又はポリオールを含有し、
前記ポリエステルの分散度(Mw/Mn)が、2.5〜10.0であることを特徴とする請求項1〜3のいずれかに記載の表面保護用粘着シート。 - 前記ポリエステルの水酸基価が、2〜50mgKOH/gであることを特徴とする請求項1〜4のいずれかに記載の表面保護用粘着シート。
- 前記ポリエステル系粘着剤組成物が、更に、水酸基価が100〜1000mgKOH/gである分岐型ポリエステルオリゴマーを含有し、
前記ポリエステル50〜99重量部に対して、前記分岐型ポリエステルオリゴマーを1〜50重量部含有することを特徴とする請求項1〜5のいずれかに記載の表面保護用粘着シート。 - 前記架橋剤が、多価イソシアヌレートであることを特徴とする請求項1〜6のいずれかに記載の表面保護用粘着シート。
- 前記粘着剤層の貯蔵弾性率が、動的粘弾性測定装置を用いて、23℃で周波数1Hzの条件下で測定した際に、1×104〜1×107Paであることを特徴とする請求項1〜7のいずれかに記載の表面保護用粘着シート。
- 23℃におけるアクリル板に対する剥離角度180°、引張速度300mm/min.の初期粘着力が、0.1〜0.5N/20mmであり、
40℃で30日保存後の粘着力が、0.1〜1.0N/20mmであることを特徴とする請求項1〜8のいずれかに記載の表面保護用粘着シート。 - 前記支持体が、生分解性であることを特徴とする請求項1〜9のいずれかに記載の表面保護用粘着シート。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009241717A JP5519996B2 (ja) | 2009-10-20 | 2009-10-20 | 表面保護用粘着シート |
CN2010800425694A CN102575132B (zh) | 2009-10-20 | 2010-10-20 | 表面保护用粘合片 |
US13/502,146 US8962136B2 (en) | 2009-10-20 | 2010-10-20 | Pressure-sensitive adhesive sheet for surface protection |
EP10824960.8A EP2492325A4 (en) | 2009-10-20 | 2010-10-20 | PRESSURE-SENSITIVE ADHESIVE SHEET FOR SURFACE PROTECTION |
PCT/JP2010/068450 WO2011049111A1 (ja) | 2009-10-20 | 2010-10-20 | 表面保護用粘着シート |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009241717A JP5519996B2 (ja) | 2009-10-20 | 2009-10-20 | 表面保護用粘着シート |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011088958A true JP2011088958A (ja) | 2011-05-06 |
JP5519996B2 JP5519996B2 (ja) | 2014-06-11 |
Family
ID=43900334
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009241717A Active JP5519996B2 (ja) | 2009-10-20 | 2009-10-20 | 表面保護用粘着シート |
Country Status (5)
Country | Link |
---|---|
US (1) | US8962136B2 (ja) |
EP (1) | EP2492325A4 (ja) |
JP (1) | JP5519996B2 (ja) |
CN (1) | CN102575132B (ja) |
WO (1) | WO2011049111A1 (ja) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20160033203A (ko) * | 2013-09-02 | 2016-03-25 | 미쯔이가가꾸가부시끼가이샤 | 적층체 |
JP2016218482A (ja) * | 2016-09-20 | 2016-12-22 | 三菱樹脂株式会社 | 光学部材 |
JP2017016142A (ja) * | 2016-09-20 | 2017-01-19 | 三菱樹脂株式会社 | 光学部材の製造方法 |
JP2018009185A (ja) * | 2017-09-04 | 2018-01-18 | 三菱ケミカル株式会社 | 積層フィルム |
JP2018020569A (ja) * | 2017-08-31 | 2018-02-08 | 三菱ケミカル株式会社 | 積層フィルム |
JP2018123325A (ja) * | 2018-03-02 | 2018-08-09 | 三菱ケミカル株式会社 | 積層ポリエステルフィルム |
WO2018174198A1 (ja) * | 2017-03-24 | 2018-09-27 | 日本合成化学工業株式会社 | 粘着剤組成物、粘着剤及び積層体 |
JP2018159929A (ja) * | 2018-05-08 | 2018-10-11 | 三菱ケミカル株式会社 | 光学部材 |
JP2020122164A (ja) * | 2015-12-22 | 2020-08-13 | 三菱ケミカル株式会社 | ポリエステル系粘着剤組成物、ポリエステル系粘着剤、光学部材用粘着シート、光学部材用基材レス両面粘着シート、粘着剤層付き光学部材、光学積層体 |
JPWO2021117826A1 (ja) * | 2019-12-13 | 2021-06-17 |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5185691B2 (ja) * | 2008-05-21 | 2013-04-17 | 日東電工株式会社 | ポリエステル系マスキングシート |
US9260639B2 (en) * | 2009-12-28 | 2016-02-16 | Nitto Denko Corporation | Polyester adhesive composition |
WO2012090774A1 (ja) * | 2010-12-27 | 2012-07-05 | シャープ株式会社 | 蒸着装置および回収装置 |
JP6081233B2 (ja) | 2012-03-16 | 2017-02-15 | 日東電工株式会社 | 粘着剤組成物、及び、粘着シート |
JP6228738B2 (ja) * | 2012-03-16 | 2017-11-08 | 日東電工株式会社 | 粘着剤組成物、及び、粘着シート |
JP6088291B2 (ja) * | 2012-03-16 | 2017-03-01 | 日東電工株式会社 | 粘着剤組成物、及び、粘着シート |
KR101789896B1 (ko) * | 2013-02-01 | 2017-10-25 | 미쯔이가가꾸가부시끼가이샤 | 표시 장치 및 적층 광학 필름 |
US8940833B2 (en) * | 2013-03-15 | 2015-01-27 | Brady Worldwide, Inc. | Polyester-based, pressure sensitive adhesive |
ES2633189T3 (es) | 2013-07-02 | 2017-09-19 | Nitto Europe N.V | Composición adhesiva insaturada fotocurable de origen biológico |
MX2016005005A (es) | 2013-10-30 | 2016-08-17 | C-Bond Systems Llc | Materiales mejorados, composiciones de tratamiento y laminados del material con nanotubos de carbono. |
JP6396062B2 (ja) * | 2014-04-03 | 2018-09-26 | 日東電工株式会社 | ポリエステル系粘着剤組成物、及び、粘着シート |
EP2957611A1 (en) * | 2014-06-20 | 2015-12-23 | Nitto Denko Corporation | Debondable adhesive composition |
EP2957303A1 (en) | 2014-06-20 | 2015-12-23 | Nitto Denko Corporation | Curable composition and skin adhesive |
JP6645100B2 (ja) * | 2014-10-28 | 2020-02-12 | 東ソー株式会社 | 積層体およびこれよりなる包装体 |
EP3050702A4 (en) * | 2014-12-13 | 2017-10-11 | Mitsubishi Chemical Corporation | Coated film |
WO2017031042A1 (en) | 2015-08-18 | 2017-02-23 | 3M Innovative Properties Company | Chemical-resistant polyester pressure-sensitive adhesive |
JP6800215B2 (ja) | 2015-08-18 | 2020-12-16 | スリーエム イノベイティブ プロパティズ カンパニー | 耐衝撃性ポリエステル感圧接着剤 |
EP3337843B1 (en) | 2015-08-18 | 2022-09-28 | 3M Innovative Properties Company | Polyester compositions |
CN108699395B (zh) | 2015-12-31 | 2022-03-01 | 科腾化学品有限责任公司 | 低聚酯及其组合物 |
US10676651B2 (en) | 2016-03-09 | 2020-06-09 | Mitsubishi Chemical Corporation | Adhesive film and process for producing the same |
WO2017189389A1 (en) | 2016-04-29 | 2017-11-02 | 3M Innovative Properties Company | Adhesive and damping film |
US11453777B2 (en) | 2016-12-16 | 2022-09-27 | Oregon State University | Pressure sensitive adhesives from plant oil-based polyols |
US11247938B2 (en) | 2017-06-10 | 2022-02-15 | C-Bond Systems, Llc | Emulsion compositions and methods for strengthening glass |
CN110387193A (zh) * | 2019-08-09 | 2019-10-29 | 苏州凡赛特材料科技有限公司 | 一种纳米金属导电膜用光学胶黏剂组合物及其胶膜 |
JP6881647B1 (ja) * | 2020-04-17 | 2021-06-02 | 東洋インキScホールディングス株式会社 | 粘着剤組成物および粘着シート |
CN114369418B (zh) * | 2021-12-29 | 2023-11-14 | 苏州世诺新材料科技有限公司 | 显示屏制程用pu保护膜及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1160716A (ja) * | 1996-11-07 | 1999-03-05 | Mitsui Chem Inc | 生分解性接着剤及びその製造方法 |
JP2000160125A (ja) * | 1998-11-27 | 2000-06-13 | Shimadzu Corp | 生体吸収性接着剤および粘着材 |
JP2004231797A (ja) * | 2003-01-30 | 2004-08-19 | Toyobo Co Ltd | 生分解性粘着剤とそのワニスおよび積層体 |
JP2007308626A (ja) * | 2006-05-19 | 2007-11-29 | Nitto Denko Corp | 低透湿性粘着シート |
JP2008013593A (ja) * | 2006-07-03 | 2008-01-24 | Nitto Denko Corp | 透明性に優れるポリエステル系粘着シート |
JP2008195819A (ja) * | 2007-02-13 | 2008-08-28 | Nitto Denko Corp | ポリエステル系粘着剤組成物 |
JP2010037463A (ja) * | 2008-08-06 | 2010-02-18 | Nitto Denko Corp | ポリエステル、ポリエステル組成物、粘着剤組成物、粘着剤層及び粘着シート |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3090221B2 (ja) | 1991-04-30 | 2000-09-18 | 東洋紡績株式会社 | ポリエステル系粘着剤 |
JP3395375B2 (ja) * | 1994-06-24 | 2003-04-14 | 東洋紡績株式会社 | 塗料用樹脂組成物 |
DK0819147T3 (da) | 1995-04-07 | 2003-09-29 | Biotec Biolog Naturverpack | Polymerblanding, som kan nedbrydes biologisk |
US6001891A (en) | 1996-06-14 | 1999-12-14 | Mitsui Chemicals, Inc. | Biodegradable aliphatic polyester elastomer and preparation process of same |
JP3938609B2 (ja) | 1997-02-25 | 2007-06-27 | 信越ポリマー株式会社 | 生分解性粘着テープ |
JP3860880B2 (ja) * | 1997-06-03 | 2006-12-20 | 共栄社化学株式会社 | ウレタンプレポリマー、その製造方法およびそれを成分とする感圧接着剤 |
US5840827A (en) * | 1998-03-11 | 1998-11-24 | Morton International, Inc. | Low molecular weight hydroxy functional polyesters for coatings |
US7053145B1 (en) * | 1998-08-31 | 2006-05-30 | Riken Technos Corporation | Fire-retardant resin composition and molded part using the same |
US6803443B1 (en) * | 2000-03-22 | 2004-10-12 | Dainippon Ink And Chemicals, Inc. | Impact modifier and polyester composition containing the modifier |
RU2283853C2 (ru) * | 2001-06-01 | 2006-09-20 | Акцо Нобель Н.В. | Композиция для покрытий |
DE10322845A1 (de) * | 2003-05-19 | 2004-12-16 | Degussa Ag | Verzweigte,amorphe Makropolyole auf Polyesterbasis mit enger Molekulargewichtsverteilung |
US7070051B2 (en) * | 2004-03-26 | 2006-07-04 | Atrion Medical Products, Inc. | Needle counter device including troughs of cohesive material |
DE102006020482A1 (de) * | 2006-04-28 | 2007-10-31 | Tesa Ag | Wieder ablösbarer Haftklebstoff aus Polyurethan |
CN101583651A (zh) * | 2006-09-04 | 2009-11-18 | 生物能源株式会社 | 聚酯多元醇 |
US7385020B2 (en) | 2006-10-13 | 2008-06-10 | 3M Innovative Properties Company | 2-octyl (meth)acrylate adhesive composition |
JP5580069B2 (ja) | 2009-02-26 | 2014-08-27 | 日東電工株式会社 | 表面保護フィルム用粘着剤組成物とその利用 |
JP2011213752A (ja) | 2010-03-31 | 2011-10-27 | Nitto Denko Corp | 粘着テープ |
JP2011213753A (ja) | 2010-03-31 | 2011-10-27 | Nitto Denko Corp | 粘着テープ |
JP2011241313A (ja) | 2010-05-19 | 2011-12-01 | Nitto Denko Corp | 粘着テープ |
JP2011241355A (ja) | 2010-05-21 | 2011-12-01 | Nitto Denko Corp | 粘着テープ |
-
2009
- 2009-10-20 JP JP2009241717A patent/JP5519996B2/ja active Active
-
2010
- 2010-10-20 US US13/502,146 patent/US8962136B2/en active Active
- 2010-10-20 EP EP10824960.8A patent/EP2492325A4/en not_active Withdrawn
- 2010-10-20 CN CN2010800425694A patent/CN102575132B/zh not_active Expired - Fee Related
- 2010-10-20 WO PCT/JP2010/068450 patent/WO2011049111A1/ja active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1160716A (ja) * | 1996-11-07 | 1999-03-05 | Mitsui Chem Inc | 生分解性接着剤及びその製造方法 |
JP2000160125A (ja) * | 1998-11-27 | 2000-06-13 | Shimadzu Corp | 生体吸収性接着剤および粘着材 |
JP2004231797A (ja) * | 2003-01-30 | 2004-08-19 | Toyobo Co Ltd | 生分解性粘着剤とそのワニスおよび積層体 |
JP2007308626A (ja) * | 2006-05-19 | 2007-11-29 | Nitto Denko Corp | 低透湿性粘着シート |
JP2008013593A (ja) * | 2006-07-03 | 2008-01-24 | Nitto Denko Corp | 透明性に優れるポリエステル系粘着シート |
JP2008195819A (ja) * | 2007-02-13 | 2008-08-28 | Nitto Denko Corp | ポリエステル系粘着剤組成物 |
JP2010037463A (ja) * | 2008-08-06 | 2010-02-18 | Nitto Denko Corp | ポリエステル、ポリエステル組成物、粘着剤組成物、粘着剤層及び粘着シート |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20160033203A (ko) * | 2013-09-02 | 2016-03-25 | 미쯔이가가꾸가부시끼가이샤 | 적층체 |
KR101885970B1 (ko) * | 2013-09-02 | 2018-08-06 | 미쯔이가가꾸가부시끼가이샤 | 적층체 |
JP2020122164A (ja) * | 2015-12-22 | 2020-08-13 | 三菱ケミカル株式会社 | ポリエステル系粘着剤組成物、ポリエステル系粘着剤、光学部材用粘着シート、光学部材用基材レス両面粘着シート、粘着剤層付き光学部材、光学積層体 |
JP7404997B2 (ja) | 2015-12-22 | 2023-12-26 | 三菱ケミカル株式会社 | ポリエステル系粘着剤組成物、ポリエステル系粘着剤、光学部材用粘着シート、光学部材用基材レス両面粘着シート、粘着剤層付き光学部材、光学積層体 |
JP2016218482A (ja) * | 2016-09-20 | 2016-12-22 | 三菱樹脂株式会社 | 光学部材 |
JP2017016142A (ja) * | 2016-09-20 | 2017-01-19 | 三菱樹脂株式会社 | 光学部材の製造方法 |
WO2018174198A1 (ja) * | 2017-03-24 | 2018-09-27 | 日本合成化学工業株式会社 | 粘着剤組成物、粘着剤及び積層体 |
JP2018020569A (ja) * | 2017-08-31 | 2018-02-08 | 三菱ケミカル株式会社 | 積層フィルム |
JP2018009185A (ja) * | 2017-09-04 | 2018-01-18 | 三菱ケミカル株式会社 | 積層フィルム |
JP2018123325A (ja) * | 2018-03-02 | 2018-08-09 | 三菱ケミカル株式会社 | 積層ポリエステルフィルム |
JP2018159929A (ja) * | 2018-05-08 | 2018-10-11 | 三菱ケミカル株式会社 | 光学部材 |
JPWO2021117826A1 (ja) * | 2019-12-13 | 2021-06-17 | ||
JP7211537B2 (ja) | 2019-12-13 | 2023-01-24 | Dic株式会社 | 粘着テープ |
Also Published As
Publication number | Publication date |
---|---|
EP2492325A1 (en) | 2012-08-29 |
JP5519996B2 (ja) | 2014-06-11 |
CN102575132B (zh) | 2013-12-04 |
WO2011049111A1 (ja) | 2011-04-28 |
EP2492325A4 (en) | 2015-01-21 |
US20120202058A1 (en) | 2012-08-09 |
US8962136B2 (en) | 2015-02-24 |
CN102575132A (zh) | 2012-07-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5519996B2 (ja) | 表面保護用粘着シート | |
JP5368249B2 (ja) | 両面粘着シート | |
JP5604037B2 (ja) | ポリエステル、ポリエステル組成物、粘着剤組成物、粘着剤層及び粘着シート | |
JP5456432B2 (ja) | 放射線硬化再剥離型粘着シート | |
JP5456431B2 (ja) | 加熱剥離型粘着シート | |
JP5368248B2 (ja) | マスキング用粘着テープ | |
JP5199021B2 (ja) | 無溶剤型ポリエステル系粘着剤組成物 | |
WO2013137110A1 (ja) | 粘着剤組成物、及び、粘着シート | |
KR20140136430A (ko) | 점착제 조성물 및 점착 시트 | |
JP2014169420A (ja) | 両面粘着テープ | |
WO2022220223A1 (ja) | 粘着剤組成物および粘着シート | |
JP2013203979A (ja) | 粘着剤組成物、及び、表面保護用粘着シート |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20111202 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20131219 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140401 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140404 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5519996 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |