JP2010536692A5 - - Google Patents
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- JP2010536692A5 JP2010536692A5 JP2010521012A JP2010521012A JP2010536692A5 JP 2010536692 A5 JP2010536692 A5 JP 2010536692A5 JP 2010521012 A JP2010521012 A JP 2010521012A JP 2010521012 A JP2010521012 A JP 2010521012A JP 2010536692 A5 JP2010536692 A5 JP 2010536692A5
- Authority
- JP
- Japan
- Prior art keywords
- iron
- zeolite
- containing aluminosilicate
- aluminosilicate zeolite
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 146
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 74
- 229910052742 iron Inorganic materials 0.000 claims description 74
- 239000010457 zeolite Substances 0.000 claims description 52
- 229910021536 Zeolite Inorganic materials 0.000 claims description 46
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 27
- 238000005342 ion exchange Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- -1 iron cations Chemical class 0.000 claims description 15
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000001308 synthesis method Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000032683 aging Effects 0.000 claims 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 3
- 239000004202 carbamide Substances 0.000 claims 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 239000004115 Sodium Silicate Substances 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 150000002505 iron Chemical class 0.000 claims 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical group [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 239000004332 silver Substances 0.000 claims 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical group [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims 1
- 239000012297 crystallization seed Substances 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 229960002089 ferrous chloride Drugs 0.000 claims 1
- 235000003891 ferrous sulphate Nutrition 0.000 claims 1
- 239000011790 ferrous sulphate Substances 0.000 claims 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims 1
- 239000000741 silica gel Substances 0.000 claims 1
- 229910002027 silica gel Inorganic materials 0.000 claims 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical group O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- 229910001388 sodium aluminate Inorganic materials 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000047 product Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000006722 reduction reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93543607P | 2007-08-13 | 2007-08-13 | |
| US60/935,436 | 2007-08-13 | ||
| PCT/US2008/009653 WO2009023202A2 (en) | 2007-08-13 | 2008-08-13 | Novel iron-containing aluminosilicate zeolites and methods of making and using same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015107726A Division JP2015205270A (ja) | 2007-08-13 | 2015-05-27 | 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010536692A JP2010536692A (ja) | 2010-12-02 |
| JP2010536692A5 true JP2010536692A5 (https=) | 2014-06-26 |
| JP6176891B2 JP6176891B2 (ja) | 2017-08-09 |
Family
ID=40262119
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010521012A Active JP6176891B2 (ja) | 2007-08-13 | 2008-08-13 | 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 |
| JP2015107726A Pending JP2015205270A (ja) | 2007-08-13 | 2015-05-27 | 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015107726A Pending JP2015205270A (ja) | 2007-08-13 | 2015-05-27 | 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8541331B2 (https=) |
| EP (2) | EP2192982A2 (https=) |
| JP (2) | JP6176891B2 (https=) |
| CN (2) | CN101827654B (https=) |
| WO (1) | WO2009023202A2 (https=) |
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| US4952385A (en) | 1987-03-02 | 1990-08-28 | Georgia Tech Research Corp. | Ferrisilicate molecular sieve and use as a catalyst |
| DD281172A5 (de) * | 1988-03-28 | 1990-08-01 | Akad Wissenschaften Ddr | Zeolithischer katalysator und verfahren zu seiner herstellung |
| US4961917A (en) | 1989-04-20 | 1990-10-09 | Engelhard Corporation | Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts |
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| JPH05305240A (ja) * | 1992-04-27 | 1993-11-19 | N E Chemcat Corp | 排気ガス浄化用触媒 |
| US5451387A (en) | 1994-07-07 | 1995-09-19 | Mobil Oil Corporation | Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst |
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| DE10020100A1 (de) * | 2000-04-22 | 2001-10-31 | Dmc2 Degussa Metals Catalysts | Verfahren und Katalysator zur Reduktion von Stickoxiden |
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| US6914026B2 (en) * | 2001-09-07 | 2005-07-05 | Engelhard Corporation | Hydrothermally stable metal promoted zeolite beta for NOx reduction |
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| JP4957176B2 (ja) * | 2006-10-24 | 2012-06-20 | 東ソー株式会社 | 窒素酸化物浄化触媒及び窒素酸化物浄化方法 |
-
2008
- 2008-08-13 CN CN2008801030115A patent/CN101827654B/zh active Active
- 2008-08-13 EP EP08795258A patent/EP2192982A2/en not_active Withdrawn
- 2008-08-13 WO PCT/US2008/009653 patent/WO2009023202A2/en not_active Ceased
- 2008-08-13 JP JP2010521012A patent/JP6176891B2/ja active Active
- 2008-08-13 EP EP13005098.2A patent/EP2689846A1/en not_active Ceased
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- 2008-08-13 CN CN201210123893.XA patent/CN102764590B/zh not_active Expired - Fee Related
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