JP2009510703A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2009510703A5 JP2009510703A5 JP2008533742A JP2008533742A JP2009510703A5 JP 2009510703 A5 JP2009510703 A5 JP 2009510703A5 JP 2008533742 A JP2008533742 A JP 2008533742A JP 2008533742 A JP2008533742 A JP 2008533742A JP 2009510703 A5 JP2009510703 A5 JP 2009510703A5
- Authority
- JP
- Japan
- Prior art keywords
- fuel cell
- cell component
- hpa
- immobilized
- extracted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000003850 cellular structures Anatomy 0.000 claims 16
- 239000000446 fuel Substances 0.000 claims 16
- 239000002131 composite material Substances 0.000 claims 4
- 239000011964 heteropoly acid Substances 0.000 claims 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 3
- 229910010272 inorganic material Inorganic materials 0.000 claims 3
- 239000011147 inorganic material Substances 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 229920001940 conductive polymer Polymers 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 239000012528 membrane Substances 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 239000002322 conducting polymer Substances 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 229910001463 metal phosphate Inorganic materials 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- NJRWNWYFPOFDFN-UHFFFAOYSA-L phosphonate(2-) Chemical compound [O-][P]([O-])=O NJRWNWYFPOFDFN-UHFFFAOYSA-L 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920005597 polymer membrane Polymers 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 230000000087 stabilizing Effects 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Claims (15)
- プロトン伝導性ポリマーと、水不溶性プロトン伝導性無機材料と、前記無機材料に共有結合することによって固定化したヘテロポリ酸とを含む複合材で作製した燃料電池構成要素。
- 複合材が、約３０ｎｍ未満の平均直径を有する粒子を含む、請求項１に記載の燃料電池構成要素。
- プロトン伝導性ポリマーが官能基を有することにより、複合材の製造中に立体安定剤として作用し、これによって成長粒子を安定化させる、請求項２に記載の燃料電池構成要素。
- ヘテロポリ酸の固定化がポリマー溶液内またはポリマー膜内で行われる、請求項１に記載の燃料電池構成要素。
- ヘテロポリ酸がタングステンまたはモリブデンを含む、請求項１に記載の燃料電池構成要素。
- 無機材料が金属化合物である、請求項１に記載の燃料電池構成要素。
- ヘテロポリ酸が、水不溶性の金属リン酸塩または金属ホスホン酸塩上に固定化されている、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡおよび非修飾ＨＰＡの酸性度が実質的に同じである、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡの表面積が、非修飾ＨＰＡと実質的に同じか、またはそれを超える、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡの多孔度が、非修飾ＨＰＡと実質的に同じか、またはそれを超える、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡが、液体の水によって、実質的に溶解および／または抽出できない、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡが、１．５Ｍ硫酸によって、実質的に溶解および／または抽出できない、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡが、液体のメタノール、エタノール、ブタノール、および高級アルコールによって、実質的に溶解および／または抽出できない、請求項１に記載の燃料電池構成要素。
- 固定化したＨＰＡが、過酸化水素またはギ酸によって、実質的に溶解および／または抽出できない、請求項１に記載の燃料電池構成要素。
- 膜電極接合体であり、前記複合材が前記膜電極接合体中のバインダーとして使用される、請求項１に記載の燃料電池構成要素。
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72285705P | 2005-09-30 | 2005-09-30 | |
| US60/722,857 | 2005-09-30 | ||
| US73144105P | 2005-10-28 | 2005-10-28 | |
| US60/731,441 | 2005-10-28 | ||
| US73681505P | 2005-11-15 | 2005-11-15 | |
| US60/736,815 | 2005-11-15 | ||
| US74865805P | 2005-12-08 | 2005-12-08 | |
| US60/748,658 | 2005-12-08 | ||
| US81935706P | 2006-07-07 | 2006-07-07 | |
| US60/819,357 | 2006-07-07 | ||
| PCT/US2006/038397 WO2007041473A1 (en) | 2005-09-30 | 2006-09-29 | Fuel cell components including immobilized heteropolyacids |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009510703A JP2009510703A (ja) | 2009-03-12 |
| JP2009510703A5 true JP2009510703A5 (ja) | 2010-01-14 |
| JP5329962B2 JP5329962B2 (ja) | 2013-10-30 |
Family
ID=37607454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008533742A Expired - Fee Related JP5329962B2 (ja) | 2005-09-30 | 2006-09-29 | 固定化ヘテロポリ酸を含む燃料電池構成要素 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8129069B2 (ja) |
| EP (1) | EP1941575A1 (ja) |
| JP (1) | JP5329962B2 (ja) |
| KR (1) | KR20080053397A (ja) |
| CA (1) | CA2624459C (ja) |
| WO (1) | WO2007041473A1 (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5194448B2 (ja) * | 2006-12-22 | 2013-05-08 | 株式会社豊田中央研究所 | 固体高分子型燃料電池 |
| EP3012895A3 (en) * | 2007-11-09 | 2016-06-01 | 3M Innovative Properties Company | Polymer electrolytes including heteropolyacids |
| WO2010058776A1 (ja) | 2008-11-19 | 2010-05-27 | 日産化学工業株式会社 | 電荷輸送性材料および電荷輸送性ワニス |
| JP5391808B2 (ja) * | 2009-04-24 | 2014-01-15 | 株式会社豊田中央研究所 | 高耐久性電解質膜、電極及び固体高分子型燃料電池 |
| JP5514380B2 (ja) * | 2010-06-21 | 2014-06-04 | 株式会社ノリタケカンパニーリミテド | 固体高分子形燃料電池用のプロトン伝導材料およびそのプロトン伝導材料の製造方法 |
| WO2016116259A1 (de) | 2015-01-21 | 2016-07-28 | Smartmaterialprinting B.V. | Biozide ausrüstung von gegenständen und wasserhaltigen reinigungs- und körperpflegemitteln mit polyoxometallat-mikro und/oder - nanopartikeln |
| DE102015000813A1 (de) | 2015-01-21 | 2016-07-21 | Smart Material Printing B.V. | Verfahren zur Vernichtung von Medikamenten und Giftstoffen und ihren Metaboliten mithilfe von Polyoxometallat-Mikro-und/oder -Nanopartikeln |
| DE102015000814A1 (de) | 2015-01-21 | 2016-07-21 | Smart Material Printing B.V. | Biozide Ausrüstung von Gegenständen mit Polyoxometallat-Mikro- und/oder -Nanopartikeln |
| WO2017214304A1 (en) | 2016-06-07 | 2017-12-14 | Battelle Memorial Institute | Coating materials, and personal protective clothing items coated with the coating materials |
| US11266865B2 (en) | 2017-12-05 | 2022-03-08 | Battelle Memorial Institute | Decontamination compositions and methods of decontamination |
| DE102018003906A1 (de) | 2018-05-07 | 2019-11-07 | Smart Material Printing | Verwendung von Polyoxometallaten gegen den Befall von Eukaryotenkulturen, Virenkulturen und Mikroorganismenpopulationen durch Mollicuten sowie mollicutenhemmende und -abtötende polyoxometallathaltige Stoffe und Verfahren |
| CN111063924B (zh) * | 2019-12-27 | 2022-10-14 | 先进储能材料国家工程研究中心有限责任公司 | 膜电极用过渡层浆料及其制备方法、膜电极及其制备方法 |
| WO2024102677A1 (en) | 2022-11-08 | 2024-05-16 | Orna Therapeutics, Inc. | Circular rna compositions |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58129782A (ja) | 1982-01-29 | 1983-08-02 | Hitachi Ltd | 溶融炭酸塩型燃料電池用電解質体の製造方法 |
| WO1996029752A1 (en) * | 1995-03-20 | 1996-09-26 | E.I. Du Pont De Nemours And Company | Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same |
| US6472344B1 (en) * | 1998-11-18 | 2002-10-29 | Battelle Memorial Institute | Catalyst of a metal heteropoly acid salt that is insoluble in a polar solvent on a non-metallic porous support and method of making |
| CA2256829A1 (en) | 1998-12-18 | 2000-06-18 | Universite Laval | Composite electrolyte membranes for fuel cells |
| IT1319649B1 (it) | 2000-11-14 | 2003-10-23 | Nuvera Fuel Cells Europ Srl | Assieme membrana-elettrodo per cella a combustibile a membranapolimerica. |
| KR100403754B1 (ko) | 2001-06-19 | 2003-10-30 | 송민규 | 연료전지용 복합 고분자 전해질 막, 이의 제조방법 및이를 포함하는 연료전지 |
| US6569309B2 (en) | 2001-07-05 | 2003-05-27 | Asahi Kasei Kabushiki Kaisha | Fuel cell type reactor and method for producing a chemical compound by using the same |
| KR100773635B1 (ko) | 2001-09-11 | 2007-11-05 | 세키스이가가쿠 고교가부시키가이샤 | 막-전극 접합체, 그의 제조 방법 및 이것을 이용한 고체고분자형 연료 전지 |
| JP2003229143A (ja) | 2002-02-06 | 2003-08-15 | Kanegafuchi Chem Ind Co Ltd | プロトン伝導性高分子膜及びそれからなる燃料電池 |
| JP2003242831A (ja) | 2002-02-12 | 2003-08-29 | National Institute Of Advanced Industrial & Technology | プロトン伝導性膜、その製造方法及びそれを用いた燃料電池 |
| US20050053818A1 (en) | 2002-03-28 | 2005-03-10 | Marc St-Arnaud | Ion exchange composite material based on proton conductive functionalized inorganic support compounds in a polymer matrix |
| US7544764B2 (en) | 2002-04-01 | 2009-06-09 | Virginia Tech Intellectual Properties, Inc. | Sulfonated polymer composition for forming fuel cell electrodes |
| US6893763B2 (en) | 2002-04-16 | 2005-05-17 | Gas Technology Institute | Composite polymer electrolyte membrane for polymer electrolyte membrane fuel cells |
| JP2003317737A (ja) | 2002-04-19 | 2003-11-07 | Nec Corp | 燃料電池およびそれに用いる触媒電極、固体電解質膜 |
| US6953873B2 (en) | 2002-05-10 | 2005-10-11 | Wisconsin Alumni Research Foundation | Low-temperature hydrocarbon production from oxygenated hydrocarbons |
| US7094490B2 (en) | 2002-05-13 | 2006-08-22 | Polyfuel, Inc. | Ion conductive block copolymers |
| JP4116328B2 (ja) | 2002-05-27 | 2008-07-09 | 本田技研工業株式会社 | 膜電極構造体及びその製造方法 |
| US6630265B1 (en) | 2002-08-13 | 2003-10-07 | Hoku Scientific, Inc. | Composite electrolyte for fuel cells |
| JP4045918B2 (ja) | 2002-10-23 | 2008-02-13 | トヨタ自動車株式会社 | プロトン伝導膜及びその製造方法 |
| US20060141334A1 (en) | 2002-11-13 | 2006-06-29 | Hitoshi Nakajima | Catalyst for fuel cell and electrode using the same |
| US6878475B2 (en) | 2002-11-22 | 2005-04-12 | T/J Technologies, Inc. | Membrane for fuel cell, and fuel cell incorporating that membrane |
| JP3714930B2 (ja) | 2002-11-29 | 2005-11-09 | 三洋電機株式会社 | 燃料電池用電極およびそれを用いた燃料電池 |
| JP2005025943A (ja) * | 2003-06-30 | 2005-01-27 | Teijin Ltd | プロトン伝導体、触媒電極、触媒電極とプロトン伝導体の接合体、燃料電池およびプロトン伝導体の製造方法 |
| US6962959B2 (en) | 2003-08-28 | 2005-11-08 | Hoku Scientific, Inc. | Composite electrolyte with crosslinking agents |
| JP4217891B2 (ja) | 2003-10-17 | 2009-02-04 | 信越化学工業株式会社 | 燃料電池用電解質膜及び燃料電池用電解質膜・電極接合体の製造方法 |
| EP1685618B1 (en) * | 2003-11-06 | 2009-09-30 | Renault s.a.s. | Ion-conducting composite membranes |
| DE602005018755D1 (de) | 2004-04-02 | 2010-02-25 | Asahi Glass Co Ltd | Elektrolytmaterial für eine polymerelektrolyt-brennstoffzelle , elektrolytmembran und membranelektrodenbaugruppe |
| JP2006120620A (ja) | 2004-09-21 | 2006-05-11 | Aisin Seiki Co Ltd | 電解質材料、電解質膜、触媒ペースト、膜電極接合体及び燃料電池 |
| JP2006103924A (ja) | 2004-10-07 | 2006-04-20 | Toshiba Elevator Co Ltd | 主ロープの振れ止装置、及びこれを備えるエレベータ |
| CN1300879C (zh) | 2004-10-20 | 2007-02-14 | 华南理工大学 | 以杂多酸为促进剂的燃料电池阳极催化剂的制备方法 |
| KR100600150B1 (ko) | 2004-11-30 | 2006-07-12 | 현대자동차주식회사 | 나노 크기의 덴드리머가 함침된 복합 전해질막 및 이의 제조방법 |
| US7118821B2 (en) | 2005-01-05 | 2006-10-10 | The Regents Of The University Of California | Hydrophilic polymer-oxide-phosphoric acid compositions for proton conducting membranes |
| US7435496B2 (en) | 2005-01-12 | 2008-10-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Anhydrous proton conductor based on heterocycle attached to a polymer backbone |
| US7622220B2 (en) | 2005-01-18 | 2009-11-24 | Samsung Sdi Co., Ltd. | Polymer electrolyte and fuel cell using the same |
| KR101320387B1 (ko) | 2005-01-25 | 2013-10-22 | 삼성에스디아이 주식회사 | Ｃｏ 제거 촉매 시스템 및 이를 채용한 연료처리장치 |
| KR101223559B1 (ko) | 2005-06-24 | 2013-01-22 | 삼성에스디아이 주식회사 | 연료 전지용 고분자 전해질 막의 제조 방법 |
-
2006
- 2006-09-29 JP JP2008533742A patent/JP5329962B2/ja not_active Expired - Fee Related
- 2006-09-29 CA CA2624459A patent/CA2624459C/en not_active Expired - Fee Related
- 2006-09-29 EP EP06815995A patent/EP1941575A1/en not_active Withdrawn
- 2006-09-29 WO PCT/US2006/038397 patent/WO2007041473A1/en active Application Filing
- 2006-09-29 KR KR1020087010335A patent/KR20080053397A/ko not_active Application Discontinuation
- 2006-09-29 US US11/992,826 patent/US8129069B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2009510703A5 (ja) | ||
| Deng et al. | Alfalfa leaf-derived porous heteroatom-doped carbon materials as efficient cathodic catalysts in microbial fuel cells | |
| Prasad et al. | Three-dimensional graphene-carbon nanotube hybrid for high-performance enzymatic biofuel cells | |
| Su et al. | Recent advances in graphene‐based materials for fuel cell applications | |
| Brouzgou et al. | Electrocatalysts for glucose electrooxidation reaction: a review | |
| Zhao et al. | Mediatorless glucose biosensor and direct electron transfer type glucose/air biofuel cell enabled with carbon nanodots | |
| Campbell et al. | Membrane/mediator-free rechargeable enzymatic biofuel cell utilizing graphene/single-wall carbon nanotube cogel electrodes | |
| Wang et al. | Nitrogen-doped porous carbons as electrode materials for high-performance supercapacitor and dye-sensitized solar cell | |
| Xiang et al. | Layer-by-layer self-assembly in the development of electrochemical energy conversion and storage devices from fuel cells to supercapacitors | |
| Qiao et al. | Nanostructured catalysts in fuel cells | |
| Izadi-Najafabadi et al. | High-power supercapacitor electrodes from single-walled carbon nanohorn/nanotube composite | |
| Li et al. | Carbon nanotube film by filtration as cathode catalyst support for proton-exchange membrane fuel cell | |
| Zhang et al. | Polyethylenimine-enhanced electrocatalytic reduction of CO2 to formate at nitrogen-doped carbon nanomaterials | |
| Yuan et al. | CoP nanoparticles in situ grown in three-dimensional hierarchical nanoporous carbons as superior electrocatalysts for hydrogen evolution | |
| Wang et al. | Proton exchange membrane fuel cells with carbon nanotube based electrodes | |
| Islam et al. | Energy conversion and storage in fuel cells and super-capacitors from chemical modifications of carbon allotropes: State-of-art and prospect | |
| EP3022785B1 (en) | Microtubes made of carbon nanotubes | |
| Duan et al. | Self-stable WP/C support with excellent cocatalytic functionality for Pt: enhanced catalytic activity and durability for methanol electro-oxidation | |
| JP4575330B2 (ja) | 燃料電池用アノード、その製造方法およびそれを備えた燃料電池 | |
| Yang et al. | Polyaniline-reduced graphene oxide hybrid nanosheets with nearly vertical orientation anchoring palladium nanoparticles for highly active and stable electrocatalysis | |
| JP2009532828A5 (ja) | ||
| CN103424449A (zh) | 二茂铁接枝壳聚糖-碳纳米管-酶复合膜修饰三维石墨烯复合材料及其制备方法 | |
| JP5636746B2 (ja) | 燃料電池 | |
| WO2009004959A1 (ja) | 膜電極接合体及び膜電極接合体の製造方法、固体高分子形燃料電池 | |
| US20140193741A1 (en) | Polymer electrolyte membrane for fuel cell, membrane electrode assembly and fuel cell including the same |