JP2008535154A - 硫化リチウム電池およびこれを製造する方法 - Google Patents
硫化リチウム電池およびこれを製造する方法 Download PDFInfo
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- JP2008535154A JP2008535154A JP2008502465A JP2008502465A JP2008535154A JP 2008535154 A JP2008535154 A JP 2008535154A JP 2008502465 A JP2008502465 A JP 2008502465A JP 2008502465 A JP2008502465 A JP 2008502465A JP 2008535154 A JP2008535154 A JP 2008535154A
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- Prior art keywords
- lithium
- sulfur
- electrical energy
- cathode
- chemical source
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000011593 sulfur Substances 0.000 claims abstract description 80
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 80
- 239000003792 electrolyte Substances 0.000 claims abstract description 52
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 239000000126 substance Substances 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 17
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 14
- 239000012528 membrane Substances 0.000 claims abstract description 10
- 239000004020 conductor Substances 0.000 claims abstract description 8
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 7
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 7
- 229910052744 lithium Inorganic materials 0.000 claims description 37
- 239000000725 suspension Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- -1 lithium hexafluorophosphate Chemical compound 0.000 claims description 8
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical group [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 claims description 7
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 239000000084 colloidal system Substances 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 4
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 4
- 239000002674 ointment Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 2
- 229930188620 butyrolactone Natural products 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 2
- 229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 claims description 2
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 2
- MPDOUGUGIVBSGZ-UHFFFAOYSA-N n-(cyclobutylmethyl)-3-(trifluoromethyl)aniline Chemical compound FC(F)(F)C1=CC=CC(NCC2CCC2)=C1 MPDOUGUGIVBSGZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004065 semiconductor Substances 0.000 claims description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims description 2
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 claims description 2
- 239000007769 metal material Substances 0.000 claims 1
- 239000004745 nonwoven fabric Substances 0.000 claims 1
- 239000002759 woven fabric Substances 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 36
- 150000008117 polysulfides Polymers 0.000 description 31
- 229920001021 polysulfide Polymers 0.000 description 29
- 239000005077 polysulfide Substances 0.000 description 27
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229910018091 Li 2 S Inorganic materials 0.000 description 5
- 229920000642 polymer Chemical class 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910000733 Li alloy Inorganic materials 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 229940021013 electrolyte solution Drugs 0.000 description 3
- 239000001989 lithium alloy Substances 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- MQKATURVIVFOQI-UHFFFAOYSA-N [S-][S-].[Li+].[Li+] Chemical compound [S-][S-].[Li+].[Li+] MQKATURVIVFOQI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000010 aprotic solvent Substances 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011263 electroactive material Substances 0.000 description 2
- 239000011262 electrochemically active material Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- GBOJNWWRSXRMLL-UHFFFAOYSA-M [Li+].[SH-].S Chemical compound [Li+].[SH-].S GBOJNWWRSXRMLL-UHFFFAOYSA-M 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000006183 anode active material Substances 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HGVHMIAKUYLQLL-UHFFFAOYSA-N ethene;propane-1,2,3-triol Chemical compound C=C.OCC(O)CO HGVHMIAKUYLQLL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000014233 sulfur utilization Effects 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/4911—Electric battery cell making including sealing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0505790A GB2424511B (en) | 2005-03-22 | 2005-03-22 | Lithium sulphide battery and method of producing the same |
| US66459205P | 2005-03-24 | 2005-03-24 | |
| PCT/GB2006/001020 WO2006100464A2 (en) | 2005-03-22 | 2006-03-21 | Lithium sulphide battery and method of producing the same |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013249611A Division JP2014089965A (ja) | 2005-03-22 | 2013-12-02 | 硫化リチウム電池およびこれを製造する方法 |
| JP2013249610A Division JP2014089964A (ja) | 2005-03-22 | 2013-12-02 | 硫化リチウム電池およびこれを製造する方法 |
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| JP2008535154A true JP2008535154A (ja) | 2008-08-28 |
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| JP2013249611A Pending JP2014089965A (ja) | 2005-03-22 | 2013-12-02 | 硫化リチウム電池およびこれを製造する方法 |
| JP2013249610A Pending JP2014089964A (ja) | 2005-03-22 | 2013-12-02 | 硫化リチウム電池およびこれを製造する方法 |
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| JP2013249611A Pending JP2014089965A (ja) | 2005-03-22 | 2013-12-02 | 硫化リチウム電池およびこれを製造する方法 |
| JP2013249610A Pending JP2014089964A (ja) | 2005-03-22 | 2013-12-02 | 硫化リチウム電池およびこれを製造する方法 |
Country Status (6)
| Country | Link |
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| US (3) | US7695861B2 (enExample) |
| EP (1) | EP1867000B1 (enExample) |
| JP (3) | JP2008535154A (enExample) |
| KR (1) | KR101301115B1 (enExample) |
| RU (1) | RU2402842C2 (enExample) |
| WO (1) | WO2006100464A2 (enExample) |
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| JP2014525654A (ja) * | 2011-09-02 | 2014-09-29 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | リチウム硫黄(Li−S)タイプの電気化学バッテリー、及びその製造方法 |
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- 2006-03-21 EP EP06726451A patent/EP1867000B1/en not_active Not-in-force
- 2006-03-21 JP JP2008502465A patent/JP2008535154A/ja not_active Withdrawn
- 2006-03-21 KR KR1020077019092A patent/KR101301115B1/ko not_active Expired - Fee Related
- 2006-03-21 WO PCT/GB2006/001020 patent/WO2006100464A2/en not_active Ceased
- 2006-03-21 RU RU2007139012/09A patent/RU2402842C2/ru active
- 2006-03-22 US US11/386,113 patent/US7695861B2/en active Active
-
2010
- 2010-04-12 US US12/758,228 patent/US20100196757A1/en not_active Abandoned
-
2012
- 2012-04-02 US US13/437,134 patent/US8361652B2/en not_active Expired - Fee Related
-
2013
- 2013-12-02 JP JP2013249611A patent/JP2014089965A/ja active Pending
- 2013-12-02 JP JP2013249610A patent/JP2014089964A/ja active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002367678A (ja) * | 2001-06-01 | 2002-12-20 | Samsung Sdi Co Ltd | リチウム−硫黄電池 |
| JP2004179160A (ja) * | 2002-11-26 | 2004-06-24 | Samsung Sdi Co Ltd | リチウム−硫黄電池用正極 |
| JP2005108724A (ja) * | 2003-09-30 | 2005-04-21 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
| JP2005158313A (ja) * | 2003-11-21 | 2005-06-16 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010511995A (ja) * | 2006-12-04 | 2010-04-15 | サイオン パワー コーポレイション | リチウム電池内における電解質の分離 |
| US8617748B2 (en) | 2006-12-04 | 2013-12-31 | Sion Power Corporation | Separation of electrolytes |
| US10629954B2 (en) | 2006-12-04 | 2020-04-21 | Sion Power Corporation | Separation of electrolytes |
| US11316204B2 (en) | 2006-12-04 | 2022-04-26 | Sion Power Corporation | Separation of electrolytes |
| JP2014525654A (ja) * | 2011-09-02 | 2014-09-29 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | リチウム硫黄(Li−S)タイプの電気化学バッテリー、及びその製造方法 |
| JP2014238943A (ja) * | 2013-06-06 | 2014-12-18 | 株式会社豊田自動織機 | リチウムイオン二次電池用集電体、リチウムイオン二次電池用電極及びリチウムイオン二次電池 |
| JP2023049469A (ja) * | 2021-09-29 | 2023-04-10 | 株式会社Abri | リチウム硫黄二次電池用正極、リチウム硫黄二次電池及びリチウム硫黄二次電池用正極の製造方法 |
| JP7753024B2 (ja) | 2021-09-29 | 2025-10-14 | 古河電池株式会社 | リチウム硫黄二次電池用正極、リチウム硫黄二次電池及びリチウム硫黄二次電池用正極の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US7695861B2 (en) | 2010-04-13 |
| JP2014089964A (ja) | 2014-05-15 |
| WO2006100464A2 (en) | 2006-09-28 |
| US20100196757A1 (en) | 2010-08-05 |
| KR20070113208A (ko) | 2007-11-28 |
| JP2014089965A (ja) | 2014-05-15 |
| EP1867000B1 (en) | 2011-10-05 |
| US20060234126A1 (en) | 2006-10-19 |
| US20120189921A1 (en) | 2012-07-26 |
| WO2006100464A3 (en) | 2006-12-21 |
| RU2402842C2 (ru) | 2010-10-27 |
| RU2007139012A (ru) | 2009-04-27 |
| US8361652B2 (en) | 2013-01-29 |
| KR101301115B1 (ko) | 2013-09-03 |
| EP1867000A2 (en) | 2007-12-19 |
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