KR101301115B1 - 황화리튬 전지 및 그의 제조 방법 - Google Patents

황화리튬 전지 및 그의 제조 방법 Download PDF

Info

Publication number
KR101301115B1
KR101301115B1 KR1020077019092A KR20077019092A KR101301115B1 KR 101301115 B1 KR101301115 B1 KR 101301115B1 KR 1020077019092 A KR1020077019092 A KR 1020077019092A KR 20077019092 A KR20077019092 A KR 20077019092A KR 101301115 B1 KR101301115 B1 KR 101301115B1
Authority
KR
South Korea
Prior art keywords
lithium
sulfur
cathode
aprotic electrolyte
electrical energy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020077019092A
Other languages
English (en)
Korean (ko)
Other versions
KR20070113208A (ko
Inventor
블라디미르 콜로스니친
엘레나 카라세바
Original Assignee
옥시스 에너지 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0505790A external-priority patent/GB2424511B/en
Application filed by 옥시스 에너지 리미티드 filed Critical 옥시스 에너지 리미티드
Publication of KR20070113208A publication Critical patent/KR20070113208A/ko
Application granted granted Critical
Publication of KR101301115B1 publication Critical patent/KR101301115B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
    • H01M10/3909—Sodium-sulfur cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
    • H01M10/3909—Sodium-sulfur cells
    • H01M10/3918—Sodium-sulfur cells characterised by the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96—Carbon-based electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y10T29/4911—Electric battery cell making including sealing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y10T29/49115—Electric battery cell making including coating or impregnating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Connection Of Batteries Or Terminals (AREA)
KR1020077019092A 2005-03-22 2006-03-21 황화리튬 전지 및 그의 제조 방법 Expired - Fee Related KR101301115B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB0505790A GB2424511B (en) 2005-03-22 2005-03-22 Lithium sulphide battery and method of producing the same
GB0505790.6 2005-03-22
US66459205P 2005-03-24 2005-03-24
US60/664,592 2005-03-24
PCT/GB2006/001020 WO2006100464A2 (en) 2005-03-22 2006-03-21 Lithium sulphide battery and method of producing the same

Publications (2)

Publication Number Publication Date
KR20070113208A KR20070113208A (ko) 2007-11-28
KR101301115B1 true KR101301115B1 (ko) 2013-09-03

Family

ID=36968857

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020077019092A Expired - Fee Related KR101301115B1 (ko) 2005-03-22 2006-03-21 황화리튬 전지 및 그의 제조 방법

Country Status (6)

Country Link
US (3) US7695861B2 (enExample)
EP (1) EP1867000B1 (enExample)
JP (3) JP2008535154A (enExample)
KR (1) KR101301115B1 (enExample)
RU (1) RU2402842C2 (enExample)
WO (1) WO2006100464A2 (enExample)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10629947B2 (en) * 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell
US20060024579A1 (en) 2004-07-27 2006-02-02 Vladimir Kolosnitsyn Battery electrode structure and method for manufacture thereof
JP5466364B2 (ja) * 2004-12-02 2014-04-09 オクシス・エナジー・リミテッド リチウム・硫黄電池用電解質及びこれを使用するリチウム・硫黄電池
JP5651284B2 (ja) * 2005-01-18 2015-01-07 オクシス・エナジー・リミテッド リチウム−硫黄電池
EP1867000B1 (en) * 2005-03-22 2011-10-05 Oxis Energy Limited Lithium sulphide battery and method of producing the same
JP5442257B2 (ja) * 2005-09-26 2014-03-12 オクシス・エナジー・リミテッド 高い比エネルギーを備えたリチウム−硫黄バッテリ
GB0615870D0 (en) * 2006-08-10 2006-09-20 Oxis Energy Ltd An electrolyte for batteries with a metal lithium electrode
WO2008070059A2 (en) 2006-12-04 2008-06-12 Sion Power Corporation Separation of electrolytes in lithium batteries
US20110076560A1 (en) * 2009-08-28 2011-03-31 Sion Power Corporation Electrochemical cells comprising porous structures comprising sulfur
US11909077B2 (en) 2008-06-12 2024-02-20 Massachusetts Institute Of Technology High energy density redox flow device
US8722226B2 (en) 2008-06-12 2014-05-13 24M Technologies, Inc. High energy density redox flow device
EP2409349A4 (en) * 2009-03-19 2013-05-01 Sion Power Corp CATHODE FOR LITHIUM BATTERY
DE102010018731A1 (de) * 2010-04-29 2011-11-03 Li-Tec Battery Gmbh Lithium-Schwefel-Batterie
GB2482914A (en) * 2010-08-20 2012-02-22 Leclanche Sa Lithium Cell Electrolyte
CN103299455A (zh) * 2010-12-28 2013-09-11 三井金属矿业株式会社 锂二次电池用正极活性物质的制造方法
FR2979755B1 (fr) * 2011-09-02 2015-06-05 Commissariat Energie Atomique Accumulateur electrochimique de type lithium-soufre (li-s) et son procede de realisation
US9077041B2 (en) 2012-02-14 2015-07-07 Sion Power Corporation Electrode structure for electrochemical cell
EP2629352A1 (en) 2012-02-17 2013-08-21 Oxis Energy Limited Reinforced metal foil electrode
US9406960B2 (en) * 2012-03-28 2016-08-02 Battelle Memorial Institute Energy storage systems having an electrode comprising LixSy
KR101991149B1 (ko) 2012-12-19 2019-06-19 시온 파워 코퍼레이션 전극 구조물 및 그의 제조 방법
US9257699B2 (en) 2013-03-07 2016-02-09 Uchicago Argonne, Llc Sulfur cathode hosted in porous organic polymeric matrices
EP2784852B1 (en) 2013-03-25 2018-05-16 Oxis Energy Limited A method of charging a lithium-sulphur cell
EP2784850A1 (en) 2013-03-25 2014-10-01 Oxis Energy Limited A method of cycling a lithium-sulphur cell
PL2784851T3 (pl) 2013-03-25 2015-12-31 Oxis Energy Ltd Sposób ładowania ogniwa litowo-siarkowego
KR101497330B1 (ko) 2013-06-03 2015-03-02 주식회사 엘지화학 황-리튬 이온 전지용 전극 조립체 및 이를 포함하는 황-리튬 이온 전지
JP6048751B2 (ja) * 2013-06-06 2016-12-21 株式会社豊田自動織機 リチウムイオン二次電池用集電体、リチウムイオン二次電池用電極及びリチウムイオン二次電池
GB2517228B (en) 2013-08-15 2016-03-02 Oxis Energy Ltd Laminate cell
WO2015023154A1 (ko) * 2013-08-16 2015-02-19 주식회사 엘지화학 리튬-황 전지용 양극 및 이의 제조방법
US9899705B2 (en) 2013-12-17 2018-02-20 Oxis Energy Limited Electrolyte for a lithium-sulphur cell
WO2015126932A1 (en) * 2014-02-18 2015-08-27 Brookhaven Science Associates, Llc Multifunctional cathode additives for battery technologies
JP2017515277A (ja) 2014-05-01 2017-06-08 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ 電極製造方法および関連システムおよび物品
HUE042287T2 (hu) 2014-05-30 2019-06-28 Oxis Energy Ltd Lítium-kén cella
US20180233742A1 (en) * 2014-10-08 2018-08-16 Wayne State University Electrocatalysis of lithium polysulfides: current collectors as electrodes in li/s battery configuration
US10439219B2 (en) * 2015-04-17 2019-10-08 Uchicago Argonne, Llc Ultrastable cathodes for lithium sulfur batteries
US11784341B2 (en) * 2015-12-08 2023-10-10 The Chinese University Of Hong Kong High-energy density and low-cost flow electrochemical devices with moving rechargeable anode and cathode belts
JP6686860B2 (ja) * 2016-12-09 2020-04-22 トヨタ自動車株式会社 硫化物固体電解質の製造方法
CN106816634B (zh) * 2017-03-10 2019-12-10 中国计量大学 一种伪高浓度锂硫电池电解液和锂硫电池
PL3605703T3 (pl) * 2017-03-22 2021-10-25 Mitsubishi Gas Chemical Company, Inc. Sposób wytwarzania elektrolitu stałego na bazie lgps
WO2018222349A1 (en) * 2017-06-02 2018-12-06 Nanotek Instruments, Inc. Shape-conformable alkali metal-sulfur battery
KR102160707B1 (ko) * 2017-09-22 2020-09-28 주식회사 엘지화학 리튬-황 전지의 수명 개선 방법
KR102713206B1 (ko) * 2018-11-01 2024-10-02 주식회사 엘지에너지솔루션 Li2S/S 대칭셀의 구동 방법
US12237498B2 (en) 2019-07-22 2025-02-25 University Of Wyoming Apparatus and methods for fabrication of carbon foams and silicon-carbon composite anodes
US11283070B1 (en) 2021-04-22 2022-03-22 Massachusetts Instilute of Technology Aluminum-chalcogen batteries with alkali halide molten salt electrolytes
JP7753024B2 (ja) * 2021-09-29 2025-10-14 古河電池株式会社 リチウム硫黄二次電池用正極、リチウム硫黄二次電池及びリチウム硫黄二次電池用正極の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117590A (en) 1995-06-07 2000-09-12 Moltech Corporation Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same
US20020039677A1 (en) 2000-07-17 2002-04-04 Kazuya Iwamoto Non-aqueous electrochemical apparatus
US20020192557A1 (en) 2001-06-01 2002-12-19 Samsung Sdi Co., Ltd. Lithium-sulfur batteries

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3185590A (en) 1961-01-06 1965-05-25 North American Aviation Inc Lightweight secondary battery
US3578500A (en) 1968-07-08 1971-05-11 American Cyanamid Co Nonaqueous electro-chemical current producing cell having soluble cathode depolarizer
US3639174A (en) 1970-04-22 1972-02-01 Du Pont Voltaic cells with lithium-aluminum alloy anode and nonaqueous solvent electrolyte system
US3778310A (en) 1972-05-01 1973-12-11 Du Pont High energy density battery having unsaturated heterocyclic solvent containing electrolyte
US3877983A (en) 1973-05-14 1975-04-15 Du Pont Thin film polymer-bonded cathode
US3907597A (en) 1974-09-27 1975-09-23 Union Carbide Corp Nonaqueous cell having an electrolyte containing sulfolane or an alkyl-substituted derivative thereof
US3947291A (en) * 1974-09-30 1976-03-30 The United States Of America As Represented By The United States Energy Research And Development Administration Electrochemical cell assembled in discharged state
US3993501A (en) * 1975-03-24 1976-11-23 Union Carbide Corporation Nonaqueous electrochemical cell
US4048389A (en) * 1976-02-18 1977-09-13 Union Carbide Corporation Cathode or cathode collector arcuate bodies for use in various cell systems
US4060674A (en) 1976-12-14 1977-11-29 Exxon Research And Engineering Company Alkali metal anode-containing cells having electrolytes of organometallic-alkali metal salts and organic solvents
US4104451A (en) 1977-09-26 1978-08-01 Exxon Research & Engineering Co. Alkali metal anode/chalcogenide cathode reversible batteries having alkali metal polyaryl metallic compound electrolytes
US4118550A (en) 1977-09-26 1978-10-03 Eic Corporation Aprotic solvent electrolytes and batteries using same
US4163829A (en) 1977-11-14 1979-08-07 Union Carbide Corporation Metallic reducing additives for solid cathodes for use in nonaqueous cells
FR2442512A1 (fr) 1978-11-22 1980-06-20 Anvar Nouveaux materiaux elastomeres a conduction ionique
US4218523A (en) * 1979-02-28 1980-08-19 Union Carbide Corporation Nonaqueous electrochemical cell
US4252876A (en) 1979-07-02 1981-02-24 Eic Corporation Lithium battery
IL61085A (en) * 1980-09-19 1983-07-31 Univ Ramot Nonaqueous sulfur cell
JPS59194361A (ja) 1983-03-18 1984-11-05 Toshiba Battery Co Ltd 空気電池
US4499161A (en) 1983-04-25 1985-02-12 Eic Laboratories, Inc. Electrochemical cell using dimethoxymethane and/or trimethoxymethane as solvent for electrolyte
US4550064A (en) 1983-12-08 1985-10-29 California Institute Of Technology High cycle life secondary lithium battery
FR2576712B1 (fr) 1985-01-30 1988-07-08 Accumulateurs Fixes Generateur electrochimique a electrolyte non aqueux
EP0208254B1 (en) 1985-07-05 1993-02-24 Showa Denko Kabushiki Kaisha Secondary battery
US4725927A (en) 1986-04-08 1988-02-16 Asahi Glass Company Ltd. Electric double layer capacitor
CA2016777C (en) 1989-05-16 1993-10-12 Norio Takami Nonaqueous electrolyte secondary battery
US5219684A (en) 1990-05-16 1993-06-15 Her Majesty The Queen In Right Of Canada, As Represented By The Province Of British Columbia Electrochemical cells containing a safety electrolyte solvent
US5587253A (en) 1993-03-05 1996-12-24 Bell Communications Research, Inc. Low resistance rechargeable lithium-ion battery
US5460905A (en) 1993-06-16 1995-10-24 Moltech Corporation High capacity cathodes for secondary cells
US5648187A (en) 1994-02-16 1997-07-15 Moltech Corporation Stabilized anode for lithium-polymer batteries
US5961672A (en) 1994-02-16 1999-10-05 Moltech Corporation Stabilized anode for lithium-polymer batteries
JPH0869812A (ja) 1994-08-30 1996-03-12 Shin Kobe Electric Mach Co Ltd 密閉形鉛蓄電池およびその製造法
JPH08138650A (ja) 1994-11-01 1996-05-31 Dainippon Ink & Chem Inc 非水電解液二次電池用炭素質電極板および二次電池
US6020089A (en) 1994-11-07 2000-02-01 Sumitomo Electric Industries, Ltd. Electrode plate for battery
US6030720A (en) 1994-11-23 2000-02-29 Polyplus Battery Co., Inc. Liquid electrolyte lithium-sulfur batteries
US5814420A (en) * 1994-11-23 1998-09-29 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US5686201A (en) 1994-11-23 1997-11-11 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US5582623A (en) 1994-11-23 1996-12-10 Polyplus Battery Company, Inc. Methods of fabricating rechargeable positive electrodes
US5848351A (en) 1995-04-03 1998-12-08 Mitsubishi Materials Corporation Porous metallic material having high specific surface area, method of producing the same, porous metallic plate material and electrode for alkaline secondary battery
JPH08298229A (ja) 1995-04-26 1996-11-12 Mitsubishi Chem Corp 電気二重層コンデンサ用電解液
JPH08298230A (ja) 1995-04-26 1996-11-12 Mitsubishi Chem Corp 電気二重層コンデンサ用電解液
US5529860A (en) 1995-06-07 1996-06-25 Moltech Corporation Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same
US5773168A (en) * 1995-08-23 1998-06-30 Kabushiki Kaisha Toshiba Nonaqueous electrolyte secondary battery and method for manufacturing the same
JPH09147913A (ja) 1995-11-22 1997-06-06 Sanyo Electric Co Ltd 非水電解質電池
US5797428A (en) 1996-01-11 1998-08-25 Vemco Corporation Pop-alert device
WO1997044840A1 (en) 1996-05-22 1997-11-27 Moltech Corporation Composite cathodes, electrochemical cells comprising novel composite cathodes, and processes for fabricating same
JP4083224B2 (ja) 1996-06-14 2008-04-30 サイオン パワー コーポレイション ２次電池セルの電解質に有用な組成物
JPH10284076A (ja) 1997-04-01 1998-10-23 Matsushita Electric Ind Co Ltd アルカリ蓄電池及びその電極の製造方法
US6090504A (en) 1997-09-24 2000-07-18 Korea Kumho Petrochemical Co., Ltd. High capacity composite electrode and secondary cell therefrom
WO1999019932A1 (en) 1997-10-15 1999-04-22 Moltech Corporation Non-aqueous electrolyte solvents for secondary cells
US6201100B1 (en) 1997-12-19 2001-03-13 Moltech Corporation Electroactive, energy-storing, highly crosslinked, polysulfide-containing organic polymers and methods for making same
US6302928B1 (en) 1998-12-17 2001-10-16 Moltech Corporation Electrochemical cells with high volumetric density of electroactive sulfur-containing materials in cathode active layers
JP3573992B2 (ja) 1999-02-15 2004-10-06 三洋電機株式会社 リチウム二次電池
JP2000311684A (ja) * 1999-04-26 2000-11-07 Matsushita Electric Ind Co Ltd リチウム二次電池およびその正極の製造方法
JP2000340225A (ja) * 1999-05-26 2000-12-08 Matsushita Electric Ind Co Ltd 複合電極組成物およびこれを用いたリチウム電池
KR100322449B1 (ko) 1999-06-07 2002-02-07 김순택 리튬 이차 전지용 전해액 및 이를 사용한 리튬 이차 전지
US6733924B1 (en) 1999-11-23 2004-05-11 Moltech Corporation Lithium anodes for electrochemical cells
US6797428B1 (en) 1999-11-23 2004-09-28 Moltech Corporation Lithium anodes for electrochemical cells
WO2001097304A1 (en) 2000-06-12 2001-12-20 Korea Institute Of Science And Technology Multi-layered lithium electrode, its preparation and lithium batteries comprising it
KR100326466B1 (ko) * 2000-07-25 2002-02-28 김순택 리튬 설퍼 전지용 전해액
KR100326467B1 (ko) 2000-07-25 2002-02-28 김순택 리튬 설퍼 전지용 전해액
JP4080335B2 (ja) 2000-12-21 2008-04-23 シオン・パワー・コーポレーション 電気化学電池のためのリチウム負極
US6632573B1 (en) 2001-02-20 2003-10-14 Polyplus Battery Company Electrolytes with strong oxidizing additives for lithium/sulfur batteries
JP2002329495A (ja) * 2001-05-01 2002-11-15 Matsushita Electric Ind Co Ltd リチウム二次電池とその製造方法
KR100472513B1 (ko) 2002-11-16 2005-03-11 삼성에스디아이 주식회사 리튬 설퍼 전지용 유기 전해액 및 이를 채용한 리튬 설퍼전지
JP2004179160A (ja) 2002-11-26 2004-06-24 Samsung Sdi Co Ltd リチウム−硫黄電池用正極
JP4055642B2 (ja) * 2003-05-01 2008-03-05 日産自動車株式会社 高速充放電用電極および電池
JP2005108724A (ja) * 2003-09-30 2005-04-21 Sanyo Electric Co Ltd 非水電解質二次電池
JP2005158313A (ja) * 2003-11-21 2005-06-16 Sanyo Electric Co Ltd 非水電解質二次電池
JP4535722B2 (ja) * 2003-12-24 2010-09-01 三洋電機株式会社 非水電解質二次電池
JP2005251473A (ja) * 2004-03-02 2005-09-15 Sanyo Electric Co Ltd 非水電解質二次電池
US20060024579A1 (en) 2004-07-27 2006-02-02 Vladimir Kolosnitsyn Battery electrode structure and method for manufacture thereof
JP5466364B2 (ja) 2004-12-02 2014-04-09 オクシス・エナジー・リミテッド リチウム・硫黄電池用電解質及びこれを使用するリチウム・硫黄電池
JP5651284B2 (ja) 2005-01-18 2015-01-07 オクシス・エナジー・リミテッド リチウム−硫黄電池
EP1867000B1 (en) * 2005-03-22 2011-10-05 Oxis Energy Limited Lithium sulphide battery and method of producing the same
JP5442257B2 (ja) 2005-09-26 2014-03-12 オクシス・エナジー・リミテッド 高い比エネルギーを備えたリチウム−硫黄バッテリ

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117590A (en) 1995-06-07 2000-09-12 Moltech Corporation Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same
US20020039677A1 (en) 2000-07-17 2002-04-04 Kazuya Iwamoto Non-aqueous electrochemical apparatus
US20020192557A1 (en) 2001-06-01 2002-12-19 Samsung Sdi Co., Ltd. Lithium-sulfur batteries
JP2002367678A (ja) * 2001-06-01 2002-12-20 Samsung Sdi Co Ltd リチウム−硫黄電池

Also Published As

Publication number Publication date
US7695861B2 (en) 2010-04-13
JP2014089964A (ja) 2014-05-15
JP2008535154A (ja) 2008-08-28
WO2006100464A2 (en) 2006-09-28
US20100196757A1 (en) 2010-08-05
KR20070113208A (ko) 2007-11-28
JP2014089965A (ja) 2014-05-15
EP1867000B1 (en) 2011-10-05
US20060234126A1 (en) 2006-10-19
US20120189921A1 (en) 2012-07-26
WO2006100464A3 (en) 2006-12-21
RU2402842C2 (ru) 2010-10-27
RU2007139012A (ru) 2009-04-27
US8361652B2 (en) 2013-01-29
EP1867000A2 (en) 2007-12-19

Similar Documents

Publication Publication Date Title
KR101301115B1 (ko) 황화리튬 전지 및 그의 제조 방법
JP5947774B2 (ja) 高い比エネルギーを備えたリチウム−硫黄バッテリ
JP5297383B2 (ja) 高比エネルギーのリチウム−硫黄電池及びその動作法
US9196929B2 (en) Electrolyte compositions for batteries using sulphur or sulphur compounds
KR20100136564A (ko) 네거티브 리튬 전극을 구비한 재충전식 전지
KR20150049794A (ko) 리튬황 전지의 양극 및 이의 제조방법
US9406960B2 (en) Energy storage systems having an electrode comprising LixSy
CN101278426B (zh) 具有高比能量的锂-硫电池
CN101128954B (zh) 硫化锂电池及其制造方法
RU2431908C2 (ru) Химический источник электрической энергии
GB2422244A (en) Improvements relating to electrolyte compositions for batteries using sulphur or sulphur compounds
GB2443852A (en) A Lithium-Sulphur battery with a high specific energy and a method of operating same

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

FPAY Annual fee payment

Payment date: 20160726

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20170725

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

FPAY Annual fee payment

Payment date: 20180724

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

FPAY Annual fee payment

Payment date: 20190724

Year of fee payment: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 10

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R14-asn-PN2301

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 11

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R14-asn-PN2301

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20240823

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20240823