JP2007530736A - 粒子含有固体表面材料 - Google Patents
粒子含有固体表面材料 Download PDFInfo
- Publication number
- JP2007530736A JP2007530736A JP2007505048A JP2007505048A JP2007530736A JP 2007530736 A JP2007530736 A JP 2007530736A JP 2007505048 A JP2007505048 A JP 2007505048A JP 2007505048 A JP2007505048 A JP 2007505048A JP 2007530736 A JP2007530736 A JP 2007530736A
- Authority
- JP
- Japan
- Prior art keywords
- particles
- composition
- range
- meth
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002245 particle Substances 0.000 title claims abstract description 66
- 239000000463 material Substances 0.000 title claims abstract description 37
- 239000007787 solid Substances 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 239000007788 liquid Substances 0.000 claims abstract description 27
- 238000009826 distribution Methods 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 15
- 239000002243 precursor Substances 0.000 claims abstract description 3
- 238000000465 moulding Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 229920006037 cross link polymer Polymers 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 3
- 239000008199 coating composition Substances 0.000 claims description 2
- 239000008247 solid mixture Substances 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 17
- 239000000178 monomer Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- -1 2-ethylhexyl Chemical group 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- 239000000654 additive Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000012669 liquid formulation Substances 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229910052612 amphibole Inorganic materials 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 150000004682 monohydrates Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052611 pyroxene Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- JBMKAUGHUNFTOL-UHFFFAOYSA-N Aldoclor Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC2=C1NC=NS2(=O)=O JBMKAUGHUNFTOL-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 239000010441 alabaster Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011045 chalcedony Substances 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229910052949 galena Inorganic materials 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 229910052598 goethite Inorganic materials 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 description 1
- 239000012705 liquid precursor Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000005332 obsidian Substances 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000011044 quartzite Substances 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910021646 siderite Inorganic materials 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910052950 sphalerite Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229910052861 titanite Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Dental Preparations (AREA)
Abstract
Description
(a)1ミクロン〜300ミクロンの範囲の分布を有する第1の粒子、および
(b)0.1mm〜12mmの範囲の分布を有する第2の粒子、
を含み、該成形組成物が、少なくとも2つのカルボン酸基を有し、および1モル当り300グラム〜5,000グラムの範囲内の分子量を有するポリカルボン酸またはその塩をさらに含有することを特徴とする組成物に関する。
固体表面材料の液体前駆体の必須成分は液状の重合可能な成分である。
本発明の成形組成物は場合によっては少なくとも1種の非架橋樹脂ポリマーを含んでいる。本発明の非架橋樹脂ポリマーは、反応性、非反応性、またはこれらの組み合せであってもよい。非架橋樹脂ポリマーは、そのポリマーが成形組成物中の他の成分と物理的に会合するか、または化学的に反応する場合「反応性」である。
本発明において固体粒子の沈降を遅延または防止するための必須成分は、少なくとも2つのカルボン酸基を有し、および1モル当り300グラム〜5,000グラムの範囲内の分子量を有するポリカルボン酸またはその塩である。好ましい範囲は1モル当り300グラム〜1000グラムである。
本発明では、粒子は2つの異なる径分布で存在している。本発明の粒子沈降を遅延または減少する効果は、ただ1つの粒子径分布が存在している場合は所望の程度には起こらないと考えられる。
液状成形組成物は、典型的には、硬化剤、顔料およびその他の添加剤などのさらなる成分を含んでいるものである。
表に掲載されている成分を反応ケトルに加え、減圧下にて高速分散ブレードで4分間混合した。得られた混合物を1リットルの目盛り付きシリンダーの中に注いだ。熱伝対をこの混合物中に入れ、その目盛り付きシリンダーを60℃の水浴の中に沈めた。反応温度を反応が完結するまで監視した(約1時間)。冷却してサンプルを目盛り付きシリンダーから難なく取り出し、縦方向にカットして粒子の沈降を観察した。ほとんど全て、すなわち個々の粒子の95%超が、得られた物品の縦断面のおよそ三分の一の部分に集中していた。個々の粒子の5%未満が縦方向断面の残りの三分の二の部分にランダムに存在していた。
表に掲載されている成分をByk(登録商標)−P105(n−ブチルメタアクリレート中70重量%の低分子量カルボン酸ポリマー)5gと一緒に反応ケトルに加え、減圧下にて高速分散ブレードで4分間混合した。得られた混合物を1リットルの目盛り付きシリンダーの中に注いだ。熱伝対をこの混合物中に入れ、その目盛り付きシリンダーを60℃の水浴の中に沈めた。反応温度を反応が完結するまで監視した(約1時間)。冷却してサンプルを目盛り付きシリンダーから難なく取り出し、縦方向にカットして粒子の沈降が起こったかどうかを観察した。縦方向の断面には、均一性があり、多く見ても、沈降が起こっていたのは少量であった。
表に掲載されている成分をEfka(登録商標)5071(カルボン酸のアルキロールアンモニウム塩51〜55%)5gと一緒に反応ケトルに加え、減圧下にて高速分散ブレードで4分間混合した。得られた混合物を1リットルの目盛り付きシリンダーの中に注いだ。熱伝対をこの混合物中に入れ、その目盛り付きシリンダーを60℃の水浴の中に沈めた。反応温度を反応が完結するまで監視した(約1時間)。冷却してサンプルを目盛り付きシリンダーから難なく取り出し、縦方向にカットして粒子の沈降が起こったかどうかを観察した。縦方向の断面には、均一性があり、多く見ても、沈降が起こっていたのは少量であった。
表に掲載されている成分をEfka(登録商標)5065(アルキルベンゼン/ジイソブチルケトン中有機変性されたポリシロキサンと組み合わせた不飽和カルボン酸50〜54%)5gと一緒に反応ケトルに加え、減圧下にて高速分散ブレードで4分間混合した。得られた混合物を1リットルの目盛り付きシリンダーの中に注いだ。熱伝対をこの混合物中に入れ、その目盛り付きシリンダーを60℃の水浴の中に沈めた。反応温度を反応が完結するまで監視した(約1時間)。冷却してサンプルを目盛り付きシリンダーから難なく取り出し、縦方向にカットして粒子の沈降が起こったかどうかを観察した。縦方向の断面には、均一性があり、多く見ても、沈降が起こっていたのは少量であった。
Claims (10)
- 固体表面材料の前駆体である液状成形組成物であって、液状の重合可能な成分、少なくとも2つのカルボン酸基を有し、および1モル当り300グラム〜50,000グラムの範囲内の分子量を有するポリカルボン酸またはその塩、および固体粒子を含み、該粒子が、
(a)1ミクロン〜300ミクロンの範囲の分布を有する第1の粒子、および
(b)0.1mm〜12mmの範囲の分布を有する第2の粒子、
を含むことを特徴とする組成物。 - 前記分子量が1モル当り300グラム〜1000グラムの範囲であることを特徴とする請求項1に記載の組成物。
- 酸または塩の濃度が、液状の重合可能な成分の0.1〜1.0重量パーセントの範囲であることを特徴とする請求項1に記載の組成物。
- 第1の粒子が1〜100ミクロンの範囲であり、第2の粒子が3〜5mmの範囲であることを特徴とする請求項1に記載の組成物。
- アクリル酸またはメタクリル酸のエステルを含有することを特徴とする請求項1に記載の組成物。
- 非架橋ポリマーを含有することを特徴とする請求項1に記載の組成物。
- 第1の粒子が1〜100ミクロンの範囲であり、第2の粒子が0.1〜5mmの範囲であることを特徴とする請求項1に記載の組成物。
- 組成物の全重量を基準にして、第1の粒子が10〜70重量パーセントの量で存在しており、第2の粒子が1〜50重量パーセントの量で存在していることを特徴とする請求項1に記載の組成物。
- 第1の粒子が30〜65重量パーセントの量で存在しており、第2の粒子が3〜40重量パーセントの量で存在していることを特徴とする請求項8に記載の組成物。
- 請求項1に記載の液体コーティング組成物から形成された固体組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/806,583 | 2004-03-23 | ||
US10/806,583 US7247667B2 (en) | 2004-03-23 | 2004-03-23 | Particle containing solid surface material |
PCT/US2005/009281 WO2005095504A1 (en) | 2004-03-23 | 2005-03-21 | Particle containing solid surface material |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2007530736A true JP2007530736A (ja) | 2007-11-01 |
JP2007530736A5 JP2007530736A5 (ja) | 2008-03-13 |
JP4880585B2 JP4880585B2 (ja) | 2012-02-22 |
Family
ID=34964451
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007505048A Active JP4880585B2 (ja) | 2004-03-23 | 2005-03-21 | 粒子含有固体表面材料 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7247667B2 (ja) |
EP (1) | EP1730223B1 (ja) |
JP (1) | JP4880585B2 (ja) |
KR (1) | KR101221133B1 (ja) |
AU (1) | AU2005228855B2 (ja) |
BR (1) | BRPI0508203A (ja) |
CA (1) | CA2557431C (ja) |
DE (1) | DE602005004900T2 (ja) |
MX (1) | MXPA06010777A (ja) |
NZ (1) | NZ549066A (ja) |
WO (1) | WO2005095504A1 (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10297827B2 (en) | 2004-01-06 | 2019-05-21 | Sion Power Corporation | Electrochemical cell, components thereof, and methods of making and using same |
US8828610B2 (en) | 2004-01-06 | 2014-09-09 | Sion Power Corporation | Electrolytes for lithium sulfur cells |
US7358012B2 (en) | 2004-01-06 | 2008-04-15 | Sion Power Corporation | Electrolytes for lithium sulfur cells |
CA2554134C (en) * | 2004-01-23 | 2012-09-11 | Blanco Gmbh + Co Kg | Casting mass, in particular, for the production of kitchen sinks, molded sanitary articles, kitchen worktops or the like |
US20090099292A1 (en) * | 2007-10-12 | 2009-04-16 | Arizona Cultured Stone Products, Inc. | Filler system and process for manufacturing cast polymer parts |
US20090298968A1 (en) * | 2008-06-03 | 2009-12-03 | Rafael Bury | Decorative composition and method of using it |
DE102008032204A1 (de) * | 2008-07-09 | 2010-02-11 | A.S. Crèation Tapetenfabrik GmbH | PUR-Tapete mit dekorativer Oberfläche |
EP2609647B1 (en) | 2010-08-24 | 2017-03-15 | Sion Power Corporation | Electrolyte materials for use in electrochemical cells |
US8735002B2 (en) | 2011-09-07 | 2014-05-27 | Sion Power Corporation | Lithium sulfur electrochemical cell including insoluble nitrogen-containing compound |
US9577289B2 (en) | 2012-12-17 | 2017-02-21 | Sion Power Corporation | Lithium-ion electrochemical cell, components thereof, and methods of making and using same |
KR101562092B1 (ko) * | 2012-12-20 | 2015-10-20 | 제일모직주식회사 | 무정형 무늬를 갖는 실리카 인조대리석 및 그 제조방법 |
CN115259834B (zh) * | 2022-06-08 | 2023-02-28 | 景德镇陶瓷大学 | 一种以高钙型铁尾矿为主要原料的建筑陶瓷制备方法及其陶瓷制品 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS515383A (ja) * | 1974-05-29 | 1976-01-17 | Ici Ltd | |
JPH0558697A (ja) * | 1990-12-21 | 1993-03-09 | Enichem Sintesi Spa | 人工の大理石またはみかげ石の生産のための組成物 |
JPH07501098A (ja) * | 1991-11-15 | 1995-02-02 | インペリアル ケミカル インダストリーズ パブリック リミティド カンパニー | 重合性組成物 |
JPH10310459A (ja) * | 1997-03-10 | 1998-11-24 | Kumagai Gumi Co Ltd | レジンコンクリート |
JP2003138026A (ja) * | 2001-11-05 | 2003-05-14 | Nippon Shokubai Co Ltd | 樹脂組成物および成形品 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1571428A1 (de) | 1966-08-18 | 1970-12-10 | Domus Hartbeton Richard Bauer | Moertelmischung sowie Verfahren und Vorrichtung zu deren Herstellung |
US3865788A (en) | 1973-08-20 | 1975-02-11 | Dart Ind Inc | Organopolysiloxane elastomers exhibiting high elongation |
US3865778A (en) * | 1974-02-07 | 1975-02-11 | Gen Electric | Heat vulcanizable silicone rubber compositions resistant to oil degradation |
US4221697A (en) * | 1974-05-29 | 1980-09-09 | Imperial Chemical Industries Limited | Composite materials |
US4085246A (en) | 1975-06-18 | 1978-04-18 | E. I. Du Pont De Nemours And Company | Simulated granite and its preparation |
US4115479A (en) * | 1976-08-11 | 1978-09-19 | Vynacron Dental Co. | Casting resins by polymerizing liquid monomer in mixture of particulated vinyl halide resins |
US4229328A (en) * | 1978-11-27 | 1980-10-21 | Sony Corporation | Electrically conductive resin composition |
GB2147001B (en) | 1983-09-24 | 1987-02-11 | Bip Chemicals Ltd | Filled thermoplastics |
JPS63239052A (ja) * | 1987-03-27 | 1988-10-05 | 松下電工株式会社 | 人造大理石の製造方法 |
US5212217A (en) * | 1987-11-26 | 1993-05-18 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Artificial marble from reactive thermoplastic, monomer and anhydride |
JPH062804B2 (ja) * | 1987-11-26 | 1994-01-12 | 株式会社日本触媒 | 人工大理石用樹脂組成物 |
WO1990001470A1 (en) * | 1988-07-29 | 1990-02-22 | E.I. Du Pont De Nemours And Company | Simulated colored granite and process |
JPH0286642A (ja) * | 1988-09-22 | 1990-03-27 | Mitsui Petrochem Ind Ltd | 人造石用組成物および人造石成型品 |
US5281633A (en) * | 1988-10-21 | 1994-01-25 | Takeda Chemical Industries, Ltd. | Unsaturated polyester molding compounds and the articles thereof |
US4925886A (en) | 1989-01-23 | 1990-05-15 | General Motors Corporation | High temperature epoxy tooling composition of bifunctional epoxy, trifunctional epoxy, anhydride, imidazole and interstitially matched filler |
US5985972A (en) * | 1993-11-26 | 1999-11-16 | Aristech Acrylics Llc | Acrylic sheet having uniform distribution of coloring and mineral filler before and after thermoforming |
WO1996011890A1 (fr) * | 1994-10-14 | 1996-04-25 | Mitsubishi Rayon Co., Ltd. | Marbre artificiel et son procede de production |
DE19507875A1 (de) | 1995-03-07 | 1996-09-12 | Roehm Gmbh | Verfahren zur Herstellung hochgefüllter Kunststoffe |
US6348092B1 (en) | 1999-10-25 | 2002-02-19 | George K. Atkinson | Surface treatments for pigments providing improved dispersibility and exhibiting biocidal activity |
KR100422788B1 (ko) * | 2001-10-09 | 2004-03-16 | 주식회사 화성산업 | 천연석 질감을 갖는 박판 인조석재 및 이의 제조방법 |
US20050096417A1 (en) * | 2003-11-03 | 2005-05-05 | Quackenbush James M. | Curable resinous compositions and scratch resistant countertops derived therefrom |
-
2004
- 2004-03-23 US US10/806,583 patent/US7247667B2/en active Active
-
2005
- 2005-03-21 DE DE602005004900T patent/DE602005004900T2/de active Active
- 2005-03-21 EP EP05731335A patent/EP1730223B1/en active Active
- 2005-03-21 BR BRPI0508203-0A patent/BRPI0508203A/pt active Search and Examination
- 2005-03-21 WO PCT/US2005/009281 patent/WO2005095504A1/en active IP Right Grant
- 2005-03-21 MX MXPA06010777A patent/MXPA06010777A/es active IP Right Grant
- 2005-03-21 JP JP2007505048A patent/JP4880585B2/ja active Active
- 2005-03-21 CA CA2557431A patent/CA2557431C/en not_active Expired - Fee Related
- 2005-03-21 AU AU2005228855A patent/AU2005228855B2/en not_active Ceased
- 2005-03-21 NZ NZ549066A patent/NZ549066A/xx not_active IP Right Cessation
- 2005-03-21 KR KR1020067019541A patent/KR101221133B1/ko active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS515383A (ja) * | 1974-05-29 | 1976-01-17 | Ici Ltd | |
JPH0558697A (ja) * | 1990-12-21 | 1993-03-09 | Enichem Sintesi Spa | 人工の大理石またはみかげ石の生産のための組成物 |
JPH07501098A (ja) * | 1991-11-15 | 1995-02-02 | インペリアル ケミカル インダストリーズ パブリック リミティド カンパニー | 重合性組成物 |
JPH10310459A (ja) * | 1997-03-10 | 1998-11-24 | Kumagai Gumi Co Ltd | レジンコンクリート |
JP2003138026A (ja) * | 2001-11-05 | 2003-05-14 | Nippon Shokubai Co Ltd | 樹脂組成物および成形品 |
Also Published As
Publication number | Publication date |
---|---|
EP1730223A1 (en) | 2006-12-13 |
BRPI0508203A (pt) | 2007-07-17 |
US7247667B2 (en) | 2007-07-24 |
NZ549066A (en) | 2009-07-31 |
CA2557431A1 (en) | 2005-10-13 |
EP1730223B1 (en) | 2008-02-20 |
DE602005004900T2 (de) | 2009-02-12 |
JP4880585B2 (ja) | 2012-02-22 |
MXPA06010777A (es) | 2006-12-15 |
AU2005228855B2 (en) | 2009-11-26 |
WO2005095504A1 (en) | 2005-10-13 |
KR101221133B1 (ko) | 2013-01-10 |
DE602005004900D1 (de) | 2008-04-03 |
CA2557431C (en) | 2013-02-12 |
AU2005228855A1 (en) | 2005-10-13 |
KR20070005639A (ko) | 2007-01-10 |
US20050215683A1 (en) | 2005-09-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4880585B2 (ja) | 粒子含有固体表面材料 | |
JP2008508390A (ja) | スチレン−メタクリル酸メチル共重合体を含む樹脂組成物、該組成物を用いて製造された人造大理石及びその製造方法 | |
RU2360881C2 (ru) | Композитное изделие с твердой поверхностью, содержащее охру | |
JP2008546888A (ja) | 固体充填剤を含有する重合性組成物、それによって形成された物品および形成方法 | |
JPS6124357B2 (ja) | ||
US8481611B2 (en) | Artificial marble and preparation method thereof | |
WO1991001353A1 (en) | Resin-based artificial marble compositions | |
JPH05156112A (ja) | 高充填重合性組成物 | |
WO1998035919A1 (fr) | Pierre artificielle noctilucente ou fluorescente | |
KR101404426B1 (ko) | 발포 또는 개방 세포 구조를 갖는 인조대리석용 칩, 이를 포함하는 인조대리석 및 그 제조방법 | |
KR20040005044A (ko) | 마블칩의 침강 편차가 없는 인조 대리석 | |
WO2015023569A1 (en) | Panels jointed with methacrylate ipn adhesive | |
CN115180872A (zh) | 用于合成石材的组合物 | |
EP3033365A1 (en) | Polymerizable adhesive that forms methacrylate ipn | |
JP4766777B2 (ja) | 液状/粉末状からなる2材型硬化組成物 | |
JP2000053838A (ja) | 人工大理石用樹脂組成物、その成形体及び成形体の接着方法 | |
KR100898555B1 (ko) | 가공성과 내스크래치성이 우수한 경화성 조성물, 경화물 및그 제조방법 | |
KR20060064154A (ko) | 미분칩을 함유한 인조 대리석 조성물 | |
WO2008143391A1 (en) | Artificial marble | |
JP2000044759A (ja) | 人工大理石用樹脂組成物 | |
JP2001145918A (ja) | 人工石板の製造方法及び人工石板 | |
JP2000351118A (ja) | シリカ系成形材料の取り扱い方法 | |
JP2000351902A (ja) | シリカ系成形材料およびその成形方法 | |
JPH05163049A (ja) | 透明感に優れた人工大理石又は模造花こう岩、及びそれらを製造する方法 | |
JP2002321956A (ja) | 人工大理石の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080122 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080122 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100811 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100813 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101115 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101122 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101208 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110701 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111013 |
|
RD13 | Notification of appointment of power of sub attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7433 Effective date: 20111014 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20111014 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20111107 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111129 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111201 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4880585 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141209 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |