JP2007525802A - 電気化学電池に使用するための液体材料 - Google Patents
電気化学電池に使用するための液体材料 Download PDFInfo
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- JP2007525802A JP2007525802A JP2006551306A JP2006551306A JP2007525802A JP 2007525802 A JP2007525802 A JP 2007525802A JP 2006551306 A JP2006551306 A JP 2006551306A JP 2006551306 A JP2006551306 A JP 2006551306A JP 2007525802 A JP2007525802 A JP 2007525802A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
- C08J5/2262—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation containing fluorine
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0221—Organic resins; Organic polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0234—Carbonaceous material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Conductive Materials (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53870604P | 2004-01-23 | 2004-01-23 | |
| US53887804P | 2004-01-23 | 2004-01-23 | |
| PCT/US2005/001956 WO2005086632A2 (en) | 2004-01-23 | 2005-01-21 | Liquid materials for use in electrochemical cells |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007525802A true JP2007525802A (ja) | 2007-09-06 |
| JP2007525802A5 JP2007525802A5 (https=) | 2008-11-06 |
Family
ID=34976057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006551306A Pending JP2007525802A (ja) | 2004-01-23 | 2005-01-21 | 電気化学電池に使用するための液体材料 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7435495B2 (https=) |
| EP (1) | EP1751814A4 (https=) |
| JP (1) | JP2007525802A (https=) |
| KR (1) | KR20070015130A (https=) |
| CA (1) | CA2554160A1 (https=) |
| TW (1) | TW200537731A (https=) |
| WO (1) | WO2005086632A2 (https=) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008149815A1 (ja) * | 2007-06-04 | 2008-12-11 | Kuraray Co., Ltd. | 高分子電解質、高分子電解質膜、膜-電極接合体及び固体高分子型燃料電池 |
| JP2009289463A (ja) * | 2008-05-27 | 2009-12-10 | Toyota Motor Corp | 固体高分子型燃料電池用膜電極接合体の製造方法、及び固体高分子型燃料電池 |
| JP2011241344A (ja) * | 2010-05-20 | 2011-12-01 | Toyota Central R&D Labs Inc | 高分子電解質及びその製造方法、イミドモノマ、並びに、電池 |
| JP2012009196A (ja) * | 2010-06-23 | 2012-01-12 | Toyota Motor Corp | 膜電極拡散層接合体およびその作製方法 |
| JP2012517095A (ja) * | 2009-02-05 | 2012-07-26 | ザ リサーチ ファウンデーション オブ ステイト ユニバーシティ オブ ニューヨーク | 移動変更用誘電勾配領域を有するエネルギー変換セルおよびその方法 |
Families Citing this family (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004102714A1 (ja) * | 2003-05-13 | 2004-11-25 | Asahi Glass Company, Limited | 固体高分子型燃料電池用電解質ポリマー、その製造方法及び膜・電極接合体 |
| CN1997691B (zh) * | 2003-09-23 | 2011-07-20 | 北卡罗来纳大学查珀尔希尔分校 | 光固化的全氟聚醚用作微流体器件中的新材料 |
| KR20070015130A (ko) * | 2004-01-23 | 2007-02-01 | 더 유니버시티 오브 노쓰 캐롤라이나 엣 채플 힐 | 전기화학 전지에 사용하기 위한 액체 물질 |
| CN101189271A (zh) * | 2004-02-13 | 2008-05-28 | 北卡罗来纳大学查珀尔希尔分校 | 制造微流体设备的功能材料和新型方法 |
| US7745036B2 (en) * | 2005-11-10 | 2010-06-29 | Panasonic Corporation | Direct oxidation fuel cell system and membrane electrode assembly thereof |
| EP1816493A1 (en) * | 2006-02-07 | 2007-08-08 | ETH Zürich | Tunable diffraction grating |
| JPWO2008023632A1 (ja) * | 2006-08-22 | 2010-01-07 | 株式会社東芝 | 膜電極接合体及びその製造方法と燃料電池 |
| US20100055459A1 (en) * | 2006-08-30 | 2010-03-04 | Liquidia Technologies, Inc. | Nanoparticles Having Functional Additives for Self and Directed Assembly and Methods of Fabricating Same |
| WO2008127455A2 (en) * | 2006-12-05 | 2008-10-23 | Liquidia Technologies, Inc. | Nanoarrays and methods and materials for fabricating same |
| GB0715225D0 (en) | 2007-08-03 | 2007-09-12 | Rolls Royce Fuel Cell Systems | A fuel cell and a method of manufacturing a fuel cell |
| EP2062933A1 (en) * | 2007-11-26 | 2009-05-27 | Solvay Solexis S.p.A. | Fluoroionomer liquid composition |
| DE102007060719A1 (de) * | 2007-12-09 | 2009-06-10 | FuMA-Tech Gesellschaft für funktionelle Membranen und Anlagentechnologie mbH | Brennstoffzelle, Protonen leitende Membran, Membran-Elektroden-Einheit, Verwendungen von Ionomeren und Kit |
| US9893337B2 (en) | 2008-02-13 | 2018-02-13 | Seeo, Inc. | Multi-phase electrolyte lithium batteries |
| US7867019B1 (en) * | 2009-07-17 | 2011-01-11 | Fluke Corporation | Thermal imaging device with a battery pack with a shock absorber |
| JP4988963B2 (ja) | 2010-02-04 | 2012-08-01 | パナソニック株式会社 | 燃料電池用高分子電解質膜の製造方法 |
| KR101272512B1 (ko) | 2010-12-03 | 2013-06-10 | 현대자동차주식회사 | 연료전지용 막-전극 어셈블리 제조 장치 및 방법 |
| JP5728452B2 (ja) * | 2011-09-28 | 2015-06-03 | 株式会社東芝 | 電気化学セル用触媒層、膜電極接合体及び電気化学セル |
| DE13847827T1 (de) | 2012-10-19 | 2016-03-10 | The University Of North Carolina At Chapel Hill | Ionenleitende polymere und polymermischungen für alkalimetallionenbatterien |
| BR112015018105A2 (pt) | 2013-02-12 | 2017-07-18 | Carbon3D Inc | método e aparelho para fabricação tridimensional |
| EP2956823B2 (en) | 2013-02-12 | 2019-07-03 | CARBON3D, Inc. | Continuous liquid interphase printing |
| KR20150139827A (ko) | 2013-04-01 | 2015-12-14 | 더 유니버시티 오브 노쓰 캐롤라이나 엣 채플 힐 | 알칼리 금속 이온 배터리를 위한 이온 전도성 플루오로중합체 카르보네이트 |
| WO2015142546A1 (en) | 2014-03-21 | 2015-09-24 | Carbon3D, Inc. | Method and apparatus for three-dimensional fabrication with gas injection through carrier |
| US10661501B2 (en) | 2014-06-20 | 2020-05-26 | Carbon, Inc. | Three-dimensional printing method using increased light intensity and apparatus therefor |
| MX2016017099A (es) | 2014-06-20 | 2017-08-07 | Carbon Inc | Impresion tridimensional con alimentacion reciproca de liquido polimerizable. |
| WO2015195909A1 (en) | 2014-06-20 | 2015-12-23 | Carbon3D, Inc. | Three-dimensional printing using tiled light engines |
| MX2016016627A (es) | 2014-06-23 | 2017-06-06 | Carbon Inc | Metodos de produccion de objetos tridimensionales a partir de materiales que tienen multiples mecanismos de endurecimiento. |
| US9212246B1 (en) | 2014-07-30 | 2015-12-15 | Nissan North America, Inc. | Methods of producing cross-linked polymer electrolyte membranes having free-radical scavengers |
| US9350035B2 (en) | 2014-07-30 | 2016-05-24 | Nissan North America, Inc. | Cross-linked polymer electrolyte membranes |
| US9403746B2 (en) | 2014-07-30 | 2016-08-02 | Nissan North America, Inc. | Cross-linked polymer electrolyte membranes and crosslinking monomer |
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| US11020898B2 (en) | 2015-01-30 | 2021-06-01 | Carbon, Inc. | Build plates for continuous liquid interface printing having permeable base and adhesive for increasing permeability and related methods, systems and devices |
| EP3250368A1 (en) | 2015-01-30 | 2017-12-06 | Carbon, Inc. | Build plates for continuous liquid interface printing having permeable sheets and related methods, systems and devices |
| US10077231B2 (en) | 2015-02-03 | 2018-09-18 | Blue Current, Inc. | Functionalized fluoropolymers and electrolyte compositions |
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| JP2018515893A (ja) * | 2015-05-21 | 2018-06-14 | ザ ユニバーシティ オブ ノース カロライナ アット チャペル ヒルThe University Of North Carolina At Chapel Hill | アルカリバッテリーの為のハイブリッド型固体シングルイオン伝導性電解質 |
| WO2016200559A1 (en) | 2015-06-09 | 2016-12-15 | Seeo, Inc. | Peo-based graft copolymers with pendant fluorinated groups for use as electrolytes |
| WO2017038487A1 (ja) * | 2015-08-31 | 2017-03-09 | 富士フイルム株式会社 | 半導体ナノ粒子、分散液、フィルムおよび半導体ナノ粒子の製造方法 |
| KR20180081489A (ko) | 2015-09-25 | 2018-07-16 | 카본, 인크. | 조명 패널을 갖는 연속적인 액체 상간 프린팅을 위한 빌드 플레이트 조립체 및 이와 관련된 방법, 시스템 및 장치 |
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| WO2008149815A1 (ja) * | 2007-06-04 | 2008-12-11 | Kuraray Co., Ltd. | 高分子電解質、高分子電解質膜、膜-電極接合体及び固体高分子型燃料電池 |
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| JP2012517095A (ja) * | 2009-02-05 | 2012-07-26 | ザ リサーチ ファウンデーション オブ ステイト ユニバーシティ オブ ニューヨーク | 移動変更用誘電勾配領域を有するエネルギー変換セルおよびその方法 |
| JP2011241344A (ja) * | 2010-05-20 | 2011-12-01 | Toyota Central R&D Labs Inc | 高分子電解質及びその製造方法、イミドモノマ、並びに、電池 |
| JP2012009196A (ja) * | 2010-06-23 | 2012-01-12 | Toyota Motor Corp | 膜電極拡散層接合体およびその作製方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090023038A1 (en) | 2009-01-22 |
| CA2554160A1 (en) | 2005-09-22 |
| EP1751814A2 (en) | 2007-02-14 |
| US20060083971A1 (en) | 2006-04-20 |
| WO2005086632A3 (en) | 2008-01-03 |
| WO2005086632A2 (en) | 2005-09-22 |
| TW200537731A (en) | 2005-11-16 |
| US7435495B2 (en) | 2008-10-14 |
| KR20070015130A (ko) | 2007-02-01 |
| EP1751814A4 (en) | 2010-01-13 |
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