JP2007503305A5 - - Google Patents
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- Publication number
- JP2007503305A5 JP2007503305A5 JP2006524620A JP2006524620A JP2007503305A5 JP 2007503305 A5 JP2007503305 A5 JP 2007503305A5 JP 2006524620 A JP2006524620 A JP 2006524620A JP 2006524620 A JP2006524620 A JP 2006524620A JP 2007503305 A5 JP2007503305 A5 JP 2007503305A5
- Authority
- JP
- Japan
- Prior art keywords
- support
- alumina
- modifier
- preformed
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 8
- 239000003054 catalyst Substances 0.000 claims 6
- 239000003607 modifier Substances 0.000 claims 6
- 150000001336 alkenes Chemical class 0.000 claims 5
- 238000001035 drying Methods 0.000 claims 5
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 4
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims 4
- 230000002708 enhancing effect Effects 0.000 claims 4
- 238000006735 epoxidation reaction Methods 0.000 claims 4
- 239000012808 vapor phase Substances 0.000 claims 4
- 239000004115 Sodium Silicate Substances 0.000 claims 3
- 238000001354 calcination Methods 0.000 claims 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 2
- 238000000151 deposition Methods 0.000 claims 2
- 238000010304 firing Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 239000004332 silver Substances 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- 239000004111 Potassium silicate Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003426 co-catalyst Substances 0.000 claims 1
- 239000003398 denaturant Substances 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims 1
- 229910052912 lithium silicate Inorganic materials 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 229910052913 potassium silicate Inorganic materials 0.000 claims 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims 1
- 235000019353 potassium silicate Nutrition 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical group [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49745203P | 2003-08-22 | 2003-08-22 | |
| US60/497,452 | 2003-08-22 | ||
| PCT/US2004/017103 WO2005023418A1 (en) | 2003-08-22 | 2004-06-02 | Improved alumina carriers and silver-based catalysts for the production of alkylene oxides |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007503305A JP2007503305A (ja) | 2007-02-22 |
| JP2007503305A5 true JP2007503305A5 (cg-RX-API-DMAC7.html) | 2007-08-02 |
| JP4870561B2 JP4870561B2 (ja) | 2012-02-08 |
Family
ID=34272572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006524620A Expired - Fee Related JP4870561B2 (ja) | 2003-08-22 | 2004-06-02 | アルキレンオキサイドの製造用の改良されたアルミナ担体及び銀系触媒 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20060258532A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1658136A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP4870561B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1838991A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2538992C (cg-RX-API-DMAC7.html) |
| IN (1) | IN2006CH00632A (cg-RX-API-DMAC7.html) |
| RU (1) | RU2372342C2 (cg-RX-API-DMAC7.html) |
| SG (1) | SG177010A1 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI352623B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2005023418A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2340607C2 (ru) * | 2003-08-22 | 2008-12-10 | Дау Текнолоджи Инвестментс Ллс | Модифицированные носители из оксида алюминия и катализаторы на основе серебра для получения алкиленоксидов |
| WO2005039757A1 (en) | 2003-10-16 | 2005-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production |
| MY140568A (en) | 2004-06-18 | 2009-12-31 | Shell Int Research | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
| WO2006009756A1 (en) * | 2004-06-18 | 2006-01-26 | Shell Internationale Research Maatschappij B.V. | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
| BRPI0514814A (pt) * | 2004-09-01 | 2008-06-24 | Shell Int Research | processo de epoxidação de olefina, um catalisador para uso no processo, um veìculo para uso na preparação do catalisador, e processo para preparar o veìculo |
| US8536083B2 (en) | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
| JP5063367B2 (ja) * | 2005-02-21 | 2012-10-31 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンエポキシ化方法、この方法において使用する触媒、この触媒を作製する際に使用する担体、およびこの担体を作製する方法 |
| TWI334363B (en) * | 2005-06-07 | 2010-12-11 | Saint Gobain Ceramics | A catalyst carrier |
| WO2006133183A2 (en) * | 2005-06-07 | 2006-12-14 | Shell Internationale Research Maatschappij B.V. | A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
| WO2007123932A2 (en) * | 2006-04-18 | 2007-11-01 | Dow Global Technologies Inc. | Alkylene oxide catalyst and use thereof |
| US10159961B2 (en) | 2006-04-18 | 2018-12-25 | Dow Global Technologies Llc | Alkylene oxide catalyst and use thereof |
| WO2007129649A1 (ja) * | 2006-05-02 | 2007-11-15 | Nippon Shokubai Co., Ltd. | オレフィンの部分酸化用触媒、その製造方法およびアルキレンオキサイドの製造方法 |
| EP2620212A3 (en) | 2006-11-01 | 2014-01-15 | Dow Global Technologies LLC | Process for modifying shaped porous bodies of alpha-alumina, epoxidation catalyst comprising modified alpha-alumina and epoxidation method |
| JP5581058B2 (ja) * | 2008-01-11 | 2014-08-27 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| US8349765B2 (en) * | 2008-07-18 | 2013-01-08 | Scientific Design Company, Inc. | Mullite-containing carrier for ethylene oxide catalysts |
| JP5328452B2 (ja) * | 2009-03-31 | 2013-10-30 | 株式会社日本触媒 | 酸化エチレン製造用触媒の担体、酸化エチレン製造用触媒および酸化エチレンの製造方法 |
| CN102458651B (zh) | 2009-04-21 | 2015-06-10 | 陶氏技术投资有限公司 | 铼助催化的环氧化催化剂及其制造和使用方法 |
| EP2424826A2 (en) | 2009-04-29 | 2012-03-07 | Dow Technology Investments LLC | Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same |
| US8586769B2 (en) * | 2010-06-04 | 2013-11-19 | Scientific Design Company, Inc. | Carrier for ethylene oxide catalysts |
| CA2837864C (en) * | 2011-06-06 | 2019-07-23 | Dow Technology Investments Llc | Methods for producing epoxidation catalysts and epoxidation methods utilizing them |
| SG11201406103RA (en) * | 2012-03-27 | 2014-10-30 | Dow Technology Investments Llc | Method of making a manganese containing supported silver catalyst intermediate |
| CN103357438B (zh) * | 2012-03-28 | 2016-03-30 | 中国石油化工股份有限公司 | 一种制备用于银催化剂的氧化铝载体的方法及其银催化剂 |
| CN105916577B (zh) * | 2013-12-19 | 2018-03-30 | 科学设计有限公司 | 用于环氧乙烷催化剂制备的高浓度银溶液 |
| CN107790153B (zh) * | 2016-08-30 | 2020-10-27 | 中国石油化工股份有限公司 | 一种硅改性的费托合成催化剂及其应用 |
| CN107774259B (zh) * | 2016-08-30 | 2020-09-22 | 中国石油化工股份有限公司 | 一种费托合成催化剂及其应用 |
| TWI772322B (zh) * | 2016-09-02 | 2022-08-01 | 美商陶氏科技投資有限公司 | 製備環氧化催化劑之方法 |
| CN106947290A (zh) * | 2017-03-31 | 2017-07-14 | 合肥悦兰信息技术有限公司 | 彩色二氧化硅粉体材料的制备方法 |
| US20190022628A1 (en) * | 2017-07-24 | 2019-01-24 | Scientific Design Company, Inc. | Post impregnation heat treatment for silver-based epoxidation catalysts |
| CN112439399B (zh) * | 2019-08-29 | 2023-05-09 | 中国石油化工股份有限公司 | 一种α-氧化铝载体及制备方法和银催化剂与应用 |
| CN113244931B (zh) * | 2020-02-11 | 2022-05-03 | 中国石油化工股份有限公司 | 催化剂以及含不饱和烃气体的催化氧化脱氧方法 |
| CN114425373B (zh) * | 2020-09-25 | 2023-09-08 | 中国石油化工股份有限公司 | 一种α-氧化铝载体及制备方法和银催化剂与应用 |
| CN117654481A (zh) * | 2022-08-24 | 2024-03-08 | 中国石油化工股份有限公司 | 一种银催化剂用α-氧化铝载体及制备方法和银催化剂与应用 |
| US20250281920A1 (en) * | 2024-03-08 | 2025-09-11 | Scientific Design Company, Inc. | Methods for reducing small pores of catalyst carriers |
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| JP5063367B2 (ja) * | 2005-02-21 | 2012-10-31 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンエポキシ化方法、この方法において使用する触媒、この触媒を作製する際に使用する担体、およびこの担体を作製する方法 |
-
2004
- 2004-06-02 WO PCT/US2004/017103 patent/WO2005023418A1/en not_active Ceased
- 2004-06-02 EP EP04753843A patent/EP1658136A1/en not_active Withdrawn
- 2004-06-02 CA CA2538992A patent/CA2538992C/en not_active Expired - Lifetime
- 2004-06-02 RU RU2006109006/04A patent/RU2372342C2/ru not_active IP Right Cessation
- 2004-06-02 SG SG2008039414A patent/SG177010A1/en unknown
- 2004-06-02 JP JP2006524620A patent/JP4870561B2/ja not_active Expired - Fee Related
- 2004-06-02 CN CNA2004800241939A patent/CN1838991A/zh active Pending
- 2004-06-02 US US10/567,178 patent/US20060258532A1/en not_active Abandoned
- 2004-08-20 TW TW093125176A patent/TWI352623B/zh not_active IP Right Cessation
-
2006
- 2006-02-21 IN IN632CH2006 patent/IN2006CH00632A/en unknown
-
2010
- 2010-11-16 US US12/947,446 patent/US20110082029A1/en not_active Abandoned
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