JP2006524734A - 潤滑剤組成物 - Google Patents
潤滑剤組成物 Download PDFInfo
- Publication number
- JP2006524734A JP2006524734A JP2006506173A JP2006506173A JP2006524734A JP 2006524734 A JP2006524734 A JP 2006524734A JP 2006506173 A JP2006506173 A JP 2006506173A JP 2006506173 A JP2006506173 A JP 2006506173A JP 2006524734 A JP2006524734 A JP 2006524734A
- Authority
- JP
- Japan
- Prior art keywords
- neutral
- phosphate
- lubricant composition
- alkyl
- same meaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 239000000314 lubricant Substances 0.000 title claims abstract description 22
- -1 alkyl phosphorus compound Chemical class 0.000 claims abstract description 40
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011593 sulfur Substances 0.000 claims abstract description 38
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 38
- 230000007935 neutral effect Effects 0.000 claims abstract description 31
- 239000003921 oil Substances 0.000 claims abstract description 22
- 239000011574 phosphorus Substances 0.000 claims abstract description 17
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 13
- 239000012530 fluid Substances 0.000 claims abstract description 12
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005555 metalworking Methods 0.000 claims abstract description 8
- 239000010720 hydraulic oil Substances 0.000 claims abstract description 5
- 239000010723 turbine oil Substances 0.000 claims abstract description 5
- 239000012208 gear oil Substances 0.000 claims abstract description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 3
- HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 235000019198 oils Nutrition 0.000 claims description 20
- 229910019142 PO4 Inorganic materials 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 6
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 4
- 238000003672 processing method Methods 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 2
- OXFUXNFMHFCELM-UHFFFAOYSA-N tripropan-2-yl phosphate Chemical compound CC(C)OP(=O)(OC(C)C)OC(C)C OXFUXNFMHFCELM-UHFFFAOYSA-N 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- SPWVOTAHZLTQIV-UHFFFAOYSA-N 2,2,2-tributoxyethyl dihydrogen phosphite Chemical compound CCCCOC(COP(O)O)(OCCCC)OCCCC SPWVOTAHZLTQIV-UHFFFAOYSA-N 0.000 claims 1
- UJEZRICRVISIGK-UHFFFAOYSA-N 2-butoxyethyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCOCCCC)OCCCCCCCC UJEZRICRVISIGK-UHFFFAOYSA-N 0.000 claims 1
- QCGWSXUHMHSZRB-UHFFFAOYSA-N CCCCCCCCO[PH2]=O Chemical compound CCCCCCCCO[PH2]=O QCGWSXUHMHSZRB-UHFFFAOYSA-N 0.000 claims 1
- URZBWYCBVGRNDX-UHFFFAOYSA-N CCCCOCCO[PH2]=O Chemical compound CCCCOCCO[PH2]=O URZBWYCBVGRNDX-UHFFFAOYSA-N 0.000 claims 1
- XRGKFCPXITXBGE-UHFFFAOYSA-N P(OCCCCCCCC)(OCC(OCCCC)OCCCC)=O Chemical compound P(OCCCCCCCC)(OCC(OCCCC)OCCCC)=O XRGKFCPXITXBGE-UHFFFAOYSA-N 0.000 claims 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 claims 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 claims 1
- QOQNJVLFFRMJTQ-UHFFFAOYSA-N trioctyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OCCCCCCCC QOQNJVLFFRMJTQ-UHFFFAOYSA-N 0.000 claims 1
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 claims 1
- 239000000969 carrier Substances 0.000 abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 4
- 239000000194 fatty acid Substances 0.000 abstract description 4
- 229930195729 fatty acid Natural products 0.000 abstract description 4
- 239000005077 polysulfide Substances 0.000 abstract description 3
- 229920001021 polysulfide Polymers 0.000 abstract description 3
- 150000008117 polysulfides Polymers 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical class [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 description 15
- 239000000654 additive Substances 0.000 description 11
- 239000005069 Extreme pressure additive Substances 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 9
- 238000005520 cutting process Methods 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000002173 cutting fluid Substances 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000007866 anti-wear additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011885 synergistic combination Substances 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- PAIUCYAPMAEPIT-UHFFFAOYSA-N C(CCCCCCC)C(CCCCCCC)(CCCCCCCC)OP(O)=O Chemical compound C(CCCCCCC)C(CCCCCCC)(CCCCCCCC)OP(O)=O PAIUCYAPMAEPIT-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004907 Macro-emulsion Substances 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical class OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2221/041—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving sulfurisation of macromolecular compounds, e.g. polyolefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0309571 | 2003-04-28 | ||
| PCT/GB2004/001750 WO2004096959A1 (en) | 2003-04-28 | 2004-04-23 | Lubricant compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006524734A true JP2006524734A (ja) | 2006-11-02 |
| JP2006524734A5 JP2006524734A5 (enExample) | 2010-10-28 |
Family
ID=33397008
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006506173A Pending JP2006524734A (ja) | 2003-04-28 | 2004-04-23 | 潤滑剤組成物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20070087944A1 (enExample) |
| EP (1) | EP1618173A1 (enExample) |
| JP (1) | JP2006524734A (enExample) |
| KR (1) | KR20060015536A (enExample) |
| WO (1) | WO2004096959A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007231116A (ja) * | 2006-02-28 | 2007-09-13 | Nippon Oil Corp | 金属加工油組成物 |
| JP2008081532A (ja) * | 2006-09-26 | 2008-04-10 | Neos Co Ltd | 水溶性金属加工油剤組成物 |
| JP2012524167A (ja) * | 2009-04-15 | 2012-10-11 | ドルフ ケタール ケミカルズ（Ｉ） プライベート リミテッド | 高温ナフテン酸腐食防止のための非ポリマー性かつ非汚損性添加剤及びその使用方法 |
| JP2019206671A (ja) * | 2018-05-30 | 2019-12-05 | 出光興産株式会社 | 潤滑油組成物及びその製造方法、駆動系機器の潤滑方法並びに駆動系機器 |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0420256D0 (en) | 2004-09-13 | 2004-10-13 | Cassells John M | Method and apparatus for sampling and analysis of fluids |
| EP1690920A1 (en) | 2005-02-11 | 2006-08-16 | JohnsonDiversey, Inc. | Lubricant concentrate containing a phosphate triester |
| US20090036338A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Metalworking Fluid Compositions and Preparation Thereof |
| US20090036333A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Metalworking Fluid Compositions and Preparation Thereof |
| EP2147968A1 (en) | 2008-06-05 | 2010-01-27 | Castrol Limited | Compositions and methods |
| US9771540B2 (en) | 2009-01-20 | 2017-09-26 | Exxonmobil Research And Engineering Company | Hydraulic oil compositions with improved hydraulic motor efficiency |
| US10414964B2 (en) | 2015-06-30 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Lubricant compositions containing phosphates and/or phosphites and methods of making and using same |
| US10844264B2 (en) | 2015-06-30 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Lubricant compositions comprising diol functional groups and methods of making and using same |
| JP2017132875A (ja) | 2016-01-27 | 2017-08-03 | 東燃ゼネラル石油株式会社 | 潤滑油組成物 |
| JP6730122B2 (ja) * | 2016-07-28 | 2020-07-29 | Ｅｍｇルブリカンツ合同会社 | 潤滑油組成物 |
| IT201800010416A1 (it) * | 2018-11-19 | 2020-05-19 | Lamberti Spa | Additivi lubrificanti per la lavorazione dei metalli |
| CN111662773B (zh) * | 2019-03-07 | 2022-02-08 | 东莞市鹏润压铸材料科技有限公司 | 一种长效全合成镁合金切削液及加工方法 |
| KR20230119214A (ko) * | 2020-12-15 | 2023-08-16 | 토탈에너지스 원테크 | 엔진의 금속 부품의 부식 및/또는 마찰부식을 방지하기위한 윤활 조성물 |
| CN119775309A (zh) * | 2024-11-28 | 2025-04-08 | 云浮市云天新材料有限公司 | 一种抗乳化润滑液、其制备方法及其应用 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4925406B1 (enExample) * | 1969-11-26 | 1974-06-29 | ||
| JPS6160791A (ja) * | 1984-08-31 | 1986-03-28 | Hitachi Ltd | 塑性加工用潤滑剤及びそれを用いた塑性加工方法 |
| JPS61211398A (ja) * | 1985-03-18 | 1986-09-19 | Hitachi Ltd | 塑性加工用潤滑剤とその使用方法 |
| JPS62207396A (ja) * | 1986-03-07 | 1987-09-11 | Hitachi Ltd | 塑性加工用潤滑油およびそれを用いた塑性加工品 |
| JPH02300295A (ja) * | 1989-05-16 | 1990-12-12 | Yushiro Chem Ind Co Ltd | 不水溶性金属加工用切削油剤 |
| JPH08502542A (ja) * | 1992-10-30 | 1996-03-19 | カストロール・リミテッド | 防食性潤滑剤組成物 |
| JPH09125084A (ja) * | 1995-11-06 | 1997-05-13 | Nippon Oil Co Ltd | 切削加工油剤組成物 |
| JPH11209776A (ja) * | 1998-01-28 | 1999-08-03 | Idemitsu Kosan Co Ltd | 潤滑油組成物 |
| JP2000239684A (ja) * | 1999-02-24 | 2000-09-05 | Kyodo Yushi Co Ltd | 熱間圧延油及び熱間圧延方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB749678A (en) * | 1952-07-24 | 1956-05-30 | Res And Engineering Company | Lubricating oil composition |
| GB1205177A (en) * | 1968-05-22 | 1970-09-16 | Castrol Ltd | Improvements in or relating to lubricating compositions |
| GB1365943A (en) * | 1970-09-16 | 1974-09-04 | Gaf Corp | Metalworking additive and composition and process for making the same |
| US3843542A (en) * | 1972-07-31 | 1974-10-22 | Chevron Res | Hydraulic oil |
| US4137187A (en) * | 1977-08-10 | 1979-01-30 | Chevron Research Company | Antiwear additive and lubricating oil composition containing same |
| EP0135932B1 (en) * | 1983-09-28 | 1990-05-02 | Hitachi, Ltd. | Lubricant for metal forming and process for metal forming |
| US5308654A (en) * | 1990-05-30 | 1994-05-03 | Henkel Corporation | Method for lubricating steel tubing prior to cold drawing |
| WO1994028092A1 (en) * | 1993-05-27 | 1994-12-08 | Tonen Corporation | Refrigerator oil |
| JP3422869B2 (ja) * | 1995-01-27 | 2003-06-30 | 新日本石油株式会社 | Ｈｃｆｃ冷媒及びｈｆｃ冷媒に共用可能な冷凍機油組成物 |
| US6136759A (en) * | 1998-01-29 | 2000-10-24 | Idemitsu Kosan Co., Ltd. | Additive composition |
| US6255260B1 (en) * | 1998-03-26 | 2001-07-03 | David J. Stork | Metal forming lubricant with differential solid lubricants |
| CA2347794A1 (en) * | 1998-11-10 | 2000-05-18 | Exxonmobil Research And Engineering Company | Phosphate ester base stocks comprising mixed n-butyl/isobutyl phosphate esters and aircraft hydraulic fluids comprising the same |
| JP2000290676A (ja) * | 1999-04-05 | 2000-10-17 | Idemitsu Kosan Co Ltd | 金属加工油組成物 |
-
2004
- 2004-04-23 EP EP04729132A patent/EP1618173A1/en not_active Withdrawn
- 2004-04-23 JP JP2006506173A patent/JP2006524734A/ja active Pending
- 2004-04-23 US US10/554,653 patent/US20070087944A1/en not_active Abandoned
- 2004-04-23 WO PCT/GB2004/001750 patent/WO2004096959A1/en not_active Ceased
- 2004-04-23 KR KR1020057020339A patent/KR20060015536A/ko not_active Ceased
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4925406B1 (enExample) * | 1969-11-26 | 1974-06-29 | ||
| JPS6160791A (ja) * | 1984-08-31 | 1986-03-28 | Hitachi Ltd | 塑性加工用潤滑剤及びそれを用いた塑性加工方法 |
| JPS61211398A (ja) * | 1985-03-18 | 1986-09-19 | Hitachi Ltd | 塑性加工用潤滑剤とその使用方法 |
| JPS62207396A (ja) * | 1986-03-07 | 1987-09-11 | Hitachi Ltd | 塑性加工用潤滑油およびそれを用いた塑性加工品 |
| JPH02300295A (ja) * | 1989-05-16 | 1990-12-12 | Yushiro Chem Ind Co Ltd | 不水溶性金属加工用切削油剤 |
| JPH08502542A (ja) * | 1992-10-30 | 1996-03-19 | カストロール・リミテッド | 防食性潤滑剤組成物 |
| JPH09125084A (ja) * | 1995-11-06 | 1997-05-13 | Nippon Oil Co Ltd | 切削加工油剤組成物 |
| JPH11209776A (ja) * | 1998-01-28 | 1999-08-03 | Idemitsu Kosan Co Ltd | 潤滑油組成物 |
| JP2000239684A (ja) * | 1999-02-24 | 2000-09-05 | Kyodo Yushi Co Ltd | 熱間圧延油及び熱間圧延方法 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007231116A (ja) * | 2006-02-28 | 2007-09-13 | Nippon Oil Corp | 金属加工油組成物 |
| JP2008081532A (ja) * | 2006-09-26 | 2008-04-10 | Neos Co Ltd | 水溶性金属加工油剤組成物 |
| JP2012524167A (ja) * | 2009-04-15 | 2012-10-11 | ドルフ ケタール ケミカルズ（Ｉ） プライベート リミテッド | 高温ナフテン酸腐食防止のための非ポリマー性かつ非汚損性添加剤及びその使用方法 |
| JP2019206671A (ja) * | 2018-05-30 | 2019-12-05 | 出光興産株式会社 | 潤滑油組成物及びその製造方法、駆動系機器の潤滑方法並びに駆動系機器 |
| WO2019230405A1 (ja) * | 2018-05-30 | 2019-12-05 | 出光興産株式会社 | 潤滑油組成物及びその製造方法、駆動系機器の潤滑方法並びに駆動系機器 |
| JP7099876B2 (ja) | 2018-05-30 | 2022-07-12 | 出光興産株式会社 | 潤滑油組成物及びその製造方法、駆動系機器の潤滑方法並びに駆動系機器 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1618173A1 (en) | 2006-01-25 |
| US20070087944A1 (en) | 2007-04-19 |
| WO2004096959A1 (en) | 2004-11-11 |
| KR20060015536A (ko) | 2006-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2006524734A (ja) | 潤滑剤組成物 | |
| US4250046A (en) | Diethanol disulfide as an extreme pressure and anti-wear additive in water soluble metalworking fluids | |
| JP3816949B2 (ja) | 切削又は研削油組成物 | |
| CN108431191B (zh) | 金属加工液 | |
| Phillips et al. | Ashless phosphorus–containing lubricating oil additives | |
| JPS61141793A (ja) | 摺動兼金属加工用潤滑組成物を用いた工作機械の潤滑方法 | |
| WO2011121608A2 (en) | A broaching oil or heavy duty neat cutting oil composition | |
| JPWO1995032267A1 (ja) | 切削又は研削油組成物 | |
| JPH11279581A (ja) | 金属加工用水溶性油剤 | |
| JPH0780111B2 (ja) | 工作機械の潤滑方法 | |
| US6355604B2 (en) | Multifunctional aqueous lubricant based on dithiodiglycolic acid | |
| JP4321963B2 (ja) | リン酸エステル潤滑剤組成物および金属成形用途 | |
| GB1599714A (en) | High production rate metal shaping process | |
| JPH04202400A (ja) | 工作機械潤滑油兼用水溶性金属加工用油剤及び該油剤を用いた潤滑方法 | |
| JPH07508526A (ja) | ｏ，ｏ−ジアルキルジチオりん酸のアダクツの使用 | |
| JPH08501119A (ja) | 無アミン冷却潤滑剤 | |
| KR20020092976A (ko) | 인 화합물 및 황 화합물계 다용도 윤활제 | |
| JPH04178500A (ja) | 切削性良好な水溶性切削油剤組成物 | |
| JP2969280B2 (ja) | 金属加工油 | |
| JPS60141795A (ja) | 難削材用の切削・研削油剤 | |
| JP2000351982A (ja) | 切削研削加工用油剤組成物 | |
| JPH0747754B2 (ja) | 不水溶性金属加工用切削油剤 | |
| TW202513782A (zh) | 經改良潤滑流體及新穎含硫功能性添加劑 | |
| Nuțiu et al. | Composition for Anticorrosive Cooling and Protection Emulsion | |
| US2511731A (en) | Extreme pressure lubricants |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070202 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100601 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100604 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20100906 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20101008 |