US20070087944A1 - Lubricant compositions - Google Patents

Lubricant compositions Download PDF

Info

Publication number
US20070087944A1
US20070087944A1 US10/554,653 US55465304A US2007087944A1 US 20070087944 A1 US20070087944 A1 US 20070087944A1 US 55465304 A US55465304 A US 55465304A US 2007087944 A1 US2007087944 A1 US 2007087944A1
Authority
US
United States
Prior art keywords
phosphate
lubricant composition
neutral
sulphur
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/554,653
Other languages
English (en)
Inventor
William Phillips
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Switzerland GmbH
Original Assignee
Great Lakes Chemical Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Great Lakes Chemical Europe GmbH filed Critical Great Lakes Chemical Europe GmbH
Assigned to GREAT LAKES CHEMICAL (EUROPE) GMBH reassignment GREAT LAKES CHEMICAL (EUROPE) GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PHILLIPS, WILLIAM DAVID
Publication of US20070087944A1 publication Critical patent/US20070087944A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C10M2203/1065—Naphthenic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2221/041—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving sulfurisation of macromolecular compounds, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel

Definitions

  • This invention relates to novel lubricant compositions that are useful as lubricants in high load carrying oils, e.g. metal working fluids, gear oils, extreme pressure turbine oils and hydraulic oils.
  • the lubricant compositions of the invention are especially useful in metal working fluids.
  • the cutting of metal involves the expenditure of significant amounts of energy and the development of high temperatures as the cutting tool removes metal from the workpiece.
  • the lubricant used is able to operate efficiently under the conditions of operation. This means essentially that it is capable of working at very high loads and quickly removing the heat generated by the cutting process.
  • Mineral oil alone does not have sufficient lubricity to perform this function and it is necessary to incorporate additives to enhance this aspect of the oil's performance.
  • the most common extreme pressure additives have been those containing chlorine (for example C14-17 chlorinated paraffins), phosphorus containing additives in the form of neutral triaryl phosphates, alkyl or alkylaryl acid phosphates and alkylpolyalkoxy or alkylarylpolyalkoxy acid phosphates and sulphur carriers (for example sulphurised olefins, sulphurised esters, and sulphurised fats).
  • sulphur carriers for example sulphurised olefins, sulphurised esters, and sulphurised fats.
  • the level of performance offered by the different additives varies depending on the temperatures at which the active species are released to form a salt layer at the metal surface. This in turn depends on the speed and feed rate of the cutting tool, the type and hardness of the alloy being machined and the specific machining operation.
  • oil in water emulsions and water based solutions are also commonly used in applications which require less lubricity.
  • additives are required to improve the lubrication performance of the fluid.
  • the type of phosphorus-containing additives which are found in metal working fluids are typically alkyl or alkylaryl acid phosphates and alkylpolyalkoxy or alkylarylpolyalkoxy acid phosphates used either as the free acid or neutralised with basic materials such as alkanolamines and caustic soda e.g. products sold under the trade marks of Lubrhophos and Rhodafac; neutral triaryl phosphates e.g. synthetic isopropylated phenyl phosphates such as are available commercially under the Durad trde mark.
  • One objective of the present invention is to provide a novel lubricant composition which improves the cutting performance of both neat oil and water based cutting fluids.
  • Another objective of the present invention is to replace acid phosphates as extreme pressure/anti wear additives in metal working applications. This objective has been achieved by the combination of certain neutral alkyl phosphorus compounds with certain sulphur carriers.
  • a lubricant composition for a high load carrying oil comprising:
  • the lubricant composition of the invention can comprise one or more of the compounds of general formulae I to XIII.
  • the neutral alkyl phosphorus compound and the sulphur carrier are utilised in a weight ratio of P to S content from 1:50 to 1:1, preferably a weight ratio of 1:1 to 1:30.
  • Preferred sulphur carriers are selected from at least one of sulphurised synthetic esters, sulphurised hydrocarbons (e.g. sulphurised olefins), sulphurised vegetable oils and fats, metal sulphonates, metal dialkyldithiophosphates and triaryl phosphorothionates.
  • sulphurised synthetic esters e.g. sulphurised hydrocarbons (e.g. sulphurised olefins), sulphurised vegetable oils and fats, metal sulphonates, metal dialkyldithiophosphates and triaryl phosphorothionates.
  • the sulphur carriers serve to release sulphur at the cutting face of the workpiece where it reacts to form a lubricating film at relatively high temperatures.
  • the present invention is also a high load carrying oil which contains a lubricant composition as described above.
  • the high load carrying oil may be a metal working fluid, a gear oil, an extreme pressure turbine oil or a hydraulic oil.
  • the present invention is also a method for working metal comprising (a) contacting a metal workpiece with a lubricant composition as described above and (b) working the metal workpiece.
  • the lubricant composition of the invention can include other components conventional in the art, e.g. surfactants, non-ionic alcohols.
  • Durad is a registered trade mark of Great Lakes Chemical Corporation.
  • an automatic drilling machine is used to drill holes in metal discs 40 mm thick.
  • the holes are 18 mm deep while, for oil-based cutting fluids, the drill feeds and speeds were 0.13 mm/rev (or 156 mm/min) and 1200 rpm respectively. Tests were carried out until the drill failed either due to breakage or to excessive wear. The average of at least duplicate test results are quoted.
  • the metal used was EN24T carbon steel; the drill feeds and speeds were as indicated below and the base stock was an ISO VG 22 paraffinic oil. In this case the S/P ratio was 13:1.
  • the formulation containing Durad TiBP is seen to be significantly more active than the chlorparaffin.
  • Formulation (w/w) 1 2 3 TiBP 0.6 — Sulphur carrier (36.7% sulphur - all active) 2.5 — 4.3 Chlorparaffin (40% chlorine) — 8.0 — ISO VG 22 paraffinic oil 96.9 92.0 95.7 Holes drilled to failure 280 140 100
  • B Drill Life Tests on Stainless Steel Using Neat Oil: A Comparison with Acid Phosphates
  • Stainless steel type 304 was used for this study.
  • the sulphur carriers used were a 4:1 mix of a sulphurised fatty acid ester (26% total sulphur of which 15% is active) and a dialkyl polysulphide (40% total sulphur of which 36% is active).
  • the levels of sulphur and phosphorus used were 1.5% and 0.5% respectively giving an S/P ratio of 3:1.
  • the oil used was an ISO VG 22 Group 1 base.
  • Durad TiBP is seen to be a most effective additive which in combination with the sulphur carriers shows a significant improvement over the sulphur carriers alone.
  • the sulphur carriers used RC2526 and RC2540 were the same as used in the previous Examples.
  • the drill feed rate was 150 mm/min and the speed was 1500 rpm. The depth of hole was 18 mm.
  • Formulation (w/w) Holes drilled to failure Sulphur carriers alone 56 Sulphur carriers plus Dioctyl octyl phosphonate 336 Sulphur carriers plus TBEP 500+
  • lubricity additives such as fatty oils and long chain esters can be used in cutting fluids, these were not included in the formulations shown above.
  • a major benefit of the present invention is that neutral alkyl phosphorus compounds provide a synergistic performance with sulphur carriers in both neat oil and aqueous cutting fluids on both mild steel and stainless steel. Such a synergistic combination enables the formulation of cutting fluids with the following properties:
  • neutral alkyl phosphorus compounds also allows higher levels of phosphorus to be used when necessary. Where acid phosphates are used, the acidity effectively limits the level of phosphorus that can be used because the acid can become corrosive at high levels. This allows for more flexibility in formulating mixtures of P/S and higher levels where necessary depending on the severity of the worling process.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
US10/554,653 2003-04-28 2004-04-23 Lubricant compositions Abandoned US20070087944A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0309571 2003-04-28
GB0309571.8 2003-04-28
PCT/GB2004/001750 WO2004096959A1 (en) 2003-04-28 2004-04-23 Lubricant compositions

Publications (1)

Publication Number Publication Date
US20070087944A1 true US20070087944A1 (en) 2007-04-19

Family

ID=33397008

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/554,653 Abandoned US20070087944A1 (en) 2003-04-28 2004-04-23 Lubricant compositions

Country Status (5)

Country Link
US (1) US20070087944A1 (enExample)
EP (1) EP1618173A1 (enExample)
JP (1) JP2006524734A (enExample)
KR (1) KR20060015536A (enExample)
WO (1) WO2004096959A1 (enExample)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090036338A1 (en) * 2007-07-31 2009-02-05 Chevron U.S.A. Inc. Metalworking Fluid Compositions and Preparation Thereof
US20090036333A1 (en) * 2007-07-31 2009-02-05 Chevron U.S.A. Inc. Metalworking Fluid Compositions and Preparation Thereof
WO2010119417A1 (en) * 2009-04-15 2010-10-21 Dorf Ketal Chemicals (I) Pvt. Ltd. An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same
US10414964B2 (en) 2015-06-30 2019-09-17 Exxonmobil Chemical Patents Inc. Lubricant compositions containing phosphates and/or phosphites and methods of making and using same
CN111662773A (zh) * 2019-03-07 2020-09-15 东莞市鹏润压铸材料科技有限公司 一种长效全合成镁合金切削液及加工方法
US10844264B2 (en) 2015-06-30 2020-11-24 Exxonmobil Chemical Patents Inc. Lubricant compositions comprising diol functional groups and methods of making and using same
US11274261B2 (en) * 2018-11-19 2022-03-15 Lamberti Spa Lubricant additives for metal working
US20240076571A1 (en) * 2020-12-15 2024-03-07 Totalenergies Onetech Lubricating composition to prevent corrosion and/or tribocorrosion of metallic parts in an engine
CN119775309A (zh) * 2024-11-28 2025-04-08 云浮市云天新材料有限公司 一种抗乳化润滑液、其制备方法及其应用

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0420256D0 (en) 2004-09-13 2004-10-13 Cassells John M Method and apparatus for sampling and analysis of fluids
EP1690920A1 (en) 2005-02-11 2006-08-16 JohnsonDiversey, Inc. Lubricant concentrate containing a phosphate triester
JP4979244B2 (ja) * 2006-02-28 2012-07-18 Ｊｘ日鉱日石エネルギー株式会社 金属加工油組成物
JP5232372B2 (ja) * 2006-09-26 2013-07-10 株式会社ネオス 水溶性金属加工油剤組成物
EP2147968A1 (en) 2008-06-05 2010-01-27 Castrol Limited Compositions and methods
US9771540B2 (en) 2009-01-20 2017-09-26 Exxonmobil Research And Engineering Company Hydraulic oil compositions with improved hydraulic motor efficiency
JP2017132875A (ja) 2016-01-27 2017-08-03 東燃ゼネラル石油株式会社 潤滑油組成物
JP6730122B2 (ja) * 2016-07-28 2020-07-29 Ｅｍｇルブリカンツ合同会社 潤滑油組成物
JP7099876B2 (ja) * 2018-05-30 2022-07-12 出光興産株式会社 潤滑油組成物及びその製造方法、駆動系機器の潤滑方法並びに駆動系機器

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3843542A (en) * 1972-07-31 1974-10-22 Chevron Res Hydraulic oil
US3933658A (en) * 1970-09-16 1976-01-20 Gaf Corporation Metalworking additive and composition
US4137187A (en) * 1977-08-10 1979-01-30 Chevron Research Company Antiwear additive and lubricating oil composition containing same
US4612127A (en) * 1983-09-28 1986-09-16 Hitachi, Ltd. Lubricant for metal forming and process for metal forming
US5308654A (en) * 1990-05-30 1994-05-03 Henkel Corporation Method for lubricating steel tubing prior to cold drawing
US5728655A (en) * 1995-01-27 1998-03-17 Mitsubishi Oil Company, Limited Refrigerating machine oil composition for use with HCFC and HFC refrigerants
US5804096A (en) * 1993-05-27 1998-09-08 Tonen Corporation Refrigerating machine oil
US6136759A (en) * 1998-01-29 2000-10-24 Idemitsu Kosan Co., Ltd. Additive composition
US6255260B1 (en) * 1998-03-26 2001-07-03 David J. Stork Metal forming lubricant with differential solid lubricants
US6254799B1 (en) * 1998-11-10 2001-07-03 Exxonmobil Research And Engineering Company Phosphate ester base stocks comprising mixed n-butyl/isobutyl phosphate esters and aircraft hydraulic fluids comprising the same
US6562766B1 (en) * 1999-04-05 2003-05-13 Idemitsu Kosan Co., Ltd. Metal working oil composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB749678A (en) * 1952-07-24 1956-05-30 Res And Engineering Company Lubricating oil composition
GB1205177A (en) * 1968-05-22 1970-09-16 Castrol Ltd Improvements in or relating to lubricating compositions
JPS4925406B1 (enExample) * 1969-11-26 1974-06-29
JPH0229714B2 (ja) * 1984-08-31 1990-07-02 Hitachi Ltd Soseikakoyojunkatsuzaioyobisoreomochiitasoseikakohoho
JPS61211398A (ja) * 1985-03-18 1986-09-19 Hitachi Ltd 塑性加工用潤滑剤とその使用方法
JPS62207396A (ja) * 1986-03-07 1987-09-11 Hitachi Ltd 塑性加工用潤滑油およびそれを用いた塑性加工品
JPH0747754B2 (ja) * 1989-05-16 1995-05-24 ユシロ化学工業株式会社 不水溶性金属加工用切削油剤
GB2272000B (en) * 1992-10-30 1997-03-26 Castrol Ltd A method of inhibiting corrosion
JP3425020B2 (ja) * 1995-11-06 2003-07-07 新日本石油株式会社 切削加工油剤組成物
JPH11209776A (ja) * 1998-01-28 1999-08-03 Idemitsu Kosan Co Ltd 潤滑油組成物
JP4464477B2 (ja) * 1999-02-24 2010-05-19 協同油脂株式会社 熱間圧延油及び熱間圧延方法

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3933658A (en) * 1970-09-16 1976-01-20 Gaf Corporation Metalworking additive and composition
US3843542A (en) * 1972-07-31 1974-10-22 Chevron Res Hydraulic oil
US4137187A (en) * 1977-08-10 1979-01-30 Chevron Research Company Antiwear additive and lubricating oil composition containing same
US4612127A (en) * 1983-09-28 1986-09-16 Hitachi, Ltd. Lubricant for metal forming and process for metal forming
US5308654A (en) * 1990-05-30 1994-05-03 Henkel Corporation Method for lubricating steel tubing prior to cold drawing
US5804096A (en) * 1993-05-27 1998-09-08 Tonen Corporation Refrigerating machine oil
US5728655A (en) * 1995-01-27 1998-03-17 Mitsubishi Oil Company, Limited Refrigerating machine oil composition for use with HCFC and HFC refrigerants
US6136759A (en) * 1998-01-29 2000-10-24 Idemitsu Kosan Co., Ltd. Additive composition
US6255260B1 (en) * 1998-03-26 2001-07-03 David J. Stork Metal forming lubricant with differential solid lubricants
US6254799B1 (en) * 1998-11-10 2001-07-03 Exxonmobil Research And Engineering Company Phosphate ester base stocks comprising mixed n-butyl/isobutyl phosphate esters and aircraft hydraulic fluids comprising the same
US6562766B1 (en) * 1999-04-05 2003-05-13 Idemitsu Kosan Co., Ltd. Metal working oil composition

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090036338A1 (en) * 2007-07-31 2009-02-05 Chevron U.S.A. Inc. Metalworking Fluid Compositions and Preparation Thereof
US20090036333A1 (en) * 2007-07-31 2009-02-05 Chevron U.S.A. Inc. Metalworking Fluid Compositions and Preparation Thereof
KR101644592B1 (ko) 2009-04-15 2016-08-01 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 고온 나프텐산 부식 억제에 효과적인 신규 비중합 및 논-파울링 첨가제, 및 이를 이용한 고온 나프텐산 부식 억제 방법
KR20120013380A (ko) * 2009-04-15 2012-02-14 도르프 케탈 케미칼즈 (아이) 피브이티 리미티드 고온 나프텐산 부식 억제에 효과적인 신규 비중합 및 논-파울링 첨가제, 및 이를 이용한 고온 나프텐산 부식 억제 방법
CN102459521A (zh) * 2009-04-15 2012-05-16 多尔夫凯塔尔化学制品（I）私人有限公司 用于抑制高温环烷酸腐蚀的有效的新型非聚合物且不污性添加剂及其使用方法
AU2010238162B2 (en) * 2009-04-15 2014-05-15 Dorf Ketal Chemicals (I) Pvt. Ltd. An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same
WO2010119417A1 (en) * 2009-04-15 2010-10-21 Dorf Ketal Chemicals (I) Pvt. Ltd. An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same
US9777230B2 (en) 2009-04-15 2017-10-03 Dorf Ketal Chemicals (India) Private Limited Effective novel non-polymeric and non-fouling additive for inhibiting high-temperature naphthenic acid corrosion and method of using the same
US10414964B2 (en) 2015-06-30 2019-09-17 Exxonmobil Chemical Patents Inc. Lubricant compositions containing phosphates and/or phosphites and methods of making and using same
US10844264B2 (en) 2015-06-30 2020-11-24 Exxonmobil Chemical Patents Inc. Lubricant compositions comprising diol functional groups and methods of making and using same
US11274261B2 (en) * 2018-11-19 2022-03-15 Lamberti Spa Lubricant additives for metal working
CN111662773A (zh) * 2019-03-07 2020-09-15 东莞市鹏润压铸材料科技有限公司 一种长效全合成镁合金切削液及加工方法
US20240076571A1 (en) * 2020-12-15 2024-03-07 Totalenergies Onetech Lubricating composition to prevent corrosion and/or tribocorrosion of metallic parts in an engine
US12187973B2 (en) * 2020-12-15 2025-01-07 Totalenergies Onetech Lubricating composition to prevent corrosion and/or tribocorrosion of metallic parts in an engine
CN119775309A (zh) * 2024-11-28 2025-04-08 云浮市云天新材料有限公司 一种抗乳化润滑液、其制备方法及其应用

Also Published As

Publication number Publication date
JP2006524734A (ja) 2006-11-02
EP1618173A1 (en) 2006-01-25
WO2004096959A1 (en) 2004-11-11
KR20060015536A (ko) 2006-02-17

Similar Documents

Publication Publication Date Title
US20070087944A1 (en) Lubricant compositions
US11186800B2 (en) Metalworking fluid
US4250046A (en) Diethanol disulfide as an extreme pressure and anti-wear additive in water soluble metalworking fluids
JPS61141793A (ja) 摺動兼金属加工用潤滑組成物を用いた工作機械の潤滑方法
GB1321173A (en) Method of lubricating machine tools
WO2011121608A2 (en) A broaching oil or heavy duty neat cutting oil composition
KR100525973B1 (ko) 금속가공액
US7645727B2 (en) Gear cutting oil
CN106929137A (zh) 全合成切削液
Clarens et al. Experimental comparison of vegetable and petroleum base oils in metalworking fluids using the tapping torque test
JPH11279581A (ja) 金属加工用水溶性油剤
JPS61142050A (ja) 工作機械の潤滑方法
US20130150271A1 (en) Metalworking fluid composition and method for its use in the machining of compacted graphite iron
US5348670A (en) Phosphorous amine lubricant additives
GB1599714A (en) High production rate metal shaping process
CA2496230C (en) Antimicrobial metal working fluids
JP2002003881A (ja) ジチオジグリコール酸をベースとする多機能水性潤滑剤
JPH04202400A (ja) 工作機械潤滑油兼用水溶性金属加工用油剤及び該油剤を用いた潤滑方法
JPH04178500A (ja) 切削性良好な水溶性切削油剤組成物
TW202513782A (zh) 經改良潤滑流體及新穎含硫功能性添加劑
JPH0445557B2 (enExample)
Nuțiu et al. Composition for Anticorrosive Cooling and Protection Emulsion
Beiswanger et al. Phosphate ester acids as load-carrying additives and rust inhibitors for metalworking fluids
JP3109540B2 (ja) 摺動面用潤滑油剤
EP0375412A1 (en) Synthetic metalworking fluid

Legal Events

Date Code Title Description
AS Assignment

Owner name: GREAT LAKES CHEMICAL (EUROPE) GMBH, SWITZERLAND

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PHILLIPS, WILLIAM DAVID;REEL/FRAME:017886/0363

Effective date: 20051020

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION