JP2002504565A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2002504565A5 JP2002504565A5 JP2000532445A JP2000532445A JP2002504565A5 JP 2002504565 A5 JP2002504565 A5 JP 2002504565A5 JP 2000532445 A JP2000532445 A JP 2000532445A JP 2000532445 A JP2000532445 A JP 2000532445A JP 2002504565 A5 JP2002504565 A5 JP 2002504565A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- aryl
- compound
- metallocene
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 125000000217 alkyl group Chemical group 0.000 description 17
- 125000003118 aryl group Chemical group 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 8
- 125000003710 aryl alkyl group Chemical group 0.000 description 7
- 125000002877 alkyl aryl group Chemical group 0.000 description 6
- -1 Lewis acid cation Chemical class 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 150000008040 ionic compounds Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000005018 aryl alkenyl group Chemical group 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Chemical group 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 125000004407 fluoroaryl group Chemical group 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Chemical group 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052715 tantalum Chemical group 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical group [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19806435A DE19806435A1 (de) | 1998-02-17 | 1998-02-17 | Verfahren zur Herstellung eines geträgerten Katalysatorsystems |
| DE19806435.7 | 1998-02-17 | ||
| PCT/EP1999/000784 WO1999042493A1 (de) | 1998-02-17 | 1999-02-05 | Verfahren zur herstellung eines geträgerten katalysatorsystems |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002504565A JP2002504565A (ja) | 2002-02-12 |
| JP2002504565A5 true JP2002504565A5 (https=) | 2006-05-11 |
Family
ID=7857945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000532445A Pending JP2002504565A (ja) | 1998-02-17 | 1999-02-05 | 担持触媒組成物の製造 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6683018B1 (https=) |
| EP (1) | EP1056785B1 (https=) |
| JP (1) | JP2002504565A (https=) |
| DE (2) | DE19806435A1 (https=) |
| WO (1) | WO1999042493A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19927766A1 (de) * | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
| US6492293B1 (en) | 1999-11-12 | 2002-12-10 | Bp Chemicals Limited | Polymerisation catalyst |
| EP1099714A1 (en) * | 1999-11-12 | 2001-05-16 | BP Chemicals Limited | Polymerisation catalyst |
| BRPI0307672B1 (pt) * | 2002-02-14 | 2015-12-22 | Monsanto Technology Llc | processo para a oxidação de aminas terciárias |
| US7390920B2 (en) * | 2002-02-14 | 2008-06-24 | Monsanto Technology Llc | Oxidation catalyst and process |
| AU2004264436B2 (en) * | 2003-08-14 | 2010-11-25 | Monsanto Technology Llc | Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts |
| AU2006214086B2 (en) * | 2005-02-17 | 2012-01-19 | Monsanto Technology Llc | Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts |
| WO2007098432A2 (en) * | 2006-02-17 | 2007-08-30 | Monsanto Technology Llc | Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE186918T1 (de) * | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
| JP2895199B2 (ja) * | 1990-10-02 | 1999-05-24 | 三井化学株式会社 | オレフィンの重合触媒 |
| JP3255716B2 (ja) * | 1991-07-11 | 2002-02-12 | 出光興産株式会社 | オレフィンの重合方法及びオレフィン重合用触媒 |
| JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| CA2171831A1 (en) * | 1993-09-17 | 1995-03-23 | Moses Olukayode Jejelowo | Polymerization catalyst systems, their production and use |
| EP0729477B1 (en) | 1993-11-19 | 1999-10-27 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5498582A (en) | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
| IT1273701B (it) | 1994-07-29 | 1997-07-09 | Enichem Elastomers | Derivati metallorganici del grupo iiia e procedimento per la loro preparazione |
| CA2186696A1 (en) * | 1995-09-29 | 1997-03-30 | Takashi Seki | Catalyst component and catalyst |
| JPH09151206A (ja) * | 1995-09-29 | 1997-06-10 | Nippon Oil Co Ltd | オレフィン類重合用触媒成分、オレフィン類重合用触媒およびポリオレフィンの製造方法 |
| DE19602543A1 (de) * | 1996-01-25 | 1997-07-31 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden |
| DE19606165A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation |
| DE19606167A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Geträgerte Katalysatorsysteme |
| DE19606166A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation |
| DE19616523A1 (de) * | 1996-04-25 | 1997-11-06 | Basf Ag | Polymerisationskatalysatoren mit beta-Diketiminat-Liganden |
| DE19617230A1 (de) * | 1996-04-30 | 1997-11-06 | Basf Ag | Oxidierte Metallocen-Polyolefin-Wachse |
| EP0909279B1 (de) * | 1996-07-04 | 2001-04-25 | Basf Aktiengesellschaft | Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren |
-
1998
- 1998-02-17 DE DE19806435A patent/DE19806435A1/de not_active Withdrawn
-
1999
- 1999-02-05 WO PCT/EP1999/000784 patent/WO1999042493A1/de not_active Ceased
- 1999-02-05 US US09/622,211 patent/US6683018B1/en not_active Expired - Fee Related
- 1999-02-05 EP EP99913145A patent/EP1056785B1/de not_active Expired - Lifetime
- 1999-02-05 JP JP2000532445A patent/JP2002504565A/ja active Pending
- 1999-02-05 DE DE59911328T patent/DE59911328D1/de not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4116148B2 (ja) | 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法 | |
| CA2141496C (en) | Organometallic fluorenyl compounds, preparation, and use | |
| US5103030A (en) | Process for the preparation of a chiral stereorigid metallocene | |
| KR100682115B1 (ko) | 올레핀 중합 촉매 시스템을 위한 치환 메탈로센 화합물, 그 중간체 및 그 제조 방법 | |
| EP0574370B1 (en) | Metallocene catalyst component with good catalyst efficiency after aging | |
| RU2203288C2 (ru) | Способ получения циклоолефиновых со(полимеров) для технических применений | |
| JP3683040B2 (ja) | シンジオタクチツク／アイソタクチツクブロツクポリオレフインの製造方法 | |
| JP3645309B2 (ja) | 半サンドウィッチ構造を有する架橋錯体の製造法 | |
| JP4771500B2 (ja) | シンジオタクチック／アタクチックブロックポリオレフィン類、それを製造するための触媒および方法 | |
| JP2002523575A5 (https=) | ||
| EP0427696A2 (en) | Process and catalyst for producing syndiotactic polymers | |
| EP0656075A1 (en) | Electrochemical preparation of addition polymerization catalysts | |
| US5962714A (en) | Monocyclopentadienyl transition metal catalyst and olefin polymerization process | |
| JP4028077B2 (ja) | α−オレフィン重合用触媒 | |
| JP2002504565A5 (https=) | ||
| JP2002522571A5 (https=) | ||
| WO1998031690A1 (fr) | COMPOSES ORGANIQUES CONTENANT DU SILICIUM OU DU GERMANIUM COMPLEXES DE METAUX DE TRANSITION, CATALYSEUR DE POLYMERISATION D'α-OLEFINE, ET PROCEDES DE PRODUCTION DE POLYMERES D'α-OLEFINE | |
| JP4202397B2 (ja) | α−オレフィン重合用触媒 | |
| JP2004534829A (ja) | メタロセン、オレフィンポリマー製造用の触媒系における使用 | |
| JP4080570B2 (ja) | メタロセン化合物類の精製法及びα−オレフィンの重合方法 | |
| JP3973472B2 (ja) | オレフィン重合用触媒成分、オレフィン重合用触媒、およびオレフィン重合体の製造方法 | |
| JP2004501928A (ja) | ラセミメタロセン錯体の製造方法 | |
| JP3811563B2 (ja) | 新規な遷移金属化合物、α−オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法 | |
| JPH11279189A (ja) | ビス（２−置換−４−フェニル−シクロペンタジエニル）配位子を有するメタロセン化合物およびその製造方法 | |
| ITTO960601A1 (it) | Catalizzatore di addotto di metallocene sindiospecifico |