JP2002503546A5 - - Google Patents
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- Publication number
- JP2002503546A5 JP2002503546A5 JP2000532213A JP2000532213A JP2002503546A5 JP 2002503546 A5 JP2002503546 A5 JP 2002503546A5 JP 2000532213 A JP2000532213 A JP 2000532213A JP 2000532213 A JP2000532213 A JP 2000532213A JP 2002503546 A5 JP2002503546 A5 JP 2002503546A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst support
- precursor
- support
- solution
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 description 28
- 238000000034 method Methods 0.000 description 17
- 239000002243 precursor Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 238000001354 calcination Methods 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011260 aqueous acid Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA98/1440 | 1998-02-20 | ||
| ZA981440 | 1998-02-20 | ||
| ZA98/11882 | 1998-12-28 | ||
| ZA9811882 | 1998-12-28 | ||
| PCT/GB1999/000527 WO1999042214A1 (en) | 1998-02-20 | 1999-02-19 | Process for producing hydrocarbons from a synthesis gas, and catalysts therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002503546A JP2002503546A (ja) | 2002-02-05 |
| JP2002503546A5 true JP2002503546A5 (enExample) | 2006-04-13 |
Family
ID=27144497
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000532213A Pending JP2002503546A (ja) | 1998-02-20 | 1999-02-19 | 合成ガスから炭化水素を製造する方法およびそのための触媒 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6638889B1 (enExample) |
| EP (1) | EP1058580B2 (enExample) |
| JP (1) | JP2002503546A (enExample) |
| KR (1) | KR20010041156A (enExample) |
| CN (1) | CN1291116A (enExample) |
| AT (1) | ATE258826T1 (enExample) |
| AU (1) | AU745771B2 (enExample) |
| BR (1) | BRPI9908011B1 (enExample) |
| CA (1) | CA2320914A1 (enExample) |
| DE (1) | DE69914585T3 (enExample) |
| DZ (1) | DZ2724A1 (enExample) |
| ES (1) | ES2212529T3 (enExample) |
| GB (1) | GB2352194B (enExample) |
| MX (1) | MXPA00007920A (enExample) |
| NO (1) | NO20004147L (enExample) |
| NZ (1) | NZ506373A (enExample) |
| PE (1) | PE20000258A1 (enExample) |
| PL (1) | PL342737A1 (enExample) |
| RU (1) | RU2226127C2 (enExample) |
| WO (1) | WO1999042214A1 (enExample) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DZ2724A1 (fr) | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
| RU2223821C2 (ru) | 1998-10-05 | 2004-02-20 | Сэсол Текнолоджи (Проприетери) Лимитед | Способ приготовления предшественника катализатора фишера-тропша |
| BR0016078B1 (pt) | 1999-12-01 | 2014-04-01 | Sasol Tech Pty Ltd | Processo para preparar um precursor de catalisador de cobalto de fischer-tropsch. |
| US6977273B2 (en) | 2000-03-01 | 2005-12-20 | Institut Francais Du Petrole | Process for synthesising hydrocarbons in the presence of a catalyst comprising a group VIII metal supported on silica-alumina |
| FR2821074B1 (fr) * | 2001-02-16 | 2004-06-04 | Inst Francais Du Petrole | Procede de synthese d'hydrocarbures en presence d'un catalyseur comprenant un metal du groupe viii supporte sur silice-alumine |
| JP4949592B2 (ja) * | 2000-06-12 | 2012-06-13 | サソール テクノロジー（プロプライエタリー）リミテッド | コバルト触媒 |
| WO2002002229A2 (en) | 2000-07-03 | 2002-01-10 | Conoco Inc. | Fischer-tropsch processes and catalysts using aluminum borate supports |
| AU7657801A (en) | 2000-07-24 | 2002-02-05 | Sasol Tech Pty Ltd | Production of hydrocarbons from a synthesis gas |
| ES2186547B1 (es) * | 2001-06-15 | 2004-08-01 | Universidad Politecnica De Valencia | Un catalizador bimetalico para el tratamiento de aguas que contienen nitratos. |
| JP2003024786A (ja) * | 2001-07-13 | 2003-01-28 | Nippon Oil Corp | フィッシャー・トロプシュ合成用触媒および炭化水素の製造法 |
| JP4263597B2 (ja) * | 2001-07-27 | 2009-05-13 | サソール テクノロジー（プロプライエタリー）リミテッド | フィッシャー−トロプシュ合成によるワックスの製造 |
| DE60204907T2 (de) | 2001-10-25 | 2006-04-20 | Sasol Technology (Proprietary) Ltd. | Verfahren zur aktivierung von cobaltkatalysatoren |
| AU2003277409C1 (en) | 2002-10-16 | 2009-06-25 | Conocophillips Company | Fischer-Tropsch processes and catalysts using stabilized supports |
| AU2003301247A1 (en) | 2002-10-16 | 2004-05-04 | Conocophillips Company | Fischer-tropsch processes and catalysts made from a material comprising boehmite |
| EP1551785A4 (en) | 2002-10-16 | 2006-04-05 | Conocophillips Co | STABILIZED MOUNTAIN ALUMINUM OXIDE CATALYST CARRIERS AS BOEHMIT AND CATALYSTS MANUFACTURED THEREOF |
| US7341976B2 (en) | 2002-10-16 | 2008-03-11 | Conocophillips Company | Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using |
| WO2004043583A2 (en) * | 2002-11-11 | 2004-05-27 | Conocophillips Company | Improved supports for high surface area catalysts |
| JP4870900B2 (ja) * | 2003-02-24 | 2012-02-08 | 戸田工業株式会社 | 炭化水素分解用触媒及びその製造方法、並びに該炭化水素分解用触媒を用いた水素製造方法 |
| RU2314869C2 (ru) * | 2003-03-31 | 2008-01-20 | Каунсил Оф Сайентифик Энд Индастриал Рисерч | Катализатор синтеза углеводородов из синтез-газа, способ получения катализатора |
| US7253136B2 (en) | 2003-04-11 | 2007-08-07 | Exxonmobile Research And Engineering Company | Preparation of titania and cobalt aluminate catalyst supports and their use in Fischer-Tropsch synthesis |
| US7163963B2 (en) | 2003-09-08 | 2007-01-16 | Conocophillips Company | Chemically and thermally stabilized alumina for Fischer-Tropsch catalysts |
| WO2005037745A1 (en) | 2003-10-16 | 2005-04-28 | Conocophillips Company | Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same |
| US7541310B2 (en) | 2003-10-16 | 2009-06-02 | Conocophillips Company | Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same |
| US20050119118A1 (en) * | 2003-12-02 | 2005-06-02 | Walsh Troy L. | Water gas shift catalyst for fuel cells application |
| CN101060929B (zh) * | 2003-12-12 | 2012-05-09 | 合成石油公司 | 改性催化剂载体 |
| GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
| EP1732683A1 (en) * | 2004-03-12 | 2006-12-20 | Saint-Gobain Ceramics and Plastics, Inc. | Method of forming a spray dried alumina catalyst carrier, alumina carrier and catalyst comprising it |
| US7365040B2 (en) | 2004-04-26 | 2008-04-29 | Sasoltechnology (Proprietary) Limited | Catalysts |
| US7361626B2 (en) * | 2004-04-30 | 2008-04-22 | Engelhard Corporation | Supported catalyst |
| AU2005286263B2 (en) | 2004-09-23 | 2010-07-08 | Petro Sa | Promoted Fischer-Tropsch catalysts |
| FR2879477A1 (fr) * | 2004-12-17 | 2006-06-23 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fischer-tropsch |
| FR2879478B1 (fr) * | 2004-12-17 | 2007-10-26 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fisher-tropsch |
| BRPI0512669B1 (pt) * | 2005-01-11 | 2015-11-24 | Basf Nederland B V | processos para a produção de um catalisador fisher-tropsch suportado |
| ITMI20051410A1 (it) | 2005-07-22 | 2007-01-23 | Eni Spa | Procedimento per la preparazione di catalizzatori di fischer-tropsch ad alta stabilita' meccanica, termica e chimica |
| US8969236B2 (en) | 2006-04-27 | 2015-03-03 | University Of Wyoming Research Corporation | Process and catalyst for production of mixed alcohols from synthesis gas |
| AU2007243242B2 (en) | 2006-04-27 | 2011-01-27 | University Of Wyoming Research Corporation | Process and catalyst for production of mixed alcohols from synthesis gas |
| CN101522296A (zh) * | 2006-10-06 | 2009-09-02 | 格雷斯公司 | 耐硫的氧化铝催化剂载体 |
| CN101522297B (zh) * | 2006-10-06 | 2012-12-12 | 格雷斯公司 | 耐硫的氧化铝催化剂载体 |
| WO2008087147A1 (en) * | 2007-01-18 | 2008-07-24 | Shell Internationale Research Maatschappij B.V. | Fischer-tropsch catalyst support and catalyst |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| US8067333B2 (en) | 2007-05-04 | 2011-11-29 | Sasol Technology (Proprietary) Limited | Catalysts |
| AU2008249609B2 (en) | 2007-05-11 | 2011-11-03 | Sasol Technology (Proprietary) Limited | Catalysts |
| US20090098032A1 (en) * | 2007-10-11 | 2009-04-16 | Basf Catalysts Llc | Methods of making aluminosilicate coated alumina |
| WO2009127990A1 (en) | 2008-04-15 | 2009-10-22 | Sasol Technology (Proprietary) Limited | Catalysts |
| DE102008025307A1 (de) * | 2008-05-27 | 2009-12-03 | Süd-Chemie AG | Kobalt-Fischer-Tropsch-Katalysator |
| US20100160464A1 (en) * | 2008-12-24 | 2010-06-24 | Chevron U.S.A. Inc. | Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst |
| US8268745B2 (en) | 2009-01-08 | 2012-09-18 | China Petroleum & Chemical Corporation | Silicate-resistant desulfurization sorbent |
| WO2010140077A2 (en) | 2009-06-03 | 2010-12-09 | Sasol Technology (Proprietary) Limited | Catalysts |
| GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
| US9409149B2 (en) | 2009-10-08 | 2016-08-09 | W. R. Grace & Co.-Conn. | Sulfur resistant cladded titania—alumina supports |
| EP2660229B1 (en) | 2009-10-13 | 2018-04-25 | Sasol Technology (PTY) Limited | Production of hydrocarbons |
| GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
| US7943674B1 (en) | 2009-11-20 | 2011-05-17 | Chevron U.S.A. Inc. | Zeolite supported cobalt hybrid fischer-tropsch catalyst |
| GB201000993D0 (en) * | 2010-01-22 | 2010-03-10 | Johnson Matthey Plc | Catalyst support |
| GB2482171B (en) | 2010-07-22 | 2018-04-11 | Gtl F1 Ag | Catalyst treatment |
| EP2603316B1 (en) | 2010-08-09 | 2017-04-19 | Gtl. F1 Ag | Fischer-tropsch catalysts |
| CN102441393B (zh) * | 2010-10-12 | 2016-01-13 | 中国石油化工股份有限公司 | 一种以改性氧化铝为载体的费托合成催化剂及其应用 |
| US8445550B2 (en) | 2010-11-23 | 2013-05-21 | Chevron U.S.A. Inc. | Ruthenium hybrid fischer-tropsch catalyst, and methods for preparation and use thereof |
| BR112013020246A2 (pt) | 2011-02-09 | 2020-08-04 | Sasol Technology(Proprietary)Limited | catalisadores |
| US9527061B2 (en) | 2011-04-28 | 2016-12-27 | Sasol Technology (Proprietary) Limited | Catalysts |
| PL406362A1 (pl) | 2011-06-07 | 2014-11-10 | Sasol Technology (Proprietary) Limited | Sposób wytwarzania co najmniej jednego produktu z co najmniej jednego reagenta gazowego w złożu zawiesinowym |
| UA113520C2 (xx) | 2011-06-07 | 2017-02-10 | Спосіб одержання щонайменше одного продукту зі щонайменше одного газоподібного реагенту в суспензійному шарі | |
| CN102989452B (zh) * | 2011-09-09 | 2014-10-15 | 中国石油天然气股份有限公司 | 一种含复合载体的碳二前加氢催化剂及其制备方法 |
| CA2858530C (en) | 2011-12-14 | 2018-04-17 | Sasol Technology (Proprietary) Limited | Catalysts |
| EP2797685A2 (en) | 2011-12-28 | 2014-11-05 | Furanix Technologies B.V | Process for carrying out a reaction involving a liquid reaction mixture |
| RU2628068C2 (ru) | 2012-08-02 | 2017-08-14 | Сасол Текнолоджи (Проприетэри) Лимитэд | Катализаторы |
| GB201214122D0 (en) * | 2012-08-07 | 2012-09-19 | Oxford Catalysts Ltd | Treating of catalyst support |
| WO2015104056A1 (en) | 2014-01-09 | 2015-07-16 | Statoil Petroleum As | Catalyst support and catalyst for fischer-tropsch synthesis |
| CN103920496B (zh) * | 2014-04-22 | 2015-11-18 | 武汉凯迪工程技术研究总院有限公司 | 介孔材料包覆式钴基费托合成催化剂及其制备方法 |
| US9233360B1 (en) | 2014-09-10 | 2016-01-12 | Chevron U.S.A. Inc. | Stable support for Fischer-Tropsch catalyst |
| EP3344725B1 (en) * | 2015-09-04 | 2024-12-18 | Clariant International Ltd | Catalyst support materials and catalyst materials useful for fischer-tropsch processes |
| CN106588526B (zh) * | 2015-10-20 | 2019-07-23 | 中国石油化工股份有限公司 | 一种以煤和炼厂干气为原料制烯烃的系统以及制烯烃的方法 |
| CN105289613B (zh) * | 2015-11-04 | 2017-12-19 | 中国科学院山西煤炭化学研究所 | 氧化铝负载钴费托合成催化剂及制法和应用 |
| WO2017131232A1 (ja) * | 2016-01-29 | 2017-08-03 | Ｊｘエネルギー株式会社 | フィッシャー・トロプシュ合成用触媒、フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法 |
| US9975099B2 (en) | 2016-03-16 | 2018-05-22 | Kabushiki Kaisha Toshiba | Fuel synthesis catalyst and fuel synthesis system |
| EA201892824A1 (ru) | 2016-08-11 | 2019-07-31 | Сасол Соутх Африка Лимитед | Кобальтосодержащая каталитическая композиция |
| EP3351300A1 (en) * | 2017-01-20 | 2018-07-25 | SASOL Germany GmbH | Manganese oxide containing alumina composition, a method for manufacturing the same and use thereof |
| FR3064498B1 (fr) * | 2017-03-30 | 2021-10-29 | Ifp Energies Now | Procede de preparation de catalyseurs a base de cobalt |
| CN109304174B (zh) * | 2017-07-26 | 2021-08-10 | 国家能源投资集团有限责任公司 | 制备费托合成钴基催化剂的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1200540A (en) * | 1983-10-24 | 1986-02-11 | Atomic Energy Of Canada Limited - Energie Atomique Du Canada, Limitee | Method of manufacturing a crystalline silica/platinum catalyst structure |
| US4708945A (en) * | 1985-12-31 | 1987-11-24 | Exxon Research And Engineering Company | Catalysts comprising silica supported on a boehmite-like surface, their preparation and use |
| US5169821A (en) * | 1991-11-14 | 1992-12-08 | Exxon Research And Engineering Company | Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process |
| EP0586196A1 (en) * | 1992-09-01 | 1994-03-09 | JOSEPH CROSFIELD & SONS LTD. | Silicone modified hydrotreating catalysts |
| US5424262A (en) * | 1994-02-25 | 1995-06-13 | Energy, Mines And Resources Canada | Fluidized cracking catalyst with in situ metal traps |
| US5639798A (en) * | 1994-12-15 | 1997-06-17 | Wexford P.A. Syncrude Limited Partnership | Process and catalyst for production of hydrocarbons |
| DZ2013A1 (fr) | 1995-04-07 | 2002-10-23 | Sastech Ltd | Catalyseurs. |
| WO1997020216A1 (en) * | 1995-11-27 | 1997-06-05 | W.R. Grace & Co.-Conn. | Organically modified inorganic oxides using silane-modified inorganic oxides |
| DE19641141A1 (de) | 1996-10-05 | 1998-04-16 | Rwe Dea Ag | Verfahren zur Herstellung von dispergierbaren Alumosilikaten |
| DZ2724A1 (fr) | 1998-02-20 | 2003-09-01 | Sasol Tech Pty Ltd | Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs. |
-
1999
- 1999-02-16 DZ DZ990025A patent/DZ2724A1/xx active
- 1999-02-19 AT AT99906328T patent/ATE258826T1/de not_active IP Right Cessation
- 1999-02-19 NZ NZ506373A patent/NZ506373A/xx not_active Application Discontinuation
- 1999-02-19 RU RU2000124068/04A patent/RU2226127C2/ru active
- 1999-02-19 PE PE1999000149A patent/PE20000258A1/es not_active Application Discontinuation
- 1999-02-19 AU AU26302/99A patent/AU745771B2/en not_active Expired
- 1999-02-19 BR BRPI9908011-7A patent/BRPI9908011B1/pt not_active IP Right Cessation
- 1999-02-19 ES ES99906328T patent/ES2212529T3/es not_active Expired - Lifetime
- 1999-02-19 KR KR1020007009206A patent/KR20010041156A/ko not_active Withdrawn
- 1999-02-19 WO PCT/GB1999/000527 patent/WO1999042214A1/en not_active Ceased
- 1999-02-19 GB GB0019749A patent/GB2352194B/en not_active Expired - Fee Related
- 1999-02-19 JP JP2000532213A patent/JP2002503546A/ja active Pending
- 1999-02-19 DE DE69914585.6T patent/DE69914585T3/de not_active Expired - Lifetime
- 1999-02-19 CA CA002320914A patent/CA2320914A1/en not_active Abandoned
- 1999-02-19 EP EP99906328.2A patent/EP1058580B2/en not_active Expired - Lifetime
- 1999-02-19 PL PL99342737A patent/PL342737A1/xx unknown
- 1999-02-19 CN CN99803102A patent/CN1291116A/zh active Pending
-
2000
- 2000-08-11 US US09/636,787 patent/US6638889B1/en not_active Expired - Lifetime
- 2000-08-14 MX MXPA00007920 patent/MXPA00007920A/es unknown
- 2000-08-18 NO NO20004147A patent/NO20004147L/no not_active Application Discontinuation
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