JP2001524564A5 - - Google Patents
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- JP2001524564A5 JP2001524564A5 JP2000522156A JP2000522156A JP2001524564A5 JP 2001524564 A5 JP2001524564 A5 JP 2001524564A5 JP 2000522156 A JP2000522156 A JP 2000522156A JP 2000522156 A JP2000522156 A JP 2000522156A JP 2001524564 A5 JP2001524564 A5 JP 2001524564A5
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- JP
- Japan
- Prior art keywords
- compound
- matrix
- formula
- light
- europium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000000463 material Substances 0.000 description 124
- 239000000203 mixture Substances 0.000 description 92
- 150000001875 compounds Chemical class 0.000 description 55
- 239000011159 matrix material Substances 0.000 description 54
- 238000006243 chemical reaction Methods 0.000 description 47
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 42
- -1 benzoylbenzoate anion Chemical class 0.000 description 41
- 239000000654 additive Substances 0.000 description 38
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 36
- 229910052586 apatite Inorganic materials 0.000 description 32
- 229910019142 PO4 Inorganic materials 0.000 description 26
- 238000004519 manufacturing process Methods 0.000 description 26
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 25
- 239000003795 chemical substances by application Substances 0.000 description 24
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical group [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 24
- 239000010408 film Substances 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 22
- 229910052693 Europium Inorganic materials 0.000 description 20
- 230000000996 additive effect Effects 0.000 description 20
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 229910001940 europium oxide Inorganic materials 0.000 description 16
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 16
- 229910052688 Gadolinium Inorganic materials 0.000 description 15
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 15
- 229910052772 Samarium Inorganic materials 0.000 description 14
- 239000011521 glass Substances 0.000 description 14
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 14
- DTQVDTLACAAQTR-UHFFFAOYSA-N trifluoroacetic acid Substances OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 14
- 239000004698 Polyethylene Substances 0.000 description 12
- 229920000573 polyethylene Polymers 0.000 description 12
- 239000004327 boric acid Substances 0.000 description 11
- 239000000835 fiber Substances 0.000 description 11
- 239000007790 solid phase Substances 0.000 description 11
- 229910052717 sulfur Inorganic materials 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229910052771 Terbium Inorganic materials 0.000 description 10
- 229920000728 polyester Polymers 0.000 description 10
- DOSGOCSVHPUUIA-UHFFFAOYSA-N samarium(3+) Chemical compound [Sm+3] DOSGOCSVHPUUIA-UHFFFAOYSA-N 0.000 description 10
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 10
- 239000004952 Polyamide Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 150000001450 anions Chemical class 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 9
- RJOJUSXNYCILHH-UHFFFAOYSA-N gadolinium(3+) Chemical compound [Gd+3] RJOJUSXNYCILHH-UHFFFAOYSA-N 0.000 description 9
- 230000005855 radiation Effects 0.000 description 9
- 239000005368 silicate glass Substances 0.000 description 9
- HKCRVXUAKWXBLE-UHFFFAOYSA-N terbium(3+) Chemical compound [Tb+3] HKCRVXUAKWXBLE-UHFFFAOYSA-N 0.000 description 9
- 239000004254 Ammonium phosphate Substances 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 8
- 239000004922 lacquer Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000004417 polycarbonate Substances 0.000 description 8
- 229910052761 rare earth metal Inorganic materials 0.000 description 8
- 150000004760 silicates Chemical class 0.000 description 8
- 230000003595 spectral effect Effects 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 101100326757 Drosophila melanogaster Capr gene Proteins 0.000 description 7
- 229910015667 MoO4 Inorganic materials 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 7
- 229910052794 bromium Inorganic materials 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 229920002647 polyamide Polymers 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 239000012209 synthetic fiber Substances 0.000 description 7
- 229920001169 thermoplastic Polymers 0.000 description 7
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- 229910002651 NO3 Inorganic materials 0.000 description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- LNBHUCHAFZUEGJ-UHFFFAOYSA-N europium(3+) Chemical compound [Eu+3] LNBHUCHAFZUEGJ-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 6
- 239000004926 polymethyl methacrylate Substances 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 235000019289 ammonium phosphates Nutrition 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052746 lanthanum Inorganic materials 0.000 description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 5
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920002994 synthetic fiber Polymers 0.000 description 5
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 5
- 229910052727 yttrium Inorganic materials 0.000 description 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical group [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 5
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229910052684 Cerium Inorganic materials 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 229910052692 Dysprosium Inorganic materials 0.000 description 4
- 229910052691 Erbium Inorganic materials 0.000 description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 4
- 229910052689 Holmium Inorganic materials 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910052779 Neodymium Inorganic materials 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910052777 Praseodymium Inorganic materials 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229910052769 Ytterbium Inorganic materials 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052793 cadmium Inorganic materials 0.000 description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 4
- 229910052792 caesium Inorganic materials 0.000 description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 4
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 4
- GAGGCOKRLXYWIV-UHFFFAOYSA-N europium(3+);trinitrate Chemical compound [Eu+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GAGGCOKRLXYWIV-UHFFFAOYSA-N 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
- 239000011487 hemp Substances 0.000 description 4
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 4
- 229910052701 rubidium Inorganic materials 0.000 description 4
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 4
- 239000011669 selenium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 239000011135 tin Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002265 electronic spectrum Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 229910052587 fluorapatite Inorganic materials 0.000 description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
- 229940037201 oris Drugs 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- TXBBUSUXYMIVOS-UHFFFAOYSA-N thenoyltrifluoroacetone Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CS1 TXBBUSUXYMIVOS-UHFFFAOYSA-N 0.000 description 3
- POILWHVDKZOXJZ-ONEGZZNKSA-M (E)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C/C(C)=O POILWHVDKZOXJZ-ONEGZZNKSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 2
- 229920006051 Capron® Polymers 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 244000088415 Raphanus sativus Species 0.000 description 2
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 2
- 229940075613 gadolinium oxide Drugs 0.000 description 2
- MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(III) nitrate Inorganic materials [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 2
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
- QAMFBRUWYYMMGJ-UHFFFAOYSA-N hexafluoroacetylacetone Chemical compound FC(F)(F)C(=O)CC(=O)C(F)(F)F QAMFBRUWYYMMGJ-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
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| GB0119729D0 (en) | 2001-08-14 | 2001-10-03 | Qinetiq Ltd | Triboluminescent materials and devices |
| WO2003022037A1 (fr) * | 2001-09-12 | 2003-03-20 | Jury Petrovich Kuznetsov | Matiere luminescente pour optimiser les procedes de photosynthese et de croissance des vegetaux |
| DE102004034189B4 (de) * | 2004-07-14 | 2019-10-17 | Giesecke+Devrient Currency Technology Gmbh | Wertdokument |
| JP2007039564A (ja) * | 2005-08-03 | 2007-02-15 | Kri Inc | 高効率赤色発光体 |
| FR2893945B1 (fr) * | 2005-11-29 | 2011-04-22 | Extrusion Du Polyethylene A Barbier & Cie Soc D | Films de couverture de serre fluorescents |
| KR100761942B1 (ko) * | 2006-01-11 | 2007-10-04 | 한국에너지기술연구원 | 광 변환 그린하우스 필름용 광 활성 무기첨가제 및 이를함유하는 그린하우스 필름 |
| RU2319728C1 (ru) * | 2006-06-13 | 2008-03-20 | Государственное образовательное учреждение высшего профессионального образования "Северо-Кавказский государственный технический университет" | Материал для преобразования света и композиция для его получения |
| JP5030550B2 (ja) * | 2006-11-22 | 2012-09-19 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物及び成形体 |
| RU2407770C2 (ru) * | 2007-03-09 | 2010-12-27 | Общество с ограниченной ответственностью Научно-производственная фирма "СВЕТ" | Светопреобразующий материал и композиция для его получения |
| JP2010533223A (ja) * | 2007-07-11 | 2010-10-21 | エンビオ カンパニー リミテッド | 光活性無機添加剤およびこれを含む光転換フィルム |
| GB2453953A (en) * | 2007-10-23 | 2009-04-29 | Univ Brunel | Protection of plastics using UV-absorbing phosphors |
| KR100893003B1 (ko) | 2007-11-26 | 2009-04-10 | 한국에너지기술연구원 | 농업용 고분자 필름을 제조하기 위한 고분자 조성물, 이를이용한 필름의 제조방법과 그 필름 |
| RU2395458C2 (ru) * | 2008-08-07 | 2010-07-27 | Федеральное казённое предприятие "Государственный научно-исследовательский институт химических продуктов" (ФКП "ГосНИИХП") | Полихлорцинкаты редкоземельных элементов |
| KR100983602B1 (ko) | 2008-09-05 | 2010-09-27 | 주식회사 엔비오 | 광 변환 농업용 그린하우스 필름을 제조하기 위한 고분자 조성물과 이를 이용한 그린하우스 필름의 제조방법과 그 그린하우스 필름 |
| CN101358128B (zh) * | 2008-09-11 | 2011-06-15 | 南京工业大学 | 稀土有机配合物转光剂及其制备方法 |
| CN102656705B (zh) * | 2009-09-29 | 2015-06-17 | 日立化成株式会社 | 波长转换用荧光材料和树脂组合物、太阳能电池模块及其制法 |
| CN102127317B (zh) * | 2011-01-20 | 2013-04-17 | 中国科学院长春应用化学研究所 | 稀土着色剂及其制备方法 |
| RU2471713C2 (ru) * | 2011-03-25 | 2013-01-10 | Учреждение Российской академии наук Институт химии твердого тела Уральского отделения РАН | Способ получения сложного ванадата цинка и кадмия |
| CN102516979A (zh) * | 2011-12-01 | 2012-06-27 | 上海大学 | 用于植物照明光源的色转换有机材料及其应用 |
| US9204598B2 (en) | 2013-05-27 | 2015-12-08 | Saudi Basic Indsutries Corporation | Solar energy funneling using thermoplastics for agricultural applications |
| CN106905967B (zh) * | 2017-02-20 | 2019-04-09 | 中国计量大学 | 一种硼磷酸盐绿色荧光粉及其制备方法 |
| US10160405B1 (en) | 2017-08-22 | 2018-12-25 | Ford Global Technologies, Llc | Vehicle decal assembly |
| JP2021533227A (ja) * | 2018-08-03 | 2021-12-02 | ボード オブ リージェンツ, ザ ユニバーシティ オブ テキサス システムBoard Of Regents, The University Of Texas System | ポリマー性マトリックスにおける蛍光体の分散を増進させるための方法及び組成物 |
| CN110790779B (zh) * | 2018-08-03 | 2022-11-01 | 阜阳师范学院 | 一种以磷酸钙盐为基体的稀土复合荧光材料及其制备方法 |
| CN109971477B (zh) * | 2019-01-25 | 2022-02-08 | 云南大学 | 一种钐掺杂硼磷酸盐橙红色荧光粉及其制备方法和应用 |
| CN111944221B (zh) * | 2020-07-31 | 2022-05-27 | 中国农业科学院农业环境与可持续发展研究所 | 一种低波段紫外吸收抗菌转光膜及其制备方法 |
| RU2761209C1 (ru) * | 2021-04-06 | 2021-12-06 | Федеральное государственное бюджетное учреждение науки Институт химии Дальневосточного отделения Российской академии наук (ИХ ДВО РАН) | Способ получения боратов лантана, легированных европием и тербием |
| CN119931662B (zh) * | 2025-04-09 | 2025-07-29 | 内蒙古中科宏特高新科技有限责任公司 | 一种稀土硫氧化镧转光剂及其制备方法 |
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| US3949134A (en) | 1973-07-18 | 1976-04-06 | Material Distributors Corporation | Solar control film for use by consumers and the like |
| JPS53136050A (en) | 1977-05-04 | 1978-11-28 | Nippon Carbide Ind Co Ltd | Covering material for agricultural use |
| FR2419955A1 (fr) | 1978-03-17 | 1979-10-12 | Alcudia Empresa Ind Quimi | Pellicules de polyolefine destinees a etre utilisees en agriculture |
| SU1381128A1 (ru) | 1981-08-10 | 1988-03-15 | Институт общей и неорганической химии им.Н.С.Курнакова | Полимерна композици (ее варианты) |
| US4376183A (en) * | 1981-09-14 | 1983-03-08 | E. I. Du Pont De Nemours And Company | Inorganic films with poly(vinyl alcohol) and coating compositions for making them |
| SU1463737A1 (ru) | 1983-09-16 | 1989-03-07 | Институт Химии Башкирского Филиала Ан Ссср | Полимерна композици дл пленочных покрытий сельскохоз йственного назначени |
| WO1985001945A1 (fr) * | 1983-10-31 | 1985-05-09 | Institut Obschei I Neorganicheskoi Khimii Imeni N. | Materiau polymere de revetement de serres chaudes |
| JPS60104141A (ja) * | 1983-11-12 | 1985-06-08 | Kyowa Chem Ind Co Ltd | 農業用フイルム |
| US4559381A (en) | 1984-01-13 | 1985-12-17 | Alcudia, Empresa Para La Indusrria Quimica, S.A. | Polymeric covering materials for growing plants or crops |
| SU1552616A1 (ru) | 1987-12-30 | 1996-05-20 | Институт Химии Дальневосточного Отделения Ан Ссср | Полимерная композиция |
| GB8827529D0 (en) | 1988-11-25 | 1988-12-29 | Du Pont Canada | Radiation protection material |
| JPH03158103A (ja) | 1989-11-17 | 1991-07-08 | Orido Eng:Kk | 日傘類 |
| RU2036217C1 (ru) * | 1991-04-24 | 1995-05-27 | Карасев Владимир Егорович | Полимерная композиция для получения пленки |
| RU2047623C1 (ru) * | 1992-07-30 | 1995-11-10 | Научно-производственная фирма "Сталго" | Полимерная композиция для получения пленок |
| RU2047624C1 (ru) * | 1992-07-30 | 1995-11-10 | Научно-производственная фирма "Сталго" | Полимерная композиция для получения пленок |
| DE9301250U1 (de) | 1993-01-29 | 1993-04-01 | Mutzhas, Irmgard, 81479 München | Festkörper-Sonnenschutzmittel zur optimalen Hautbräunung |
| CA2188427C (en) | 1994-04-29 | 2000-06-27 | Robert A. Volkmann | Neurotransmitter release enhancers |
| RU2059999C1 (ru) * | 1994-11-23 | 1996-05-10 | Щелоков Роберт Николаевич | Полимерная композиция для светотрансформирующего пленочного материала |
| US6153665A (en) | 1998-10-26 | 2000-11-28 | Ram Phosphorix Llc | Doped polymer sheeting for covering hotbeds and greenhouses and method of fabrication of such |
-
1997
- 1997-11-25 US US09/555,104 patent/US6589450B1/en not_active Expired - Fee Related
- 1997-11-25 DE DE69716492T patent/DE69716492T2/de not_active Expired - Fee Related
- 1997-11-25 JP JP2000522156A patent/JP2001524564A/ja not_active Ceased
- 1997-11-25 CA CA002312871A patent/CA2312871A1/en not_active Abandoned
- 1997-11-25 ES ES97954964T patent/ES2182156T3/es not_active Expired - Lifetime
- 1997-11-25 WO PCT/RU1997/000375 patent/WO1999027006A1/ru not_active Ceased
- 1997-11-25 AU AU61259/98A patent/AU751028B2/en not_active Ceased
- 1997-11-25 TR TR2000/01521T patent/TR200001521T2/xx unknown
- 1997-11-25 RU RU98102984A patent/RU2132856C1/ru not_active IP Right Cessation
- 1997-11-25 AT AT97954964T patent/ATE226228T1/de not_active IP Right Cessation
- 1997-11-25 KR KR1020007005724A patent/KR100540268B1/ko not_active Expired - Fee Related
- 1997-11-25 EP EP97954964A patent/EP1035160B1/en not_active Expired - Lifetime
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