IN2014DN09747A - - Google Patents
Info
- Publication number
- IN2014DN09747A IN2014DN09747A IN9747DEN2014A IN2014DN09747A IN 2014DN09747 A IN2014DN09747 A IN 2014DN09747A IN 9747DEN2014 A IN9747DEN2014 A IN 9747DEN2014A IN 2014DN09747 A IN2014DN09747 A IN 2014DN09747A
- Authority
- IN
- India
- Prior art keywords
- compound
- temperature
- order
- formula
- isothiuronium salt
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 abstract 7
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 3
- 229920006295 polythiol Polymers 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C335/00—Thioureas, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C335/30—Isothioureas
- C07C335/32—Isothioureas having sulfur atoms of isothiourea groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
- C08G18/7642—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012179896 | 2012-08-14 | ||
| PCT/JP2013/001207 WO2014027427A1 (ja) | 2012-08-14 | 2013-02-28 | ポリチオール化合物の製造方法、光学材料用重合性組成物およびその用途 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2014DN09747A true IN2014DN09747A (enrdf_load_html_response) | 2015-07-31 |
Family
ID=50685489
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN9746DEN2014 IN2014DN09746A (enrdf_load_html_response) | 2012-08-14 | 2013-02-28 | |
| IN9747DEN2014 IN2014DN09747A (enrdf_load_html_response) | 2012-08-14 | 2014-11-18 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN9746DEN2014 IN2014DN09746A (enrdf_load_html_response) | 2012-08-14 | 2013-02-28 |
Country Status (7)
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5373226B1 (ja) * | 2012-08-14 | 2013-12-18 | 三井化学株式会社 | ポリチオール組成物、光学材料用重合性組成物およびその用途 |
| JPWO2014136663A1 (ja) * | 2013-03-04 | 2017-02-09 | 三菱瓦斯化学株式会社 | 光学材料用組成物及びそれを用いた光学材料 |
| EP2801586B1 (de) | 2013-05-07 | 2016-04-13 | Bruno Bock Chemische Fabrik GmbH & Co. KG | Gießharz auf Polythiourethanbasis mit hoher Bruchfestigkeit und niedrigem spezifischen Gewicht |
| CN105683160B (zh) | 2013-11-01 | 2018-02-16 | 三菱瓦斯化学株式会社 | 多硫醇化合物及其制造方法 |
| TWI699389B (zh) * | 2014-07-18 | 2020-07-21 | 日商三菱瓦斯化學股份有限公司 | 聚硫醇組成物及其製造方法 |
| CN104402783B (zh) * | 2014-12-15 | 2015-08-12 | 黄河三角洲京博化工研究院有限公司 | 一种巯基化合物的制备方法 |
| WO2017175407A1 (ja) * | 2016-04-06 | 2017-10-12 | ホヤ レンズ タイランド リミテッド | 光学部材の製造方法 |
| CN105693575B (zh) * | 2016-04-08 | 2018-06-29 | 佛山汉维科技有限公司 | 一种分离纯化多元硫醇的方法与设备 |
| CN105949096B (zh) * | 2016-05-19 | 2018-03-02 | 湖北鼎龙控股股份有限公司 | 光学眼镜片材料、精制多元硫醇以及多元硫醇粗品的后处理方法 |
| WO2018003061A1 (ja) * | 2016-06-30 | 2018-01-04 | ホヤ レンズ タイランド リミテッド | 硬化物の製造方法、硬化物および眼鏡レンズ基材 |
| CN108884028B (zh) * | 2016-06-30 | 2020-10-09 | 豪雅镜片泰国有限公司 | 多硫醇化合物的制造方法、固化性组合物的制造方法、及固化物的制造方法 |
| EP3486272B1 (en) * | 2016-07-14 | 2021-04-28 | SKC Co., Ltd. | Aromatic polythiol compound for optical material |
| JP6632493B2 (ja) | 2016-08-05 | 2020-01-22 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法 |
| JP6633990B2 (ja) * | 2016-08-08 | 2020-01-22 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法 |
| KR101971110B1 (ko) * | 2016-08-30 | 2019-04-22 | 에스케이씨 주식회사 | 광학 재료용 폴리티올 화합물 |
| KR101885879B1 (ko) * | 2016-08-30 | 2018-08-07 | 에스케이씨 주식회사 | 광학 재료용 폴리티올 조성물 및 이의 제조방법 |
| US10365958B2 (en) * | 2016-09-13 | 2019-07-30 | Hewlett Packard Enterprise Development Lp | Storage drive management to fail a storage drive based on adjustable failure criteria |
| JP6851762B2 (ja) * | 2016-09-30 | 2021-03-31 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | 光学材料用ポリチオール化合物の製造方法 |
| JP2018058922A (ja) * | 2016-09-30 | 2018-04-12 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | 光学材料の製造方法 |
| CN106831511B (zh) * | 2017-01-24 | 2018-05-25 | 郯城博化化工科技有限公司 | 一种多元硫醇化合物的制备方法 |
| KR101893558B1 (ko) * | 2017-02-03 | 2018-08-30 | 에스케이씨 주식회사 | 플라스틱 렌즈용 중합성 조성물 |
| CN113372250B (zh) * | 2017-02-15 | 2023-12-08 | Ks试验研究株式会社 | 多硫醇化合物、其制备方法、由其制备的透明氨基甲酸酯类树脂以及光学体 |
| JP6846507B2 (ja) * | 2017-03-24 | 2021-03-24 | 三井化学株式会社 | ポリチオール化合物の製造方法、重合性組成物およびその用途 |
| KR101902974B1 (ko) * | 2017-03-31 | 2018-10-02 | 에스케이씨 주식회사 | 폴리티올 화합물의 탈수 방법 |
| CN107235876B (zh) * | 2017-06-30 | 2019-01-18 | 山东益丰生化环保股份有限公司 | 一种多巯基化合物粗产物的后处理方法 |
| KR101996981B1 (ko) * | 2017-10-18 | 2019-07-05 | 에스케이씨 주식회사 | 플라스틱 렌즈용 중합성 조성물 |
| CN107721892B (zh) * | 2017-10-31 | 2020-10-23 | 淮阴师范学院 | 一种硫代多元硫醇、制备方法及在透明聚氨酯材料中的应用 |
| JP6797855B2 (ja) * | 2018-03-29 | 2020-12-09 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法 |
| JP6797856B2 (ja) * | 2018-03-29 | 2020-12-09 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法 |
| CN111868025B (zh) * | 2018-03-30 | 2023-12-12 | 三井化学株式会社 | 有机巯基化合物或其中间体的制造方法、（多）硫醇成分、光学材料用聚合性组合物、成型体、光学材料及透镜 |
| KR102034214B1 (ko) * | 2018-04-25 | 2019-10-18 | 에스케이씨 주식회사 | 보관안정성이 개선된 폴리티올의 제조방법 |
| KR102036246B1 (ko) * | 2018-07-04 | 2019-10-24 | 에스케이씨 주식회사 | 고품질 폴리티올의 제조방법 |
| CN110305049B (zh) * | 2019-07-08 | 2021-05-28 | 山东益丰生化环保股份有限公司 | 一种生产低色度聚硫醇化合物的方法 |
| EP4001974A4 (en) | 2019-07-17 | 2023-08-02 | Mitsui Chemicals, Inc. | POLYTHIOL COMPOSITION AND APPLICATION THEREOF |
| CN110835409B (zh) * | 2019-12-03 | 2020-08-28 | 山东益丰生化环保股份有限公司 | 一种利用微通道反应器连续反应生产聚硫醇的方法 |
| KR20210075617A (ko) * | 2019-12-13 | 2021-06-23 | 에스케이씨 주식회사 | 폴리티올 조성물의 제조 방법 |
| JP7059343B2 (ja) * | 2019-12-13 | 2022-04-25 | エスケイシー・カンパニー・リミテッド | ポリチオール組成物の調製方法 |
| JP7437932B2 (ja) * | 2019-12-27 | 2024-02-26 | 三井化学株式会社 | 廃水処理方法 |
| CN116874734A (zh) | 2020-01-27 | 2023-10-13 | 三井化学株式会社 | 光学材料用聚合性组合物、光学材料用聚合性预聚物组合物、固化物及光学材料的制造方法 |
| CN116178654A (zh) | 2020-01-27 | 2023-05-30 | 三井化学株式会社 | 光学材料用聚合性组合物、光学材料用聚合性预聚物组合物、固化物及光学材料的制造方法 |
| CN113498420A (zh) * | 2020-02-05 | 2021-10-12 | 三井化学株式会社 | 硫氨酯树脂原料的制造方法及其应用、多硫醇组合物的制造方法及其应用、以及多硫醇组合物 |
| WO2021182526A1 (ja) | 2020-03-10 | 2021-09-16 | 三井化学株式会社 | 光学材料用重合性組成物、光学材料用重合性プレポリマー組成物、硬化物及び光学材料の製造方法 |
| KR102122703B1 (ko) | 2020-04-09 | 2020-06-26 | 주식회사 대원에프엔씨 | 폴리티올 화합물의 제조 방법과 이를 포함한 광학 재료용 중합성 조성물 및 광학 렌즈 |
| CN116390965A (zh) * | 2020-09-01 | 2023-07-04 | Skc株式会社 | 多硫醇组合物、光学组合物和光学产品 |
| KR102564990B1 (ko) * | 2020-12-01 | 2023-08-07 | 에스케이씨 주식회사 | 폴리티올 조성물 및 이를 포함하는 중합성 조성물 |
| KR20220033890A (ko) * | 2020-09-10 | 2022-03-17 | 에스케이씨 주식회사 | 폴리티올 조성물 및 이를 포함하는 광학용 중합성 조성물 |
| CN112358613B (zh) * | 2020-10-27 | 2022-09-13 | 益丰新材料股份有限公司 | 一种光学树脂用聚硫醇及其制备方法和应用 |
| PH12022551277A1 (en) | 2020-11-13 | 2023-11-20 | Mitsui Chemicals Inc | Polythiol composition, polymerizable composition, resin, molded body, optical material, and lens |
| GB2615967B (en) * | 2020-11-27 | 2024-09-11 | Sk Pucore Co Ltd | Polythiol composition, optical composition and optical product |
| US20230365738A1 (en) | 2020-12-25 | 2023-11-16 | Mitsui Chemicals, Inc. | Polythiol composition, polymerizable composition, resin, molded article, optical material, and lens |
| KR20240018587A (ko) | 2021-07-30 | 2024-02-13 | 미쯔이가가꾸가부시끼가이샤 | 폴리티올 조성물 및 그의 응용 |
| JP7611428B2 (ja) | 2021-12-24 | 2025-01-09 | 三井化学株式会社 | 光学部材の製造方法及び硬化物 |
| KR20240093746A (ko) | 2022-09-14 | 2024-06-24 | 미쯔이가가꾸가부시끼가이샤 | 폴리티올 조성물, 중합성 조성물, 수지, 성형체, 광학 재료 및 렌즈 |
| CN119855808A (zh) | 2022-09-26 | 2025-04-18 | 三井化学株式会社 | 多硫醇组合物的制造方法及其应用 |
| CN120019099A (zh) | 2022-10-14 | 2025-05-16 | 三井化学株式会社 | 多硫醇组合物、聚合性组合物、树脂、成型体、光学材料及透镜 |
| WO2024080383A1 (ja) | 2022-10-14 | 2024-04-18 | 三井化学株式会社 | ポリチオール組成物、重合性組成物、樹脂、成形体、光学材料及びレンズ |
| WO2025100411A1 (ja) * | 2023-11-09 | 2025-05-15 | 三井化学株式会社 | ポリチオール組成物及びその応用 |
| WO2025127038A1 (ja) * | 2023-12-15 | 2025-06-19 | 三井化学株式会社 | チオール化合物の製造方法及びその応用 |
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| JP2621991B2 (ja) | 1988-12-22 | 1997-06-18 | 三井東圧化学株式会社 | メルカプト化合物及びその製造方法 |
| US5191055A (en) | 1988-12-22 | 1993-03-02 | Mitsui Toatsu Chemicals, Inc. | Mercapto compound, a high refractive index resin and lens and a process for preparing them |
| US5087758A (en) * | 1988-12-22 | 1992-02-11 | Mitsui Toatsu Chemicals, Inc. | Mercapto compound, a high refractive index resin and lens and a process for preparing them |
| US5608115A (en) * | 1994-01-26 | 1997-03-04 | Mitsui Toatsu Chemicals, Inc. | Polythiol useful for preparing sulfur-containing urethane-based resin and process for producing the same |
| JP4426017B2 (ja) * | 1999-07-27 | 2010-03-03 | 三井化学株式会社 | 有機メルカプト化合物の製造方法 |
| CN1171924C (zh) * | 2002-11-05 | 2004-10-20 | 浙江大学 | 一种制备聚硫代氨基甲酸酯光学塑料的方法 |
| CN101180553B (zh) * | 2006-01-31 | 2011-12-14 | 什里兰工业研究学院 | 二甘醇双烯丙基碳酸酯cr-39的改进透镜及其制备方法 |
| EP2008998B1 (en) * | 2006-04-19 | 2013-06-05 | Mitsui Chemicals, Inc. | Process for production of (poly)thiol compound for use as optical material |
| KR20110033960A (ko) | 2006-04-20 | 2011-04-01 | 미쓰이 가가쿠 가부시키가이샤 | 광학재료용 폴리티올 화합물의 제조방법 및 그것을 포함하는 중합성 조성물 |
| KR101016322B1 (ko) | 2008-12-30 | 2011-02-22 | 주식회사 포스코 | 이송 벨트 가이드 장치 |
| CN101614831B (zh) * | 2009-08-11 | 2010-10-27 | 杭州新顺化工有限公司 | 高折射率树脂镜片及其制备方法 |
| KR20120058635A (ko) * | 2010-08-13 | 2012-06-08 | 주식회사 케이오씨솔루션 | 광학렌즈용 폴리티올 화합물의 제조법 및 이를 포함하는 수지 조성물 |
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2013
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- 2013-02-28 CN CN201610391136.9A patent/CN105906773B/zh active Active
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- 2013-02-28 WO PCT/JP2013/001207 patent/WO2014027427A1/ja active Application Filing
- 2013-02-28 KR KR1020147032266A patent/KR101661835B1/ko active Active
- 2013-02-28 KR KR1020167004566A patent/KR101879962B1/ko active Active
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- 2013-02-28 KR KR20147032265A patent/KR20140141723A/ko not_active Ceased
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