HRP20120266T1 - Smjese koje sadržavaju epoksi smole i mješavine amina s derivatima gvanidina - Google Patents
Smjese koje sadržavaju epoksi smole i mješavine amina s derivatima gvanidina Download PDFInfo
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- HRP20120266T1 HRP20120266T1 HR20120266T HRP20120266T HRP20120266T1 HR P20120266 T1 HRP20120266 T1 HR P20120266T1 HR 20120266 T HR20120266 T HR 20120266T HR P20120266 T HRP20120266 T HR P20120266T HR P20120266 T1 HRP20120266 T1 HR P20120266T1
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- polyetheramine
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- 239000000203 mixture Substances 0.000 title claims abstract 28
- 239000003822 epoxy resin Substances 0.000 title claims abstract 14
- 229920000647 polyepoxide Polymers 0.000 title claims abstract 14
- 150000001412 amines Chemical class 0.000 title claims abstract 8
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 title claims abstract 4
- 150000002357 guanidines Chemical class 0.000 title 1
- 229940083094 guanine derivative acting on arteriolar smooth muscle Drugs 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 13
- 125000001931 aliphatic group Chemical group 0.000 claims 12
- 229920001451 polypropylene glycol Polymers 0.000 claims 12
- 238000005576 amination reaction Methods 0.000 claims 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 6
- 229920001577 copolymer Polymers 0.000 claims 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 6
- 238000005266 casting Methods 0.000 claims 5
- 238000006243 chemical reaction Methods 0.000 claims 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 239000002202 Polyethylene glycol Substances 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- 229920001223 polyethylene glycol Polymers 0.000 claims 4
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims 3
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims 3
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 2
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 239000000835 fiber Substances 0.000 claims 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- -1 menthendiamine Chemical compound 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims 2
- XBTRYWRVOBZSGM-UHFFFAOYSA-N (4-methylphenyl)methanediamine Chemical compound CC1=CC=C(C(N)N)C=C1 XBTRYWRVOBZSGM-UHFFFAOYSA-N 0.000 claims 1
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 claims 1
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 claims 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 claims 1
- GXVUZYLYWKWJIM-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanamine Chemical compound NCCOCCN GXVUZYLYWKWJIM-UHFFFAOYSA-N 0.000 claims 1
- STMZGJLCKJFMLQ-UHFFFAOYSA-N 2-[3-(2-aminoethyl)cyclohexyl]ethanamine Chemical compound NCCC1CCCC(CCN)C1 STMZGJLCKJFMLQ-UHFFFAOYSA-N 0.000 claims 1
- POTQBGGWSWSMCX-UHFFFAOYSA-N 3-[2-(3-aminopropoxy)ethoxy]propan-1-amine Chemical compound NCCCOCCOCCCN POTQBGGWSWSMCX-UHFFFAOYSA-N 0.000 claims 1
- JCEZOHLWDIONSP-UHFFFAOYSA-N 3-[2-[2-(3-aminopropoxy)ethoxy]ethoxy]propan-1-amine Chemical compound NCCCOCCOCCOCCCN JCEZOHLWDIONSP-UHFFFAOYSA-N 0.000 claims 1
- YOOSAIJKYCBPFW-UHFFFAOYSA-N 3-[4-(3-aminopropoxy)butoxy]propan-1-amine Chemical compound NCCCOCCCCOCCCN YOOSAIJKYCBPFW-UHFFFAOYSA-N 0.000 claims 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 claims 1
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 claims 1
- DZAUJYISWHNNMG-UHFFFAOYSA-N 4-ethyl-4-n-methyloctane-1,4-diamine Chemical compound CCCCC(CC)(NC)CCCN DZAUJYISWHNNMG-UHFFFAOYSA-N 0.000 claims 1
- QTKDDPSHNLZGRO-UHFFFAOYSA-N 4-methylcyclohexane-1,3-diamine Chemical compound CC1CCC(N)CC1N QTKDDPSHNLZGRO-UHFFFAOYSA-N 0.000 claims 1
- 239000009261 D 400 Substances 0.000 claims 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- XMSVKICKONKVNM-UHFFFAOYSA-N bicyclo[2.2.1]heptane-3,4-diamine Chemical compound C1CC2(N)C(N)CC1C2 XMSVKICKONKVNM-UHFFFAOYSA-N 0.000 claims 1
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 claims 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 claims 1
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- IWBOPFCKHIJFMS-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl) ether Chemical compound NCCOCCOCCN IWBOPFCKHIJFMS-UHFFFAOYSA-N 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 claims 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004848 polyfunctional curative Substances 0.000 abstract 2
- 150000002118 epoxides Chemical class 0.000 abstract 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
- C07C279/04—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to acyclic carbon atoms of a carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
- C07C279/16—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
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Abstract
Smjesa koja sadržiα) jednu ili više epoksi smola?) mješavinu koja sadrži1) 0.3 do 0.9 ekvivalenta amina, po ekvivalentu epoksida korištene komponente α), u komponenti a) za stvrdnjavanje, i 2) komponenta za stvrdnjavanje b), naznačena time što komponenta za stvrdnjavanje a) sadrži jedan ili više amina čija je funkcionalnost ? 2, i barem jedan amin, koji, kada se pomiješa u stehiometrijskom omjeru s epoksi smolom za smjesu od 100 g, daje pri sobnoj temperaturi vrijeme stvrdnjavanja kraće od 24 h, i komponenta za stvrdnjavanje b) sadrži barem jedan spoj formule I gdje je udio komponente za stvrdnjavanje b) 5% do 55%tež, na osnovu masenog udjela u mješavini, i u formuli I su R1 do R3, R5 i R6 svaki nezavisno organski radikal s 1 do 20 C atoma i vodik, a R4 se odabire između grupe organskih radikala s 1 do 20 C atoma i grupe -C(NH)NR5R6. Patent sadrži još 16 patentnih zahtjeva.
Claims (17)
1. Smjesa koja sadrži
α) jednu ili više epoksi smola
β) mješavinu koja sadrži
1) 0.3 do 0.9 ekvivalenta amina, po ekvivalentu epoksida korištene komponente α), u komponenti a) za stvrdnjavanje, i
2) komponenta za stvrdnjavanje b),
naznačena time što komponenta za stvrdnjavanje a) sadrži jedan ili više amina čija je funkcionalnost ≥ 2, i barem jedan amin, koji, kada se pomiješa u stehiometrijskom omjeru s epoksi smolom za smjesu od , daje pri sobnoj temperaturi vrijeme stvrdnjavanja kraće od 24 h, i komponenta za stvrdnjavanje b) sadrži barem jedan spoj formule I
[image]
gdje je udio komponente za stvrdnjavanje b) 5% do 55%tež, na osnovu masenog udjela u mješavini, i u formuli I su R1 do R3, R5 i R6 svaki nezavisno organski radikal s 1 do atoma i vodik, a R4 se odabire između grupe organskih radikala s 1 do atoma i grupe -C(NH)NR5R6.
2. Smjesa prema zahtjevu 1, naznačena time što se komponenta za stvrdnjavanje a) izabire iz grupe amina čija je funkcionalnost ≥ 2.
3. Smjesa prema bilo kojem od zahtjeva 1 i 2, naznačena time što komponenta za stvrdnjavanje a) sadrži barem dvije komponente za stvrdnjavanje a1) i a2), komponenta za stvrdnjavanje a1) je barem jedan polieteramin čija je funkcionalnost ≥ 2 i komponenta za stvrdnjavanje a2) je barem jedan drugi amin čija je funkcionalnost ≥ 2.
4. Smjesa prema bilo kojem od zahtjeva 1 do 3, naznačena time što se komponenta za stvrdnjavanje a1) izabire iz grupe koja obuhvaća 3,6-dioksa-1,8-oktandiamin, 4,7,10-trioksa-1,13-tridekandiamin, 4,7-dioksa-1,10-dekandiamin, 4,9-dioksa-1,12-dodekandiamin, polieteramin na bazi trietilen glikola s prosječnom molarnom masom 148, difunkcionalni, primarni polieteramin pripremljen aminacijom etilen glikola s klicom propilen oksida, s prosječnom molarnom masom 176, difunkcionalni, primarni polieteramin na bazi propilen oksida s prosječnom molarnom masom 4000, difunkcionalni, primarni polieteramin pripremljen aminacijom polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 2003, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 900, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 600, difunkcionalni, primarni polieteramin pripremljen aminacijom dietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 220, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola s prosječnom molarnom masom 1000, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola s prosječnom molarnom masom 1900, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola s prosječnom molarnom masom 1400, polietertriamin na bazi barem trihidro alkohola s klicom butilen oksida, s prosječnom molarnom masom 400, alifatski polieteramin pripremljen aminacijom alkohola s klicom butilen oksida, s prosječnom molarnom masom 219, polieteramin na bazi pentaeritritola i propilen oksida s prosječnom molarnom masom 600, difunkcionalni, primarni polieteramin na bazi polipropilen glikola s prosječnom molarnom masom 2000, difunkcionalni, primarni polieteramin na bazi polipropilen glikola s prosječnom molarnom masom 230, difunkcionalni, primarni polieteramin na bazi polipropilen glikola s prosječnom molarnom masom 400, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida s trimetilolpropanom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 403, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida s glicerolom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 5000, i polieteramin s prosječnom molarnom masom 400, pripremljen aminacijom poliTHF s prosječnom molarnom masom 250, i komponenta za stvrdnjavanje a2) se izabire iz grupe koja obuhvaća 1,12-diaminododekan, 1,10-diaminodekan, 1,2-diaminocikloheksan, 1,2-propandiamin, 1,3-bis(aminometil)cikloheksan, 1,3-propandiamin, 1-metil-2,4-diaminocikloheksan, 2,2’-oksibis(etilamin), 3,3’-dimetil-4,4’-diaminodicikloheksilmetan, 4,4’-metilendianilin, 4-etil-4-metilamino-1-oktilamin, dietilentriamin, etilendiamin, heksametilendiamin, izoforondiamin, mentendiamin, ksililendiamin, N-aminoetilpiperazin, neopentandiamin, norbornandiamin, oktametilendiamin, piperazin, 4,8-diaminotri-ciklo[5.2.1.0]dekan, tolilendiamin, trietilentetramin, i trimetilheksametilendiamin.
5. Smjesa prema bilo kojem od zahtjeva 1 do 4, naznačena time što se radikali R1 do R3, R5, i R6 u spojevima formule I svaki nezavisno izabiru iz grupe koja obuhvaća vodik, metil, etil, n-propil, izopropil, n-butil, sec-butil, fenil, i o-tolil, a R4 se izabire iz grupe koja obuhvaća metil, etil, n-propil, izopropil, n-butil, secbutil, fenil, o-tolil, i skupinu -C(NH)NR5R6-.
6. Smjesa prema zahtjevu 1, naznačena time što mješavina kao komponentu za stvrdnjavanje a1) sadrži polieteramin čija je funkcionalnost ≥ 2, izabran iz grupe koja obuhvaća difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 230, difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 400, alifatski, difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 2000, difunkcionalni, primarni polieteramin pripremljen aminacijom dietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 220, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida trimetilolpropanom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 403, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 900, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola, s prosječnom molarnom masom 1000, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola, s prosječnom molarnom masom 1900, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola, s prosječnom molarnom masom 1400, polietertriamin na bazi barem trihidro alkohola s klicom butilen oksida, s prosječnom molarnom masom 400, alifatski polieteramin pripremljen aminacijom alkohola s klicom butilen oksida, s prosječnom molarnom masom 219, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida s glicerolom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 5000, i kao komponentu za stvrdnjavanje a2) drugi amin čija je funkcionalnost ≥ 2, izabran iz grupe koja obuhvaća izoforondiamin, aminoetilpiperazin, 1,3 bis(aminoetil)cikloheksan, i trietilentetramin, omjer a1) prema a2) je u rasponu od 0.1 do 10:1.
7. Smjesa prema bilo kojem od zahtjeva 1 do 6, naznačena time što mješavina kao komponentu za stvrdnjavanje a1) sadrži polieteramin izabran iz grupe koja obuhvaća polieteramin D 230, polieteramin D 400, polieteramin T 403, polieteramin T 5000, komponenta za stvrdnjavanje a2) se izabire iz grupe koja obuhvaća izoforondiamin, aminoetilpiperazin, 1,3-bis(aminometil)cikloheksan, i trietilentetraamin, i komponenta za stvrdnjavanje b) je tetrametilgvanidin, a omjer komponente za stvrdnjavanje a1) prema komponenti za stvrdnjavanje a2) je u rasponu od 1.5 do 10:1, i 10 do 60mol% manje mješavine se dodaje u epoksi smolu nego što je potrebno za reakciju aktivne epoksi skupine na amino funkcijama mješavine.
8. Smjesa prema bilo kojem od zahtjeva 1 do 7, naznačena time što smjesa dalje sadrži materijal ojačan vlaknima.
9. Postupak pripreme smjese prema bilo kojem od zahtjeva 1 do 8, naznačen time što obuhvaća miješanje jedne ili više epoksi smola s mješavinom na temperaturama ispod početne temperature stvrdnjavanja komponente za stvrdnjavanje a).
10. Uporaba smjese prema bilo kojem od zahtjeva 1 do 8 za proizvodnju stvrdnute epoksi smole.
11. Uporaba prema zahtjevu 10, naznačena time što je stvrdnuta epoksi smola odljev iz kalupa.
12. Uporaba prema zahtjevu 11, naznačena time što odljev sadrži potporni materijal.
13. Stvrdnuta epoksi smola koji se može dobiti stvrdnjavanjem smjese prema bilo kojem od zahtjeva 1 do 8.
14. Stvrdnuta epoksi smola prema zahtjevu 13, naznačena time što je stvrdnuta epoksi smola odljev iz kalupa.
15. Odljev prema zahtjevu 14, naznačen time što je ojačan vlaknima.
16. Odljev prema zahtjevu 15 koji se može dobiti stvrdnjavanjem u kalupu koji je obložen materijalom ojačanim vlaknima i uvođenjem smjese prema bilo kojem od zahtjeva 1 do 7 u kalupu pomoću infuzijske tehnike.
17. Odljev prema bilo kojem od zahtjeva 15 i 16, naznačen time što je odljev ojačani sastavni dio za oštrice rotora na turbinama vjetrenjača.
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| KR101969083B1 (ko) | 2011-06-30 | 2019-04-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 아민 경화제와 과량의 에폭사이드기의 혼합물을 함유하는 경화성 에폭시 수지 시스템 |
| US8431444B2 (en) * | 2011-08-16 | 2013-04-30 | General Electric Company | Epoxy encapsulating and lamination adhesive and method of making same |
| EP2797731A2 (de) * | 2011-12-29 | 2014-11-05 | BASF Coatings GmbH | Verwendung von biologisch abbaubaren kunststofffolien in verfahren zur herstellung faserverstärkter kunststoffe mittels vakuuminfusion |
| US9193862B2 (en) | 2012-02-22 | 2015-11-24 | Basf Se | Blends for composite materials |
| JP2015511264A (ja) * | 2012-02-22 | 2015-04-16 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 複合材用のブレンド |
| FR2996984B1 (fr) | 2012-10-19 | 2014-12-26 | Paul Boye Technologies | Support, notamment textile, biocide |
| JP6200715B2 (ja) * | 2013-07-24 | 2017-09-20 | ナミックス株式会社 | エポキシ樹脂組成物、アンダーフィル剤、接着剤、および半導体装置 |
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| KR102580662B1 (ko) * | 2015-03-26 | 2023-09-21 | 훈츠만 어드밴스트 머티리얼스 라이센싱 (스위처랜드) 게엠베하 | 전기공학용 절연 시스템의 제조방법, 그에 의해 얻어진 물품 및 그의 용도 |
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| TW201016743A (en) | 2010-05-01 |
| PT2307359E (pt) | 2012-02-02 |
| CA2729895A1 (en) | 2010-01-28 |
| CN102105441A (zh) | 2011-06-22 |
| KR101562422B1 (ko) | 2015-10-22 |
| CA2729895C (en) | 2016-09-27 |
| EP2307359B1 (de) | 2012-01-04 |
| SI2307359T1 (sl) | 2012-05-31 |
| MX2011000688A (es) | 2011-03-15 |
| TWI460201B (zh) | 2014-11-11 |
| ATE540022T1 (de) | 2012-01-15 |
| JP2011528743A (ja) | 2011-11-24 |
| PL2307359T3 (pl) | 2012-06-29 |
| CN102105441B (zh) | 2015-02-11 |
| US9012020B2 (en) | 2015-04-21 |
| ES2379691T3 (es) | 2012-04-30 |
| KR20110052645A (ko) | 2011-05-18 |
| EP2307359A1 (de) | 2011-04-13 |
| US20110190419A1 (en) | 2011-08-04 |
| DK2307359T3 (da) | 2012-05-07 |
| JP2015052119A (ja) | 2015-03-19 |
| US20140107255A1 (en) | 2014-04-17 |
| US8741426B2 (en) | 2014-06-03 |
| WO2010010048A1 (de) | 2010-01-28 |
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