HRP20120234T1 - Mješavine amina s derivatima gvanidina - Google Patents
Mješavine amina s derivatima gvanidina Download PDFInfo
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- HRP20120234T1 HRP20120234T1 HR20120234T HRP20120234T HRP20120234T1 HR P20120234 T1 HRP20120234 T1 HR P20120234T1 HR 20120234 T HR20120234 T HR 20120234T HR P20120234 T HRP20120234 T HR P20120234T HR P20120234 T1 HRP20120234 T1 HR P20120234T1
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- 239000000203 mixture Substances 0.000 title claims abstract 20
- 150000001412 amines Chemical class 0.000 title claims 3
- 150000002357 guanidines Chemical class 0.000 title 1
- 229940083094 guanine derivative acting on arteriolar smooth muscle Drugs 0.000 title 1
- 239000003822 epoxy resin Substances 0.000 claims abstract 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract 7
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000000853 adhesive Substances 0.000 claims abstract 3
- 230000001070 adhesive effect Effects 0.000 claims abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 14
- 125000001931 aliphatic group Chemical group 0.000 claims 13
- 229920001451 polypropylene glycol Polymers 0.000 claims 13
- 238000005576 amination reaction Methods 0.000 claims 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 6
- 229920001577 copolymer Polymers 0.000 claims 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 6
- 239000002202 Polyethylene glycol Substances 0.000 claims 5
- 229920001223 polyethylene glycol Polymers 0.000 claims 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 claims 3
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 2
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 claims 2
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 claims 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 claims 1
- GXVUZYLYWKWJIM-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanamine Chemical compound NCCOCCN GXVUZYLYWKWJIM-UHFFFAOYSA-N 0.000 claims 1
- POTQBGGWSWSMCX-UHFFFAOYSA-N 3-[2-(3-aminopropoxy)ethoxy]propan-1-amine Chemical compound NCCCOCCOCCCN POTQBGGWSWSMCX-UHFFFAOYSA-N 0.000 claims 1
- JCEZOHLWDIONSP-UHFFFAOYSA-N 3-[2-[2-(3-aminopropoxy)ethoxy]ethoxy]propan-1-amine Chemical compound NCCCOCCOCCOCCCN JCEZOHLWDIONSP-UHFFFAOYSA-N 0.000 claims 1
- YOOSAIJKYCBPFW-UHFFFAOYSA-N 3-[4-(3-aminopropoxy)butoxy]propan-1-amine Chemical compound NCCCOCCCCOCCCN YOOSAIJKYCBPFW-UHFFFAOYSA-N 0.000 claims 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 claims 1
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 claims 1
- DZAUJYISWHNNMG-UHFFFAOYSA-N 4-ethyl-4-n-methyloctane-1,4-diamine Chemical compound CCCCC(CC)(NC)CCCN DZAUJYISWHNNMG-UHFFFAOYSA-N 0.000 claims 1
- QTKDDPSHNLZGRO-UHFFFAOYSA-N 4-methylcyclohexane-1,3-diamine Chemical compound CC1CCC(N)CC1N QTKDDPSHNLZGRO-UHFFFAOYSA-N 0.000 claims 1
- 239000009261 D 400 Substances 0.000 claims 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 claims 1
- XMSVKICKONKVNM-UHFFFAOYSA-N bicyclo[2.2.1]heptane-3,4-diamine Chemical compound C1CC2(N)C(N)CC1C2 XMSVKICKONKVNM-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 claims 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 claims 1
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 claims 1
- IWBOPFCKHIJFMS-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl) ether Chemical compound NCCOCCOCCN IWBOPFCKHIJFMS-UHFFFAOYSA-N 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- -1 menthendiamine Chemical compound 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 claims 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000009816 wet lamination Methods 0.000 claims 1
- 239000004848 polyfunctional curative Substances 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
- C07C211/36—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton containing at least two amino groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
- C07C279/04—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to acyclic carbon atoms of a carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Mješavina koja sadrži komponentu za stvrdnjavanje a1), komponentu za stvrdnjavanje a2) i komponentu za stvrdnjavanje b), naznačena time što je korištena komponenta za stvrdnjavanje a1) polieteramin čija je funkcionalnost ? 2, korištena komponenta za stvrdnjavanje a2) je drugi amin čija je funkcionalnost ? 2, i korištena komponenta za stvrdnjavanje b) čini 5% do 55%tež mješavine, i to je spoj formule I gdje su R1 do R3, R5 i R6 svaki nezavisno izabrani iz grupe koja obuhvaća vodik i organski radikal s 1 do 20 C atoma, a R4 se odabire između grupe organskih radikala s 1 do 20 C atoma i skupine -C(NH)NR5R6; pri čemu je omjer a1) prema a2) u rasponu od 0.1 do 10:1. Patent sadrži još 12 patentnih zahtjeva.
Claims (13)
1. Mješavina koja sadrži komponentu za stvrdnjavanje a1), komponentu za stvrdnjavanje a2) i komponentu za stvrdnjavanje b), naznačena time što je
korištena komponenta za stvrdnjavanje a1) polieteramin čija je funkcionalnost ≥ 2,
korištena komponenta za stvrdnjavanje a2) je drugi amin čija je funkcionalnost ≥ 2, i
korištena komponenta za stvrdnjavanje b) čini 5% do 55%tež mješavine, i to je spoj formule I
[image]
gdje su R1 do R3, R5 i R6 svaki nezavisno izabrani iz grupe koja obuhvaća vodik i organski radikal s 1 do 20 C atoma, a R4 se odabire između grupe organskih radikala s 1 do 20 C atoma i skupine -C(NH)NR5R6;
pri čemu je omjer a1) prema a2) u rasponu od 0.1 do 10:1.
2. Smjesa prema zahtjevu 1, naznačena time što
korištena komponenta za stvrdnjavanje a1) jest polieteramin čija je funkcionalnost ≥ 2, a izabire se iz grupe koja obuhvaća 3,6-dioksa-1,8-oktandiamin, 4,7,10-trioksa-1,13-tridekandiamin, 4,7-dioksa-1,10-dekandiamin, 4,9-dioksa-1,12-dodekandiamin, polieteramin na bazi trietilen glikola s prosječnom molarnom masom 148, difunkcionalni, primarni polieteramin pripremljen aminacijom etilen glikola s klicom propilen oksida, s prosječnom molarnom masom 176, difunkcionalni, primarni polieteramin na bazi propilen oksida s prosječnom molarnom masom 4000, difunkcionalni, primarni polieteramin pripremljen aminacijom polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 2003, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 2003, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 900, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 600, difunkcionalni, primarni polieteramin pripremljen aminacijom dietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 220, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola s prosječnom molarnom masom 1000, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola s prosječnom molarnom masom 1900, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola s prosječnom molarnom masom 1400, polietertriamin na bazi barem trihidro alkohola s klicom butilen oksida, s prosječnom molarnom masom 400, alifatski polieteramin pripremljen aminacijom alkohola s klicom butilen oksida, s prosječnom molarnom masom 219, polieteramin na bazi pentaeritritola i propilen oksida s prosječnom molarnom masom 600, difunkcionalni, primarni polieteramin na bazi polipropilen glikola s prosječnom molarnom masom 2000, difunkcionalni, primarni polieteramin na bazi polipropilen glikola s prosječnom molarnom masom 230, difunkcionalni, primarni polieteramin na bazi polipropilen glikola s prosječnom molarnom masom 400, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida s trimetilolpropanom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 403, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida s glicerolom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 5000, i polieteramin s prosječnom molarnom masom 400, pripremljen aminacijom poliTHF s prosječnom molarnom masom 250,
korištena komponenta za stvrdnjavanje a2) jest drugi amin čija je funkcionalnost ≥ 2, a izabire se iz grupe koja obuhvaća 1,12-diaminododekan, 1,10-diaminodekan, 1,2-diaminocikloheksan, 1,2-propandiamin, 1,3-bis(aminometil)cikloheksan, 1,3-propandiamin, 1-metil-2,4-diaminocikloheksan, 2,2’-oksibis(etilamin), 3,3’-dimetil-4,4’-diaminodicikloheksilmetan, 4,4’-metilendianilin, 4-etil-4-metilamino-1-oktilamin, dietilentriamin, etilendiamin, heksametilendiamin, izoforondiamin, mentendiamin, ksililendiamin, N-aminoetilpiperazin, neopentandiamin, norbornandiamin, oktametilendiamin, piperazin, 4,8-diaminotri-ciklo[5.2.1.0]dekan, tolilendiamin, trietilentetramin, i trimetilheksametilendiamin.
3. Mješavina prema bilo kojem od zahtjeva 1 i 2, naznačena time što se polieteramini za komponentu za stvrdnjavanje a1) izabiru iz grupe koja obuhvaća difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 230, difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 400, alifatski, difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 2000, difunkcionalni, primarni polieteramin pripremljen aminacijom dietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 220, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida trimetilolpropanom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 403, alifatski polieteramin na bazi polietilen glikola s klicom propilen oksida, s prosječnom molarnom masom 900, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola, s prosječnom molarnom masom 1000, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola, s prosječnom molarnom masom 1900, alifatski polieteramin na bazi kopolimera poli(tetrametilen eter glikola) i polipropilen glikola, s prosječnom molarnom masom 1400, polietertriamin na bazi barem trihidro alkohola s klicom butilen oksida, s prosječnom molarnom masom 400, alifatski polieteramin pripremljen aminacijom alkohola s klicom butilen oksida, s prosječnom molarnom masom 219, trifunkcionalni, primarni polieteramin pripremljen reakcijom propilen oksida s glicerolom, nakon čega slijedi aminacija terminalnih OH skupina, s prosječnom molarnom masom 5000.
4. Mješavina prema bilo kojem od zahtjeva 1 do 3, naznačena time što se komponenta za stvrdnjavanje b) izabire iz grupe koja obuhvaća tetrametilgvanidin, o-tolilbigvanidin i pentametilbigvanidin.
5. Mješavina prema bilo kojem od zahtjeva 1 do 4, naznačena time što se komponenta za stvrdnjavanje a1) izabire iz grupe koja obuhvaća polieteramin D 230, polieteramin D 400, polieteramin T 403 i polieteramin T 5000, komponenta za stvrdnjavanje a2) se izabire iz grupe koja obuhvaća izoforondiamin, aminoetilpiperazin, 1,3-bis(aminometil)cikloheksan, i trietilentetraamin, a komponenta za stvrdnjavanje b) je tetrametilgvanidin, a omjer komponente za stvrdnjavanje a1) prema komponenti za stvrdnjavanje a2) je u rasponu od 1.5 do 10:1.
6. Mješavina prema bilo kojem od zahtjeva 1 do 5, naznačena time što je korištena komponenta za stvrdnjavanje a1) difunkcionalni, primarni polieteramin na bazi polipropilen glikola, s prosječnom molarnom masom 230, komponenta za stvrdnjavanje a2) je izoforondiamin, a komponenta za stvrdnjavanje b) je tetrametilgvanidin.
7. Mješavina prema bilo kojem od zahtjeva 1 do 6, naznačena time što dalje sadrži materijal ojačan vlaknima i/ili punila.
8. Postupak pripreme mješavine prema bilo kojem od zahtjeva 1 do 7, naznačen time što obuhvaća zajedničko miješanje komponenti za stvrdnjavanje a1), a2) i b) na temperaturi ispod 160°C.
9. Uporaba mješavine prema bilo kojem od zahtjeva 1 do 7 za stvrdnjavanje epoksi smola.
10. Uporaba prema zahtjevu 9 kao sredstva za stvrdnjavanje za materijale impregnirane smolom (prepreg) ili VARTM, za širenje filamenata, pultruziju (izvlačenje) ili sustav mokrog laminiranja.
11. Uporaba mješavine prema bilo kojem od zahtjeva 1 do 7 gdje su epoksi smole strukturalni adhezivi.
12. Strukturalni adheziv koji sadrži mješavinu prema bilo kojem od zahtjeva 1 do 7.
13. Stvrdnuta epoksi smola koja se može dobiti reakcijskom epoksi smole s mješavinom prema bilo kojem od zahtjeva 1 do 7.
Applications Claiming Priority (3)
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| EP08160857 | 2008-07-22 | ||
| EP2009058700 | 2009-07-08 | ||
| PCT/EP2009/059210 WO2010010045A1 (de) | 2008-07-22 | 2009-07-17 | Mischungen von aminen mit guanidin-derivaten |
Publications (1)
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|---|---|
| HRP20120234T1 true HRP20120234T1 (hr) | 2012-04-30 |
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| HR20120234T HRP20120234T1 (hr) | 2008-07-22 | 2012-03-13 | Mješavine amina s derivatima gvanidina |
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| EP (1) | EP2307358B1 (hr) |
| JP (2) | JP2011528741A (hr) |
| KR (1) | KR101562421B1 (hr) |
| CN (2) | CN103588958B (hr) |
| AT (1) | ATE538088T1 (hr) |
| BR (1) | BRPI0915938A2 (hr) |
| CA (1) | CA2730518C (hr) |
| DK (1) | DK2307358T3 (hr) |
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| HR (1) | HRP20120234T1 (hr) |
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| PL (1) | PL2307358T3 (hr) |
| PT (1) | PT2307358E (hr) |
| SI (1) | SI2307358T1 (hr) |
| TW (1) | TWI450912B (hr) |
| WO (1) | WO2010010045A1 (hr) |
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| CN102105441B (zh) * | 2008-07-22 | 2015-02-11 | 巴斯夫欧洲公司 | 包含环氧树脂以及胺与胍衍生物的混合物的共混物 |
| MX2011006417A (es) * | 2010-06-24 | 2012-01-02 | Momentive Specialty Chem Inc | Sistemas de epoxi mejorados para materiales compuestos. |
| CN102391475A (zh) * | 2011-09-29 | 2012-03-28 | 东方电气集团东方汽轮机有限公司 | 风力发电机叶片用潜伏型环氧树脂体系及其制备方法 |
| JP2015511264A (ja) | 2012-02-22 | 2015-04-16 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 複合材用のブレンド |
| US9193862B2 (en) | 2012-02-22 | 2015-11-24 | Basf Se | Blends for composite materials |
| CN102731968B (zh) * | 2012-07-24 | 2013-08-21 | 广州市博汇新材料科技有限公司 | 一种低烟阻燃含有环氧树脂的组合物及其制备方法 |
| WO2014035393A1 (en) | 2012-08-30 | 2014-03-06 | Empire Technology Development Llc | Switchable ionic adhesive coating for recyclable carbon fiber |
| DE102014209355A1 (de) | 2014-05-16 | 2015-11-19 | Evonik Degussa Gmbh | Guanidinhaltige Polyoxyalkylene und Verfahren zur Herstellung |
| CN104961656B (zh) * | 2015-05-27 | 2017-01-25 | 山西大学 | 一种双胍化合物及其制备方法 |
| EP3178863B1 (de) * | 2015-12-11 | 2019-08-28 | Evonik Degussa GmbH | Epoxidharz-zusammensetzungen zur herstellung von lagerstabilen composites |
| ES2748607T3 (es) * | 2015-12-11 | 2020-03-17 | Evonik Operations Gmbh | Formulaciones de resina epoxídica latentes para procesos de impregnación de líquido para la producción de compuestos reforzados con fibras |
| KR102364545B1 (ko) * | 2016-06-16 | 2022-02-21 | 헌츠만 페트로케미칼 엘엘씨 | 에폭시 수지 조성물을 경화시키기 위한 배합물 |
| CN106045886B (zh) * | 2016-06-21 | 2018-05-01 | 武汉工程大学 | 一种化合物二﹣(双胍基对苯基)甲烷及其合成方法、应用 |
| CN105885014A (zh) * | 2016-06-21 | 2016-08-24 | 武汉工程大学 | 新型化合物二﹣（双胍基对苯基）甲烷作为固化剂在环氧树脂体系的应用 |
| CN106753143A (zh) * | 2016-12-21 | 2017-05-31 | 南京诺邦新材料有限公司 | 一种具有导热功能的低温固化底部填充胶及其制备方法 |
| EP3725818A1 (de) | 2019-04-18 | 2020-10-21 | Basf Se | Epoxidharz-basierte faser-matrix-zusammensetzungen mit alkyl-substituierten ethylenaminen |
| CN112358633B (zh) * | 2020-10-23 | 2022-05-10 | 广州市聚欣盈复合材料科技股份有限公司 | 一种碳布-环氧树脂复合材料及其制备方法与应用 |
| WO2023094302A1 (en) | 2021-11-29 | 2023-06-01 | Basf Se | New aliphatic polyamines for use as curing agent for epoxy resins |
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| JP5021469B2 (ja) * | 2004-07-09 | 2012-09-05 | ハンツマン・アドヴァンスト・マテリアルズ・（スイッツランド）・ゲーエムベーハー | アミン組成物 |
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| DE102006056311B4 (de) | 2006-11-29 | 2018-03-01 | Alzchem Trostberg Gmbh | Verwendung von Guanidin-Derivaten als Beschleuniger bei der Härtung von Epoxidharzsystemen |
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2009
- 2009-07-17 KR KR1020117003919A patent/KR101562421B1/ko not_active IP Right Cessation
- 2009-07-17 ES ES09780758T patent/ES2377376T3/es active Active
- 2009-07-17 CN CN201310506975.7A patent/CN103588958B/zh active Active
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- 2009-07-17 US US13/054,945 patent/US9328058B2/en active Active
- 2009-07-17 PT PT09780758T patent/PT2307358E/pt unknown
- 2009-07-17 SI SI200930206T patent/SI2307358T1/sl unknown
- 2009-07-17 BR BRPI0915938-0A patent/BRPI0915938A2/pt not_active IP Right Cessation
- 2009-07-17 JP JP2011519131A patent/JP2011528741A/ja active Pending
- 2009-07-17 CN CN2009801285231A patent/CN102105440B/zh active Active
- 2009-07-17 AT AT09780758T patent/ATE538088T1/de active
- 2009-07-17 PL PL09780758T patent/PL2307358T3/pl unknown
- 2009-07-17 EP EP09780758A patent/EP2307358B1/de not_active Revoked
- 2009-07-17 DK DK09780758.0T patent/DK2307358T3/da active
- 2009-07-17 WO PCT/EP2009/059210 patent/WO2010010045A1/de active Application Filing
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Also Published As
| Publication number | Publication date |
|---|---|
| PL2307358T3 (pl) | 2012-05-31 |
| JP2015083675A (ja) | 2015-04-30 |
| CN103588958A (zh) | 2014-02-19 |
| MX2011000421A (es) | 2011-02-22 |
| CN103588958B (zh) | 2017-01-18 |
| CA2730518A1 (en) | 2010-01-28 |
| CN102105440A (zh) | 2011-06-22 |
| JP2011528741A (ja) | 2011-11-24 |
| WO2010010045A1 (de) | 2010-01-28 |
| EP2307358A1 (de) | 2011-04-13 |
| EP2307358B1 (de) | 2011-12-21 |
| US20110130524A1 (en) | 2011-06-02 |
| KR20110044241A (ko) | 2011-04-28 |
| ES2377376T3 (es) | 2012-03-27 |
| DK2307358T3 (da) | 2012-04-10 |
| ATE538088T1 (de) | 2012-01-15 |
| SI2307358T1 (sl) | 2012-04-30 |
| CN102105440B (zh) | 2013-11-27 |
| KR101562421B1 (ko) | 2015-10-21 |
| PT2307358E (pt) | 2012-02-08 |
| US9328058B2 (en) | 2016-05-03 |
| CA2730518C (en) | 2016-09-27 |
| TWI450912B (zh) | 2014-09-01 |
| TW201026736A (en) | 2010-07-16 |
| BRPI0915938A2 (pt) | 2018-10-30 |
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