GB1582595A - Chiral acid esters - Google Patents

Chiral acid esters Download PDF

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Publication number
GB1582595A
GB1582595A GB16866/77A GB1686677A GB1582595A GB 1582595 A GB1582595 A GB 1582595A GB 16866/77 A GB16866/77 A GB 16866/77A GB 1686677 A GB1686677 A GB 1686677A GB 1582595 A GB1582595 A GB 1582595A
Authority
GB
United Kingdom
Prior art keywords
cyano
cyclopropane
chiral acid
ester
phenoxybenzyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16866/77A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9172256&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=GB1582595(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of GB1582595A publication Critical patent/GB1582595A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/13Amines
    • A61K31/135Amines having aromatic rings, e.g. ketamine, nortriptyline
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/33Heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62Oxygen or sulfur atoms
    • C07D213/63One oxygen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62Oxygen or sulfur atoms
    • C07D213/63One oxygen atom
    • C07D213/64One oxygen atom attached in position 2 or 6
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32One oxygen, sulfur or nitrogen atom
    • C07D239/34One oxygen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D241/00Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/18Oxygen or sulfur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Public Health (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Quinoline Compounds (AREA)
GB16866/77A 1976-04-23 1977-04-22 Chiral acid esters Expired GB1582595A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7612094A FR2375161A1 (fr) 1976-04-23 1976-04-23 Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s)

Publications (1)

Publication Number Publication Date
GB1582595A true GB1582595A (en) 1981-01-14

Family

ID=9172256

Family Applications (2)

Application Number Title Priority Date Filing Date
GB16866/77A Expired GB1582595A (en) 1976-04-23 1977-04-22 Chiral acid esters
GB16867/77A Expired GB1582596A (en) 1976-04-23 1977-04-22 Cyclopropane carboxylic esters

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB16867/77A Expired GB1582596A (en) 1976-04-23 1977-04-22 Cyclopropane carboxylic esters

Country Status (39)

Country Link
US (2) US4133826A (US08088918-20120103-C00476.png)
JP (2) JPS52131559A (US08088918-20120103-C00476.png)
AR (1) AR228557A1 (US08088918-20120103-C00476.png)
AT (2) AT364675B (US08088918-20120103-C00476.png)
AU (1) AU512155B2 (US08088918-20120103-C00476.png)
BE (1) BE853867A (US08088918-20120103-C00476.png)
BR (1) BR7702576A (US08088918-20120103-C00476.png)
CA (1) CA1130311A (US08088918-20120103-C00476.png)
CH (1) CH620889A5 (US08088918-20120103-C00476.png)
CS (1) CS214851B2 (US08088918-20120103-C00476.png)
DD (1) DD130929A5 (US08088918-20120103-C00476.png)
DE (1) DE2718039C2 (US08088918-20120103-C00476.png)
DK (2) DK171573B1 (US08088918-20120103-C00476.png)
ES (1) ES458112A1 (US08088918-20120103-C00476.png)
FR (1) FR2375161A1 (US08088918-20120103-C00476.png)
GB (2) GB1582595A (US08088918-20120103-C00476.png)
GR (1) GR63104B (US08088918-20120103-C00476.png)
GT (1) GT197957492A (US08088918-20120103-C00476.png)
HK (2) HK51984A (US08088918-20120103-C00476.png)
HR (1) HRP931394B1 (US08088918-20120103-C00476.png)
HU (1) HU181942B (US08088918-20120103-C00476.png)
IE (1) IE45496B1 (US08088918-20120103-C00476.png)
IL (1) IL51958A (US08088918-20120103-C00476.png)
IT (1) IT1073208B (US08088918-20120103-C00476.png)
LU (1) LU77183A1 (US08088918-20120103-C00476.png)
MX (1) MX5299E (US08088918-20120103-C00476.png)
MY (1) MY8500509A (US08088918-20120103-C00476.png)
NL (1) NL180934C (US08088918-20120103-C00476.png)
NO (1) NO149104C (US08088918-20120103-C00476.png)
NZ (1) NZ183938A (US08088918-20120103-C00476.png)
OA (1) OA05636A (US08088918-20120103-C00476.png)
PL (2) PL113207B1 (US08088918-20120103-C00476.png)
PT (1) PT66468B (US08088918-20120103-C00476.png)
SE (2) SE446629B (US08088918-20120103-C00476.png)
SG (2) SG23284G (US08088918-20120103-C00476.png)
SU (1) SU990082A3 (US08088918-20120103-C00476.png)
TR (1) TR19049A (US08088918-20120103-C00476.png)
YU (1) YU40297B (US08088918-20120103-C00476.png)
ZA (1) ZA772474B (US08088918-20120103-C00476.png)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2187385A (en) * 1986-03-07 1987-09-09 Shell Int Research Method of combatting colorado beetles using chemical compounds and compositions containing the chemical compounds
US5004822A (en) * 1971-12-21 1991-04-02 National Research Development Corporation Insecticides

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1599876A (en) * 1977-06-13 1981-10-07 Shell Int Research Conversion of a stereoisomer into its diastereoisomer
CH635563A5 (fr) * 1977-07-07 1983-04-15 Sumitomo Chemical Co Procede pour la preparation d'un alpha-cyano-3-phenoxybenzyle optiquement actif.
FR2402411A1 (fr) * 1977-09-08 1979-04-06 Roussel Uclaf Application comme pesticide, dans la lutte contre les acariens et contre les nematodes parasites des vegetaux, d'esters d'acides cyclopropane carboxyliques a chaine dihalovinylique et les compositions acaricides et nematicides les renfermant
CA1215717A (en) * 1977-09-26 1986-12-23 Samuel B. Soloway Process for converting a stereoisomeric ester into its diastereoisomer
JPS54103831A (en) * 1978-01-27 1979-08-15 Sumitomo Chem Co Ltd Separation of stereoisomers of higher active cyanoo33 phenoxybenzyl 22*44chlorophenyl**isovalerate
ZA7911B (en) * 1978-01-31 1980-01-30 Roussel Uclaf Optically-active substituted benzyl alcohol and process for preparing it
FR2419939A1 (fr) * 1978-03-17 1979-10-12 Roussel Uclaf Procede de preparation d'un ether d'alcool a-cyane optiquement actif
FR2428029A1 (fr) * 1978-06-06 1980-01-04 Roussel Uclaf Esters d'acides cyclopropane carboxyliques substitues d'alcool a-cyane, leur procede de preparation et les compositions insecticides ou nematicides les renfermant
FR2447899A2 (fr) * 1979-02-05 1980-08-29 Roussel Uclaf Alcool benzylique substitue optiquement actif et son procede de preparation
JPS55104249A (en) * 1979-02-05 1980-08-09 Sumitomo Chem Co Ltd Optically active carboxylic ester its preparation, and insecticide, and acaricide comprising it
JPS55104253A (en) * 1979-02-06 1980-08-09 Sumitomo Chem Co Ltd Stereoisomer of more active carboxylic ester, method of obtaining it, insecticide and acaricide comprising it
US4261921A (en) * 1979-06-06 1981-04-14 Fmc Corporation Process for preparation of a crystalline insecticidal pyrethroid enantiomer pair
US4308279A (en) * 1979-06-06 1981-12-29 Fmc Corporation Crystalline, insecticidal pyrethroid
FR2458542A1 (fr) * 1979-06-12 1981-01-02 Roussel Uclaf Procede de preparation d'alcools a-cyanes optiquement actifs
FR2471187A1 (fr) * 1979-12-10 1981-06-19 Roussel Uclaf Nouvelles compositions destinees a la lutte contre les parasites des animaux a sang chaud
DE2928406A1 (de) * 1979-07-13 1981-01-29 Bayer Ag Neue menthylester, verfahren zu ihrer herstellung und ihre verwendung zur enantiomerentrennung chiraler carbonsaeuren
JPS5657756A (en) * 1979-10-15 1981-05-20 Sumitomo Chem Co Ltd Preparation of more highly active carboxylic ester
CA1150301A (en) * 1979-11-27 1983-07-19 Michael J. Bull Cyclopropane carboxylic acid ester derivatives
FR2470602A1 (fr) * 1979-12-04 1981-06-12 Roussel Uclaf A titre de produit destine a la lutte contre les acariens parasites des animaux, le 1r, cis 2,2-dimethyl 3-(2,2-dichlorovinyl) cyclopropane-1-carboxylate de (s) a-cyano 3-phenoxy benzyle
JPS56133253A (en) * 1980-03-24 1981-10-19 Sumitomo Chem Co Ltd Optical isomer of cyanohydrin ester, its production and insecticide and acaricide containing the same as effective ingredient
US4260633A (en) * 1980-04-21 1981-04-07 Zoecon Corporation Pesticidal esters of amino acids
CA1162560A (en) 1980-04-23 1984-02-21 Ronald F. Mason Process for preparing cyclopropane carboxylic acid ester derivatives
CA1150730A (en) * 1980-04-23 1983-07-26 Michael J. Bull Process for preparing cyclopropane carboxylic acid ester derivatives
JPS5793948A (en) * 1980-12-02 1982-06-11 Sumitomo Chem Co Ltd Preparation of stereoisomer mixture of higher active phenylacetic ester derivative
USRE32289E (en) * 1982-04-26 1986-11-18 Phillips Petroleum Company Cyanohydrocarbylated alkoxylates and glycerides
US4455255A (en) * 1982-04-26 1984-06-19 Phillips Petroleum Company Cyanohydrocarbylated alkoxylates and glycerides
ATE28324T1 (de) * 1982-10-18 1987-08-15 Ici Plc Insektizides produkt und seine herstellung.
EP0291626A3 (en) 1982-11-22 1989-05-31 E.I. Du Pont De Nemours And Company Process for the preparation of optically-active cyanomethyl esters
DE3401483A1 (de) * 1984-01-18 1985-07-25 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl-ester
GB8418331D0 (en) * 1984-07-18 1984-08-22 Ici Plc Insecticidal ester
GB8422872D0 (en) * 1984-09-11 1984-10-17 Ici Plc Insecticidal product
HU198373B (en) * 1986-01-08 1989-10-30 Chinoin Gyogyszer Es Vegyeszet Artropodicide composition containing trans-cipermetrin isomeres and process for producing the active components
CA1275108A (en) * 1985-01-16 1990-10-09 Laszlo Pap Insecticidal composition comprising more than one active ingredients
DE3522629A1 (de) * 1985-06-25 1987-01-08 Bayer Ag Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl -ester
US5164411A (en) * 1991-01-25 1992-11-17 Fmc Corporation Pyrethroid compositions
GB9127355D0 (en) * 1991-12-24 1992-02-19 Ici Plc Isomerisation process
JPH0660372U (ja) * 1993-01-29 1994-08-23 株式会社釣研 うき止め体
JP3139693B2 (ja) * 1993-02-18 2001-03-05 横河電機株式会社 入出力ユニット
GB0229803D0 (en) 2002-12-20 2003-01-29 Syngenta Ltd Chemical process

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3046299A (en) * 1958-07-28 1962-07-24 Rhone Poulenc Sa Process for the preparation of cyclopropane-carboxylic acids of transform
FR2036088A5 (US08088918-20120103-C00476.png) * 1969-03-04 1970-12-24 Roussel Uclaf
JPS515450B1 (US08088918-20120103-C00476.png) * 1971-06-29 1976-02-20
US3906026A (en) * 1972-05-16 1975-09-16 Sumitomo Chemical Co Process for preparing alkyl trans-chrysanthemate
US4024163A (en) * 1972-05-25 1977-05-17 National Research Development Corporation Insecticides
DE2326077C2 (de) * 1972-05-25 1985-12-12 National Research Development Corp., London Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide
DE2439177C2 (de) 1973-08-15 1984-02-02 National Research Development Corp., London (±)-α-Cyan-3-phenoxybenzyl-(1R,trans)- und (1R,cis)-2,2-dimethyl-3-(2,2-dibromvinyl)-cyclopropancarboxylat und (S)-α-Cyan-3-phenoxybenzyl-(1R,cis)-2,2-dimethyl-3-(2,2-dibromvinyl)-cyclopropancarboxylat, Verfahren zur Herstellung des (S)-Isomeren und diese Verbindungen enthaltende Insektizide
JPS5813522B2 (ja) * 1974-10-24 1983-03-14 住友化学工業株式会社 新しいシクロプロパンカルボン酸エステルを含有する殺虫、殺ダニ剤

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5004822A (en) * 1971-12-21 1991-04-02 National Research Development Corporation Insecticides
GB2187385A (en) * 1986-03-07 1987-09-09 Shell Int Research Method of combatting colorado beetles using chemical compounds and compositions containing the chemical compounds

Also Published As

Publication number Publication date
ATA929178A (de) 1981-04-15
PT66468A (fr) 1977-05-01
NO149104C (no) 1984-02-15
DK171573B1 (da) 1997-01-20
TR19049A (tr) 1978-04-12
US4136195A (en) 1979-01-23
AT364675B (de) 1981-11-10
FR2375161B1 (US08088918-20120103-C00476.png) 1979-04-13
LU77183A1 (US08088918-20120103-C00476.png) 1977-11-22
DK317589A (da) 1989-06-27
MY8500509A (en) 1985-12-31
IE45496B1 (en) 1982-09-08
YU104777A (en) 1983-04-30
AR228557A1 (es) 1983-03-30
CA1130311A (fr) 1982-08-24
HK51984A (en) 1984-06-22
PL117200B1 (en) 1981-07-31
MX5299E (es) 1983-06-13
PT66468B (fr) 1979-03-09
CH620889A5 (US08088918-20120103-C00476.png) 1980-12-31
OA05636A (fr) 1981-04-30
NL7704521A (nl) 1977-10-25
NL180934B (nl) 1986-12-16
NO149104B (no) 1983-11-07
SG23284G (en) 1985-01-04
AU512155B2 (en) 1980-09-25
SE7704518L (sv) 1977-10-24
NZ183938A (en) 1979-10-25
SE8204715L (sv) 1982-08-16
ATA289677A (de) 1980-07-15
BR7702576A (pt) 1977-11-29
JPS52148040A (en) 1977-12-08
JPS6127385B2 (US08088918-20120103-C00476.png) 1986-06-25
GR63104B (en) 1979-09-05
DE2718039A1 (de) 1977-11-17
FR2375161A1 (fr) 1978-07-21
SE8204715D0 (sv) 1982-08-16
PL113207B1 (en) 1980-11-29
AT360970B (de) 1981-02-10
JPS52131559A (en) 1977-11-04
DE2718039C2 (de) 1985-02-28
NL180934C (nl) 1987-05-18
GT197957492A (es) 1980-10-11
ES458112A1 (es) 1978-03-16
SU990082A3 (ru) 1983-01-15
CS214851B2 (en) 1982-06-25
SE446629B (sv) 1986-09-29
DK317589D0 (da) 1989-06-27
IE45496L (en) 1977-10-23
GB1582596A (en) 1981-01-14
PL197553A1 (pl) 1978-01-02
ZA772474B (en) 1978-06-28
BE853867A (fr) 1977-10-24
US4133826A (en) 1979-01-09
IL51958A (en) 1983-02-23
DK170732B1 (da) 1995-12-27
AU2459577A (en) 1978-11-02
NO771244L (no) 1977-10-25
YU40297B (en) 1985-12-31
DD130929A5 (de) 1978-05-17
DK177077A (da) 1977-10-24
HK51884A (en) 1984-06-22
HU181942B (en) 1983-11-28
SG23184G (en) 1985-01-04
SE449359B (sv) 1987-04-27
HRP931394B1 (en) 1996-04-30
IT1073208B (it) 1985-04-13
JPS612642B2 (US08088918-20120103-C00476.png) 1986-01-27

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PS Patent sealed [section 19, patents act 1949]
430B Application (made) for amendment of specification (sect. 30/1949)
430 Proceeding under section 30 patents act 1949
SP Amendment (slips) printed
704A Declaration that licence is not available as of right for an excepted use (par. 4a/1977)
PE20 Patent expired after termination of 20 years

Effective date: 19970421