DK177077A - Fremgangsmade til omdannelse af en chiral ester af en optisk aktiv alfa-cyaneret sekunder alkohol med r-struktur til ester mellem chiral syre og alfa-cyaneret sekunder alkohol med s-strktur - Google Patents

Fremgangsmade til omdannelse af en chiral ester af en optisk aktiv alfa-cyaneret sekunder alkohol med r-struktur til ester mellem chiral syre og alfa-cyaneret sekunder alkohol med s-strktur

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Publication number
DK177077A
DK177077A DK177077A DK177077A DK177077A DK 177077 A DK177077 A DK 177077A DK 177077 A DK177077 A DK 177077A DK 177077 A DK177077 A DK 177077A DK 177077 A DK177077 A DK 177077A
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DK
Denmark
Prior art keywords
cyanced
alcohol
ester
alfa
chiral
Prior art date
Application number
DK177077A
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English (en)
Other versions
DK171573B1 (da
Inventor
Julien Warnant
Jacques Prost-Marechal
Philippe Cosquer
Original Assignee
Roussel Uclaf
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9172256&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK177077(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Roussel Uclaf filed Critical Roussel Uclaf
Publication of DK177077A publication Critical patent/DK177077A/da
Application granted granted Critical
Publication of DK171573B1 publication Critical patent/DK171573B1/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/13—Amines
    • A61K31/135—Amines having aromatic rings, e.g. ketamine, nortriptyline
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/34—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/18—Oxygen or sulfur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Quinoline Compounds (AREA)
DK177077A 1976-04-23 1977-04-22 Fremgangsmåde til omdannelse af en chiral ester mellem en dihalogeneret cyclopropancarboxylsyre med to asymmetriske carbonatomer i ringen og en optisk aktiv alfa-cyaneret sekundær alkohol med R-struktur eller en racemisk alkohol med R,S-struktur eller den chirale ester er en blanding af estere af alkohol med R-struktur og alkohol med S-struktur til ester mellem nævnte syre og alkohol med S-struktu DK171573B1 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7612094A FR2375161A1 (fr) 1976-04-23 1976-04-23 Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s)
FR7612094 1976-04-23

Publications (2)

Publication Number Publication Date
DK177077A true DK177077A (da) 1977-10-24
DK171573B1 DK171573B1 (da) 1997-01-20

Family

ID=9172256

Family Applications (2)

Application Number Title Priority Date Filing Date
DK177077A DK171573B1 (da) 1976-04-23 1977-04-22 Fremgangsmåde til omdannelse af en chiral ester mellem en dihalogeneret cyclopropancarboxylsyre med to asymmetriske carbonatomer i ringen og en optisk aktiv alfa-cyaneret sekundær alkohol med R-struktur eller en racemisk alkohol med R,S-struktur eller den chirale ester er en blanding af estere af alkohol med R-struktur og alkohol med S-struktur til ester mellem nævnte syre og alkohol med S-struktu
DK317589A DK170732B1 (da) 1976-04-23 1989-06-27 Insekticid 2,2-dimethyl-3R-(2,2-dichlorvinyl)-cyclopropan-1R-carboxylsyre-S-alpha-3-phenoxybenzylester samt insekticidt præparat

Family Applications After (1)

Application Number Title Priority Date Filing Date
DK317589A DK170732B1 (da) 1976-04-23 1989-06-27 Insekticid 2,2-dimethyl-3R-(2,2-dichlorvinyl)-cyclopropan-1R-carboxylsyre-S-alpha-3-phenoxybenzylester samt insekticidt præparat

Country Status (39)

Country Link
US (2) US4136195A (da)
JP (2) JPS52148040A (da)
AR (1) AR228557A1 (da)
AT (2) AT360970B (da)
AU (1) AU512155B2 (da)
BE (1) BE853867A (da)
BR (1) BR7702576A (da)
CA (1) CA1130311A (da)
CH (1) CH620889A5 (da)
CS (1) CS214851B2 (da)
DD (1) DD130929A5 (da)
DE (1) DE2718039C2 (da)
DK (2) DK171573B1 (da)
ES (1) ES458112A1 (da)
FR (1) FR2375161A1 (da)
GB (2) GB1582596A (da)
GR (1) GR63104B (da)
GT (1) GT197957492A (da)
HK (2) HK51984A (da)
HR (1) HRP931394B1 (da)
HU (1) HU181942B (da)
IE (1) IE45496B1 (da)
IL (1) IL51958A (da)
IT (1) IT1073208B (da)
LU (1) LU77183A1 (da)
MX (1) MX5299E (da)
MY (1) MY8500509A (da)
NL (1) NL180934C (da)
NO (1) NO149104C (da)
NZ (1) NZ183938A (da)
OA (1) OA05636A (da)
PL (2) PL117200B1 (da)
PT (1) PT66468B (da)
SE (2) SE446629B (da)
SG (2) SG23284G (da)
SU (1) SU990082A3 (da)
TR (1) TR19049A (da)
YU (1) YU40297B (da)
ZA (1) ZA772474B (da)

Families Citing this family (41)

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Publication number Priority date Publication date Assignee Title
DE2326077C2 (de) * 1972-05-25 1985-12-12 National Research Development Corp., London Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide
GB1599876A (en) * 1977-06-13 1981-10-07 Shell Int Research Conversion of a stereoisomer into its diastereoisomer
CH635563A5 (fr) * 1977-07-07 1983-04-15 Sumitomo Chemical Co Procede pour la preparation d'un alpha-cyano-3-phenoxybenzyle optiquement actif.
FR2402411A1 (fr) * 1977-09-08 1979-04-06 Roussel Uclaf Application comme pesticide, dans la lutte contre les acariens et contre les nematodes parasites des vegetaux, d'esters d'acides cyclopropane carboxyliques a chaine dihalovinylique et les compositions acaricides et nematicides les renfermant
CA1215717A (en) * 1977-09-26 1986-12-23 Samuel B. Soloway Process for converting a stereoisomeric ester into its diastereoisomer
JPS54103831A (en) * 1978-01-27 1979-08-15 Sumitomo Chem Co Ltd Separation of stereoisomers of higher active cyanoo33 phenoxybenzyl 22*44chlorophenyl**isovalerate
ZA7911B (en) * 1978-01-31 1980-01-30 Roussel Uclaf Optically-active substituted benzyl alcohol and process for preparing it
FR2419939A1 (fr) * 1978-03-17 1979-10-12 Roussel Uclaf Procede de preparation d'un ether d'alcool a-cyane optiquement actif
FR2428029A1 (fr) * 1978-06-06 1980-01-04 Roussel Uclaf Esters d'acides cyclopropane carboxyliques substitues d'alcool a-cyane, leur procede de preparation et les compositions insecticides ou nematicides les renfermant
FR2447899A2 (fr) * 1979-02-05 1980-08-29 Roussel Uclaf Alcool benzylique substitue optiquement actif et son procede de preparation
JPS55104249A (en) * 1979-02-05 1980-08-09 Sumitomo Chem Co Ltd Optically active carboxylic ester its preparation, and insecticide, and acaricide comprising it
JPS55104253A (en) * 1979-02-06 1980-08-09 Sumitomo Chem Co Ltd Stereoisomer of more active carboxylic ester, method of obtaining it, insecticide and acaricide comprising it
US4308279A (en) * 1979-06-06 1981-12-29 Fmc Corporation Crystalline, insecticidal pyrethroid
US4261921A (en) * 1979-06-06 1981-04-14 Fmc Corporation Process for preparation of a crystalline insecticidal pyrethroid enantiomer pair
FR2458542A1 (fr) * 1979-06-12 1981-01-02 Roussel Uclaf Procede de preparation d'alcools a-cyanes optiquement actifs
FR2471187A1 (fr) * 1979-12-10 1981-06-19 Roussel Uclaf Nouvelles compositions destinees a la lutte contre les parasites des animaux a sang chaud
DE2928406A1 (de) * 1979-07-13 1981-01-29 Bayer Ag Neue menthylester, verfahren zu ihrer herstellung und ihre verwendung zur enantiomerentrennung chiraler carbonsaeuren
JPS5657756A (en) * 1979-10-15 1981-05-20 Sumitomo Chem Co Ltd Preparation of more highly active carboxylic ester
CA1150301A (en) * 1979-11-27 1983-07-19 Michael J. Bull Cyclopropane carboxylic acid ester derivatives
FR2470602A1 (fr) * 1979-12-04 1981-06-12 Roussel Uclaf A titre de produit destine a la lutte contre les acariens parasites des animaux, le 1r, cis 2,2-dimethyl 3-(2,2-dichlorovinyl) cyclopropane-1-carboxylate de (s) a-cyano 3-phenoxy benzyle
JPS56133253A (en) * 1980-03-24 1981-10-19 Sumitomo Chem Co Ltd Optical isomer of cyanohydrin ester, its production and insecticide and acaricide containing the same as effective ingredient
US4260633A (en) * 1980-04-21 1981-04-07 Zoecon Corporation Pesticidal esters of amino acids
CA1150730A (en) * 1980-04-23 1983-07-26 Michael J. Bull Process for preparing cyclopropane carboxylic acid ester derivatives
CA1162560A (en) 1980-04-23 1984-02-21 Ronald F. Mason Process for preparing cyclopropane carboxylic acid ester derivatives
JPS5793948A (en) * 1980-12-02 1982-06-11 Sumitomo Chem Co Ltd Preparation of stereoisomer mixture of higher active phenylacetic ester derivative
USRE32289E (en) * 1982-04-26 1986-11-18 Phillips Petroleum Company Cyanohydrocarbylated alkoxylates and glycerides
US4455255A (en) * 1982-04-26 1984-06-19 Phillips Petroleum Company Cyanohydrocarbylated alkoxylates and glycerides
DE3372480D1 (en) * 1982-10-18 1987-08-20 Ici Plc Insecticidal product and preparation thereof
EP0291626A3 (en) 1982-11-22 1989-05-31 E.I. Du Pont De Nemours And Company Process for the preparation of optically-active cyanomethyl esters
DE3401483A1 (de) * 1984-01-18 1985-07-25 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl-ester
GB8418331D0 (en) * 1984-07-18 1984-08-22 Ici Plc Insecticidal ester
GB8422872D0 (en) * 1984-09-11 1984-10-17 Ici Plc Insecticidal product
HU198373B (en) * 1986-01-08 1989-10-30 Chinoin Gyogyszer Es Vegyeszet Artropodicide composition containing trans-cipermetrin isomeres and process for producing the active components
CA1275108A (en) * 1985-01-16 1990-10-09 Laszlo Pap Insecticidal composition comprising more than one active ingredients
DE3522629A1 (de) * 1985-06-25 1987-01-08 Bayer Ag Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl -ester
GB2187385A (en) * 1986-03-07 1987-09-09 Shell Int Research Method of combatting colorado beetles using chemical compounds and compositions containing the chemical compounds
US5164411A (en) * 1991-01-25 1992-11-17 Fmc Corporation Pyrethroid compositions
GB9127355D0 (en) * 1991-12-24 1992-02-19 Ici Plc Isomerisation process
JPH0660372U (ja) * 1993-01-29 1994-08-23 株式会社釣研 うき止め体
JP3139693B2 (ja) * 1993-02-18 2001-03-05 横河電機株式会社 入出力ユニット
GB0229803D0 (en) 2002-12-20 2003-01-29 Syngenta Ltd Chemical process

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Publication number Priority date Publication date Assignee Title
US3046299A (en) * 1958-07-28 1962-07-24 Rhone Poulenc Sa Process for the preparation of cyclopropane-carboxylic acids of transform
FR2036088A5 (da) * 1969-03-04 1970-12-24 Roussel Uclaf
JPS515450B1 (da) * 1971-06-29 1976-02-20
US3906026A (en) * 1972-05-16 1975-09-16 Sumitomo Chemical Co Process for preparing alkyl trans-chrysanthemate
US4024163A (en) * 1972-05-25 1977-05-17 National Research Development Corporation Insecticides
DE2326077C2 (de) * 1972-05-25 1985-12-12 National Research Development Corp., London Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide
CH608941A5 (en) 1973-08-15 1979-02-15 Nat Res Dev Use of a synthetic pyrethroid as insecticide
JPS5813522B2 (ja) * 1974-10-24 1983-03-14 住友化学工業株式会社 新しいシクロプロパンカルボン酸エステルを含有する殺虫、殺ダニ剤

Also Published As

Publication number Publication date
GT197957492A (es) 1980-10-11
LU77183A1 (da) 1977-11-22
JPS612642B2 (da) 1986-01-27
DK171573B1 (da) 1997-01-20
SU990082A3 (ru) 1983-01-15
IL51958A (en) 1983-02-23
CH620889A5 (da) 1980-12-31
MY8500509A (en) 1985-12-31
DE2718039A1 (de) 1977-11-17
SE8204715D0 (sv) 1982-08-16
YU104777A (en) 1983-04-30
HK51884A (en) 1984-06-22
NO149104C (no) 1984-02-15
CA1130311A (fr) 1982-08-24
PT66468A (fr) 1977-05-01
NZ183938A (en) 1979-10-25
FR2375161A1 (fr) 1978-07-21
DD130929A5 (de) 1978-05-17
BE853867A (fr) 1977-10-24
NO771244L (no) 1977-10-25
GR63104B (en) 1979-09-05
IE45496B1 (en) 1982-09-08
HK51984A (en) 1984-06-22
YU40297B (en) 1985-12-31
HRP931394B1 (en) 1996-04-30
DK170732B1 (da) 1995-12-27
SE446629B (sv) 1986-09-29
PT66468B (fr) 1979-03-09
NO149104B (no) 1983-11-07
AR228557A1 (es) 1983-03-30
PL113207B1 (en) 1980-11-29
NL7704521A (nl) 1977-10-25
HU181942B (en) 1983-11-28
ATA289677A (de) 1980-07-15
CS214851B2 (en) 1982-06-25
AT364675B (de) 1981-11-10
PL117200B1 (en) 1981-07-31
US4133826A (en) 1979-01-09
ES458112A1 (es) 1978-03-16
AT360970B (de) 1981-02-10
ZA772474B (en) 1978-06-28
ATA929178A (de) 1981-04-15
FR2375161B1 (da) 1979-04-13
DK317589D0 (da) 1989-06-27
IE45496L (en) 1977-10-23
US4136195A (en) 1979-01-23
OA05636A (fr) 1981-04-30
TR19049A (tr) 1978-04-12
JPS6127385B2 (da) 1986-06-25
NL180934C (nl) 1987-05-18
AU512155B2 (en) 1980-09-25
NL180934B (nl) 1986-12-16
SE449359B (sv) 1987-04-27
GB1582596A (en) 1981-01-14
BR7702576A (pt) 1977-11-29
DK317589A (da) 1989-06-27
AU2459577A (en) 1978-11-02
DE2718039C2 (de) 1985-02-28
JPS52148040A (en) 1977-12-08
IT1073208B (it) 1985-04-13
SE7704518L (sv) 1977-10-24
SE8204715L (sv) 1982-08-16
GB1582595A (en) 1981-01-14
PL197553A1 (pl) 1978-01-02
SG23184G (en) 1985-01-04
MX5299E (es) 1983-06-13
JPS52131559A (en) 1977-11-04
SG23284G (en) 1985-01-04

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