FR2375161A1 - Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s) - Google Patents
Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s)Info
- Publication number
- FR2375161A1 FR2375161A1 FR7612094A FR7612094A FR2375161A1 FR 2375161 A1 FR2375161 A1 FR 2375161A1 FR 7612094 A FR7612094 A FR 7612094A FR 7612094 A FR7612094 A FR 7612094A FR 2375161 A1 FR2375161 A1 FR 2375161A1
- Authority
- FR
- France
- Prior art keywords
- acid ester
- chiral acid
- cyane
- secondary alcohol
- optically active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/13—Amines
- A61K31/135—Amines having aromatic rings, e.g. ketamine, nortriptyline
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/53—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/34—One oxygen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
- C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D241/18—Oxygen or sulfur atoms
Abstract
L'invention a pour objet un procédé de transformation d'un ester d'acide chiral A d'alcool secondaire alpha -cyané B optiquement actif de structure R en ester d'acide chiral A d'alcool secondaire alpha -cyané B optiquement actif de structure S caractérisé en ce que l'on soumet l'ester d'acide chiral A d'alcool B optiquement actif de structure R à l'action d'un agent basique choisi dans le groupe constitué par l'ammoniaque, les amines secondaires, les amines tertiaires et les bases fortes qui, elles, sont utilisées en quantité catalytique, au sein d'un solvant ou d'un mélange de solvants dans lequel l'ester d'acide chiral A d'alcool B de structure S est insoluble, et l'ester d'acide chiral A d'alcool B de structure R est soluble, puis isole du milieu réactionnel, l'ester d'acide chiral A d'alcool B de structure S ainsi insolubilisé.
Priority Applications (53)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7612094A FR2375161A1 (fr) | 1976-04-23 | 1976-04-23 | Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s) |
NO771244A NO149104C (no) | 1976-04-23 | 1977-04-06 | Fremgangsmaate ved fremstilling av estere av 2,2-dimethyl-3-(2`,2`-substituert-vinyl)-cyclopropan-carboxylsyre og alfa-cyano-3-fenoxyvenzylalkohol med struktur (s) |
OA56142A OA05636A (fr) | 1976-04-23 | 1977-04-15 | Procédé de transformation d'un ester d'acide chiral d'alcool secondaire -cyané optiquement actif de structure (R) en ester d'acide chiral d'alcool secondaire -cyané de structure (S), produits et compositions insecticides. |
SE7704518A SE446629B (sv) | 1976-04-23 | 1977-04-20 | Sett att omvandla en optiskt aktiv ester av en kiralsyra och en sekunder alfa-cyanalkohol med strukturen (r) till en ester av en kiralsyra och en sekunder alfa-cyanalkohol med strukturen (s) |
YU1047/77A YU40297B (en) | 1976-04-23 | 1977-04-21 | Process for transforming esters of cis-or trans-2,2-dimethyl-3r-(2,2-dihalovinyl)-cyclopropane-1r-carboxylic acid |
CA276,725A CA1130311A (fr) | 1976-04-23 | 1977-04-21 | PROCEDE DE TRANSFORMATION D'UN ESTER D'ACIDE CHIRAL D'ALCOOL SECONDAIRE .alpha.-CYANE OPTIQUEMENT ACTIF DE STRUCTURE (R) EN ESTER D'ACIDE CHIRAL D'ALCOOL SECONDAIRE .alpha.-CYANE DE STRUCTURE (S) |
BR7702576A BR7702576A (pt) | 1976-04-23 | 1977-04-22 | Processo de transformacao de um ester de acido quiralico de alcool oticamente ativo de estrutura(r)em ester de acido quiralico de alcool de estrutura(s)e composicoes inseticidas |
US05/789,842 US4136195A (en) | 1976-04-23 | 1977-04-22 | Insecticidal cyclopropane carboxylates |
PL1977213280A PL113207B1 (en) | 1976-04-23 | 1977-04-22 | Insecticide |
ES458112A ES458112A1 (es) | 1976-04-23 | 1977-04-22 | Procedimiento de transformacion de un ester de acido quiral. |
AR267315A AR228557A1 (es) | 1976-04-23 | 1977-04-22 | Procedimiento de transformacion de un ester de acido quiral de alcohol secundario alpha-cianado,opticamente activo,de estructura(r)en un ester de acido quiral de alcohol secundario alpha-cianado de estructura(s),los productos y las composiciones insecticidas |
HU77RO923A HU181942B (en) | 1976-04-23 | 1977-04-22 | Insecticide compositions containing esters of bracket-s-bracket closed-alpha-cyano-sec-alcohols with kyral acids and process for producing the active agents with transforming the ester containing bracket-r-bracket closed isomere of the alcohol |
LU77183A LU77183A1 (fr) | 1976-04-23 | 1977-04-22 | |
PT66468A PT66468B (fr) | 1976-04-23 | 1977-04-22 | Procede de transformation d'un ester chiral d'alcool secondaire alpha-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire alpha-cyane de structure(s) |
US05/789,774 US4133826A (en) | 1976-04-23 | 1977-04-22 | Novel inversion process |
IT49095/77A IT1073208B (it) | 1976-04-23 | 1977-04-22 | Procedimento per la trasformazione di un estere di acido chirale con alcool secondario alfa-cianato otticamente attivo di struttura r in e estere di acido chirale con alcool secondario alfa-cianato di struttura s prodotto ottenuto e composizioni insetticide che lo contengono come principio attivo |
DE2718039A DE2718039C2 (de) | 1976-04-23 | 1977-04-22 | Verfahren zur Umwandlung eines Esters einer optisch aktiven Cyclopropancarbonsäure und eines optisch aktiven Alkohols der Struktur (R) in einen Ester der chiralen Säure des optisch aktiven Alkohols der Struktur (S), (S)-α-Cyano-3-phenoxybenzyl-2,2-dimethyl-3R-(2,2-dichlorvinyl)-cyclopropan-1R-Carboxylat und dieses enthaltende insektizide Mittel |
GB16867/77A GB1582596A (en) | 1976-04-23 | 1977-04-22 | Cyclopropane carboxylic esters |
SU772481551A SU990082A3 (ru) | 1976-04-23 | 1977-04-22 | Способ получени /S/-L-циано-3-феноксибензилового эфира цис-или транс-2,2-диметил-3R-(2,2-дигалогеновинил)-циклопропан-1R-карбоновой кислоты |
DD7700198553A DD130929A5 (de) | 1976-04-23 | 1977-04-22 | Verfahren zur umwandlung eines optisch-aktiven alpha-zyano-sek-alkoholchiralsaeureesters |
GB16866/77A GB1582595A (en) | 1976-04-23 | 1977-04-22 | Chiral acid esters |
CH506077A CH620889A5 (fr) | 1976-04-23 | 1977-04-22 | |
DK177077A DK171573B1 (da) | 1976-04-23 | 1977-04-22 | Fremgangsmåde til omdannelse af en chiral ester mellem en dihalogeneret cyclopropancarboxylsyre med to asymmetriske carbonatomer i ringen og en optisk aktiv alfa-cyaneret sekundær alkohol med R-struktur eller en racemisk alkohol med R,S-struktur eller den chirale ester er en blanding af estere af alkohol med R-struktur og alkohol med S-struktur til ester mellem nævnte syre og alkohol med S-struktu |
PL1977197553A PL117200B1 (en) | 1976-04-23 | 1977-04-22 | Method of transformatiom of ester of chirallic acid with optically active,secondary alpha-cyano alcohol of /r/ configuration,into ester of chirallic acid with secondary alpha-cyano alcohol of/s/configurationski aktivnym vtorichnym-cianovym spirtom s konfiguraciejj/r/w efir khiralevojj kisloty so vtorichnym-cianovym siirtom s konfiguraciejj/s/ |
BE176937A BE853867A (fr) | 1976-04-23 | 1977-04-22 | Procede de transformation d'un ester d'acide chiral d'alcool secondaire alpha-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire alpha-cyane de structure (s) |
MX775658U MX5299E (es) | 1976-04-23 | 1977-04-22 | Procedimiento para transformar un ester de acido quiral de alcohol secundario alfa-cianado opticamente activo de estructura(r) o racemico(r,s)en un ester de acido quiral de alcohol secundario alfa-cianado opticamente activo de estructura(s) |
GR53282A GR63104B (en) | 1976-04-23 | 1977-04-23 | Process for the transformation of an ester of an optically active acid with a secondary,a-cyanated optically active alcohol of r structure to an ester of an optically active acid with a secondary a cyanated,optically active alcohol of s structure,products and insecticidal compositions |
JP4729977A JPS52131559A (en) | 1976-04-23 | 1977-04-23 | New cyclopropane carboxylic acid ester and insecticide compositions |
JP4729877A JPS52148040A (en) | 1976-04-23 | 1977-04-23 | Method of converting chiralic acid of optically active alphaacyano secondary alcohol with *r* configuration to acid of alphaacyano secondary alcohol and pesticidal composition |
AT289677A AT360970B (de) | 1976-04-23 | 1977-04-25 | Verfahren zur herstellung eines 2,2-dimethyl-3r -(2'-substituierten-vinyl)-cyclopropancarbon- saeureesters mit dem (s)-alpha-cyano-3-phenoxy- benzylalkohol |
IE831/77A IE45496B1 (en) | 1976-04-23 | 1977-04-25 | Chiral acid esters |
ZA00772474A ZA772474B (en) | 1976-04-23 | 1977-04-25 | Process for converting a chiral acid ester of an optically-active a-cyano secondary alcohol of structure(r)into a chiral acid ester of a-cyano secondary alcohol of structure(s),products and insecticidal compositions |
NLAANVRAGE7704521,A NL180934C (nl) | 1976-04-23 | 1977-04-25 | Werkwijze voor de bereiding van een ester van een chiraal 3-(gesubstitueerd vinyl)-cyclopropaancarbonzuur waarbij twee koolstofatomen van de ring asymmetrische koolstofatomen zijn met een optisch aktieve alfa-cyaan-3-fenoxybenzylalkohol met (s) struktuur. |
CS772711A CS214851B2 (en) | 1976-04-23 | 1977-04-25 | Method of making the chiral acid ester |
TR19049A TR19049A (tr) | 1976-04-23 | 1977-04-25 | Optik olarak aktif olan(r)struektueruendeki alpha-siyane alkol sekonderin asit siral'inin esterinin(s)struektueruendeki alpha-siyane alkol sekonderin asit siralinin esterine doenuestueruelmesi icin usul |
AT0929178A AT364675B (de) | 1976-04-23 | 1977-04-25 | Insektizide zubereitung |
AU24595/77A AU512155B2 (en) | 1976-04-23 | 1977-04-26 | Preparation of chiral acid esters of chiral alcohols of structure (s) |
NZ183938A NZ183938A (en) | 1976-04-23 | 1977-04-26 | Preparation of a chiral acid ester of(s)- -cyano-3-phenoxybenzyl alcohol |
IL51958A IL51958A (en) | 1976-04-23 | 1977-04-27 | Process for inversion of configuration of chiral acid esters of alpha-cyano-3-phenoxybenzyl alcohol,chiral esters of(r)or(s)alpha-cyano benzyl alcohol with dimethyl-3(r)dihalovinyl-1(r)cyclopropane-carboxylic acid and insecticidal compositions containing them |
FR7717014A FR2421876A1 (fr) | 1976-04-23 | 1977-06-03 | Esters d'acide cyclopropane carboxylique a chaine dihalovinylique |
GT197957492A GT197957492A (es) | 1976-04-23 | 1979-04-20 | Procedimiento de transformacion de un ester de acido quiral de alcohol secundario alfa-cianado,opticamente activo de es tructura (k) en un ester de acido quinal de alcohol secun... |
AT125880A AT366028B (de) | 1976-04-23 | 1980-03-06 | Verfahren zur herstellung eines (d)-isopropyl-p -chlorphenylessigsaeureesters mit dem (s)-alpha-cy-ano-3-phenoxybenzylalkohol |
CS81436A CS214852B2 (cs) | 1976-04-23 | 1981-01-21 | Insekticidní prostředek |
SE8204715A SE449359B (sv) | 1976-04-23 | 1982-08-16 | (s) alfa-cyan-3-fenoxibensyl-2,2-dimetyl-3r-(2,2-diklorovinyl)-cyklopropan-1r-karboxylat och dess anvendning i insektsdodande kompositioner |
SG232/84A SG23284G (en) | 1976-04-23 | 1984-03-12 | Cyclopropane carboxylic acid esters |
SG231/84A SG23184G (en) | 1976-04-23 | 1984-03-12 | Chiral acid esters |
HK518/84A HK51884A (en) | 1976-04-23 | 1984-06-22 | Chiral acid esters |
HK519/84A HK51984A (en) | 1976-04-23 | 1984-06-22 | Cyclopropane carboxylic acid esters |
NLAANVRAGE8502001,A NL188676C (nl) | 1976-04-23 | 1985-07-11 | Werkwijze ter bereiding van een preparaat met insecticidewerking op basis van een ester van een chiraal 2,2-dimethyl 3r-(2,2-dihalogeenvinyl)-cyclopropaan-1-carbonzuur met een optisch aktief alfa-cyaan-3-fenoxybenzylalcohol. |
MY509/85A MY8500509A (en) | 1976-04-23 | 1985-12-30 | Cyclopropane carboxylic acid esters |
DK317589A DK170732B1 (da) | 1976-04-23 | 1989-06-27 | Insekticid 2,2-dimethyl-3R-(2,2-dichlorvinyl)-cyclopropan-1R-carboxylsyre-S-alpha-3-phenoxybenzylester samt insekticidt præparat |
HRP-1047/77A HRP931394B1 (en) | 1976-04-23 | 1993-11-11 | Process for the transformation of esters, cis or trans-2,2-dimethyl-3r(2,2-dihalogeno vinyl)-cyclopropane-1r of carbixilic acid |
MD94-0277A MD245C2 (ro) | 1976-04-23 | 1994-09-08 | Procedeu de obţinere a esterului (S)- -cian-3-fenoxibenzilic al acidului cis-sau trans-2,2-dimetil-3R-(2,2-dihalogenovinil)-ciclopropan-1R-carbonic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7612094A FR2375161A1 (fr) | 1976-04-23 | 1976-04-23 | Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s) |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2375161A1 true FR2375161A1 (fr) | 1978-07-21 |
FR2375161B1 FR2375161B1 (fr) | 1979-04-13 |
Family
ID=9172256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7612094A Granted FR2375161A1 (fr) | 1976-04-23 | 1976-04-23 | Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s) |
Country Status (39)
Country | Link |
---|---|
US (2) | US4133826A (fr) |
JP (2) | JPS52131559A (fr) |
AR (1) | AR228557A1 (fr) |
AT (2) | AT360970B (fr) |
AU (1) | AU512155B2 (fr) |
BE (1) | BE853867A (fr) |
BR (1) | BR7702576A (fr) |
CA (1) | CA1130311A (fr) |
CH (1) | CH620889A5 (fr) |
CS (1) | CS214851B2 (fr) |
DD (1) | DD130929A5 (fr) |
DE (1) | DE2718039C2 (fr) |
DK (2) | DK171573B1 (fr) |
ES (1) | ES458112A1 (fr) |
FR (1) | FR2375161A1 (fr) |
GB (2) | GB1582595A (fr) |
GR (1) | GR63104B (fr) |
GT (1) | GT197957492A (fr) |
HK (2) | HK51884A (fr) |
HR (1) | HRP931394B1 (fr) |
HU (1) | HU181942B (fr) |
IE (1) | IE45496B1 (fr) |
IL (1) | IL51958A (fr) |
IT (1) | IT1073208B (fr) |
LU (1) | LU77183A1 (fr) |
MX (1) | MX5299E (fr) |
MY (1) | MY8500509A (fr) |
NL (1) | NL180934C (fr) |
NO (1) | NO149104C (fr) |
NZ (1) | NZ183938A (fr) |
OA (1) | OA05636A (fr) |
PL (2) | PL117200B1 (fr) |
PT (1) | PT66468B (fr) |
SE (2) | SE446629B (fr) |
SG (2) | SG23284G (fr) |
SU (1) | SU990082A3 (fr) |
TR (1) | TR19049A (fr) |
YU (1) | YU40297B (fr) |
ZA (1) | ZA772474B (fr) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2447899A2 (fr) * | 1979-02-05 | 1980-08-29 | Roussel Uclaf | Alcool benzylique substitue optiquement actif et son procede de preparation |
FR2458542A1 (fr) * | 1979-06-12 | 1981-01-02 | Roussel Uclaf | Procede de preparation d'alcools a-cyanes optiquement actifs |
EP0022382A1 (fr) * | 1979-06-06 | 1981-01-14 | FMC Corporation | Paire d'énantiomères pyréthroide cristalline insecticide, procédé pour sa préparation, et composition |
FR2470117A1 (fr) * | 1979-11-27 | 1981-05-29 | Shell Int Research | Derives d'esters d'acides cyclopropanecarboxyliques, leur preparation et leur application comme pesticides |
FR2470602A1 (fr) * | 1979-12-04 | 1981-06-12 | Roussel Uclaf | A titre de produit destine a la lutte contre les acariens parasites des animaux, le 1r, cis 2,2-dimethyl 3-(2,2-dichlorovinyl) cyclopropane-1-carboxylate de (s) a-cyano 3-phenoxy benzyle |
FR2471187A1 (fr) * | 1979-12-10 | 1981-06-19 | Roussel Uclaf | Nouvelles compositions destinees a la lutte contre les parasites des animaux a sang chaud |
FR2481274A1 (fr) * | 1980-04-23 | 1981-10-30 | Shell Int Research | Procede de preparation de derives esters d'acides cyclopropane-carboxyliques |
FR2481275A1 (fr) * | 1980-04-23 | 1981-10-30 | Shell Int Research | Procede de preparation de derives esters d'acides cyclopropane carboxyliques |
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DE2326077C2 (de) * | 1972-05-25 | 1985-12-12 | National Research Development Corp., London | Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide |
GB1599876A (en) * | 1977-06-13 | 1981-10-07 | Shell Int Research | Conversion of a stereoisomer into its diastereoisomer |
CH635563A5 (fr) * | 1977-07-07 | 1983-04-15 | Sumitomo Chemical Co | Procede pour la preparation d'un alpha-cyano-3-phenoxybenzyle optiquement actif. |
FR2402411A1 (fr) * | 1977-09-08 | 1979-04-06 | Roussel Uclaf | Application comme pesticide, dans la lutte contre les acariens et contre les nematodes parasites des vegetaux, d'esters d'acides cyclopropane carboxyliques a chaine dihalovinylique et les compositions acaricides et nematicides les renfermant |
CA1215717A (fr) * | 1977-09-26 | 1986-12-23 | Samuel B. Soloway | Methode de conversion d'un ester stereo-isomerique a sa forme de diastereo-isomere |
JPS54103831A (en) * | 1978-01-27 | 1979-08-15 | Sumitomo Chem Co Ltd | Separation of stereoisomers of higher active cyanoo33 phenoxybenzyl 22*44chlorophenyl**isovalerate |
ZA7911B (en) * | 1978-01-31 | 1980-01-30 | Roussel Uclaf | Optically-active substituted benzyl alcohol and process for preparing it |
FR2419939A1 (fr) * | 1978-03-17 | 1979-10-12 | Roussel Uclaf | Procede de preparation d'un ether d'alcool a-cyane optiquement actif |
FR2428029A1 (fr) * | 1978-06-06 | 1980-01-04 | Roussel Uclaf | Esters d'acides cyclopropane carboxyliques substitues d'alcool a-cyane, leur procede de preparation et les compositions insecticides ou nematicides les renfermant |
JPS55104249A (en) * | 1979-02-05 | 1980-08-09 | Sumitomo Chem Co Ltd | Optically active carboxylic ester its preparation, and insecticide, and acaricide comprising it |
JPS55104253A (en) * | 1979-02-06 | 1980-08-09 | Sumitomo Chem Co Ltd | Stereoisomer of more active carboxylic ester, method of obtaining it, insecticide and acaricide comprising it |
US4308279A (en) * | 1979-06-06 | 1981-12-29 | Fmc Corporation | Crystalline, insecticidal pyrethroid |
DE2928406A1 (de) * | 1979-07-13 | 1981-01-29 | Bayer Ag | Neue menthylester, verfahren zu ihrer herstellung und ihre verwendung zur enantiomerentrennung chiraler carbonsaeuren |
JPS5657756A (en) * | 1979-10-15 | 1981-05-20 | Sumitomo Chem Co Ltd | Preparation of more highly active carboxylic ester |
JPS56133253A (en) * | 1980-03-24 | 1981-10-19 | Sumitomo Chem Co Ltd | Optical isomer of cyanohydrin ester, its production and insecticide and acaricide containing the same as effective ingredient |
US4260633A (en) * | 1980-04-21 | 1981-04-07 | Zoecon Corporation | Pesticidal esters of amino acids |
JPS5793948A (en) * | 1980-12-02 | 1982-06-11 | Sumitomo Chem Co Ltd | Preparation of stereoisomer mixture of higher active phenylacetic ester derivative |
US4455255A (en) * | 1982-04-26 | 1984-06-19 | Phillips Petroleum Company | Cyanohydrocarbylated alkoxylates and glycerides |
USRE32289E (en) * | 1982-04-26 | 1986-11-18 | Phillips Petroleum Company | Cyanohydrocarbylated alkoxylates and glycerides |
ATE28324T1 (de) * | 1982-10-18 | 1987-08-15 | Ici Plc | Insektizides produkt und seine herstellung. |
EP0291626A3 (fr) | 1982-11-22 | 1989-05-31 | E.I. Du Pont De Nemours And Company | Procédé pour la préparation d'esters cyanométhyliques optiquement actifs |
DE3401483A1 (de) * | 1984-01-18 | 1985-07-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl-ester |
GB8418331D0 (en) * | 1984-07-18 | 1984-08-22 | Ici Plc | Insecticidal ester |
GB8422872D0 (en) * | 1984-09-11 | 1984-10-17 | Ici Plc | Insecticidal product |
HU198373B (en) * | 1986-01-08 | 1989-10-30 | Chinoin Gyogyszer Es Vegyeszet | Artropodicide composition containing trans-cipermetrin isomeres and process for producing the active components |
CA1275108A (fr) * | 1985-01-16 | 1990-10-09 | Laszlo Pap | Composition insecticide renfermant plus d'un agent actif |
DE3522629A1 (de) * | 1985-06-25 | 1987-01-08 | Bayer Ag | Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl -ester |
GB2187385A (en) * | 1986-03-07 | 1987-09-09 | Shell Int Research | Method of combatting colorado beetles using chemical compounds and compositions containing the chemical compounds |
US5164411A (en) * | 1991-01-25 | 1992-11-17 | Fmc Corporation | Pyrethroid compositions |
GB9127355D0 (en) * | 1991-12-24 | 1992-02-19 | Ici Plc | Isomerisation process |
JPH0660372U (ja) * | 1993-01-29 | 1994-08-23 | 株式会社釣研 | うき止め体 |
JP3139693B2 (ja) * | 1993-02-18 | 2001-03-05 | 横河電機株式会社 | 入出力ユニット |
GB0229803D0 (en) * | 2002-12-20 | 2003-01-29 | Syngenta Ltd | Chemical process |
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US3046299A (en) * | 1958-07-28 | 1962-07-24 | Rhone Poulenc Sa | Process for the preparation of cyclopropane-carboxylic acids of transform |
FR2036088A5 (fr) * | 1969-03-04 | 1970-12-24 | Roussel Uclaf | |
JPS515450B1 (fr) * | 1971-06-29 | 1976-02-20 | ||
US3906026A (en) * | 1972-05-16 | 1975-09-16 | Sumitomo Chemical Co | Process for preparing alkyl trans-chrysanthemate |
US4024163A (en) * | 1972-05-25 | 1977-05-17 | National Research Development Corporation | Insecticides |
DE2326077C2 (de) * | 1972-05-25 | 1985-12-12 | National Research Development Corp., London | Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide |
NL178590C (nl) | 1973-08-15 | 1986-04-16 | Nat Res Dev | Werkwijze voor het bereiden van een insecticide preparaat; werkwijze voor het bereiden van een synthetisch pyrethroide. |
JPS5813522B2 (ja) * | 1974-10-24 | 1983-03-14 | 住友化学工業株式会社 | 新しいシクロプロパンカルボン酸エステルを含有する殺虫、殺ダニ剤 |
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1976
- 1976-04-23 FR FR7612094A patent/FR2375161A1/fr active Granted
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1977
- 1977-04-06 NO NO771244A patent/NO149104C/no unknown
- 1977-04-15 OA OA56142A patent/OA05636A/fr unknown
- 1977-04-20 SE SE7704518A patent/SE446629B/xx not_active IP Right Cessation
- 1977-04-21 YU YU1047/77A patent/YU40297B/xx unknown
- 1977-04-21 CA CA276,725A patent/CA1130311A/fr not_active Expired
- 1977-04-22 BR BR7702576A patent/BR7702576A/pt unknown
- 1977-04-22 DD DD7700198553A patent/DD130929A5/xx unknown
- 1977-04-22 LU LU77183A patent/LU77183A1/xx unknown
- 1977-04-22 IT IT49095/77A patent/IT1073208B/it active
- 1977-04-22 DE DE2718039A patent/DE2718039C2/de not_active Expired
- 1977-04-22 PL PL1977197553A patent/PL117200B1/pl not_active IP Right Cessation
- 1977-04-22 BE BE176937A patent/BE853867A/fr not_active IP Right Cessation
- 1977-04-22 PT PT66468A patent/PT66468B/fr unknown
- 1977-04-22 GB GB16866/77A patent/GB1582595A/en not_active Expired
- 1977-04-22 ES ES458112A patent/ES458112A1/es not_active Expired
- 1977-04-22 US US05/789,774 patent/US4133826A/en not_active Expired - Lifetime
- 1977-04-22 SU SU772481551A patent/SU990082A3/ru active
- 1977-04-22 PL PL1977213280A patent/PL113207B1/pl unknown
- 1977-04-22 US US05/789,842 patent/US4136195A/en not_active Expired - Lifetime
- 1977-04-22 HU HU77RO923A patent/HU181942B/hu unknown
- 1977-04-22 CH CH506077A patent/CH620889A5/fr not_active IP Right Cessation
- 1977-04-22 DK DK177077A patent/DK171573B1/da not_active IP Right Cessation
- 1977-04-22 MX MX775658U patent/MX5299E/es unknown
- 1977-04-22 GB GB16867/77A patent/GB1582596A/en not_active Expired
- 1977-04-22 AR AR267315A patent/AR228557A1/es active
- 1977-04-23 JP JP4729977A patent/JPS52131559A/ja active Granted
- 1977-04-23 GR GR53282A patent/GR63104B/el unknown
- 1977-04-23 JP JP4729877A patent/JPS52148040A/ja active Granted
- 1977-04-25 IE IE831/77A patent/IE45496B1/en not_active IP Right Cessation
- 1977-04-25 TR TR19049A patent/TR19049A/xx unknown
- 1977-04-25 CS CS772711A patent/CS214851B2/cs unknown
- 1977-04-25 ZA ZA00772474A patent/ZA772474B/xx unknown
- 1977-04-25 NL NLAANVRAGE7704521,A patent/NL180934C/xx not_active IP Right Cessation
- 1977-04-25 AT AT289677A patent/AT360970B/de not_active IP Right Cessation
- 1977-04-25 AT AT0929178A patent/AT364675B/de active
- 1977-04-26 NZ NZ183938A patent/NZ183938A/xx unknown
- 1977-04-26 AU AU24595/77A patent/AU512155B2/en not_active Expired
- 1977-04-27 IL IL51958A patent/IL51958A/xx unknown
-
1979
- 1979-04-20 GT GT197957492A patent/GT197957492A/es unknown
-
1982
- 1982-08-16 SE SE8204715A patent/SE449359B/sv not_active IP Right Cessation
-
1984
- 1984-03-12 SG SG232/84A patent/SG23284G/en unknown
- 1984-03-12 SG SG231/84A patent/SG23184G/en unknown
- 1984-06-22 HK HK518/84A patent/HK51884A/xx unknown
- 1984-06-22 HK HK519/84A patent/HK51984A/xx unknown
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1985
- 1985-12-30 MY MY509/85A patent/MY8500509A/xx unknown
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1989
- 1989-06-27 DK DK317589A patent/DK170732B1/da not_active IP Right Cessation
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1993
- 1993-11-11 HR HRP-1047/77A patent/HRP931394B1/xx not_active IP Right Cessation
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2447899A2 (fr) * | 1979-02-05 | 1980-08-29 | Roussel Uclaf | Alcool benzylique substitue optiquement actif et son procede de preparation |
EP0022382A1 (fr) * | 1979-06-06 | 1981-01-14 | FMC Corporation | Paire d'énantiomères pyréthroide cristalline insecticide, procédé pour sa préparation, et composition |
FR2458542A1 (fr) * | 1979-06-12 | 1981-01-02 | Roussel Uclaf | Procede de preparation d'alcools a-cyanes optiquement actifs |
EP0021925A1 (fr) * | 1979-06-12 | 1981-01-07 | Roussel-Uclaf | Procédé de préparation d'alcools alpha-cyanés optiquement actifs |
FR2470117A1 (fr) * | 1979-11-27 | 1981-05-29 | Shell Int Research | Derives d'esters d'acides cyclopropanecarboxyliques, leur preparation et leur application comme pesticides |
FR2470602A1 (fr) * | 1979-12-04 | 1981-06-12 | Roussel Uclaf | A titre de produit destine a la lutte contre les acariens parasites des animaux, le 1r, cis 2,2-dimethyl 3-(2,2-dichlorovinyl) cyclopropane-1-carboxylate de (s) a-cyano 3-phenoxy benzyle |
FR2471187A1 (fr) * | 1979-12-10 | 1981-06-19 | Roussel Uclaf | Nouvelles compositions destinees a la lutte contre les parasites des animaux a sang chaud |
FR2481274A1 (fr) * | 1980-04-23 | 1981-10-30 | Shell Int Research | Procede de preparation de derives esters d'acides cyclopropane-carboxyliques |
FR2481275A1 (fr) * | 1980-04-23 | 1981-10-30 | Shell Int Research | Procede de preparation de derives esters d'acides cyclopropane carboxyliques |
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