FI90052B - Foerfarande foer framstaellning av kalciumsulfat-alfa-semihydrat fraon finfoerdelat kalciumsulfat-dihydrat - Google Patents
Foerfarande foer framstaellning av kalciumsulfat-alfa-semihydrat fraon finfoerdelat kalciumsulfat-dihydrat Download PDFInfo
- Publication number
- FI90052B FI90052B FI882327A FI882327A FI90052B FI 90052 B FI90052 B FI 90052B FI 882327 A FI882327 A FI 882327A FI 882327 A FI882327 A FI 882327A FI 90052 B FI90052 B FI 90052B
- Authority
- FI
- Finland
- Prior art keywords
- autoclave
- calcium sulfate
- calcium sulphate
- hydrate
- calcium
- Prior art date
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- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 127
- 235000011132 calcium sulphate Nutrition 0.000 claims description 52
- 239000013078 crystal Substances 0.000 claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 239000011148 porous material Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 35
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 26
- 239000001175 calcium sulphate Substances 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 21
- 229910052602 gypsum Inorganic materials 0.000 claims description 20
- 239000010440 gypsum Substances 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- 239000002023 wood Substances 0.000 claims description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000003546 flue gas Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000003077 lignite Substances 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 239000007858 starting material Substances 0.000 claims description 5
- 239000004566 building material Substances 0.000 claims description 4
- 239000003415 peat Substances 0.000 claims description 4
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000004021 humic acid Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000005065 mining Methods 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 239000004568 cement Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000004567 concrete Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- 238000001953 recrystallisation Methods 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 230000005641 tunneling Effects 0.000 claims 1
- 230000006835 compression Effects 0.000 description 13
- 238000007906 compression Methods 0.000 description 13
- 238000002425 crystallisation Methods 0.000 description 11
- 230000008025 crystallization Effects 0.000 description 11
- 238000000227 grinding Methods 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- -1 acyclic carbonic acids Chemical class 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 229960002303 citric acid monohydrate Drugs 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 239000007952 growth promoter Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 210000003625 skull Anatomy 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
- C04B22/142—Sulfates
- C04B22/143—Calcium-sulfate
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
- A01K1/0152—Litter
- A01K1/0154—Litter comprising inorganic material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/466—Conversion of one form of calcium sulfate to another
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B11/00—Calcium sulfate cements
- C04B11/02—Methods and apparatus for dehydrating gypsum
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B11/00—Calcium sulfate cements
- C04B11/02—Methods and apparatus for dehydrating gypsum
- C04B11/024—Ingredients added before, or during, the calcining process, e.g. calcination modifiers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B11/00—Calcium sulfate cements
- C04B11/26—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke
- C04B11/268—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke pelletizing of the material before starting the manufacture
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Environmental Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Geology (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Moulds, Cores, Or Mandrels (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Claims (16)
1. Förfarande för framställning av kalciumsulfat-alfa-halvhydrat frän finfördelat kalciumsulfat, vid vil- 5 ket förfarande frän en fuktig kalciumsulfatblandning bil-das formkroppar, vilka leds tili en autoklav, varvid kal-ciumsulfatet omkristalliseras med hjälp av mättad vatten-änga 1 autoklaven vid 110 - 180 °C tili kalciumsulfat-al-fa-halvhydrat, varefter formkropparna avlägsnas frän 10 autoklaven och leds tili användning, känneteck-n a t därav, att frän kalciumsulfat-dihydrat, vilket an-vänds som utgängsmaterial, bildas formkroppar med en por-volym större än 15 - 60 %, och varvid porerna innehäller luft i en mängd större än 5 volym-%, och porvattenmäng-15 den, som behövs för att omkristallisera kalciumsulfat-di-hydratet tili kalciumsulfat-alfa-halvhydrat, bildas i porerna av nämnda formkroppar sä, att formkropparna införs i autoklaven vid omgivningens temperatur, varvid genom inverkan av kondensation av den mättade vattenängan pä 20 formkropparnas yta bildas porvatten, som genom inverkan av kapillarkrafter i det öppna porsystemet tränger sig in . . i formkropparna, och varvid kristalltillväxten och kris- tallstrukturen hos kalciumsulfat-alfa-halvhydratkristal-ler, som växer frän den vattenhaltiga lösningsfasen, 25 styrs medelst behandlingstemperaturen inom ovannämnda temperatursomräde samt medelst trycket av behandlingsat-mosfären i autoklaven.
2. Förfarande enligt patentkravet 1, k ä n n e -t e c k n a t därav, att man framställer formkroppar med -.30 en porvolym av 25 - 35 %.
3. Förfarande enligt patentkravet 1 eller 2, kännetecknat därav, att man framställer formkroppar, i vilka minst hälften av porvolymen fyllts med luft. .35
4. Förfarande enligt nägot av patentkraven 1-3, kännetecknat därav, att frän kalciumsulfat- II 2i 90052 dihydratet genom pressning bildas formkroppar, medan hal-ten av vattnet, som är fysikaliskt bundet i kalciumsul-fat-dihydratet, är 3 - 20 vikt-%, och under ett press-tryck av högst 14 N/mm2 även formkroppar, som utstär 5 autoklavbehandlingen.
5. Förfarande enligt nägot av patentkrav 1-4, kännetecknat därav, att för att bilda nälfor-miga kalciumsulfat-alfa-halvhydratkristaller huvudsakli-gen opereras vid en behandlingstemperatur över 140 °C. 10
6. Förfarande enligt nägot av patentkraven 1-4, kännetecknat därav, att för att bilda kompak-ta, pelarformiga kalciumsulfat-alfa-halvhydratkristaller huvudsakligen opereras vid en behandlingstemperatur av 120 - 140 “C. 15
7. Förfarande enligt nägot av patentkraven 1-6, kännetecknat därav, att för att bilda kompak-ta kalciumsulfat-alfa-halvhydratkristaller i autoklaven opereras under ett förhöjt behandlingstryck med avseende pä den mättade ängan och därför leds gas in i autoklaven. 20
8. Förfarande enligt nägot av patentkraven 1-7, kännetecknat därav, att vattnet, som efter omkristalliseringen blir kvar i formkropparnas porer, ät-minstone delvis avlägsnas genom att pä ett kontrollerat sätt minska trycket i autoklaven. 25
9. Förfarande enligt nägot av patentkraven 1-9, kännetecknat därav, att tili kalciumsulfat-dihydratet före framställningen av formkropparna sätts pä tillväxten inverkande tillsatsämnen.
10. Förfarande enligt patentkravet 9, k ä n n e -: : 30 t e c k n a t därav, att som pä tillväxten inverkan äm-nen tili kalciumsulfat-dihydratet sätts finfördelat brun-kol och/eller finfördelad torv och/eller finfördelat trä och/eller humussyra och/eller ämnen, som träet innehäller och som har motsvarande verkan. 35
11. Förfarande enligt nägot av patentkraven 1 - 10, kännetecknat därav, att som pä tili- 22 9 0 052 växten inverkande ätgärd bestär en del av kalciumsulfat-dihydratet, som skall omkristalliseras, av rökgasavsvav-lingsgips frän ett kraftverk, som använder brunkol.
12. Användning av kalciumsulfat-alfa-halvhydrat, 5 som framställts enligt nägot av patentkraven 1-11, i maid och silad form som bindemedel för byggnadsmaterial, som är genast eller tidigt bärande, vid underjordisk gjutning, i synnerhet vid tunnelbrytning eller vid ort-drivning eller som förstärkning för gruvtekniska under- 10 jordiska objekt.
13. Användning av kalciumsulfat-alfa-halvhydrat, som framställts enligt nägot av patentkraven 1 - 11, i mald och silad form som bindemedel för självutjämningsba-ra cement.
14. Användning av kalciumsulfat-alfa-halvhydrat, som framställts enligt nägot av patentkraven 1-11, i mald och silad form som härdningsmedel för snabbrepara-tionsbruk, som är avsedda för snabbmontering av betong-eller asfaltytor.
15. Användning av kalciumsulfat-alfa-halvhydrat, som framställts enligt nägot av patentkraven 1-11, i . mald och silad form som rämaterial vid framställning av fiber- och spänarmerade plattprodukter.
16. Användning av kalciumsulfat-alfa-halvhydrat, ' 25 som framställts enligt nägot av patentkraven 1-11, i mald och silad form som byggnadsmaterial vid framställning av skumporösa gipsmellanväggskivor.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3717187 | 1987-05-22 | ||
| DE3717187 | 1987-05-22 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI882327A0 FI882327A0 (fi) | 1988-05-18 |
| FI882327A FI882327A (fi) | 1988-11-23 |
| FI90052B true FI90052B (fi) | 1993-09-15 |
| FI90052C FI90052C (sv) | 1993-12-27 |
Family
ID=6328115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI882327A FI90052C (sv) | 1987-05-22 | 1988-05-18 | Förfarande för framställning av kalciumsulfat-alfa-semihydrat från fin fördelat kalciumsulfat-dihydrat |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US5015449A (sv) |
| EP (1) | EP0342272B1 (sv) |
| JP (1) | JPH0657605B2 (sv) |
| AT (1) | AT396225B (sv) |
| BE (1) | BE1002843A5 (sv) |
| CA (2) | CA1334332C (sv) |
| CH (1) | CH676974A5 (sv) |
| CS (2) | CS274599B2 (sv) |
| DD (2) | DD272291A5 (sv) |
| DK (1) | DK277088A (sv) |
| ES (2) | ES2009278A6 (sv) |
| FI (1) | FI90052C (sv) |
| FR (1) | FR2615505B1 (sv) |
| GB (1) | GB2205089B (sv) |
| GR (1) | GR1001149B (sv) |
| IT (1) | IT1217676B (sv) |
| LU (1) | LU87220A1 (sv) |
| NL (1) | NL191238C (sv) |
| NO (1) | NO179578C (sv) |
| SE (1) | SE469720B (sv) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3844938C2 (de) * | 1987-05-22 | 1996-09-19 | Pro Mineral Ges | Verfahren zur Erzeugung von Calciumsulfat-Alphahalbhydrat aus feinteiligem Calciumsulfat und dessen Verwendung |
| DE3800794A1 (de) * | 1988-01-14 | 1989-07-27 | Rwk Rhein Westfael Kalkwerke | Verfahren und anlage zur herstellung von calciumsulfat-halbhydrat in alpha-konfiguration |
| DE4008084A1 (de) * | 1990-03-14 | 1991-09-19 | Pro Mineral Ges | Verfahren zur herstellung von gipsfaserplatten, insbesondere von fussbodenplatten |
| DK170143B1 (da) * | 1990-09-26 | 1995-06-06 | Skamol As | Fremstilling og anvendelse af sorberende materiale som kattegrus |
| DE4034497C1 (sv) * | 1990-10-30 | 1992-02-13 | Metallgesellschaft Ag, 6000 Frankfurt, De | |
| DE4127930A1 (de) * | 1991-08-23 | 1993-02-25 | Bold Joerg | Verfahren zur herstellung von faserverstaerkten gipsplatten |
| US5312609A (en) * | 1992-12-31 | 1994-05-17 | Dravo Lime Company | Method of sulfur dioxide removal from gaseous streams with α-hemihydrate gypsum product formation |
| FI945805A (sv) * | 1993-12-16 | 1995-06-17 | Sicowa Verfahrenstechnik Fuet | Bindemedel för inneputsbruk |
| US5395438A (en) * | 1994-01-14 | 1995-03-07 | Usg Interiors, Inc. | Mineral wool-free acoustical tile composition |
| JP2614602B2 (ja) * | 1994-06-09 | 1997-05-28 | 小坂製錬株式会社 | 硫酸液からの板状二水石膏の連続製造法 |
| US5595713A (en) * | 1994-09-08 | 1997-01-21 | The Babcock & Wilcox Company | Hydrogen peroxide for flue gas desulfurization |
| US5562892A (en) * | 1995-01-26 | 1996-10-08 | Kirk; Donald W. | Process for the production of alpha hemihydrate calcium sulfate from flue gas sludge |
| DE69604937T2 (de) * | 1996-02-16 | 2000-06-29 | Jozsef Hadnagy | Verfahren zur herstellung von verbundplatten und formkörpern auf basis von gips |
| DE59802498D1 (de) * | 1997-05-10 | 2002-01-31 | Sicowa Verfahrenstech | Verfahren zum Herstellen von Calciumsulfat-Alphahalbhydrat |
| US6164026A (en) * | 1997-09-25 | 2000-12-26 | New Jersey Institute Of Technology | Raised access floor |
| US6652825B2 (en) | 2001-05-01 | 2003-11-25 | National Gypsum Properties Llc | Method of producing calcium sulfate alpha-hemihydrate |
| US7507257B2 (en) * | 2003-02-04 | 2009-03-24 | Wright Medical Technology, Inc. | Injectable resorbable bone graft material, powder for forming same and methods relating thereto for treating bone defects |
| US6964704B2 (en) * | 2003-03-20 | 2005-11-15 | G.B. Technologies, Llc | Calcium sulphate-based composition and methods of making same |
| CN100352767C (zh) * | 2003-03-20 | 2007-12-05 | G.B.科技有限公司 | 一种α型硫酸钙半水合物及其制造方法和含有它们的混合物 |
| JP4075709B2 (ja) * | 2003-07-02 | 2008-04-16 | 住友電装株式会社 | コネクタ |
| US7776150B2 (en) * | 2006-03-16 | 2010-08-17 | Koppern Eqipment, Inc. | Process and apparatus for handling synthetic gypsum |
| ES2873113T3 (es) * | 2006-06-29 | 2021-11-03 | Yoshino Gypsum Co | Métodos para fabricar un yeso calcinado y una placa de yeso |
| US7754006B2 (en) * | 2007-03-20 | 2010-07-13 | United States Gypsum Company | Process for manufacturing ready-mixed setting alpha-calcium sulphate hemi-hydrate and kit for same |
| DE102007024188B3 (de) * | 2007-05-24 | 2008-04-10 | Grenzebach Bsh Gmbh | Verfahren zur Herstellung von Alpha-Calciumsulfat-Halbhydrat aus Calciumsulfat-Dihydrat und zugehörige Vorrichtung |
| US20090208392A1 (en) * | 2008-02-14 | 2009-08-20 | Georgia-Pacific Gypsum, Llc | Process for producing alpha-hemihydrate gypsum |
| FI120819B (sv) * | 2008-04-09 | 2010-03-31 | Kemira Oyj | Förfarande för att rena gips |
| EP2163532A1 (de) | 2008-09-11 | 2010-03-17 | Claudius Peters Technologies GmbH | Verfahren und Anlage zur Herstellung von Hartgips |
| CN103482892A (zh) * | 2013-09-17 | 2014-01-01 | 湖北龙源石膏有限公司 | α型高强石膏粉的制备方法 |
| WO2016073393A1 (en) * | 2014-11-03 | 2016-05-12 | Georgia-Pacific Gypsum Llc | Microwave heating for gypsum manufacturing processes |
| CN105384372B (zh) * | 2015-11-27 | 2018-09-28 | 山东先罗输送机械有限公司 | 脱硫石膏制备建筑石膏的方法及其装置 |
| CN105859236A (zh) * | 2016-03-31 | 2016-08-17 | 安徽森科新材料有限公司 | 一种抗静电地板干法石膏胶凝基材及其制备方法 |
| CN106145853A (zh) * | 2016-07-01 | 2016-11-23 | 马振义 | 耐水磷石膏模合及其制备方法 |
| CN106145854A (zh) * | 2016-07-01 | 2016-11-23 | 马振义 | 耐水脱硫石膏模合及其制备方法 |
| EP3331826B1 (en) * | 2016-10-17 | 2019-02-27 | Lidds AB | A new method for producing calcium sulphate hemihydrate with unique properties |
| CN111298805B (zh) * | 2020-03-13 | 2023-04-11 | 吉林省惠净环保有限公司 | 一种燃煤催化剂及其制备方法和应用 |
| CN111807736A (zh) * | 2020-07-13 | 2020-10-23 | 湖南金隆再生金属有限公司 | 一种脱硫熟石膏加工工艺 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR602091A (fr) * | 1925-08-13 | 1926-03-12 | Rumford Chemical Works | Perfectionnements relatifs à la fabrication du plâtre de paris |
| US1901051A (en) * | 1929-08-08 | 1933-03-14 | United States Gypsum Co | High strength calcined gypsum and process of manufacturing same |
| DE800548C (de) * | 1948-10-02 | 1950-11-13 | Metallgesellschaft Akt Ges | Verfahren zur Herstellung von Baugips |
| GB829652A (en) * | 1956-01-27 | 1960-03-02 | Edmund Boergardts | Improvements in or relating to the burning of gypsum |
| GB832256A (en) * | 1957-02-18 | 1960-04-06 | British Plaster Board Holdings | Improvements in or relating to cementitious material |
| CH333247A (fr) * | 1957-10-10 | 1958-10-15 | Parechoc Sa | Raquetterie pour pièce d'horlogerie |
| US3305518A (en) * | 1963-07-09 | 1967-02-21 | United States Gypsum Co | Plaster composition containing polyvinyl acetate |
| DE1238374B (de) * | 1965-04-24 | 1967-04-06 | Giulini Ges Mit Beschraenkter | Verfahren zur Herstellung von alpha-Calciumsulfat-Halbhydrat |
| US3666581A (en) * | 1969-04-01 | 1972-05-30 | United States Gypsum Co | Method of making dried gypsum articles having improved strength to density ratio |
| BE756667A (nl) * | 1969-09-26 | 1971-03-01 | Geelen Hendrik E Van | Werkwijze voor het bereiden van alpha-calciumsulfaathalfhydraat |
| GB1429187A (en) * | 1972-05-11 | 1976-03-24 | Bpb Industries Ltd | Process for the conversion of anhydrite into gypsum |
| JPS4972187A (sv) * | 1972-11-10 | 1974-07-12 | ||
| DE2337374A1 (de) * | 1973-07-23 | 1975-04-10 | Gypsum Research | Verfahren zur herstellung von faserhaltigen baukoerpern |
| DE2433554A1 (de) * | 1974-07-12 | 1976-01-29 | Giulini Gmbh Geb | Gussmassen auf basis von alpha-calciumsulfat-halbhydrat |
| JPS5128117A (ja) * | 1974-09-04 | 1976-03-09 | Mitsui Toatsu Chemicals | Kyokasoseibutsu |
| JPS52146422A (en) * | 1976-05-31 | 1977-12-06 | Matsushita Electric Works Ltd | Production of inorganic hardend body |
| JPS5337595A (en) * | 1976-09-21 | 1978-04-06 | Osaka Kouhai Kk | Manufacturing process for higher strength gypsum hardened material from crude gypsum |
| JPS5355629A (en) * | 1976-10-29 | 1978-05-20 | Mitsubishi Heavy Ind Ltd | Method of improving supporting force of road bed |
| DE2658915C3 (de) * | 1976-12-24 | 1987-06-19 | Gebr. Knauf Westdeutsche Gipswerke, 8715 Iphofen | Verfahren zur Herstellung von stückigem Calciumsulfat-Dihydrat |
| DE2704577A1 (de) * | 1977-02-04 | 1978-08-10 | Babcock Bsh Ag | Anlage und verfahren fuer das abtrennen von alpha-kalziumsulfat-halbhydratschlaemmen aus einer suspension |
| JPS5811369B2 (ja) * | 1977-08-29 | 1983-03-02 | 太平洋セメント株式会社 | 石こう針状結晶細径繊維の製造方法 |
| JPS5510406A (en) * | 1978-07-05 | 1980-01-24 | Idemitsu Kosan Co Ltd | Production of gypsum |
| JPS5595669A (en) * | 1978-05-16 | 1980-07-21 | Mitsubishi Heavy Ind Ltd | Asphalt filler |
| JPS553314A (en) * | 1978-06-17 | 1980-01-11 | Idemitsu Kosan Co Ltd | Production of fibrous gypsum |
| JPS6041028B2 (ja) * | 1980-09-16 | 1985-09-13 | 亀雄 堀川 | 貼華焼成品の製造方法 |
| US4309391A (en) * | 1980-12-03 | 1982-01-05 | United States Gypsum Company | Lump process alpha gypsum |
| DE3048506C2 (de) * | 1980-12-22 | 1986-09-11 | Rigips GmbH, 3452 Bodenwerder | Trockene pulverförmige Putzmischung und Verfahren zu ihrer Herstellung |
| DE3117662A1 (de) * | 1981-05-05 | 1982-11-25 | Heinrich 4350 Recklinghausen Quante | Gipsstein- und gipssandsteinherstellung |
| DE3222865C2 (de) * | 1981-07-10 | 1992-10-22 | Steag Ag, 4300 Essen | Verfahren zum Granulieren von bei chemischen Prozessen anfallendem Gips und Verwendung einer Kompaktierungseinrichtung zum Granulieren von Gips nach dem Verfahren |
| DE3232077C2 (de) * | 1982-08-28 | 1986-10-23 | Rheinisch-Westfälisches Elektrizitätswerk AG, 4300 Essen | Verfahren und Vorrichtung zur Entfernung von Schwefeldioxid und anderen Schadstoffen aus Rauchgasen |
| US4604141A (en) * | 1983-04-15 | 1986-08-05 | Hitachi, Ltd. | Slip casting mold |
| DE3502637A1 (de) * | 1985-01-26 | 1986-09-11 | Frank W. Dr.-Ing. 6600 Saarbrücken Fink | Verfahren zum kalzinieren von stueckigem rauchgasentschwefelungsgips mittels dampfeinwirkung |
| DE3612931A1 (de) * | 1986-04-17 | 1987-10-22 | Hoelter Heinz | Bergbaumoertel aus abfallbergen der kohlegewinnung |
| CA1279877C (en) * | 1986-08-28 | 1991-02-05 | Richard J. Flanagan | High-strength, fire-resistant gypsum composition |
-
1988
- 1988-05-13 GB GB8811393A patent/GB2205089B/en not_active Expired - Lifetime
- 1988-05-16 CH CH1840/88A patent/CH676974A5/de not_active IP Right Cessation
- 1988-05-17 GR GR880100324A patent/GR1001149B/el unknown
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- 1988-05-18 JP JP63119404A patent/JPH0657605B2/ja not_active Expired - Lifetime
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- 1988-05-19 SE SE8801873A patent/SE469720B/sv not_active IP Right Cessation
- 1988-05-19 FR FR8806696A patent/FR2615505B1/fr not_active Expired - Lifetime
- 1988-05-20 CS CS344988A patent/CS274599B2/cs unknown
- 1988-05-20 DD DD88315964A patent/DD272291A5/de not_active IP Right Cessation
- 1988-05-20 CS CS883448A patent/CS276735B6/cs unknown
- 1988-05-20 BE BE8800563A patent/BE1002843A5/fr not_active IP Right Cessation
- 1988-05-20 ES ES8801596A patent/ES2009278A6/es not_active Expired
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- 1988-05-20 IT IT20672/88A patent/IT1217676B/it active
- 1988-05-20 DK DK277088A patent/DK277088A/da not_active Application Discontinuation
- 1988-05-20 DD DD88315961A patent/DD281593A5/de unknown
- 1988-05-23 US US07/197,604 patent/US5015449A/en not_active Expired - Fee Related
- 1988-05-23 US US07/197,442 patent/US5015450A/en not_active Expired - Fee Related
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- 1988-12-15 EP EP88120944A patent/EP0342272B1/de not_active Expired - Lifetime
- 1988-12-15 ES ES88120944T patent/ES2022975B3/es not_active Expired - Lifetime
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Owner name: SICOWA VERFAHRENSTECHNIK FUER BAUSTOFFE Owner name: PRO MINERAL GESELLSCHAFT ZUR VERWENDUNG |