FI112664B - Menetelmä alfa-olefiinien polymeroimiseksi kaasufaasissa - Google Patents
Menetelmä alfa-olefiinien polymeroimiseksi kaasufaasissa Download PDFInfo
- Publication number
- FI112664B FI112664B FI931107A FI931107A FI112664B FI 112664 B FI112664 B FI 112664B FI 931107 A FI931107 A FI 931107A FI 931107 A FI931107 A FI 931107A FI 112664 B FI112664 B FI 112664B
- Authority
- FI
- Finland
- Prior art keywords
- ethylene
- catalyst
- olefins
- process according
- polymerization
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 230000008569 process Effects 0.000 title claims abstract description 43
- 239000004711 α-olefin Substances 0.000 title claims abstract description 17
- 238000006116 polymerization reaction Methods 0.000 title claims description 30
- 239000003054 catalyst Substances 0.000 claims abstract description 53
- 239000007789 gas Substances 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000005977 Ethylene Substances 0.000 claims abstract description 37
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 10
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 35
- -1 alkylaluminum compound Chemical class 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims description 19
- 239000001294 propane Substances 0.000 claims description 17
- 239000011949 solid catalyst Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 150000001336 alkenes Chemical class 0.000 claims description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 abstract description 10
- 150000003609 titanium compounds Chemical class 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 6
- 238000012685 gas phase polymerization Methods 0.000 abstract description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract description 4
- 230000000379 polymerizing effect Effects 0.000 abstract description 3
- 235000011147 magnesium chloride Nutrition 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 28
- 239000012071 phase Substances 0.000 description 28
- 239000010936 titanium Substances 0.000 description 17
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 9
- 229910052719 titanium Inorganic materials 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- 230000003068 static effect Effects 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000004913 activation Effects 0.000 description 5
- 239000001273 butane Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 230000001603 reducing effect Effects 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 230000000877 morphologic effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000012798 spherical particle Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000007429 general method Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 229920006450 PE-VLD Polymers 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI920589A IT1254279B (it) | 1992-03-13 | 1992-03-13 | Procedimento per la polimerizzazione in fase gas delle olefine |
| ITMI920589 | 1992-03-13 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI931107A0 FI931107A0 (fi) | 1993-03-12 |
| FI931107A FI931107A (fi) | 1993-09-14 |
| FI112664B true FI112664B (fi) | 2003-12-31 |
Family
ID=11362420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI931107A FI112664B (fi) | 1992-03-13 | 1993-03-12 | Menetelmä alfa-olefiinien polymeroimiseksi kaasufaasissa |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US5733987A (fr) |
| EP (1) | EP0560312B1 (fr) |
| JP (1) | JP3910219B2 (fr) |
| KR (1) | KR100268119B1 (fr) |
| CN (1) | CN1087306C (fr) |
| AT (1) | ATE182159T1 (fr) |
| AU (1) | AU658055B2 (fr) |
| BR (1) | BR9301145A (fr) |
| CA (1) | CA2087289C (fr) |
| CZ (1) | CZ288458B6 (fr) |
| DE (1) | DE69325603T2 (fr) |
| ES (1) | ES2134225T3 (fr) |
| FI (1) | FI112664B (fr) |
| GR (1) | GR3031273T3 (fr) |
| HU (1) | HU217181B (fr) |
| IL (1) | IL105024A (fr) |
| IT (1) | IT1254279B (fr) |
| MX (1) | MX9301347A (fr) |
| MY (1) | MY110349A (fr) |
| NO (1) | NO300219B1 (fr) |
| PL (1) | PL176101B1 (fr) |
| RU (1) | RU2116318C1 (fr) |
| TW (1) | TW230210B (fr) |
| ZA (1) | ZA931726B (fr) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4872047A (en) * | 1986-11-07 | 1989-10-03 | Olin Corporation | Semiconductor die attach system |
| IT1274016B (it) * | 1994-02-21 | 1997-07-14 | Spherilene Srl | Processo per la polimerizzazione in fase gas delle a-olefine |
| US5677375A (en) * | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| EP1059309A3 (fr) * | 1996-12-31 | 2001-09-05 | ExxonMobil Chemical Patents Inc. | Procédé à plusieurs étapes pour la préparation de polyoléfines |
| US6066701A (en) * | 1996-12-31 | 2000-05-23 | Exxon Chemical Patents Inc. | Multistage method for manufacturing polyolefins |
| FI111846B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| CN1160378C (zh) | 1999-06-18 | 2004-08-04 | 巴塞尔技术有限公司 | 用于烯烃聚合的催化剂组分和由此获得的催化剂 |
| HUP0202584A3 (en) | 1999-09-10 | 2003-10-28 | Basell Technology Co Bv | Catalyst for the polymerization of olefins |
| EP1277804B1 (fr) * | 2000-02-08 | 2011-08-17 | Kaneka Corporation | Compositions durcissables |
| US6593506B1 (en) | 2000-10-12 | 2003-07-15 | Exxonmobil Chemical Patents Inc. | Olefin recovery in a polyolefin production process |
| US6495609B1 (en) | 2000-11-03 | 2002-12-17 | Exxonmobil Chemical Patents Inc. | Carbon dioxide recovery in an ethylene to ethylene oxide production process |
| WO2002074818A1 (fr) * | 2001-03-15 | 2002-09-26 | Basell Poliolefine Italia S.P.A. | Procede de (co)polymerisation d'ethylene |
| US6541578B2 (en) * | 2001-03-22 | 2003-04-01 | Nova Chemicals (International) S.A. | Increased space-time yield in gas phase polymerization |
| ATE434629T1 (de) * | 2001-06-26 | 2009-07-15 | Basell Poliolefine Srl | Verfahren zur herstellung von katalysator- komponenten für die olefinpolymerisation |
| MY136330A (en) * | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| WO2003055921A1 (fr) * | 2001-12-24 | 2003-07-10 | Basell Poliolefine Italia S.P.A. | Catalyseur ziegler-natta pour la polymerisation d'olefines |
| EP1511780B1 (fr) * | 2002-06-13 | 2007-06-27 | Basell Poliolefine Italia S.r.l. | Composants catalytiques ziegler natta pour la polymerisation d'olefines |
| CA2456951A1 (fr) * | 2002-06-13 | 2003-12-24 | Basell Poliolefine Italia S.P.A. | Procede de preparation de copolymeres ethyleniques |
| CN1726080A (zh) * | 2002-12-18 | 2006-01-25 | 巴塞尔聚烯烃意大利有限公司 | 氯化镁基加合物及由其制备的催化剂组分 |
| CA2527357A1 (fr) * | 2003-05-29 | 2004-12-09 | Basell Poliolefine Italia S.R.L. | Procede de preparation d'un composant catalyseur et composants ainsi obtenus |
| WO2005058982A1 (fr) * | 2003-12-19 | 2005-06-30 | Basell Polyolefine Gmbh | Procede de (co)polymerisation de l'ethylene |
| US20050182207A1 (en) * | 2003-12-23 | 2005-08-18 | Diwaker Singh | Gas-phase process |
| US20050137364A1 (en) * | 2003-12-23 | 2005-06-23 | Univation Technologies, Llc | Condensing mode operation of gas-phase polymerization reactor |
| KR101228401B1 (ko) * | 2004-10-14 | 2013-02-01 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀의 기체-상 중합 방법 |
| ES2309445T3 (es) | 2004-12-17 | 2008-12-16 | Borealis Technology Oy | Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas. |
| RU2007139937A (ru) * | 2005-03-30 | 2009-05-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Способ получения кристаллических (со)полимеров этилена |
| JP2008534723A (ja) * | 2005-03-30 | 2008-08-28 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用触媒成分 |
| JP2008534722A (ja) * | 2005-03-30 | 2008-08-28 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン類の重合用触媒成分 |
| US20070060724A1 (en) * | 2005-09-13 | 2007-03-15 | Nova Chemicals Corporation And Innovene Europe Ltd. | Enhanced catalyst productivity |
| EP1926755A1 (fr) * | 2005-09-19 | 2008-06-04 | Basell Poliolefine Italia S.R.L. | Procede en phase gazeuse pour la polymerisation d'olefines |
| WO2008019802A1 (fr) * | 2006-08-15 | 2008-02-21 | Basell Poliolefine Italia S.R.L. | Procédé de préparation de composants de catalyseur destinés à la polymérisation des oléfines |
| US8034735B2 (en) * | 2006-11-21 | 2011-10-11 | Basell Poliolefine Italia, s.r.l. | Catalyst component for the polymerization of olefins |
| EP2121773B1 (fr) | 2006-12-22 | 2016-11-23 | Basell Poliolefine Italia S.r.l. | Composants catalytiques pour la polymérisation d'oléfines et catalyseurs obtenus à partir de ceux-ci |
| CA2588352A1 (fr) * | 2007-05-11 | 2008-11-11 | Nova Chemicals Corporation | Methode pour estimer des valeurs "pent" |
| CN101638448B (zh) * | 2008-08-01 | 2011-06-15 | 中国石油化工股份有限公司 | 烯烃气相连续聚合方法 |
| EP2315786A1 (fr) * | 2008-08-20 | 2011-05-04 | Basell Poliolefine Italia S.r.l. | Composants de catalyseurs destinés à la polymérisation d'oléfines et catalyseurs obtenus à partir de ceux-ci |
| RU2012101640A (ru) | 2009-06-18 | 2013-07-27 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора для полимеризации олефинов и катализаторы, полученные из них |
| EP2330135B1 (fr) * | 2009-12-02 | 2012-11-07 | Borealis AG | Procédé de production de polyoléfines |
| US10138310B2 (en) | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
| CA2805769C (fr) | 2010-08-24 | 2017-11-21 | Basell Poliolefine Italia S.R.L. | Composants de catalyseur pour la polymerisation d'olefines |
| BR112013025014A2 (pt) | 2011-04-01 | 2017-01-17 | Basell Poliolefine Srl | componentes de catalisador para a polimerização de olefinas e catalisadores obtidos a partir destes |
| EP2518090A1 (fr) | 2011-04-28 | 2012-10-31 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation d'oléfines et catalyseurs ainsi obtenus |
| EP2803676A1 (fr) | 2013-05-16 | 2014-11-19 | Basell Polyolefine GmbH | Procédé de polymérisation en phase gazeuse d'éthylène ou de mélanges d'éthylène |
| CA2857456C (fr) | 2014-07-22 | 2022-05-03 | Nova Chemicals Corporation | Controle ameliore d'approvisionnement en particules |
| WO2016150996A1 (fr) * | 2015-03-25 | 2016-09-29 | Basell Polyolefine Gmbh | Procédés continus de polymérisation en phase gazeuse |
| ES2707391T3 (es) | 2015-06-23 | 2019-04-03 | Borealis Ag | Procedimiento para la producción de resinas de LLDPE |
| EP3241611B1 (fr) | 2016-05-02 | 2020-03-04 | Borealis AG | Procédé d'alimentation d'un catalyseur de polymérisation |
| WO2018011156A1 (fr) * | 2016-07-12 | 2018-01-18 | Total Raffinage Chimie | Procédé catalytique pour la dimérisation des diènes |
| BR112019000090A2 (pt) | 2016-07-15 | 2019-04-09 | Basell Poliolefine Italia Srl | catalisador para a polimerização de olefinas |
| EP3541852B1 (fr) * | 2016-11-17 | 2024-04-03 | Basell Polyolefine GmbH | Composition de polyéthylène ayant un rapport de gonflement élevé |
| ES2963183T3 (es) | 2016-12-19 | 2024-03-25 | Basell Poliolefine Italia Srl | Componentes del catalizador para la polimerización de olefinas y catalizadores obtenidos a partir de estos |
| EP3483189A1 (fr) | 2017-11-14 | 2019-05-15 | Borealis AG | Procédé automatisé permettant de mettre fin à une réaction de polymérisation d'oléfines dans des conditions d'urgence |
| KR102495156B1 (ko) | 2019-11-20 | 2023-02-06 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 촉매 성분의 제조 공정 및 그로부터 얻어지는 성분 |
| EP4251312A1 (fr) | 2020-11-27 | 2023-10-04 | Borealis AG | Système d'alimentation de catalyseur |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3954909A (en) * | 1970-06-09 | 1976-05-04 | Naphtachimie | Method of producing solid polymers |
| JPS6020405B2 (ja) * | 1976-04-06 | 1985-05-22 | 三井東圧化学株式会社 | 低密度ポリエチレンの製造方法 |
| NL7703570A (en) * | 1977-04-01 | 1978-10-03 | Applied Photophysics Ltd | Identification system for bodies containing luminous material - uses intensity-wavelength distribution in emission spectrum for testing |
| JPS603324B2 (ja) * | 1978-12-28 | 1985-01-28 | 三井化学株式会社 | エチレン共重合体の製造方法 |
| JPS5634709A (en) * | 1979-08-31 | 1981-04-07 | Mitsui Petrochem Ind Ltd | Gas phase polymerization or copolymerization of olefin |
| JPS5767612A (en) * | 1980-10-15 | 1982-04-24 | Mitsui Petrochem Ind Ltd | Preparation of ethylene copolymer |
| FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
| FR2659338B1 (fr) * | 1990-03-09 | 1993-05-07 | Bp Chemicals Snc | Procedes et dispositifs de polymerisation catalytique d'alpha-olefines en phase gazeuse. |
| IT1246614B (it) * | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| EP0528523B1 (fr) * | 1991-07-24 | 2001-10-10 | Mobil Oil Corporation | Résines de polyéthylène pour film améliorées |
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262934B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
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- 1993-03-10 DE DE69325603T patent/DE69325603T2/de not_active Expired - Fee Related
- 1993-03-10 EP EP93103809A patent/EP0560312B1/fr not_active Expired - Lifetime
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- 1993-03-12 US US08/030,654 patent/US5733987A/en not_active Expired - Fee Related
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