ES2528606T3 - Composiciones de revestimiento de control de incrustaciones novedosas - Google Patents
Composiciones de revestimiento de control de incrustaciones novedosas Download PDFInfo
- Publication number
- ES2528606T3 ES2528606T3 ES10792948.1T ES10792948T ES2528606T3 ES 2528606 T3 ES2528606 T3 ES 2528606T3 ES 10792948 T ES10792948 T ES 10792948T ES 2528606 T3 ES2528606 T3 ES 2528606T3
- Authority
- ES
- Spain
- Prior art keywords
- composition
- polysiloxane
- hydrophilic
- finishing layer
- modified
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
Una composición de revestimiento de control de incrustaciones que comprende un sistema aglutinante basado en polisiloxano, un 0,01-20 % en peso en seco de uno o más polisiloxanos modificados con un hidrófilo y uno o más biocidas, en la que la relación en peso entre el uno o más polisiloxanos modificados con un hidrófilo y el uno o más biocidas está en el intervalo del 1:0,2 a 1:6, y en la que el uno o más polisiloxanos modificados con un hidrófilo no contienen grupos que pueden reaccionar con el aglutinante o cualquier reticulante.
Description
E10792948
22-01-2015
(continuación)
- Nivel
- Descripción
- Regular
- 10 % < algas + animales < 25 %
- Malo
- Algas + animales > 25 %
Todas las entradas en la tabla de pinturas modelo están en peso a menos que se indique lo contrario.
- Pinturas modelo
- Composición de la capa de acabado A Composición de la capa de acabado B Composición de la capa de acabado C
- Parte (i)
- Polidimetilsiloxano terminado en silanol (5000 cSt)
- 54,9 55,0 55,4
- Xileno
- 21,1 21,1 21,1
- Polidimetilsiloxano siloxano 50 cSt
- 1,2 1,2 1,2
- Espesores
- 2,1 2,1 1,7
- Pigmentos
- 3,8 3,8 3,8
- Polisiloxano modificado con un hidrófilo:
- Polisiloxano modificado con poliéter (DC5103)
- 4,8 4,8 4,8
- Biocida:
- Piritiona de cinc
- 4,8 4,8
- Piritiona de cobre
- 0,0 4,8 0,0
- Total parte (i)
- 92,7 92,8 92,8
- Parte (ii)
- Silicato de etilo
- 2,2 2,2 2,2
- Xileno
- 3,5 3,5 3,5
- Metilfenil polisiloxano no reactivo
- Dilaurato de dibutilestaño
- 0,5 0,5 0,5
- 2,4-pentanodiona
- 1,1 1,1 1,1
- Total parte (ii)
- 7,3 7,2 7,2
- Total parte (i) y (ii)
- 100,0 100,0 100,0
- Comportamiento en balsa en España (12 meses)
- EXCELENTE EXCELENTE EXCELENTE
- Comportamiento en balsa en Singapur (12 meses)
- EXCELENTE EXCELENTE EXCELENTE
- Pinturas modelo
- Composición de la capa de acabado D (referencia) Composición de la capa de acabado E (referencia) Composición de la capa de acabado F (referencia)
- Parte (i)
- Polidimetilsiloxano terminado en silanol (5000 cSt)
- 55,1 57,7 58,3
- Xileno
- 21,1 22,1 22,2
- Polidimetilsiloxano siloxano 50 cSt
- 1,2 1,2 1,2
- Espesores
- 2,1 2,2 1,8
- Pigmentos
- 3,9 4,0 4,0
- Polisiloxano modificado con un hidrófilo:
- Polisiloxano modificado con poliéter (DC5103)
- 5,1
- Biocida:
- Piritiona de cinc
- Piritiona de cobre
- 4,8
- Total parte (i)
- 88,2 92,3 87,7
15
E10792948
22-01-2015
(continuación)
- Pinturas modelo
- Composición de la capa de acabado D (referencia) Composición de la capa de acabado E (referencia) Composición de la capa de acabado F (referencia)
- Parte (ii)
- Silicato de etilo
- 2,2 2,3 2,3
- Xileno
- 3,5 3,6 3,6
- Metilfenil polisiloxano no reactivo
- 4,5 4,8
- Dilaurato de dibutilestaño
- 0,5 0,5 0,5
- 2,4-pentanodiona
- 1,1 1,1 1,1
- Total parte (ii)
- 11,8 7,7 12,3
- Total parte (i) y (ii)
- 100,0 100,0 100,0
- Comportamiento en balsa en España (12 meses)
- REGULAR REGULAR REGULAR
- Comportamiento en balsa en Singapur (12 meses)
- REGULAR MALO BUENO
Comentarios a los resultados (composición A-F):
Algunos biocidas podían ser más eficaces que otros contra algunas especies de incrustantes. Debido a que las 5 especies incrustantes varían de una localización a otra, el comportamiento de la composición de capa de acabado puede variar también. Por lo tanto, se incluyen resultados de ambas localizaciones de balsa.
El comportamiento de las composiciones de capa de acabado con biocidas aumenta drásticamente cuando se añade un polisiloxano modificado con un hidrófilo, tal como un polisiloxano modificado con poliéter no reactivo (composiciones A y B) puesto que este asegura el transporte del biocida a través del revestimiento de PDMS
10 reticulado a la superficie. Los biocidas en solitario o los biocidas en combinación con polisiloxanos hidrófobos no reactivos no aumentan el rendimiento de la composición de la capa de acabado (composición D). También se ha descubierto que el uso de un polisiloxano modificado con un hidrófilo no reactivo en solitario no proporciona las ventajas de la combinación del polisiloxano modificado con un hidrófilo no reactivo y el biocida.
- Pinturas modelo
- Composición de la capa de acabado G Composición de la capa de acabado H Composición de la capa de acabado I (referencia)
- Parte (i)
- Polidimetilsiloxano terminado en silanol (5000 cSt)
- 57,2 58,6 61,0
- Xileno
- 17,0 17,7 18,2
- Espesantes
- 4,7 4,8 5,0
- Pigmentos
- 4,0 3,8 4,2
- Polisiloxano modificado con un hidrófilo:
- Polisiloxano modificado con Poliéter (DC190)
- 3,6 3,7
- Polisiloxano modificado con Poliéter (DBE-621)
- 2,8
- Biocida:
- Piritiona de cobre
- 6,1
- Piritiona de cinc
- 4,9
- Total parte (i)
- 92,6 92,5 92,1
- Parte (ii)
- Silicato de etilo
- 2,3 2,4 2,4
- Xileno
- 3,6 3,7 3,8
- Dilaurato de dibutilestaño
- 0,4 0,4 0,4
- 2,4-pentanodiona
- 1,1 1,0 1,3
- Total parte (ii)
- 7,4 7,5 7,9
- Total parte (i) y (ii)
- 100,0 100,0 100,0
- Comportamiento en balsa en España
- EXCELENTE (38 semanas) - MALO (38 semanas)
- Comportamiento en balsa en Singapur
- EXCELENTE (38 semanas) EXCELENTE (38 semanas) MALO (38 semanas)
16
E10792948
22-01-2015
Comentarios a los resultados (composiciones G-I)
Las composiciones G y H contienen biocidas, y muestran un rendimiento mejorado en comparación con la referencia (composición I) que solo contiene el polisiloxano modificado con un hidrófilo (de tipo poliéter).
- Pinturas modelo
- Composición de la capa de acabado J Composición de la capa de acabado K Composición de la capa de acabado L (referencia)
- Parte (i)
- Polidimetilsiloxano terminado en silanol (5000 cSt)
- 59,1 59,1 63,3
- Xileno
- 17,6 17,6 18,9
- Espesantes
- 4,8 4,8 5,2
- Pigmentos
- 4,1 4,1 4,4
- Polisiloxano modificado con un hidrófilo:
- Polisiloxano modificado con carboxilato de N-pirrolidona (YBD-125)
- 1,9
- Polisiloxano modificado con carbinol (CMS-222)
- 1,9
- Biocida:
- Piritiona de cinc
- 4,8 4,8
- Total parte (i)
- 92,3 92,3 91,8
- Parte (ii)
- Silicato de etilo
- 2,4 2,4 2,5
- Xileno
- 3,7 3,7 4,0
- Dilaurato de dibutilestaño
- 0,4 0,4 0,4
- 2,4-pentanodiona
- 1,2 1,2 1,3
- Total parte (ii)
- 7,7 7,7 8,2
- Total parte (i) y (ii)
- 100,0 100,0 100,0
- Comportamiento en balsa en España
- - - -
- Comportamiento en balsa en Singapur
- BUENO (24 semanas) EXCELENTE (24 semanas) REGULAR (24 semanas)
Comentarios a los resultados (composiciones J, K y L)
Se observa que los ejemplos de compuestos de PDMS no modificados con PEG hidrófilos usados en las composiciones J y K (YBD-125 y CMS-222) muestran un comportamiento mejorado en comparación con el polisiloxano sin biocida de referencia (composición L) después de 24 semanas de inmersión estática en Singapur.
- Pinturas modelo
- Composición de la capa de acabado M Composición de la capa de acabado N (referencia)
- Parte (i)
- Polidimetilsiloxano terminado en silanol (5000 cSt)
- 58,8 53,0
- Xileno
- 17,7 16,0
- Espesantes
- 4,8 4,3
- Pigmentos
- 3,8 3,4
- Polisiloxano modificado con un hidrófilo:
- Polisiloxano modificado con poliéter (BYK-331)
- 2,8 2,5
- Biocida:
- 4,5-dicloro-2-n-octil-4-isotiazolin-3ona encapsulada (91 %)
- 4,6 (4,2)
- solución de 4,5-dicloro-2-n-octil-4-isotiazolin3-ona (30 %)
- 14,0 (4,2)
- Total parte (i)
- 92,5 93,2
17
Claims (1)
-
imagen1 imagen2 imagen3
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09180360 | 2009-12-22 | ||
EP09180360 | 2009-12-22 | ||
PCT/EP2010/070509 WO2011076856A1 (en) | 2009-12-22 | 2010-12-22 | Novel fouling control coating compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2528606T3 true ES2528606T3 (es) | 2015-02-10 |
Family
ID=42111003
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES10792948.1T Active ES2528606T3 (es) | 2009-12-22 | 2010-12-22 | Composiciones de revestimiento de control de incrustaciones novedosas |
Country Status (13)
Country | Link |
---|---|
US (1) | US9534121B2 (es) |
EP (1) | EP2516559B1 (es) |
JP (2) | JP5990462B2 (es) |
KR (2) | KR102078783B1 (es) |
CN (2) | CN105368311B (es) |
BR (1) | BR112012015153A2 (es) |
DK (1) | DK2516559T3 (es) |
ES (1) | ES2528606T3 (es) |
HR (1) | HRP20150081T8 (es) |
PL (1) | PL2516559T3 (es) |
PT (1) | PT2516559E (es) |
SG (1) | SG181914A1 (es) |
WO (1) | WO2011076856A1 (es) |
Families Citing this family (50)
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US4774774A (en) * | 1986-05-22 | 1988-10-04 | Allen Jr Freddie T | Disc spring sole structure |
WO2013000478A1 (en) | 2011-06-30 | 2013-01-03 | Hempel A/S | Fouling control coating compositions comprising polysiloxane and pendant hydrophilic oligomer/polymer moieties |
EP2617778B1 (en) * | 2012-01-19 | 2021-03-17 | Jotun A/S | Fouling release coatings |
ES2856685T3 (es) | 2012-11-13 | 2021-09-28 | Chugoku Marine Paints | Composición de recubrimiento antiincrustante, película de recubrimiento antiincrustante, sustrato antiincrustante y método para mejorar la estabilidad en almacenamiento de la composición de recubrimiento antiincrustante |
JP6272359B2 (ja) * | 2013-02-15 | 2018-01-31 | モーメンティブ・パフォーマンス・マテリアルズ・インク | シリコーンヒドロゲルを含む防汚システム |
SG11201506525WA (en) * | 2013-02-26 | 2015-09-29 | Akzo Nobel Coatings Int Bv | Anti-fouling compositions with a fluorinated oxyalkylene-containing polymer or oligomer |
DK2976394T3 (en) * | 2013-03-20 | 2018-04-30 | Hempel As | NOVEL POLYSILOXANE-BASED FOULING CONTROL COATING SYSTEMS |
EP2992056A4 (en) * | 2013-05-03 | 2017-12-27 | Hempel A/S | Novel polysiloxane-based fouling-release coats |
JP6017377B2 (ja) * | 2013-07-02 | 2016-11-02 | メルクパフォーマンスマテリアルズマニュファクチャリング合同会社 | コーティング組成物 |
JP2015160892A (ja) * | 2014-02-27 | 2015-09-07 | 独立行政法人国立高等専門学校機構 | バイオフィルム形成能を抑えた防汚コンポジット皮膜 |
JP2017525786A (ja) * | 2014-07-11 | 2017-09-07 | ヘンペル エイ/エス | ポリ(オキシアルキレン)−変性アルコールを含む新規なポリシロキサン系汚損剥離コート |
US20170267872A1 (en) | 2014-12-02 | 2017-09-21 | Chugoku Marine Paints, Ltd. | Method for reinforcing fouling control coatings |
CN104387962A (zh) * | 2014-12-08 | 2015-03-04 | 江苏诺飞新材料科技有限公司 | 抗沾污有机硅表面处理剂 |
CN105038498A (zh) * | 2015-07-08 | 2015-11-11 | 当涂县科辉商贸有限公司 | 一种二氧化硅气凝胶-漂珠复合绝热保温涂料及其制备方法 |
KR20180030999A (ko) | 2015-07-13 | 2018-03-27 | 에보니크 데구사 게엠베하 | 가수분해가능한 결합제 |
EP3388493B1 (en) * | 2015-12-11 | 2020-10-21 | Chugoku Marine Paints, Ltd. | Coating composition for forming frictional resistance-reducing coating film, coating film, and substrate with coating film |
CN108368383A (zh) * | 2015-12-25 | 2018-08-03 | 中国涂料株式会社 | 用于形成降低摩擦阻力的涂膜的涂料组合物、涂膜和带涂膜的基材 |
JP6635589B2 (ja) * | 2015-12-28 | 2020-01-29 | ライオン株式会社 | 防カビ燻煙剤組成物 |
EP3467058B1 (en) | 2016-06-01 | 2024-02-21 | Chugoku Marine Paints, Ltd. | Antifouling coating composition, antifouling coating film, laminated antifouling coating film, base member provided with antifouling coating film and method for producing same, and antifouling method |
EP3474668A4 (en) * | 2016-06-22 | 2019-12-04 | Hempel A/S | AGENT PREVENTIVE COATING COMPOSITION WITH CONTROLLED RELEASE THROUGH A BIOZIDINE ACTION |
EP3494188B1 (de) * | 2016-08-03 | 2019-11-06 | Wacker Chemie AG | Vernetzbare beschichtungsmassen auf basis von organyloxysilanterminierten polymeren |
JP6887783B2 (ja) * | 2016-11-17 | 2021-06-16 | 中国塗料株式会社 | 防汚塗料組成物、防汚塗膜およびこれらの用途 |
WO2018108693A1 (en) | 2016-12-16 | 2018-06-21 | Renolit Se | Self-fusing antifouling tape |
WO2018134291A1 (en) | 2017-01-19 | 2018-07-26 | Jotun A/S | Antifouling composition |
US11440623B2 (en) | 2017-11-06 | 2022-09-13 | Hempel A/S | Method for improving a fluid dynamic profile of a marine vessel, a marine vessel having an improved fluid dynamic profile, and a coating system for improving the fluid dynamic profile |
WO2019115020A1 (en) * | 2017-12-14 | 2019-06-20 | Akzo Nobel Coatings International B.V. | Foul release coating composition, substrate coated with such coating composition, and use of such coating composition |
WO2019115747A1 (en) | 2017-12-14 | 2019-06-20 | Hempel A/S | Controlled release antifouling coating composition via biocide interaction |
CN108467282B (zh) * | 2018-03-21 | 2020-08-04 | 北京航空航天大学 | 一种分子刷接枝的自清洁材料及其制备方法与应用 |
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- 2010-12-22 EP EP10792948.1A patent/EP2516559B1/en not_active Revoked
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HRP20150081T1 (hr) | 2015-05-08 |
US9534121B2 (en) | 2017-01-03 |
JP6283060B2 (ja) | 2018-02-21 |
JP2016191056A (ja) | 2016-11-10 |
KR20120125260A (ko) | 2012-11-14 |
JP2013515122A (ja) | 2013-05-02 |
CN105368311A (zh) | 2016-03-02 |
PL2516559T3 (pl) | 2015-04-30 |
CN102782057B (zh) | 2016-04-13 |
KR20170127071A (ko) | 2017-11-20 |
US20120264847A1 (en) | 2012-10-18 |
BR112012015153A2 (pt) | 2020-09-15 |
CN102782057A (zh) | 2012-11-14 |
KR102078783B1 (ko) | 2020-02-19 |
DK2516559T3 (en) | 2015-02-02 |
EP2516559B1 (en) | 2015-01-21 |
KR101798604B1 (ko) | 2017-11-16 |
HRP20150081T8 (hr) | 2015-07-03 |
SG181914A1 (en) | 2012-07-30 |
WO2011076856A1 (en) | 2011-06-30 |
EP2516559A1 (en) | 2012-10-31 |
JP5990462B2 (ja) | 2016-09-14 |
CN105368311B (zh) | 2019-03-01 |
PT2516559E (pt) | 2015-02-06 |
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